‘SMT. SULOCHANADEVI SINGHANIA SCHOOL, THANE. | (Ge Subject | Exam [Date Time [Marks [No.of printed pages | 10th | Chemistry | Prelim 41a Ths | a 7 | ‘This question paper is divided into two sections, Section-A is compulsory. Attempt any four main questions from Section B, The intended marks of questions or parts of questions are given in brackets [ SECTION A (40 marks) (Attempt all questions from this section) Question 1 Choose the correct answers to the questions from the given options: 05) (i) The 2" member of homologous series of alkyne is (@) Cath (©) Cath (©) CoH « @ Ct (ii) Ore which can be concentrated by froth flotation (@) Zincite () Fluorspar (6) tron pyrite , . (@) Calamine < | (iiiyThe nitrate on thermal decomposition fives a metal oxide which can react both with acid ‘and an alkali to give salt sn a: (6) Calcium nitrate. << (©) Potassium nitrate (©) Copper nitrate (4) Zine nitrate (iv)ln laboratory préparation of hydrogen chloride the gas is collected by (2) Downward displacement of air | (>) Downward displacement of water ©) Upward displacement of ar - \@) Upward displacement of water | (y)o &circuit below, the lamp lights up. what could X be ? ~*~ . aii —§s) ) t er 2) Lame | J ts cade |x (a) A solution of oho! and water (b) Sodium chord sl (c) Sugar solution (4) Aqueous solution of potassium sulphate »(vi)Concentrated nitric acid completely oxidises sulphur to: (@) 80; (b) 803 (©) HS0.- (@) 880, (vil) __Xisametal which bums in oxygen and the product formed is soluble in water, ‘solution gives . (a) Pink colour with methyl orange f-ci.ch (b) Pink colour with. ‘Phenolpthalein . (€) Red colour with blue litmus tek (@) Red colour with, ‘methyl orange es a 5 (i ea 7 NP and Al +AI"*The total number of electrons in N? and AI”? Fespectively are i) (@) 7,13. ws) we &) 10,13 ©) 10,10 (@) 7,10 aN (e)The picture below show the results when tree metal str blue copper: ‘sulphate soh ips, P, 0, aadR, are placed in lution. In, a) 1-Solution turns green. I Solution becomes colourless, IH- Solution remains blue. LS 0 W ‘Which of the followirig metals could be P, Q, and R? y iPAai, ozo, R-Fe qe SAO) P-Zn, QFe, Re Ag te; CAN} Pe, O20, Rag, A YY @P-Zn,QAL, R-Fe ‘ AL (x) The compound with empirical formula AB has vapour density thrice its empirical 2- formula weight, its molecular formula wil be V0> TE-Fw) & @AB - NO: Qtens (b) ASB srw tr (©) ABs oT) @) AsBe =6CErw) ba Ms (xi)A metallic oxide which cannot be reduced by conventional reducing agent, 0g (a) ZnO, (b) Mgo- (©) PbO (@ Cuo 3d. pO (xii) ‘A student passes ammonia gas on a heated black oxide X in the combustion tube, Which leaves a residue Y. Identify X and Y, as well asthe property of ammonia demonstrated inthis particular reaction, (8) X=CuO , Y=black residue, reducing property. (b) X-MnO> , Y = black residue , oxidising property. (©) X=CuO , Y =reddish brown residue , reducing property. * (4) X=PbO, Y-yellow, reducing property (xiii) The table shown below gives information about electronic configuration of some clements. Identify the compound which is wrongly formed, Serial no. ~ Electronic configuration | Formula of compound ‘| 1 AQI B26 [AB | z B26 | C2ar [Bo | 3 C27 DG | r [ «4 | BaRe & 5 eh ear Ese i 4 3: ©2 @1 (xiv) Assertion: Saturated hydrocarbons are cheniicidi) less reactive Reason: All the valencies of carbon atom wf satisfied by single covalent bonds (@) Both A and Rare tre and Ris coneetepliation ofthe assertion (b) Both A and R are true,but Ris eget ‘explanation ofthe assertion | (©) Aistrue butRisfalse = CSS (© Ais false, butRistue SSF oN (ww) Which a concept of decreasing one of elton aint ong the following? Ye @parra SS (Na >Al>s >a. (@C> Si >Mg>Ne- @F>ci>Beh, SAY (a) Name the gas X collected inthe jar. NS (b) Write the balanced chemical equation forthe above preparation. (6) Name the drying agent used. (<0 (@ Give confirmatory test for gas X (€) What happens when gas X bums in presence of oxygen.(5 ith Column B and write answers as 1.0.2. (Gl) Match the Column A with Column B and write answers as I —e Bieicatise ~~ e As cleansing agent d. Thermometers and spirit a re —| —_ Ne Electrical fittings or household vessels | GA] Fill in the banks by choosing the An aqueous solution of gas X tums bie bydrony) ions, When ths solution is added to o_ ( sverige lead nitrate), yy ‘foams ptwhich isle n hot wae. Xisalsoa god oxiisngeducing) pyiqiose" Tec options given inthe bracts 2 1us red, so it must contain (4 S. (hydronium/ ‘set which nits hot concenated fora eats op, Dackeompdint Vibert gat) @, (hydogen sulphide! chorine)ges, hich ui moist starch iodide paper ‘ish black. Wes QT B] Calculate : \ BS 2 \ () The volume of25 moles ofaghe ZS () The mass of 2.8dm°: ‘ofammanja, C) The mass of 56 lites of a Certn S18 3.55 Find the molecular veight ofthe gas, a (nt nga S WS (9) The tendeey 2h stom to atract shared pair of electrons towards itself when 6} {Qy idicator which remains colouress in acidic medium, & Othe non-polar covalent. ‘compound in liquid state *SQ..© The organic compound formed when sium metal i ‘added to ethanol, SS ") Give the IUPAC name ofthe following compound: 2 4) q a CH C—cHh— cH, . I cho| Draw the structure of the following compounds: 8) (@) Isomer of pentane in which one carbon is attached to 3 other carbon atom. (b) Formaldehyde (©) 3,3,4~ tribromo pentanoic acid ‘SECTION B (40 marks) (Attempt any four main questions) Question 3 () Answer the following questions: (3) What happens when nitic acid is stored in plain glass botle and why? (©) How will you distinguish between dilute nitic acid and concentrated nitric acid using [4] copper metal? (©) Complete the fllowing conversion by giving complet balanced rection stating wt necessary conditions, SS N: -A,NH BY, NO AY (i) Draw the electron dot diagram to show the formation of exch of te £lidwing ‘compounds SAS a) (3) A’positively charged ion! which is formed when actd is dissolved in water. (©) A compound formed between clement P with leet configuration 2,4 and clement Q with elecronie configuration 2,47: >” (Gii(@).Name the industrial process of preparation oP eulphiric acid . Uy (&)Why sulphur trioxide is not directly disolyeditwater to get sulphuric acid in the above process ee 0 Question 4. ik Elements A, B,C, D,E and E.have following atomie number. Answer the following austions-{Do not identify te elie) 4) [ Elements) A [OB e¢] D E | F | \ - ol | | | Atomic 12 7 | iW | 7 9 i LO Shen | nat | aet | oS fa | aga (@Which bf them will have highest ionization potential ? clin Win of these clemenvs belong to Period 3 ofthe Periodic table? (6) ldentfy the halogen from Period 2 (4) Arrange te elements A,B C and Fin decreasing order of atomic size. Gi) (@) Give a balanced chemical equation for heating of zine blende in air and also calculate — (b) the number of moles of sulphur dioxide liberated by 776g of ZxS (©) the weight of ZnS required to produce 22.41 of SO? at stp. [Zn =65,8=32,0-16] [3]Catron, 25 Gad Noss (ii)On thermal decomposition of calcium nitrate a colourless ‘gas X and a coloured gas Y is released along with the reside Z. (@) Identify X and Y and Give a balanced chemical equ forthe above reaction. fy] (©) Draw the electron dot stucture showing only the suture ofthe compound Z. it] (ACaleulate the volume of HCl gas formed. when 40cm of methane reacts with chlorine ‘ecording to the following equaion.CH,+2Ch —» CHiCh +2HCI 1) Questions: (W) Complete the table: 4 Gi) State your observation ee (2) Concentrated sulphuric acid is poured on a 46) Excess of sodium hydrox dint cob de solution is added to loride solution, (G) Bie Bess passed trough bromine waterinpaee en solvent. (€) Dilute sulphuric acid is added to potassium cafe ee . . vere Giiya, senpound X with molecular formula G2HO; reacts with another ‘compound Y with ‘molecular formula C2H,0 in the Peeeans cone sulphuric acid to give a compound Z, with fruity smell, Sica ONS ~ eee (6) Identify X and Y \? (0) Draw the Branched struct of ZS Question 6. ‘ | () Givea balanced chemical ae a equation fo the following “ | (3) A pungent sreling basic gas with exces of grenish yellow gas, () Hot concenirated sulphuri acd is poured on copper metal | (6) DiluéHydrochloric acid is added to zine sulphite | (4) Thétmal composition of aluminium hydroxide in Bacyer's process. ) db are provided with ist of chemicals mentioned inthe bracket: cS o Ne - {Sodium , Lead. lon, Chlorine, Ferous hydroxide, Som oxide, Sodium sulphate, dite | hydrochloric acid, dilute sulphuric acid, Lead Afate). Using suitable chemicals from the lst given, write a balanced chemical equations forthe preparation ofthe sat given below : B) (a) Ferrous chloride (b) Lead sulphate (6) Sodium chloride i the following by selecting the correct options from the choices given: {1} (eae mons na - (sulphuric acid/hydrochloric acid /acetie acid . o) The pt of X is greater then pH of Y So X contains ~-~—---—- concentration of 1 ions, (ow/high/same).(iv).A compound contains igen 87.5% and hydrogen 12.5% find the empirical formula of the compound,[N=14 H: Q] Question 7, () Rohan wants to electroplate a spoon with nickel. 4) (2) To which electrode should he connect the atic tobe electroplated? (b) Write the equation forthe reaction that will occur at oxidising electrode (©) What should the anode be made up of? (4) Why direct current and not alternating current is used and why? Gi) Explain why? (4) ising power of elements increases on moving from left to right across a. © Oxi Period in the periodic table (6) Dilution of concentrated sulphuric acid is not done by adding water to agid, > (©) Inverted funne! arrangement is used to dissolve HCI gas in water. (4) Magnesium chloride is hard crystalline solids. Lote GipTres ements P,Q, blog ihe same prod The sulpité of Pi€ PSO, the chloride of Qis QC, tnd carbonate of Ris R,COs. oe Bl 2,8) Qa > (a) Arrange the elements in increasing order of valencies. - p sot (by Arrange th element in decreasing onder of tre 2) ses w es \ 5° @ Give the reactions for preparation ofS 5 7 (4) (a) Metane wing sodeline. > for ROD (b) Ethene using alcoholic KOH. >> orp (6) Ethane fom ethene «> (4) Acetylene from (iy Answer the flo related to extraction of alumini 4 (Name he be ed rede pre sna. (b) Why coli added in he above process? (6) Toberphite anodes are replaced periodically during the electrolysis, ‘ie reason, €(G)-Give the formula ofthe ore used for extraction of aluminium. (Gi)Distinguish between the following by using a chemical test RB () Copper sulphide and Copper sulphate (6) Potassium chloride and Calcium chloride