CS-13398
CS-13398
com
CS-13398
STANCIU SORINA - [email protected]
7
Date: 15-OCT-2024
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Co-Author
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Author
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Co-Author Department
Author Department
© 2024 STELLANTIS
ANY PRINTED COPY IS TO BE DEEMED AS UNCHECKED; THEREFORE THE UPDATED COPY MUST BE CHECKED IN THE APPROPRIATE WEB SITE
CONFIDENTIAL
THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULATED TO THIRD PARTIES WITHOUT PRIOR WRITTEN CONSENT BY THE RELEVANT STELLANTIS
COMPANY. IN CASE OF DISPUTE, THE ONLY VALID REFERENCE IS THE ENGLISH EDITION
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INTERIOR MATERIAL EMISSION REQUIREMENTS
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(STELLANTIS HARMONIZED)
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TABLE OF CONTENTS
1 GENERAL ................................................................................................................................................. 3
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1.1 Purpose .................................................................................................................................................. 3
1.2 Coverage of this Standard ..................................................................................................................... 3
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1.3 Limitations on Usage.............................................................................................................................. 3
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2 REFERENCES .......................................................................................................................................... 3
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2.1 Stellantis Internal Standards .................................................................................................................. 3
2.2 Stellantis External Standards ................................................................................................................. 4
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2.3 Regulations ............................................................................................................................................ 4
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2.4 Additional / Other documents ................................................................................................................. 4
3 DEFINITIONS/ABBREVIATIONS/ACRONYMS/SYMBOLS ..................................................................... 4
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4 REGULATED SUBSTANCES, RECYCLABILITY .................................................................................... 5
5 REQUIREMENTS/CONDITIONS ............................................................................................................. 5
5.1 Requirements For Test Preparation And Evaluation ............................................................................. 5
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Annex A ....................................................................................................................................................... 12
Annex B ....................................................................................................................................................... 13
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Annex C....................................................................................................................................................... 14
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Annex D....................................................................................................................................................... 15
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Annex E ....................................................................................................................................................... 16
Annex F ....................................................................................................................................................... 19
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1 GENERAL
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1.1 Purpose
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The purpose of this document is to establish guidelines for overall emission testing of materials used in
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interior of the vehicle. This standard defines minimal material level requirements for Fogging, Odor and
the emissions of Carbonyls, Volatile Organic Compounds (VOCs) and Total Volatile Organic Compounds
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(TVOCs).
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The standard applies to all Stellantis regions.
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1.2 Coverage of this Standard
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This specification addresses material level requirements only. The requirements established by this
standard apply to all materials supplied to STELLANTIS for usage in passenger cabin, load space and air
filtration system components.
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Emissions from textile, carpets, leathers, films, plastic components, adhesives, sealants, foams, coatings,
composite materials, elastomers, rubbers, insulation, etc. are covered under this standard. Composite
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materials which are materials composed of two or more layers intimately held at every point of contact by
bonding, cladding, etc., are also covered by this standard. When layers are intermittently held together
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by sewing, welding, etc. they are not considered to be composite materials and must be tested
individually.
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This standard applies to materials used on vehicle interior parts with a surface higher than 150 cm² and/or
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a weight of 50 g minimum. If a part is used multiple times inside the vehicle (e.g. knobs, sockets, etc) the
total volume and weight of all parts used in the interior shall be added and if the total volume and/or
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weight exceeds the above mentioned limits, the emission tests shall be done.
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2 REFERENCES
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Table 1 - References
Shield/Designator downloadable
Document Number Document Title
(if applicable) for suppliers
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Reference Title
ISO 12219-3 SCREENING METHOD FOR THE DETERMINATION OF THE EMISSIONS OF VOLATILE
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ORGANIC COMPOUNDS FROM VEHICLE INTERIOR PARTS AND MATERIALS -- MICRO-
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SCALE CHAMBER METHOD
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ISO 16000-3 INDOOR AIR -- PART 3: DETERMINATION OF FORMALDEHYDE AND OTHER CARBONYL
COMPOUNDS IN INDOOR AIR AND TEST CHAMBER AIR -- ACTIVE SAMPLING METHOD
ISO 16000-6 PART 6: DETERMINATION OF VOLATILE ORGANIC COMPOUNDS IN INDOOR AND TEST
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CHAMBER AIR BY ACTIVE SAMPLING ON TENAX TA SORBENT, THERMAL
DESORPTION AND GAS CHROMATOGRAPHY USING MS/FID
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SAE J1756 DETERMINATION OF THE FOGGING CHARACTERISTICS OF INTERIOR MATERIALS.
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2.3 Regulations
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Not applicable.
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2.4 Additional / Other documents
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Not applicable.
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3 DEFINITIONS/ABBREVIATIONS/ACRONYMS/SYMBOLS
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DNPH: 2, 4-Dinitrophenylhydrazine.
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DNPH cartridges: Air-sampling devices designated for sampling carbonyl compounds. Carbonyls are
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trapped on a high purity silica adsorbent coated with 2, 4-Dinitrophenylhydrazine, where they are
converted to hydrazone derivatives.
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stability.
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Tenax TA: A porous polymer resin based on 2.6-diphenylene oxide. It has been specifically designed for
the trapping of volatiles and semi-volatiles from air or which have been purged from liquid or solid sample
matrices; it is the most commonly used sorbent for VOCs ranging in volatility from n-hexane to n-
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hexadecane.
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Tenax TA sorbent tubes: Small tubes filled with Tenax TA, used for trapping medium to high boiling
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VOCs: Volatile Organic Compounds which are organic chemicals that have a high vapor pressure at
ordinary room temperature. Their high vapor pressure results from a low boiling point, which causes
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large numbers of molecules to evaporate or sublimate from the liquid or solid form of the compound and
enter the surrounding air.
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Not applicable.
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5 REQUIREMENTS/CONDITIONS
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5.1 Requirements For Test Preparation And Evaluation
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Testing per this standard shall be performed by an accredited laboratory that is acceptable to
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STELLANTIS Materials Engineering Department. The list with the approved testing laboratories is
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provided in section 5.3 and in the Annexes E and F of this standard.
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Sample size and quantity shall be sufficient so that all testing can be performed.
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Plastic pellet raw materials intended for the test should be molded in a test plaque; enough test plaques
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to perform all testing described below should be submitted.
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For Roll Goods materials (fabrics, leather, carpet, synthetic leather), the sample size should be minimun
1m2.
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For Paint: supplier should prepare the sample following their paint process guidelines for coating,
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thickness and drying. Paints are sprayed on the Aluminum foil. For multilayer paints, the thickness of the
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individual layers of the film shall be the same as the thickness of the painted part. If needed each paint
layer should be analyzed separately. The paint process guidelines of the paint supplier shall be followed.
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After drying the samples are vented at room temperature for 7 days. Minimum of three letter size
(approx. 8 in2 x 11 in2) samples of the prepared paint as described above should be submitted for testing.
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For Fillers, Adhesives, Sealants, Deadener Pads, etc. cured within the vehicles, the supplier has to
prepare the sample following the vehicle production process at the representative cure temperature and
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time. Material shall be applied to Aluminum foil for sample preparation. After drying the samples are
vented at room temperature for 7 days. Minimum of three letter size (A4) samples of the prepared
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Samples should not be touched with bare hands. Care shall be taken when preparing the samples to
avoid contact with oils or greases from the cutting tools or other environmental contaminants.
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The material shall be obtained no more than 24 ± 2 hours after production then stored in a clean area to
prevent possible production contamination from paint spray booths, exhaust gases, fumes, etc. It shall
not be placed in contact with other materials to eliminate cross contamination.
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The storage area conditions should not exceed 23 ± 2ºC and 50 ± 20% RH. The parts should not be
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exposed under direct solar light. The storage area should be clean and clear of any VOCs emissions.
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The part must be wrapped after 14 ± 1 days storage under conditions identified above.
All materials must be wrapped in aluminum foil that is silicon free and sealed in a Polyethylene bag 14
days after the manufacturing date, prior to shipping. Unless otherwise specified in this standard no pre- or
post-treatment of the test samples besides the production process should be allowed.
Material for testing must be labelled with the correct information: including supplier, date of manufacture,
material identification, plant, location, sampling date, packaging date and ship date. The sample label
shall be provided on the outside of the packaging only, no labelling on the material for testing itself.
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Samples of the material per this standard shall be tested for conformity with the requirements of this
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standard and approved by STELLANTIS Materials Engineering prior to start of delivery of production level
material.
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Any change to the material (manufacturing process, manufacturing location, etc.) requires a new approval
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of the product. It is the responsibility of the Material Supplier to provide STELLANTIS with documentation
of any changes and to apply for a new approval. If it was not agreed otherwise, the entire verification test
shall be repeated and documented by the supplier prior to the delivery of the changed material.
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For initial approval of raw materials, the data sheet in Annex D - Data Reporting Form has to be
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completed and sent to the responsible STELLANTIS Materials Engineer. An editable version of this form
is found in the embedded object in Annex D.
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Unless otherwise indicated, for any given construction or resin grade only the darkest color of the material
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to be supplied needs to be tested. The same goes for coatings; if the technology is the same the worst
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case of the palette shall be tested. In the case of fabrics, leather and synthetic leather materials a
representative of each color family has to be tested.
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5.2 Material Testing Requirements
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In many cases it is necessary to store the material in the laboratory before starting the test. The material
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should remain securely sealed with the packaging in order to avoid any degradation or contamination
during the storage period.
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The materials shall not be stored for more than two weeks at the testing laboratory before the start of
emissions testing,
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The material shall be tested within maximum five weeks after manufacture (the five weeks includes the
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two weeks conditioning, the one week for shipping/transportation to the testing lab and maximum two
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The material shall be open from its initial packaging and conditioned for 24 ± 4 hours @ 23 ± 2 ºC and
50 ± 10% RH prior to testing.
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The approved testing laboratories shall perform the testing and analysis and send the final test report to
the requester within 2 weeks of the test.
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All materials listed in Annex B must meet Fogging, Odor, Formaldehyde, Volatile Organic Compounds
and Measurable Volatiles of Interest emission requirements as described below.
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This list is not all-inclusive – please contact Materials Engineering Department for further clarification.
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The Carbonyls and VOCs testing listed in Table 2 include a Part A - Lead method and a Part B –
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Alternate method. The material supplier shall perform the testing based on testing availability in their
region according to either Part A or Part B requirements. The results obtained by either test method are
acceptable at the present time, until further notice.
The material supplier shall always verify with the responsible Stellantis VIAQ team member and /or with
the responsible Stellantis Materials Engineer on the applicability and acceptability of the testing to be
performed according to this standard.
The Global VIAQ team members are listed in Annex A of this document.
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Table 2 - Material Testing Requirements
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Test Procedure Requirements
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Rating 3.5 max
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NOTE considered offensive odor. The plastic smell
1. ODOR , max
shall not be defined as disturbing solely on
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the basis of being more concentrated upon
exposure to heat, but rather when it
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transitions from acceptable to unacceptable
during exposure to heat.
LP-463KC-09-01
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NOTE: this test applies to all Dry test only
In addition, the following disturbing smells
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materials in contact with the
air inside the cabin with the shall never be associated with the vehicle
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exception of acetal (POM) interior smells and are cause for
65°C ± 3°C for 1 hour
rejection: fishy, decay, garbage, sour,
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septic, rotten eggs, skunk, mold, yeast,
musky, must , stale.
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D45 1727
Reflectometric method NOTE
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and/or or
droplet streams, no crystal formation
Gravimetric
or
LP.7M133 / D45 1727
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Gravimetric method
(in BeStandard)
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Test Procedure Requirements
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Part A
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ISO 12219-3
(see Annex C for test set-up) Formaldehyde (CAS:50-00-0) : 0.1
mg/kgNOTE 3
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250 ml/min flow rate,
65°±2°C collection Acetaldehyde (CAS:75-07-0) :(target) 0.1
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3. ALDEHYDE temperature, mg/kgNOTE 3
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EVALUATION, mg/kg dry equilibration time 20 minutes
material, max 90 min collection time, Acrolein (CAS: 107-02-8) : 0.1 mg/kg
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DNPH cartridges (NOTE 1)
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and Sum of carbonyls: Report
ISO 16000-3
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High Pressure Liquid Report all compounds emitted by the
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Chromatography (HPLC) sample under test at concentrations above
analysis (NOTE 2) 0.1 mg/kg dry material
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or
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D40 5535
(list of carbonyls) Acrolein (CAS: 107-02-8: 10 ppm
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Part A
Benzene (CAS: 71-43-2) (target): 0.1 μg/g
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ISO 12219-3
(see Annex B for test set-up)
65°±2°C collection Toluene (CAS:108-88-3) : Report
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temperature,
4. MEASURABLE equilibration time 20 minutes, Ethylbenzene (CAS: 100-41-4): Report
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ISO 16000-6
Thermal Desorption (TD) and Styrene (CAS: 100-42-5): 0.1 μg/g
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Gas Chromatography /Mass (Except hard top material for which the
Spectrometry (GC/MS) targetted limit is ˂ 0.5 μg/g))
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analysis (NOTE 5)
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Test Procedure Requirements
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or Benzene (CAS: 71-43-2:< 1 µg/g tol.eq.
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Toluene (CAS:108-88-3): Report
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4. MEASURABLE Part B Ethylbenzene (CAS: 100-41-4): Report
VOLATILE D10 5495
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SUBSTANCES OF Xylene Xylene (CAS1330-20-7 (mixed isomers);
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INTEREST, μg/g (cont) 95-47-6 (o-xylene);106-42-3 (p-xylene); 108-38-3
(m-xylene):): Report
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Styrene (CAS: 100-42-5): < 10 µg/g tol.eq.
Part A
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ISO 12219-3
65°±2°C collection
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temperature,
equilibration time 20 minutes,
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ORGANIC COMPOUNDS
(TVOCs), C6 – C16, based and
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Spectrometry (GC/MS)
analysis (NOTE 4)
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or
Report
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Part B
D10 5495 Specific limit values for PU foam:
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Test Procedure Requirements
NOTE 1: Recommended cartridges: InertSep mini AERO DNPH-HR/GL Science or comparable,
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NOTE 2: Recommended Column Temperature 25C, Mobile Phase 50% CH3CN - 50% H2O, Flow Rate/Mobile Phase 1.0 ml/min
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Detection Wavelength 365nm, Injection Volume 25μl for C18 reverse phase column (recommended).
Report any deviations from the above parameters
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NOTE 3: HPLC Calibration standards are available from: Supelco: TO11/IP-6-A Aldehyde/Ketone-DNPH-Mix, 15 components in
acetonitrile, 15 μg/mL of each component (aldehyde equivalent), Sigma-Aldrich (Supelco), CRM4M7285
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NOTE 4: Recommended collection media: e.g. Supelco Tenax TA tubes, 1/4” in diameter and 3-1/2” long, depending on the
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analysis equipment used also other Tenax TA tubes can be used.
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NOTE 5: Desorption temperature: 280°C
Desorption time: 15 min
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Desorption gas flow rate: 50 ml/min
Report any deviations from the above parameters
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5.3 Approved Source list
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See Annex E and F for testing laboratories which are acceptable to STELLANTIS to perform emissions
testing.
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Fogging test results are acceptable from any accredited testing laboratories (for instance ISO 17025
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accreditation) if they have the test methods listed in their Scope of accreditation (see www.a2la.org).
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NOTE: Contact the responsible Stellantis VIAQ team member (see Annex A) if clarification is needed.
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6 DELETED REQUIREMENT
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Not applicable.
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/ IAP
Sara Galletti / EE [email protected] contributor
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8 RELEASE AND REVISION
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Change level Date Description of change
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- 26-SEP-2014 Initial release
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Section 1.1 – Purpose
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• Added Semi Volatile Organic Compound (SVOCs)
Section 2 - References
• Test method for Odor evaluation changed
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A 03-JUN-2015
Section 3 – Definitions/Abbreviations/Acronyms/Symbols
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• Added definitions for SVOCs, TVOCs and TSVOCs
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Table 2 – Material Testing Requirements updated
Collection temperature and time revised in Table 2 for SVOCs and
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B 18-SEP-2015
TSVOCs
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C 08-JUL-2016 Updated Odor Rating requirement.
Section 5.2 updated, Table 2 updated, removed 85°C temperature
D 11-JUL-2017
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required for odor test, Added Annex B, updated Annex C & D,
added Annex E
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Update odor test requirements
E 14-JUN-2019
Added Table B-2 with test sample sizes to Annex B
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updated.
H 08-JUL-2023 Changed to the new Stellantis Harmonized template
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Part B
Added clarification in Para 6, Added Annex F
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Annex A
(Informative)
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VIAQ global team contacts
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Contact the Vehicle Interior Air Quality Activity Region lead for further clarification if needed.
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Region Contact info
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Sorina Stanciu
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North America
[email protected]
Kaidi Li
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IAP
[email protected]
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Benedikte Roberz / Sara Galletti
EE
[email protected] / [email protected]
IAP
te +1 Sandhiya Balakrishnan
[email protected]
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Maisa Pabis /Julio Souza
LATAM
[email protected] / [email protected]
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Sara Galetti
MASERATI
[email protected]
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End of Annex A
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Annex B
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(Informative)
Interior Materials for testing
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Table B-1 - Interior Materials for testing
Polymer / Material
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Polypropylene, unfilled (PP) TPO foils
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Polypropylene blends (TPO, PP+EPDM, etc) TPU foils
plus all filled and reinforced Polypropylene
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Polyethylene (PE) TPO/PP foam laminates
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Acrylonitrile-Butadiene-Styrene (ABS) PVC/PP foam laminates
Polycarbonate/Acrylonitrile-Butadiene-Styrene
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(PC/ABS) ex TC All weather floor mats, rubber or TPE based
Polymethylmethacrylate (PMMA) EPDM (in glass runs, inner belt moldings and
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door seals)
Polycarbonate (PC) TPVs (in glass runs, inner belt moldings and
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door seals))
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metallization, etc)
Polyolefin foams Body applied interior NVH treatments (mastic
patches, deadener mats, liquid applied sound
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Synthetic Leather (PVC, PUR , TPU, TPO) flutter, stiffening patches, water shield,
lamination, etc.)
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End of Annex B
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Annex C
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(Informative)
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Test sample set-up
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The samples shall be placed on a clean steel wire mesh stand of the appropriate size as indicated in
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Table C-1 below.
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Chamber Diameter Chamber volume Stand measurements (LxWxD)
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64mm 115ml 55mm x 55mm x 10mm (Figure C-1)
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45mm 44.5ml 40mm x 40mm x 5mm
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Wire mesh source:
•
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McMaster Carr T304 Stainless Welded 2x2 mesh, 0.047in. Diameter wire or equivalent which
can be cut and easily bent in shape to achieve the area and the height specified above. (Large
•
volume chamber).
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McMaster Carr T304 Stainless Welded 3x3 mesh, 0.047in. Diameter wire or equivalent. (Small
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volume chamber)
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The wire mesh stand shall be cleaned prior to the test according with cleaning requirements of ISO
12219-3. The cleaning procedure shall be repeated prior to each test.
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The test sample shall be placed on the wire mesh stand, centered in the test chamber (Figure C-2).
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64mm 50mm
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45mm 35 mm
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Figure C-1 - Test stand example Figure C-2 - Test sample set-up
End of Annex C
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Annex D
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Informative
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Reporting Form
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Table D-1 - Reporting Form
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SUPPLIER MATERIAL ID
Company Name Material
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Address Production Process
Contact name Plant / Production Date
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Contact phone Part Name
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Contact e-mail Part No./ Color
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Date delivered
Test Lab name
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Place of Testing
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Project No.
Test Specification
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Observations Test Method
Test Period:
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VOCs testing
TEST RESULTS
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Formaldehyde(mg/kg) Ethylbenzene
Acetaldehyde (mg/kg) Xylene
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End of Annex D
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Annex E
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(Informative)
List of laboratories acceptable to perform microchamber VOCs testing/ ISO 12219-3
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North America:
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Intertek Automotive Research
5404 Bandera Road, San Antonio, Texas 78238
Tel: (210) 523-4671
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Contact: Joe Franklin
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[email protected]
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Intertek Tranportation Technologies
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4700 Broadmoor SE, Suite 200, Kentwood, MI 49512 USA
Tel: (616) 656-7412
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Contact: Stuart Jones
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[email protected]
Contact: Jesse Ondersma
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[email protected]
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Tel: 248-588-9770
Contact: Jeffrey Fabian
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[email protected]
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[email protected]
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P3T Lab
8214 Kipling Avenue, Woodbridge, Ontario, Canada L4L 2A4
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Tel: 416-417-8551
Contact: Marcela Rusan de Priamus
[email protected]
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Tel: 586-501-1800
Contact: Darren Shepard
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China:
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Centre Testing International (Shanghai)Co. Ltd.
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5th Building, No 777, Xinjunhuan Rd.
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Minhang District,Shanghai, China 201114
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Tel: +86-15851226836
Contact: Wang Zhonghua
[email protected]
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Intertek Automotive Service
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Building T52-8 No. 1201 Guiqiao Rd.
Jinqiao Development Zone, Shanghai, China 201206.
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Tel: +86-17717819085
Contact: Chen Pinghai
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[email protected]
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Applus+ Reliable Analysis Shanghai
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No. 12A, Lane 1365 Kang Qiao Road East Shanghai, China
Tel: +86 (0) 21 68183293
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Contact: Luna Li
[email protected]
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Europe
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Certec
Rue Jules Bordet 45
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Zone Industrielle C
B 7180 Seneffe– Belgium
Tel: +32 64 520 211
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Imat-uve gmbh
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[email protected]
[email protected]
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Intertek Polychemlab B.V.
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Koolwaterstofstraat 1, 6161 RA,
Geleen, The Netherlands
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Tel: 0031 (0)88 126 8888
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Contact: Dr. Ir. Jan-Willem Housmans
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[email protected]
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Automotive Testhouse
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Am Technologiepark 8
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D-45699 Herten
Tel: +49 2366 305-650
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Contact: Rahil Taheri
[email protected]
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SGS France
21 chemin de Marticot
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33611 CESTAS – France
+33 (0) 5 57 97 02 33
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End of Annex E
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Annex F
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(Informative)
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List of laboratories acceptable to perform carbonyls testing/D40 5535 and VOCs
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testing/D10 5495
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Europe:
Filk
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Meißner Ring 1-5
09599 Freiberg, Germany
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Tel: +49-(0)3731-366-0
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Contact: Dr. Bernd Matthes
[email protected]
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Imat-uve gmbh
Krefelder Straße 679 – 691,
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41066 Mönchengladbach, Germany
Tel: +49 2161 686-5159 or +49 2161 6865 0
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Contact: Carmen Peters
[email protected]
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[email protected]
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Automotive Testhouse
Am Technologiepark 8
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D-45699 Herten
Tel: +49 2366 305 700
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[email protected]
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SGS France
21 chemin de Marticot
33611 CESTAS – France
br
+33 (0) 5 57 97 02 33
Contact: Sylvie Teissandier
Fe
Certec
Rue Jules Bordet 45
Zone Industrielle C
B 7180 Seneffe– Belgium
Tel: +32 64 520 211
Contact: Tiphaine Pacary
[email protected]
Page: 20/20
CS-13398
Change Level: K
China
7
om 46
SGS-CSTC Standards Technical Services (Shanghai) Co., Ltd.
The 4nd Building No. 69, KangQiao Industrial Park,
.c 8
Block 159, KangQiao East Road, Pudong District, Shanghai, China
is 1
Tel: +86 (0) 21 6119 1933
nt SD
Contact: Luna Li
[email protected]
lla d:
Intertek Automotive Service
te ri
Building T52-8 No. 1201 Guiqiao Rd, Pudong District, Shanghai, China 201206.
.s se
Tel: +86 -15901809962
Contact: Mandy XU
al u
[email protected]
rn ) -
Centre Testing International (Shanghai)Co. Ltd.
te +1
5th Building, No 777, Xinjunhuan Rd. Minhang District, Shanghai, China 201114
Tel: +86 (0) 21-31073723
ex TC
Contact: Zhonghua Wang
[email protected]
e@ (U
[email protected]
ic 3:
End of Annex F
.b 0
ra 25
ah 20
az 05,
tim y
fa uar
br
Fe
on