Page 1 of 6

SAFETY DATA SHEET BTI-019

Prepared to OSHA, ACC, ANSI, WHSR, WHMIS, GHS & EU Standards SDS Revision: 3.0 SDS Revision Date: 1/31/2022

1. PRODUCT & COMPANY IDENTIFICATION

1.1 Product Name:
PRESTO BLACK® GEL
1.2 Chemical Name: Acid Mixture
1.3 Synonyms: 530150, 530151, 530150INT, 530158
1.4 Trade Names: Presto Black® Gel
1.5 Product Use: Blackening Solution for Iron and Steel
1.6 Distributor’s Name: Birchwood Laboratories LLC
1.7 Distributor’s Address: 7900 Fuller Road, Eden Prairie, MN 55344 USA
1.8 Emergency Phone: ChemTrec +1 (800) 424-9300 / +1 (703) 527-3887 or Poison Control Center +1 (855) 281-1742
1.9 Business Phone / Fax: +1 (952) 937-7900 / +1 (952) 937-7979

2. HAZARDS IDENTIFICATION
2.1 Hazard Identification: Prepared in accordance with UN Globally Harmonized standards. Intended to comply with OSHA 29 CFR 1910.1200.
Canadian WHMIS and Australian Work Health and Safety.
DANGER! TOXIC IF SWALLOWED. CAUSEs SEVERE SKIN BURNS OR EYE DAMAGE. MAY CAUSE DAMAGE TO
ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. VERY TOXIC TO AQUATIC LIFE WITH LONG
LASTING EFFECTS.
Classification: Acute Tox. (oral) 3; Skin Corr. 1A; STOT RE 2; Chronic Aquatic 1
2.2 Label Elements: Hazard Statements (H): H301 – Toxic if swallowed. H314 – Causes severe skin burns and eye
damage. H373 – May cause damage to organs through prolonged or repeated exposure. H410 –
Very toxic to aquatic life with long lasting effects.
Precautionary Statements (P): P260 - Do not breathe dust/mist/fume/vapor/spray. P264 – Wash
hands and exposed skin areas with soap and warm water thoroughly after handling. P270 – Do not
eat, drink, or smoke when using this product. P273 – Avoid release to the environment. P280 - Wear
protective gloves/ protective clothing/ eye protection/ face protection. P301+P330+P331- IF
SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+P361+P354 – IF ON SKIN: Take off
immediately all contaminated clothing. Immediately rinse with water for several minutes. P363 –
Wash contaminated clothing before reuse. P304+P340 – IF INHALED: Remover person to fresh air
and keep comfortable for breathing. P305+P354+P338 - IF IN EYES: Rinse with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P316 – Get emergency
help immediately. P321 – Specific treatment see section 4 (first aid) of this SDS. P391 – Collect
spillage. P405 – Store locked up. P501 – Dispose of contents/ container to an approved waste
disposal plant.

2.3 Other Warnings: In the event of an exposure or medical inquiry involving this product, please contact a physician or local poison control
center, who may seek advice from the U.S. manufacturer, and show them this SDS. Keep out of reach of children.

3. COMPOSITION & INGREDIENT INFORMATION

EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH NOHSC OSHA
ppm ppm ppm
ES- ES- ES-
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. % TLV STEL TWA STEL PEAK PEL STEL IDLH OTHER
7732-18-5 ZC0110000 231-791-2 60-100 NE NE NF NF NF NE NE NE
WATER

POLYOXYETHYLENE STEARYL 9005-00-9 NA 500-017-8 7-13 NA NA NF NF NF NA NA NA

WAX DERIVATIVES
7758-99-8 NA NA 5-10 (1) NA NF NF NF (1) NA 1000
CUPRIC SULFATE
Acute Tox. 4; H302
7783-00-8 VS7175000 231-974-7 1-5 (0.2) NA (0.2) NF NF (0.2) NA NA
SELENIOUS ACID
Acute Tox. (Inh) 3; Acute Tox. (oral) 3; STOT-RE 2; Acute Aquatic 1; Chronic Aquatic 1; H301, H331, H400, H402
7697-37-2 QU5775000 231-714-2 1-5 2 4 2 NF NF 2 NA 25
NITRIC ACID
Ox. Liq. 3; Skin Corr. 1A; H272, H314

4. FIRST AID MEASURES

4.1 First Aid: Ingestion: Do not induce vomiting. Call +1 (855) 281-1742 for emergency medical advice. If vomiting occurs, keep
victim’s head lowered (forward) to keep vomit from entering the lungs. Call 911 for emergency medical
transport if any symptoms noted.
Eyes: Remove and discard contact lenses if worn and flush eyes with large amounts of water for at least 20
minutes. Seek immediate medical attention when done rinsing eyes.
Skin: Remove contaminated clothing and wash exposed skin with large amounts of soap and water. Seek medical
attention if any blistering, swelling or open sores develop.
Inhalation: Move victim to fresh air. Contact emergency medical services (911) if any difficulty in breathing occurs or if
victim loses consciousness.
 Page 2 of 6
SAFETY DATA SHEET BTI-019
Prepared to OSHA, ACC, ANSI, WHSR, WHMIS, GHS & EU Standards SDS Revision: 3.0 SDS Revision Date: 1/31/2022

4. FIRST AID MEASURES – cont’d

4.2 Effects of Exposure: Eyes: Severe or permanent eye damage.
Skin: Burns upon direct contact.
Ingestion: Severe burns of mouth, throat, stomach.
Inhalation: Severe irritation or burns in respiratory tract and mucous membranes. Possible lung damage.
4.3 Symptoms of Overexposure: Eyes: Redness, burning, irritation, and swelling around eyes
Skin: Redness, burning, itching, rash, blistering of skin.
Ingestion: Nausea, vomiting, severe abdominal pain.
Inhalation: Coughing, wheezing, swelling of throat, irritation in mucous membranes, difficulty breathing.
4.4 Acute Health Effects: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory
tract. May be harmful if swallowed. Causes burns. May be harmful if absorbed through skin.
4.5 May damage the nervous system, kidney and/or liver.
4.6 Target Organs: Eyes, Skin, Nervous System, Kidneys, Liver, Respiratory System.
4.7 Medical Conditions
Aggravated by Exposure:
Pre-existing dermatitis, other skin conditions, and disorders of the target HEALTH 3
organs (eyes, skin, and respiratory system) or impaired kidney function
may be more susceptible to the effects of this substance. FLAMMABILITY 0
PHYSICAL HAZARDS 2
PROTECTIVE EQUIPMENT H
EYES SKIN LUNGS
4.8 Notes to Physician: This product contains Selenious Acid and is potentially fatal if ingested even in small amounts. 24-hour admission should
be considered in asymptomatic or minimally symptomatic patients as delayed toxic effects including pulmonary edema and
multi-organ failure may occur. 24/7 medical toxicology consultation is available at +1 (855) 281-1742.

5. FIREFIGHTING MEASURES
5.1 Fire & Explosion Hazards: Non-flammable. May react with metals to release hydrogen gas, which can form explosive mixtures with
air. May intensity fire; oxidizer. Keep/Store away from clothing/ combustible materials.
5.2 Extinguishing Methods: Use fire-extinguishing media appropriate for surrounding materials.
5.3 Firefighting Procedures: As with any fire, firefighters should wear appropriate protective equipment including a MSHA/NIOSH
approved or equivalent self-contained breathing apparatus (SCBA) and protective clothing. Fight fires
as for surrounding materials. Hazardous decomposition products may be released. Thermal
degradation may produce oxides of carbon, phosphorous, selenium and/or nitrogen, hydrocarbons
and/or derivatives. Fire should be fought from a safe distance. Keep containers cool until well after the
fire is out. Use water spray to cool fire-exposed surfaces and to protect personal. Fight fire upwind.
Prevent runoff from fire control or dilution from entering sewers, drains, drinking water supply, or any
natural waterway.

6. ACCIDENTAL RELEASE MEASURES

6.1 Spills: Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective Equipment
(PPE). Use safety glasses or safety goggles and face shield; use gloves and other protective clothing (e.g., apron, boots,
etc.) to prevent skin contact.
Small Spills: Wear appropriate protective equipment including gloves and protective eyewear. Use a non-combustible,
inert material such as vermiculite or sand to soak up the product and place into a container for later disposal.
Large Spills: Keep incompatible materials (e.g., organics such as oil) away from spill. Stay upwind and away from spill or
release. Isolate immediate hazard area and keep unauthorized personnel out of area. Stop spill or release if it can be
done with minimal risk. Wear appropriate protective equipment including respiratory protection as conditions warrant.
Recover as much free liquid as possible and collect in acid-resistant container. Use absorbent to pick up residue. Avoid
discharging liquid directly into a sewer or surface waters.

7. HANDLING & STORAGE INFORMATION

7.1 Work & Hygiene Practices: Avoid breathing mists or spray. Avoid eye and skin contact. Wear protective equipment when handling product. Keep out
of the reach of children. Do not eat, drink or smoke when handling this product. Wash thoroughly after handling. Do not
expose to heat and flame. Use only in ventilated areas. Keep out of the reach of children. Immediately clean-up and
decontaminate any spills or residues.
7.2 Storage & Handling: Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans) away from heat and direct sunlight.
Store in acid-resistant containers. Keep containers covered when not in use. Avoid temperatures above 40 °C (120 °F).
Keep away from incompatible substances (See Section 10). Protect containers from physical damage.
7.3 Special Precautions: Empty containers may retain hazardous product residues. Keep/Store away from clothing/ combustible materials.
 Page 3 of 6
SAFETY DATA SHEET BTI-019
Prepared to OSHA, ACC, ANSI, WHSR, WHMIS, GHS & EU Standards SDS Revision: 3.0 SDS Revision Date: 1/31/2022

8. EXPOSURE CONTROLS & PERSONAL PROTECTION

8.1 Exposure Limits: ACGIH NOHSC OSHA OTHER
ppm (mg/m3) ES- ES-
CHEMICAL NAME(S) TLV STEL ES-TWA STEL PEAK PEL STEL IDLH
SELENIOUS ACID (0.2) NA (0.2) NF NF (0.2) NA NA
NITRIC ACID 2 4 2 NF NF 2 NA 25
CUPRIC SULFATE (1) NA NF NF NF (1) NA 1000
8.2 Ventilation & Engineering Use local or general exhaust ventilation to effectively remove and prevent buildup of vapors or mist generated from the
Controls:
handling of this product. Ensure appropriate decontamination equipment is available (e.g., sink, safety shower, eye-wash
station).
8.3 Respiratory Protection: In instances where vapors or sprays of this product are generated, and respiratory protection is needed,
use only protection authorized by 29 CFR §1910.134, applicable U.S. State regulations, or the Canadian
CAS Standard Z94.4-93 and applicable standards of Canadian Provinces, EC member States, or
Australia.
8.4 Eye Protection: Safety glasses with side shields must be used when handling or using this product. A protective face
shield is also recommended.
8.5 Hand Protection: Wear protective, chemical-resistant gloves (e.g., neoprene) when using or handling this product.

8.6 Body Protection: A chemical resistant apron and/or protective clothing are recommended when handling or using this
product.

9. PHYSICAL & CHEMICAL PROPERTIES

9.1 Appearance: Viscous blue liquid
9.2 Odor: Odorless
9.3 Odor Threshold: 0.29 to 0.98 ppm (Nitric Acid)
9.4 pH: 1.0
9.5 Melting Point/Freezing Point: NA
9.6 Initial Boiling Point/Boiling
Range: > 100 °C (> 212 °F)
9.7 Flashpoint: Wax: 207 °C (405 °F) COC
9.8 Upper/Lower Flammability
Limits: NA
9.9 Vapor Pressure: NA
9.10 Vapor Density: < 1.0 (air = 1.0)
9.11 Relative Density: 1.017
9.12 Solubility: Insoluble (water); Soluble (isopropanol)
9.13 Partition Coefficient (log Pow): NA
9.14 Autoignition Temperature: NA
9.15 Decomposition Temperature: NA
9.16 Viscosity: NA
9.17 Other Information: Evaporation Rate: < 1.0 (ethyl ether = 1.0)

10. STABILITY & REACTIVITY

10.1 Stability: Stable at normal temperatures.
10.2 Hazardous Decomposition Reaction with organics and strong reducing agents can produce organoselenides and hydrogen selenide. Thermal
Products:
decomposition may produce selenium, nitrogen, phosphoric and copper oxides.
10.3 Hazardous Polymerization: Will not occur.
10.4 Conditions to Avoid: Excessive heat, shock, friction.
10.5 Incompatible Substances: Cyanides, water-reactive substances, strong reducing agents, chlorinated cleaners or sanitizers, combustible organic
materials, most metals.

11. TOXICOLOGICAL INFORMATION

11.1 Routes of Entry: Inhalation:YES Absorption: YES Ingestion: NO
11.2 Toxicity Data: Cupric Sulfate: LD50 (oral, rat) = 300 mg/kg
11.3 Acute Toxicity: See Section 2.4
11.4 Chronic Toxicity: See Section 2.5
11.5 Suspected Carcinogen: Selenious Acid is listed by IARC on Group 3 (not classifiable as to its carcinogenicity to humans)
11.6 Reproductive Toxicity: This product is not reported to cause reproductive toxicity in humans.
Mutagenicity: This product is not reported to produce mutagenic effects in humans.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
 Page 4 of 6
SAFETY DATA SHEET BTI-019
Prepared to OSHA, ACC, ANSI, WHSR, WHMIS, GHS & EU Standards SDS Revision: 3.0 SDS Revision Date: 1/31/2022

11. TOXICOLOGICAL INFORMATION – cont’d

11.7 Irritancy of Product: See Section 4.2
11.8 Biological Exposure Indices: NE
11.9 Physician Recommendations: This product contains Selenious Acid and is potentially fatal if ingested even in small amounts. 24-hour admission should
be considered in asymptomatic or minimally symptomatic patients as delayed toxic effects including pulmonary edema and
multi-organ failure may occur. 24/7 medical toxicology consultation is available at +1 (855) 281-1742.

12. ECOLOGICAL INFORMATION

12.1 Environmental Stability: There are no specific data available for this product.
12.2 Effects on Plants & Animals: There are no specific data available for this product.
12.3 Effects on Aquatic Life: Very toxic to aquatic life with long lasting effects.

13. DISPOSAL CONSIDERATIONS

13.1 Waste Disposal: Review current local, state and federal laws, codes, statutes and regulations to determine current status and appropriate
disposal method for the ingredients listed in Section 2. Any disposal practice must be in compliance with local, state, and
federal laws and regulations. Contact the appropriate agency for specific information. Treatment, transport, storage and
disposal of hazardous waste must be provided by a licensed facility or waste hauler.
13.2 Special Considerations: U.S. EPA Hazardous Waste – Characteristic - Corrosive (D002), Characteristic - Toxic (D010)

14. TRANSPORTATION INFORMATION

The basic description (ID Number, proper shipping name, hazard class & division, packing group) is shown for each mode of transportation. Additional
descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND): UN3264, CORROSIVE LIQUIDS, ACIDIC, INORGANIC, N.O.S. (SELENIOUS ACID, NITRIC ACID),
8, III, LTD QTY (IP VOL ≤ 5.0 L)
14.2 IATA (AIR): UN3264, CORROSIVE LIQUIDS, ACIDIC, INORGANIC, N.O.S. (SELENIOUS ACID, NITRIC ACID),
8, III, LTD QTY (IP VOL ≤ 0.5 L)
14.3 IMDG (OCN): UN3264, CORROSIVE LIQUIDS, ACIDIC, INORGANIC, N.O.S. (SELENIOUS ACID, NITRIC ACID),
8, III, LTD QTY (IP VOL ≤ 5.0 L)
14.4 TDGR (Canadian GND): UN3264, CORROSIVE LIQUIDS, ACIDIC, INORGANIC, N.O.S. (SELENIOUS ACID, NITRIC ACID),
8, III, LTD QTY (IP VOL ≤ 5.0 L)
14.5 ADR/RID (EU): UN3264, CORROSIVE LIQUIDS, ACIDIC, INORGANIC, N.O.S. (SELENIOUS ACID, NITRIC ACID),
8, III, LTD QTY (IP VOL ≤ 5.0 L)
14.6 SCT (MEXICO): UN3264, LIQUIDOS, CORROSIVOS, ACIDO, INORGANICO, N.E.P. (ACIDO SELENIO, ACIDO
NITRICO), 8, III, CANTIDAD LIMITADA (IP VOL ≤ 5.0 L)
14.7 ADGR (AUS): UN3264, CORROSIVE LIQUIDS, ACIDIC, INORGANIC, N.O.S. (SELENIOUS ACID, NITRIC ACID),
8, III, LTD QTY (IP VOL ≤ 5.0 L)

15. REGULATORY INFORMATION

15.1 SARA Reporting Requirements: This product contains Nitric Acid, Cupric Sulfate and Selenious Acid, substances subject to SARA Title III, section 313
reporting requirements.
15.2 SARA TPQ: 302 TPQ (Nitric Acid): 1,000 lbs (454 kg)
15.3 TSCA Inventory Status: The components of this product are listed on the TSCA Inventory.
15.4 CERCLA Reportable Quantity: Selenious Acid: 10 lbs (4.54 kg); Nitric Acid: 1,000 lbs (454 kg); Cupric Sulfate: 10 lbs (4.54 kg)
15.5 Other Federal Requirements: NA
15.6 Other Canadian Regulations: This product has been classified according to the hazard criteria of the HPR and the SDS contains
all of the information required by the HPR. The components of this product are listed on the
DSL/NDSL. None of the components of this product are listed on the Priorities Substances List.
WHMIS Class E (Corrosive Material). WHMIS Class D1 (Materials Causing Immediate and Serious
Toxic Effects).
15.7 State Regulatory Information: Selenious Acid is found on the following state criteria lists: Florida Toxic Substances List (FL), Massachusetts Hazardous
Substances List (MA), Minnesota Hazardous Substances List (MN), Pennsylvania Right-to-Know List (PA), and Wisconsin
Hazardous Substances List (WI).
Nitric Acid is found on the following state criteria lists: FL, MA, MN, New Jersey Right-to-Know List (NJ), PA, and
Washington Permissible Exposures List (WA).
No other ingredients in this product, present in a concentration of 1.0% or greater, are listed on any of the following state
criteria lists: California Proposition 65 (CA65), Delaware Air Quality Management List (DE), Florida Toxic Substances
List (FL), Massachusetts Hazardous Substances List (MA), Michigan Critical Substances List (MI), Minnesota Hazardous
Substances List (MN), New Jersey Right-to-Know List (NJ), New York Hazardous Substances List (NY), Pennsylvania
Right-to-Know List (PA), Washington Permissible Exposures List (WA), Wisconsin Hazardous Substances List (WI). This
product does not contain any chemicals known to the State of California to cause cancer or other reproductive harm. For
more information go to www.P65Warnings.ca.gov.
15.8 Other Requirements: This product is found on the following inventory lists: Australia - AICS, China – IECSC, Europe – ELINCS/EINEC,
Japan – ENCS; Korea – KECI; New Zealand – NZIoC; {Philippines – PICCS; USA – TSCA
 Page 5 of 6
SAFETY DATA SHEET BTI-019
Prepared to OSHA, ACC, ANSI, WHSR, WHMIS, GHS & EU Standards SDS Revision: 3.0 SDS Revision Date: 1/31/2022

16. OTHER INFORMATION

16.1 Other Information: DANGER! TOXIC IF SWALLOWED. CAUSEs SEVERE SKIN BURNS OR EYE DAMAGE. MAY CAUSE DAMAGE TO
ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. VERY TOXIC TO AQUATIC LIFE WITH LONG
LASTING EFFECTS. Obtain special instructions before use. Do not handle until all safety precautions have been read and
understood. Do not breathe dust/mist/fume/vapor/spray. Wash hands and exposed skin areas with soap and warm water
thoroughly after handling. Do not eat, drink, or smoke when using this product. Avoid release to the environment. Wear
protective gloves/ protective clothing/ eye protection/ face protection. IF SWALLOWED: Rinse mouth. Do NOT induce
vomiting. IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.
Wash contaminated clothing before reuse. IF INHALED: Remover person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get
emergency help immediately. Specific treatment see section 4 (first aid) of this SDS. Collect spillage. Store locked up.
KEEP LOCKED UP AND OUT OF REACH OF CHILDREN.
16.2 Terms & Definitions: See last page of this Safety Data Sheet.
16.3 Disclaimer: This Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR §1910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & Birchwood
Technologies’ knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy,
suitability or completeness is not guaranteed and no warranties of any type, either expressed or implied, are provided.
The information contained herein relates only to the specific product(s). If this product(s) is combined with other materials,
all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest
edition.
16.4 Prepared for: Birchwood Technologies
7900 Fuller Road
Eden Prairie, MN 55344 USA
Tel: +1 (952) 937-7900
Fax: +1 (952) 937-7979
http://www.birchwoodtechnologies.com
16.5 Prepared by: ShipMate, Inc.
P.O. Box 787
Sisters, Oregon 97759-0787 USA
Tel: +1 (310) 370-3600
Fax: +1 (310) 370-5700
http://www.shipmate.com
 Page 6 of 6
SAFETY DATA SHEET BTI-019
Prepared to OSHA, ACC, ANSI, WHSR, WHMIS, GHS & EU Standards SDS Revision: 3.0 SDS Revision Date: 1/31/2022

DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a SDS. Some of these that are commonly used include the following:

GENERAL INFORMATION: NATIONAL FIRE PROTECTION ASSOCIATION: NFPA

CAS No. Chemical Abstract Service Number FLAMMABILITY LIMITS IN AIR:

RTECS No. Registry of Toxic Effects of Chemical Substances Number Autoignition Minimum temperature required to initiate combustion in air with no other source
EINECS No. European Inventory of Existing Commercial Chemical Substances Number Temperature of ignition
LEL Lower Explosive Limit - lowest percent of vapor in air, by volume, that will explode
EXPOSURE LIMITS IN AIR: or ignite in the presence of an ignition source
UEL Upper Explosive Limit - highest percent of vapor in air, by volume, that will
ACGIH American Conference on Governmental Industrial Hygienists explode or ignite in the presence of an ignition source
IDLH Immediately Dangerous to Life and Health
NOHSC National Occupational Health and Safety Commission (Australia) HAZARD RATINGS:
OSHA U.S. Occupational Safety and Health Administration
PEL Permissible Exposure Limit 0 Minimal Hazard
STEL Short Term Exposure Limit 1 Slight Hazard
TLV Threshold Limit Value 2 Moderate Hazard
TWA Time Weighted Average 3 Severe Hazard
4 Extreme Hazard
FIRST AID MEASURES: ACD Acidic
ALK Alkaline
CPR Cardiopulmonary resuscitation - method in which a person whose heart has
stopped receives manual chest compressions and breathing to circulate blood COR Corrosive
and provide oxygen to the body. W Use No Water
OX Oxidizer
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: HMIS TREFOIL Radioactive

HEALTH, FLAMMABILITY & REACTIVITY RATINGS: TOXICOLOGICAL INFORMATION:

0 Minimal Hazard HEALTH LD50 Lethal Dose (solids & liquids) which kills 50% of the exposed animals
LC50 Lethal concentration (gases) which kills 50% of the exposed animal
1 Slight Hazard FLAMMABILITY ppm Concentration expressed in parts of material per million parts
2 Moderate Hazard PHYSICAL HAZARDS TDlo Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
3 Severe Hazard PERSONAL PROTECTION
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or toxic effects
4 Extreme Hazard TC, TCo, LClo, & LCo
IARC International Agency for Research on Cancer
PERSONAL PROTECTION RATINGS: NTP National Toxicology Program
RTECS Registry of Toxic Effects of Chemical Substances
A G BCF Bioconcentration Factor
TLm Median threshold limit
log KOW or log KOC Coefficient of Oil/Water Distribution
B H
REGULATORY INFORMATION:
C I WHMIS Canadian Workplace Hazardous Material Information System
DOT U.S. Department of Transportation
D J TC Transport Canada
EPA U.S. Environmental Protection Agency
DSL Canadian Domestic Substance List
E K NDSL Canadian Non-Domestic Substance List
PSL Canadian Priority Substances List
Consult your supervisor or SOPs for
F X special handling directions.
TSCA
EU
U.S. Toxic Substance Control Act
European Union (European Union Directive 67/548/EEC)
WGK Wassergefährdungsklassen (German Water Hazard Class)

Face Shield &

Safety Glasses Splash Goggles Gloves
Protective Eyewear

Protective Clothing
Boots Protective Apron Dust Respirator
& Full Suit Class A Class B Class C Class D1 Class D2 Class D3 Class E Class F

Compressed Flammable Oxidizing Toxic Irritation Infectious Corrosive Reactive

Dust & Vapor Half- Full Face Airline Hood/Mask

Full Face Respirator CLP/GHS (1272/2008/EC) PICTOGRAMS:
Mask Respirator Respirator or SCBA

OTHER STANDARD ABBREVIATIONS:

Carc Carcinogenic
Irrit Irritant
NA Not Available
NR No Results GHS01 GHS02 GHS03 GHS04 GHS05 GHS06 GHS07 GHS08 GHS09
ND Not Determined
Harmful Health
NE Not Established Explosive Flammable Oxidizer Pressurized Corrosive Toxic Environment
Irritating Hazard
NF Not Found
SCBA Self-Contained Breathing Apparatus
Sens Sensitization
STOT RE Specific Target Organ Toxicity – Repeat Exposure
STOT SE Specific Target Organ Toxicity – Single Exposure