SAFETY DATA SHEET

1. Identification
Product identifier ACRAGLAS (R) GEL HARDENER, 8 OZ.
Other means of identification
Product code 081-017-118
Recommended use Adhesive (epoxy hardener component).
Recommended restrictions Not available.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name BROWNELLS, INC.
Address 200 South Front Street
Montezuma, Iowa 50171
United States
Telephone (641) 623-5401
Website www.brownells.com
E-mail Not available.
Emergency phone INFOTRAC Registrant #79335
number
24 hour Emergency Number, Domestic: (800) 457-4280
24 hour Emergency Number, Foreign: +1(352) 323-3500

2. Hazard(s) identification
Physical hazards Not available.
Health hazards Acute toxicity, oral Category 3
Acute toxicity, dermal Category 3
Acute toxicity, inhalation Category 4
Skin corrosion/irritation Category 1
Serious eye damage/eye irritation Category 1
Sensitization, skin Category 1
Germ cell mutagenicity Category 2
Specific target organ toxicity, repeated Category 1
exposure
Environmental hazards Hazardous to the aquatic environment, acute Category 3
hazard
Hazardous to the aquatic environment, Category 3
long-term hazard
OSHA defined hazards Not available.
Label elements

Signal word Danger

Hazard statement Toxic in contact with skin. Toxic if swallowed. Harmful if inhaled. Causes severe skin burns and eye
damage. May cause an allergic skin reaction. Causes serious eye damage. Causes damage to
organs through prolonged or repeated exposure. Suspected of causing genetic defects. Harmful to
aquatic life with long lasting effects.

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 Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a
well-ventilated area. In case of inadequate ventilation wear respiratory protection. Wear protective
gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not
eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out
of the workplace. Avoid release to the environment. Keep out of reach of children.
Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin: Wash with plenty of water. If on
skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If in
eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If inhaled: Remove person to fresh air and keep comfortable for breathing.
Immediately call a poison center/doctor. IF exposed or concerned: Get medical advice/attention.
Specific treatment (see this label). Specific measures (see this label). Wash contaminated clothing
before reuse.
Storage Store indoors in a cool, dry place at an ambient temperature. Store locked up. Keep containers
closed when not in use. Store away from incompatible materials. Keep out of reach of children.
Disposal Dispose of in accordance with current, applicable local, state, and federal regulations.
Hazard(s) not otherwise classified (HNOC)
Not available.
Hazard(s) not otherwise Not available.
classified (HNOC)
Supplemental information 60.5% of the mixture consists of component(s) of unknown acute hazards to the aquatic
environment.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
POLYAMIDOAMINE BLEND None (Blend) 20 - < 50
BENZYL ALCOHOL 100-51-6 10 - < 20
CYCLOALIPHATIC AMINE 135108-88-2 5 - < 10
PROPYLENE GLYCOL DIAMINE, 9046-10-0 5 - < 10
2-AMINO-, DIETHER WITH
PROPYLENE
TRIETHYLENE TETRAMINE 112-24-3 5 - < 10
2,4,6-TRI(DIMETHYLAMINOMETHY 90-72-2 1-<5
L)PHENOL
PHENOL 108-95-2 1-<5
Other components below reportable levels 20 - < 30
#: This substance has workplace exposure limit(s).
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Get medical attention if symptoms persist. Do not use
mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of
a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Skin contact Remove and isolate contaminated clothing and shoes. Immediately wash off with soap and plenty
of water. Get medical attention if symptoms occur. Wash contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention.
Ingestion If swallowed, do NOT induce vomiting. Give victim water or milk. Call a physician or poison control
center immediately. Never give anything by mouth to a victim who is unconscious or is having
convulsions.
Most important Irritating to eyes, respiratory system and skin. May cause allergic skin reaction. Severe skin burns.
symptoms/effects, acute and May be absorbed through the skin in harmful amounts. Will cause eye burns, eye damage, and
delayed permanent tissue damage. Product vapor may cause lacrimation, conjuctivitis, and corneal edema
in the eyes. Swallowing can burn mouth, throat and stomach, with nausea, severe pain, and
vomiting. Preexisting pulmonary and dermatological conditions may be aggravated.
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Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
medical attention and special under observation. Symptoms may be delayed. Chemical burns: Flush with water immediately.
treatment needed While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue
flushing during transport to hospital.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet (SDS) to the doctor in attendance. If you feel
unwell, seek medical advice (show the label where possible).

5. Fire-fighting measures
Suitable extinguishing media Alcohol foam, carbon dioxide (CO2), dry chemical, foam, or water fog.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Closed containers may rupture or explode (due to pressure build-up) when exposed to extreme
the chemical heat. Fire may produce irritating, corrosive and/or toxic gases.
Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with
and precautions for face shield, gloves, rubber boots, and NIOSH approved self-contained breathing apparatus (SCBA).
firefighters
Fire fighting Move containers from fire area if you can do so without risk. Use water to cool exposed containers.
equipment/instructions Water stream directed into fire may cause frothing with subsequent spread of flame. Water runoff
can cause environmental damage.
Specific methods In the event of fire and/or explosion do not breathe fumes.
Hazardous combustion Oxides of carbon. Irritating and/or toxic fumes and gases may be emitted upon the products
products thermal decomposition or combustion.

6. Accidental release measures

Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Ensure
protective equipment and adequate ventilation. Wear appropriate protective equipment and clothing during clean-up. See
emergency procedures Section 8 of the SDS for Personal Protective Equipment. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing.
Methods and materials for Dike the spilled material, where this is possible. Stop the flow of material, if this is without risk.
containment and cleaning up Cover with plastic sheet to prevent spreading.

Clean up in accordance with all applicable regulations.

Large Spills: Absorb spill with vermiculite or other inert material. Sweep up and shovel into suitable
containers for disposal. Wash spill area with detergent solution or wipe with alcohol-soaked rags.
Dispose of all washings and contaminated items in accordance with waste regulations.

Small Spills: Absorb spill with vermiculite or other inert material. Sweep up and shovel into suitable
containers for disposal. Wash spill area with detergent solution or wipe with alcohol-soaked rags.
Dispose of all washings and contaminated items in accordance with waste regulations.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Avoid discharge into drains, water courses or onto the ground.
Do not contaminate water. Keep off of soil.

7. Handling and storage

Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Observe good industrial hygiene practices. Do not breathe
dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. In case of
inadequate ventilation, use respiratory protection. Avoid contact with eyes, skin, and clothing. Wear
personal protective equipment. See Section 8 of the SDS for Personal Protective Equipment. When
using, do not eat, drink or smoke. Wash thoroughly after handling. Remove contaminated clothes
and wash separately before reuse. Handle and open container with care. Avoid release to the
environment.
Conditions for safe storage, Store indoors in a cool, dry place at an ambient temperature. Store locked up. Keep container
including any closed when not in use. Store away from incompatible materials. See Section 10 of the SDS for
incompatibilities incompatible materials. Use care in handling/storage. Keep out of the reach of children.

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8. Exposure controls/personal protection
Occupational exposure limits
U.S. - OSHA
Components Type Value

PHENOL (CAS 108-95-2) PEL 5 ppm

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value

PHENOL (CAS 108-95-2) PEL 19 mg/m3

5 ppm
ACGIH
Components Type Value

PHENOL (CAS 108-95-2) TWA 19 mg/m3

US. ACGIH Threshold Limit Values
Components Type Value

PHENOL (CAS 108-95-2) TWA 5 ppm

U.S. - NIOSH
Components Type Value

PHENOL (CAS 108-95-2) TWA 19 mg/m3

US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value

PHENOL (CAS 108-95-2) Ceiling 60 mg/m3

15.6 ppm
TWA 19 mg/m3
5 ppm
US. Workplace Environmental Exposure Level (WEEL) Guides
Components Type Value

BENZYL ALCOHOL (CAS TWA 44.2 mg/m3

100-51-6)
10 ppm
TRIETHYLENE TETRAMINE TWA 6 mg/m3
(CAS 112-24-3)
1 ppm
Biological limit values
US. ACGIH. BEIs. Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
PHENOL (CAS 108-95-2) 250 mg/g Phenol with Creatinine in *
hydrolysis urine
* - For sampling details, please see the source document.
Exposure guidelines
US - Tennessee OELs: Skin designation
PHENOL (CAS 108-95-2) Can be absorbed through the skin.
US. ACGIH Threshold Limit Values
PHENOL (CAS 108-95-2) Can be absorbed through the skin.
US. California Code of Regulations, Title 8, Section 5155. Airborne Contaminants
PHENOL (CAS 108-95-2) Can be absorbed through the skin.
US. Minnesota Hazardous Substances List (Minn. Rules 5206.0400).
PHENOL (CAS 108-95-2) Skin designation applies.
US. NIOSH: Pocket Guide to Chemical Hazards
PHENOL (CAS 108-95-2) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
PHENOL (CAS 108-95-2) Can be absorbed through the skin.
US. Workplace Environmental Exposure Level (WEEL) Guides
TRIETHYLENE TETRAMINE (CAS 112-24-3) Can be absorbed through the skin.

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Appropriate engineering Ensure adequate ventilation, especially in confined areas. Provide eyewash station and safety
controls shower.
Individual protection measures, such as personal protective equipment
Eye/face protection Do not get in eyes. Wear chemical goggles. Face-shield.
Skin protection
Hand protection Use nitrile, supported polyvinyl alcohol (PVA), or butyl rubber gloves.
Other Avoid contact with skin and clothing. Normal work clothing (long sleeved shirts and long pants) is
recommended.
Respiratory protection Avoid breathing dust/fume/gas/mist/vapors/spray. A NIOSH approved air purifying respirator with
an organic vapor cartridge or canister may be permissible under certain circumstances where
airborne concentrations are expected to exceed exposure limits, inhalation effects occur, or if use is
performed in poorly ventilated spaces.
Thermal hazards Not available.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material and
considerations before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to
remove contaminants. When using, do not eat, drink or smoke. Keep away from food and drink. Do
not get in eyes, on skin, or on clothing.

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Paste.
Color Opaque creamy.
Odor Mild acrid.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and Not available.
boiling range
Flash point > 212.0 °F (> 100.0 °C)
Evaporation rate Slower than n-Butyl Acetate
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - Not available.
upper (%)
Explosive limit - lower Not available.
(%)
Explosive limit - upper Not available.
(%)
Vapor pressure Not available.
Vapor density Heavier than air
Relative density Not available.
Solubility(ies)
Solubility (water) Slight.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Specific gravity 1.038
VOC (Weight %) 0 g/l (Calculated).
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10. Stability and reactivity
Reactivity Not available.
Chemical stability Product is stable, when stored indoors, inside a closed container, and at ambient conditions.
Possibility of hazardous Will not occur under normal conditions.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong bases or oxidants. Strong Lewis or mineral acids. Peroxides. Phenols.
Hazardous decomposition Oxides of carbon. Irritating and/or toxic fumes and gases may be emitted upon the products
products thermal decomposition or combustion.

11. Toxicological information

Information on likely routes of exposure
Inhalation Avoid breathing dust/fume/gas/mist/vapors/spray. Harmful if inhaled. Can cause severe respiratory
irritation. May cause respiratory irritation. Heated material may cause damage to the lungs through
prolonged or repeated exposure. Vapors at elevated temperatures are irritating to the respiratory
tract.
Skin contact Do not get this material in contact with skin. Harmful in contact with skin. Toxic in contact with
skin. May cause an allergic skin reaction. May cause skin irritation. Causes severe skin burns. May
be absorbed through the skin in harmful amounts. Prolonged skin contact may cause severe skin
irritation and possible burns.
Eye contact Do not get this material in contact with eyes. Corrosive. Will cause eye burns, eye damage, and
permanent tissue damage. Causes eye irritation. Vapors at elevated temperatures are irritating to
the eyes and may conjuctivitis, lacrimation, and corneal edema when absorbed into the tissue of
the eye. Corneal edema may cause a perception of “fog” around lights or a “blue haze.” The effect
is temporary and does not have known residual effects.
Ingestion Do not swallow or taste. Toxic if swallowed. Can burn mouth, throat and stomach, with nausea,
severe pain, and vomiting. Kidney damage may occur through ingestion of significant amounts.
Symptoms related to the Irritating to eyes, respiratory system and skin. May cause allergic skin reaction. Severe skin burns.
physical, chemical and May be absorbed through the skin in harmful amounts. Will cause eye burns, eye damage, and
toxicological characteristics permanent tissue damage. Product vapor may cause lacrimation, conjuctivitis, and corneal edema
in the eyes. Swallowing can burn mouth, throat and stomach, with nausea, severe pain, and
vomiting. Preexisting pulmonary and dermatological conditions may be aggravated.
Information on toxicological effects
Acute toxicity Irritating to eyes, respiratory system and skin. Can cause severe respiratory irritation. Severe skin
burns. May cause allergic skin reaction. Toxic in contact with skin. Toxic if swallowed. Harmful if
inhaled. May be absorbed through the skin in harmful amounts. Will cause eye burns, eye damage,
and permanent tissue damage. Product vapor at elevated temperatures may cause lacrimation,
conjuctivitis, and corneal edema in the eyes. Swallowing can burn mouth, throat and stomach,
with nausea, severe pain, and vomiting.
Components Species Test Results
BENZYL ALCOHOL (CAS 100-51-6)
Acute
Dermal
LD50 Rabbit 2000 mg/kg
Oral
LD50 Mouse 1580 mg/kg
Rabbit 1940 mg/kg
Rat 1230 - 3100 mg/kg
PHENOL (CAS 108-95-2)
Acute
Dermal
LD50 Rabbit 850 mg/kg
Rat 669 mg/kg

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Components Species Test Results
Oral
LD50 Cat 0.1 g/kg
Dog 0.5 g/kg
Mouse 270 mg/kg
Rat 317 mg/kg

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes severe skin burns and eye damage.
Serious eye damage/eye Will cause eye burns, eye damage, and permanent tissue damage. Causes eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization Causes severe irritation and burns to the skin.
Germ cell mutagenicity Suspected of causing genetic defects.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
PHENOL (CAS 108-95-2) 3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity Not available.
Specific target organ toxicity Not available.
- single exposure
Specific target organ toxicity Causes damage to organs through prolonged or repeated exposure.
- repeated exposure
Aspiration hazard Not available.
Chronic effects May cause damage to organs through prolonged or repeated exposure. Preexisting pulmonary and
dermatological disorders may be aggravated by exposure to hazardous components. The nervous
system may be affected through prolonged exposure to benzyl alcohol vapors produce through the
product being heated. Repeated or prolonged overexposure to phenol via inhalation, ingestion, or
skin absorption may cause damage to the liver, kidneys, pancreas, and spleen. In addition, phenol
is mutagenic "in-vitro." Subchronic exposure to Phenol in test animals has caused abnormalities in
the central nervous system. Triethylenetetramine (TETA) caused embryofetal toxicity and fetal
malformations when fed to pregnant rats. Similar effects were not seen in studies which this
material was applied to the skin of rabbits, a more relevant route of industrial exposure. These
effects are believed to be secondary to copper deficiency, resulting from the chelating activity of
the amine. Subchronic testing of 2,4,6-tridimethylphenol in animals caused abnormalities in the
central nervous system.

12. Ecological information

Ecotoxicity Harmful to aquatic life with long lasting effects.
Persistence and degradability Not available.
Bioaccumulative potential Not available.
Mobility in soil Not available.
Other adverse effects Not available.

13. Disposal considerations

Disposal instructions Dispose of in accordance with current, applicable local, state, and federal regulations.
Waste from residues / Not available.
unused products
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.

14. Transport information

DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.

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IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not available.
Annex II of MARPOL 73/78
and the IBC Code

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard,
29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
PHENOL (CAS 108-95-2) Listed.
SARA 304 Emergency release notification
PHENOL (CAS 108-95-2) 1000 LBS
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Chemical name CAS number Reportable Threshold Threshold Threshold
quantity planning quantity planning planning
quantity, lower quantity, upper
value value
PHENOL 108-95-2 1000 500 lbs 10000 lbs
SARA 311/312 No
Hazardous chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
PHENOL 108-95-2 1-<5
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
PHENOL (CAS 108-95-2)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is
not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section
11100)
Not listed.
US. Massachusetts RTK - Substance List
BENZYL ALCOHOL (CAS 100-51-6)
PHENOL (CAS 108-95-2)
TRIETHYLENE TETRAMINE (CAS 112-24-3)
US. New Jersey Worker and Community Right-to-Know Act
PHENOL (CAS 108-95-2)
TRIETHYLENE TETRAMINE (CAS 112-24-3)
US. Pennsylvania Worker and Community Right-to-Know Law
BENZYL ALCOHOL (CAS 100-51-6)
PHENOL (CAS 108-95-2)

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 TRIETHYLENE TETRAMINE (CAS 112-24-3)
US. Rhode Island RTK
PHENOL (CAS 108-95-2)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any
chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) No
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of Existing Commercial Chemical Substances No
(EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
New Zealand New Zealand Inventory No
Philippines Philippine Inventory of Chemicals and Chemical Substances No
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 02-19-2015
Revision date 06-01-2015
Version # 02
References ACGIH
EPA: AQUIRE database
NLM: Hazardous Substances Data Base
US. IARC Monographs on Occupational Exposures to Chemical Agents
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information, and belief at the date of its publication. The information given is designed only as
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision Information Product and Company Identification: Alternate Trade Names
Hazard(s) identification: Hazard statement
Hazard(s) identification: Prevention
Hazard(s) identification: Response
Toxicological information: Ingestion
Ecological Information: Ecotoxicity

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