Sec: JR MPC ALL DATE: 30 -12-2024

Time: 03:00 Hrs. EAMCET PTE-09 Max Marks: 160

IMPORTANT INSTRUCTIONS: -
EAMCET MODEL
MATHEMATICS:
+Ve - Ve No. of Total
Q.NO Question Type
Marks Marks Q’S marks
(Q.N : 1 – 80) Questions with Single Answer Type 1 0 80 80
Total 80 80

PHYSICS:
+Ve - Ve No.of Total
Q.NO Question Type
Mark Marks Q’S Marks
(Q.N : 81 – 120) Questions with Single Answer Type 1 0 40 40
Total 40 40

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Mark Marks Q’S marks
(Q.N : 121 – 160) Questions with Single Answer Type 1 0 40 40
Total 40 40

SYLLABUS
MATHS : Vector :: Cross product , scalar triple product. (70℅)
Application of derivatives, addition of vectors, dot product (30℅)
PHYSICS : Kinetic Theory of Gases, First law of thermodynamics - isobaric,
isochoric, isothermal and adiabatic processes.
CHEMISTRY : Organic complete

QUESTION PAPER ANALYSIS

SUBJECT EASY MODERATE DIFFICULT

MATHS 65 15 0
PHYSICS 25 13 2
CHEMISTRY 23 14 3
TOTAL 113 42 5
 MATHS Max Marks: 80
(SINGLE CORRECT ANSWER TYPE)
This section contains 80 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +1 for correct answer, 0 if not attempted and 0 if not correct.

1. If a = i − 2 j − 3k, b = 2 i + j − k and c = i + 3 j − 2k then a  (b  c)

A) 10 B) -10 C) -20 D) 20
2. If  a + 2b 2b + c 5c + a  = k  abc  then k=
A) 2 B) 4 C) 8 D) 12
3. If  i + 4 j + 6k 2 i + a j + 3k i + 2 j − 3k  = 18 then a =
A) -4 B) 4 C) 4 D) 1
a  (b  c) b  (c  a) c  (a  b)
4. If [abc] = 1 then + +
(c  a)  b (a  b)  c (b  c)  a
A) 3 B) 1 C) -1 D) 0
5. The volume of a parallelopiped whose edges are represented by −12 i + k,3 j − k and
2 i + j − 15k is 546 then  = ______
A) -3 B) -2 C) 2 D) 3
6. The perpendicular distance from origin to the plane passing through the points
2 i − 2 j + k,3i + 2 j − k,3i − j − 2k is
12 25 10 15
A) B) C) D)
30 110 60 187
7. The lines r = a + tb, r = c + sd are coplanar if
A) (a − b)  c  d = 0 B) (a − c)  b  d = 0
C) (b − c)  a  d = 0 D) (b − d)  a  c = 0
[a + b b + c c + a]
8. If [abc]  0 then =
[a b c]
A) 1 B) -1 C) 2 D) -3
9. The vectors 2 i + 3 j − 2k,2 i − j + 4k , 3i + 2 j forms
A) right-handed system B) left handed system
C) cannot be decide D) orthonormal triad
a
10. If the volume of tetrahedron with edges i + j − k, i + aj + k and i + 2 j − k is then a=
6
A) 0 B) 1 C) 2 D) -1
11. If a, b, c are vectors such that [abc] = 4 then  a  b b  c c  a  is
A) 16 B) 64 C) 4 D) 8
12. The equation of the plane passing through the points A=(2,3,-1), B=(4,5,2), C=(3,6,5)
is
A) 3x + 9y + 4z + 25 = 0 B) 3x − 9y + 4z + 25 = 0
C) 3x − 9y + 4z − 25 = 0 D) 3x − 9y − 4z − 25 = 0

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 13. The distance between the plane whose equation is r  (2 i + j − 3k) = 5 and the line
whose equation is r = i + (2 i + 5 j + 3k) is
3 5
A) B) C) 5 D) 0
14 14
14. If a  ,b ,c represents the reciprocal system of vectors of a, b, c then aa + bb + cc =
A) 0 B) 1 C) 2 D) 3

15. If (a, b) = , c is perpendicular to a and b , | a |= 3,| b |= 4,| c |= 6 then a b c  _____
6
A) 12 3 B) 48 3 C) 36 D) 72
16. If a = 2 i − j + k, b = i + 2 j − 3k c = 3i +  j + 5k are coplanar then  is a root of the
equation
A) x 2 + 3x = 4 B) x 2 + 2x = 6 C) x 2 + 3x = 6 D) x + 5 = 0
17. If the vectors a i + j + k, i + bj + k, i + j + ck (a,b,c are not equal to 1) are coplanar,
1 1 1
then + + = 
1− a 1− b 1− c
A) 0 B) 3 C) 2 D) 1
1
18. If x(a  b) + y(b  c) + z(c  a) = r and [abc] = then x + y + z =
8
A) r  (a + b + c) B) 4[ r  (a + b + c)]
C) 8[ r  (a + b + c)] D) 0
19. For any three non-zero vectors a, b, c,if | (a  b)  c |=| a || b || c | then a  b + b  c + c  a =
A) 1 B) 2 C) 0 D) 3
20. If a is a perpendicular to b and c,| a |= 2,| b |= 3,| c |= 4 and the angle between b and c
2
is , then |[abc]|=
3
A) 24 B) 12 C) 12 3 D) 24 3
21. a = i − k, b = x i + j + (1 − x)k and c = y i +  j + (1 + x − y)k then [abc] depends on
A) neither x nor y B) both x and y C) only x D) only y
22.  = p(b  c) + q(c  a) + r(a  b) and if   (a + b + c) = 1 then [abc] =
1 2
A) p+q+r B) C) 2(p + q + r) D)
p+q+r p+q+r
a a a b a c
23. If a, b, c are non coplanar vectors, then b  a b  b b  c =
ca cb cc

A)  a b c  B) [abc]2 C) 1 D) 0
24. The lines r = i − j + k + s( i + 2 j − 3k) and r = ( i − 2 j + 3k) + t(− i + j + 2k)
A) Intersect B) Do not intersect C) skew lines D) Cannot be determine

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 25. (a + b)  a1 + (b + c)  b1 + (c + a)c1 =
A) 0 B) 1 C) 2 D) 3
26. a = 2 i + 3 j − 4k, b = i + j + k , c = 4 i + 2 j + 3k then | a  (b  c) |=
A) 10 B) 1 C) 2 D) 5
27. a = 2 i + 3 j − k, b = − i + 2 j − 4k, c = i + j + k,d = i − j − k then (a  b)  (c  d) =
A) 14 B) 24 C) 36 D) 4
28. If (a  b)  (c  b) + (a  b)(b  c) = (a  c) then  =
A) | a |2 B) | b |2 C) | c |2 D) 0
29. If a, b are two unit vectors such that | a  b |= 2 then the value of  a b a  b  is
A) 1 B) 2 C) 4 D) 0
30. If four vectors a, b, c,d are coplanar, then (a  b)  (c  d) =
A) [abc]d B) [bcd]a C)  c d a  b D) Null vector
31. If a = i − 2 j − 3k, b = 2 i + j − k and c = i + 3 j − 2k , and a  (b  c) = p i + q j + rk ,
then p+q+r=
A) -4 B) 4 C) 2 D) -2
32. The vectors a  (b  c) is
A) Coplanar with b and c
B) Coplanar with a and b parallel to c
C) Coplanar with b and c , orthogonal to a
D) Coplanar with a and b , orthogonal to c
33. (a  b)  (c  d) = (a  c)(b  d) + K(a  d)(b  c) then the value of K is
A) 1 B) 0 C) -2 D) -1
34. If a, b lie in a plane normal to the plane containing c and d then | (a  b)  (c  d) |=
A) 4 B) 1 C) 0 D) 3
35. (a  b)  (c  d) = lc + md then m is
A)  a b c d  B)  c b d  C)  b c d  D) −  a b c 
1
36. Three vectors a, b, c are such that a  b = 3(a  c) . Also | a |=| b |= 1,| c |= . If the angle
3

between b and c is 60 , then
A) b = 3c + a B) b = 3a − c C) b = 3c + 2a D) b = 3c − 2a
|ab| 2
37. If | a |= 2,| b |= 4 then =
1 − cos 2 (a, b)
A) 8 B) 2 C) 64 D) 32

38. a, b are such that | a |= 3,| b |= 2 and (a, b) = . Then the area of the triangle with
3
adjacent sides a + 2b and 2a + b is
A) 5 3 B) 15 C) 9 / 2 D) 15 / 2

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 1
39. If a, b, c be three vectors such that | a + b + c |= 1, c = (a  b) and | a |= ,
2
1 1
| b |= ,| c |= , then the angle between a and b is
3 6
   
A) B) C) D)
6 4 3 2
40. a + 2 b + 3c = 0 and a  b + b  c + c  a = (b  c) then = ____
A) 2 B) 4 C) 6 D) 8
41. If ,  are roots of the equation x + 2x + 5 = 0 and
2
a = ( + ) i +  j ,
b =  i + ( + ) j + (  2 + 2 ) k then a  b =
A) i + 12 j + 12k B) −30 i + 12 j − 5k
C) −30 i − 12 j − 21k D) i − 12 j + 29k
42. a and c are unit vectors and | b |= 4 with a  b = 2a  c . The angle between a and c is
1
cos −1   . Then b − 2c =  a , if  is
4
1 1
A) 1 B) C) -4 D) −
4 4
43. A force F = 2 i −  j + 5k is applied at the point A(1,2,5) . If its moment about the point
(-1,-2,3) is 16 i − 6 j + 2k then  =
A) -2 B) -1 C) 0 D) 2
44. The vector c is perpendicular to both a = (1, −2,1), b = (2,1, −1) and c also satisfies
| c  (i − j + k) |= 2 6 then c =
i + 3j + 5k
A)  B) (−4i + 5j + k) C) (i + j + k) D) 2(i + j + k)
2
45. The vectors perpendicular to i − j − k in the plane of i − j − k and − i + j + k are
A) 2 i + j + k B) −4 i − 2 j − 2k C) 4 i + 2 j + 2k D) all the above
46. The area of the parallelogram is 4 29 sq.u. If one of adjacent side is 3i + 4 j then the
other side is
A) i − 4k B) 2 i + 4k C) −2 j − 4k D) 2 i − 4k
47. The area of the parallelogram whose adjacent sides are a and b is 2 10 sq.units. If
a = 3i + 2 j + k then b =
A) 2 i + 3 j + k B) i + j + 2k C) 3i + 3 j + k D) 3i + k
48. If A(1,2,3), B(2,3,1), C(3,1,2) then the length of the altitude through C is
A) 3 B) 3 3 C) 3 2 D) 3 / 2
r
49. If a = i + j, b = 2 j − k & r  a = b  a , r  b = a  b , then =
|r|
1 1
A) ( i − 3 j + k) B) ( i − j + k)
11 13

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 1 1
C) ( i + 3 j − k) D) ( i + j − k)
11 13
50. Forces 2 i + 7 j,2 i − 5 j + 6k, − i + 2 j − k act at a point P whose position vector is
4 i − 3 j − 2k . The vector moment of resultant of three forces acting at P about the point
Q, whose position vector is 6 i + j − 3k
A) 24 i + 13 j + 4k B) −24 i − 13 j + 4k
C) −24 i + 13 j + 4k D) −24 i − 13 j − 4k
51. If AB = 2 i − 3 j + k,CB = i + j + k , CD = 4 i − 7 j then AD =
A) 5 i + 11 j − k B) 5 i − 11 j C) 5 i + 11 j D) −5 i + 11 j
52. The unit vector in the opposite direction of the vector a = −6 i + 3 j − 2k is
1 1
A) (−6 i + 3 j − 2k) B) (6 i − 3 j − 2k)
7 7
1 1
C) (6 i − 3 j + 2k) D) (−6 i + 3 j + 2k)
7 7
53. Let ABC be a triangle and let D, E be the midpoints of the sides AB, AC respectively,
then BE + DC =
1 3 3
A) BC B) BC C) BC D) BC
2 2 4
54. If C is the mid point of AB and P is any point out side AB then
A) PA + PB + 2PC = 0 B) PA + PB + PC = 0
C) PA + PB = 2PC D) PA + PB = PC
55. The unit vector in the direction of 2 i + 3 j + k is
1 1
A)  (2 i + 3 j + k) B) − (2 i + 3 j + k)
14 14
1
C) (2 i + 3 j + k) D) 14(2 i + 3 j + k)
14
56. The three points A,B,C having position vectors (1, x, 3),(3,4,7) and (y,-2,-5) are
collinear then (x, y)
A) (2,-3) B) (-2,3) C) (-2,-3) D) (2,3)
57. Let a = i + j, b = j + k and c = a + b . If the vectors i − 2 j + k , 3i + 2 j − k and c

are coplanar then =

A) 1 B) 2 C) 3 D) -3
58. The non zero vectors a, b and c are related by a = 8b and c = −7b angle between a
and c is
 
A) B) C)  D) 0
4 2
1
59. If e = li + m j + nk is a unit vector and = , then maximum value of mn is
3
4 8 3
A)1 B) C) D)
27 27 2

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 60. The vectors AB = 3i + 4k and AC = 5i − 2 j + 4k are the sides of a triangle ABC. The
length of the median through A is
A) 72 B) 33 C) 288 D) 18
61. The orthogonal projection of a = 2i + 3j + 3k on b = i − 2 j + k (where i  j  k are unit
vectors along three mutually perpendicular directions) is
−i + 2j − k −i + 2 j − k
A) B) C) i − 2 j + k D) − i + 2 j − k
6 6
62. If  is acute angle and the vector (sin )i + (cos ) j is perpendicular to the
vector i − 3 j then  =
   
A) B) C) D)
6 5 4 3
63. If | a |= 3,| b |= 4 and | a − b |= 5 then | a + b |=
A) 6 B) 5 C) 4 D) 3
64. If a and b are unit vectors and  is the angle between them, then a-b will be a unit vector
if  =
   
A) B) C) D)
4 3 6 2
65. A particle is acted upon by constant forces 4 i + j − 3k and 3i + j − k which displace
it from a point i + 2 j + 3k to the point 5i + 4 j + k . The work done in standard units
by the forces is given by
A) 40 B) 30 C) 25 D) 15
66. The vector component of a = 2 i + 3 j + 2k perpendicular to the direction of
b = i + 2 j + k is
1 1 1 1
A) ( i + j + k) B) ( i − j + k) C) ( i + j − k) D) (− i + j − k)
3 3 3 3
67. If a, b, c are unit vectors such that a + b + c = 0 then a  b + b  c + c  a =
A) 3 / 2 B) −3 / 2 C) 2[abc] D) 0
68. If | a + b |= 1,| a − b |= 7,| a |= 4 , then | b |=
A) 1 B) 2 C) 3 D) 5
69. If the position vectors of A,B and C are respectively 2 i − j + k
i − 3 j − 5k and 3i − 4 j − 4k then cos2 A =
6 35
A) 0 B) C) D) 1
41 41
70. The perpendicular distance from origin to the plane 3x − 4y − 5z = 3 is
3 3 3
A) B) 3 C) D)
5 4 2 5 2
71. The approximate value of 1.02 is
A) 1.01 B) 1.001 C) 1.0001 D) 1.1001
72. A circular plate expands when heated from a radius of 5 cms to 5.06 cm then the
percentage increase in its area is

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 A) 0.6 B) 1.2 C) 2.4 D) 0.12
73. A particle moves in a straight line according to the law v = 4a(xsin x + cos x) where v
2

is the velocity of a particle at a distance x from the fixed point then the acceleration is
A) 2axsin x B) ax sin x C) axcos x D) 2ax cos x
74. For the curve x = t − 1, y = t − t , the tangent is perpendicular to x-axis then
2 2

1 1
A) t=0 B) t = C) t=1 D) t =
2 3
75. The slope of the tangent at (1,6) on the curve 2x + 3y = 5 is
2 2

−1 1
A) -9 B) C) D) 9
9 9
76. The tangent at A(2,4) on the curve y = x 3 − 2x 2 + 4 cuts the x-axis at T then the length
of AT =
A) 10 B) 12 C) 15 D) 17
77. The critical point of f ( x ) = 2 x + 7 at x=
−7
A) 0 B) 7 C) D) -7
2
78. The maximum value of f (x) = 2x 3 − 21x 2 + 36x + 20 in 0  x  2 is
A) 37 B) 44 C) 32 D) 30
79. x and y are two +ve numbers suchs that xy =1. Then the minimum value of x+y is
1 1
A) 4 B) C) D) 2
4 2
80. The length of diagonal of the rectangle of maximum area having perimeter 100 cm is
A) 10 2 B) 10 C) 25 2 D) 15

PHYSICS Max Marks: 40

(SINGLE CORRECT ANSWER TYPE)
This section contains 40 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +1 for correct answer, 0 if not attempted and 0 if not correct.
81. 1kg of diatomic gas is at a pressure of 8  104 N / m2 . The density of the gas is 4 kg / m3
. The energy of the gas due to its thermal motion is
A) 5  104 J B) 6 104 J C) 9  104 J D) 4  104 J
82. A cylinder of fixed capacity 22.4 litres contains helium gas at standard temperature and
pressure. What is the amount of heat needed to raise the temperature of the gas in the
cylinder by 30o C ? ( R = 8.31 J mol−1 K −1 )
A) 376.5 J B) 377.5 J C) 374.5 J D) 372.5 J
83. Gas at a pressure P0 is contained in a vessel. If the masses of all the molecules are halved
and their speeds are doubled, the resulting pressure P will be equal to
p
A) 4P0 B) 2P0 C) p 0 D) 0
2
84. If number of molecules of H 2 are double than that of O 2 , then ratio of kinetic energy
of hydrogen to that of oxygen at 300 K is

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 A) 1: 1 B) 1: 2 C) 2: 1 D) 1: 16
85. The total kinetic energy of 8 litres of helium molecules at 5 atmosphere pressure will be
(1 atmosphere = 1.013  105 pascal )
A) 607 J B) 6078 J C) 607 erg D) 6078 erg
86. At a certain temperature, the 'rms' velocity for O 2 is 400 m / sec . At the same
temperature, the 'rms' velocity for H 2 molecules will be
A) 100 m / s B) 25 m / s C) 1600 m / s D) 6400 m / s
87. At a pressure of 24 10 dyne /cm , the volume of O 2 is 10 litre and mass is 20 gm.
5 2

The 'rms' velocity will be (in m / sec )

A) 800 B) 400 C) 600 D) 200
88. The respective speeds of five molecules are 2, 1.5,1.6,1.6 and 1.2 km / sec . The most
probable speed in km / sec will be
A) 2 B) 1.58 C) 1.6 D) 1.31

89. The root mean square velocity of gas molecules at 0 C will be if at N.T.P. its density is
1.43 Kg / m3
A) 461m / s B) 164 m / s C) 461cm / s D) 164 cm / s
90. The mass of an oxygen molecule is about 16 times that of a hydrogen molecule. At room
temperature the 'rms' speed of oxygen molecules is v. The 'rms' speed of the hydrogen
molecules at the same temperature will be
A) v / 16 B) v / 4 C) 4v D) 16 v
91. The average degrees of freedom per molecule for a gas is 6. The gas performs 25 J of
work when it expands at constant pressure. The heat absorbed by gas is
A) 75 J B) 100 J C) 150 J D) 125 J
92. The mass 15 gram of Nitrogen is enclosed in a vessel at 300 K. What heat must be
supplied to it to double the 'rms' velocity of its molecules
A) 10 J B) 10 KJ C) 103 J D) 102 J
93. Determine the gas temperature at which the root mean square velocity of hydrogen
molecules exceeds their most probable velocity by 400 m / s
A) 384 K B) 342 K C) 300 K D) 280 K
94. The pressure of an ideal gas varies according to the law P = P0 − AV 2 where P0 and A
are positive constants. What is the highest temperature that can be attained by the gas?
P P0 P P0 2P P0 2P0 P0
A) 0 B) 0 C) 0 D)
nR A nR 2A nR 2A 3nR 3A
95. Temperature of 1 mole of an ideal gas is increased from 300 K to 310 K under isochoric
process. Heat supplied to the gas in this process is Q = 25R , where R= universal gas
constant. What amount of work has to be done by the gas if temperature of the gas
decreases from 310 K to 300 K adiabatically?
A) 25 R B) 20 R C) 27 R D) 28 R
96. When a system is taken from state i to state f along the path iaf, it is found that Q = 50cal
and W = 20cal . Along the path' ibf W = 36 cal. W along the path ibf is

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 A) 6 cal B) 8 cal C) 10 cal D) 9 cal
 
97. 100 g of water is heated from 30 C to 50 C ignoring slight expansion of the water, the
change in its internal energy is (specific heat of water is 4180J / Kg / K )
A) 8.4 KJ A) 8.2 KJ C) A) 8.1 KJ D) A) 8.6 KJ
98. When 5 moles of an ideal gas is compressed isothermally, its volume decreases from 5
litre to 1 litre. If the gas is at 27 C , find the work done on the gas
A) −2.007 104 J B) −3.007 104 J C) −5.007 104 J D) −4.007 104 J
99. The differential form of first law of thermodynamics is -
A) Q = W + U B) Q = W − U C) Q = U − W D) Q + U + W = 0
100. For an ideal gas graph is shown for three processes. Processes 1, 2, and 3 are respectively
work done (magnitude)

A) Isochoric, isobaric, adiabatic B) Isochoric, adiabatic, isobaric

C) isobaric, adiabatic, isochoric D) Adiabatic, isobaric, isochoric
101. A gas is expanded from volume V0 to 2V0 under three different processes. Process 1 is
isobaric, process 2 is isothermal and process 3 is isothermal and process 3 is adiabatic.
Let U1 , U 2 and U 3 be the change in internal energy of the gas in these three
processes. Then –

A) U1  U 2  U3 B) U1  U 2  U3

C) U 2  U1  U 3 D) U 2  U3  U1
102. Two spheres A and B with masses in the ratio 2: 3 and specific heat 2: 3 fall freely from
rest. If the rise in their temperatures on reaching the ground are in the ratio 1: 2 the ratio
of their heights of fall is
A) 3: 1 B) 1: 3 C) 4: 3 D) 3: 4

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 103. A 50 kg man is running at a speed of 18kmh −1 If all the kinetic energy of the man can
be used to increase the temperature of water from 20 C to 30 C , how much water can
be heated with this energy?
A) 15 g B) 20 g C) 30 g D) 40 g
104. Find the external work done by the system in kcal, when 20 kcal of heat is supplied to
the system and the increase in the internal energy is 8400 J( J = 4200 J / kcal) ?
A) 16 kcal B) 18 kcal C) 20 kcal D) 19 kcal
105. Air expands from 5 litres to 10 litres at 2 atm pressure. External workdone is
A) 10 J B) 1000 J C) 3000 J D) 300 J
106. Heat given to a system is 35 joules and work done by the system is 15 joules. The change
in the internal energy of the system will be
A) -50 J B) 20 J C) 30 J D) 50 J
107. The temperature of 5 moles of a gas at constant volume is changed from 100 C to 120 C
. The change in internal energy is 80 J. The total heat capacity of the gas at constant
volume will be in joule/kelvin is
A) 8 B) 4 C) 0.8 D) 0.4
108. For a gas, the difference between the two specific heats is 4150 J Kg −1 K −1 and the ratio
of specific heats is 1.4 . What is the specific heat of the gas at constant volume in J
Kg −1 K −1 ?
A)8475 B) 5186 C) 1660 D) 10375
109. The specific heat of air at constant pressure is 1.005 kJ / kgK and the specific heat of air
at constant volume is 0.718 kJ / kg K . Find the specific gas constant.
A) 0.287 kJ / kg K B) 0.21kJ / kg K C) 0.34 kJ / kg K D) 0.19 kJ / kg K
110. One mole of an ideal gas undergoes an isothermal change at temperature ' T ' so that its
volume V is doubled. R is the molar gas constant. Work done by the gas during this
change is
A) RT log 4 B) RTlog 2 C) RT log1 D) RT log3
111. The isothermal Bulk modulus of an ideal gas at pressure ' P ' is
A) P B) P C) P / 2 D) P / 
112. The efficiency of a heat engine if the temperature of source 227 C and that of sink is
27 C nearly
A) 0.4 B) 0.5 C) 0.6 D) 0.7
113. A block of ice falls from certain height and completely melts. If only 3 / 4 th of the
energy is absorbed by the block, the height of the fall should be ( L = 363 SI units and
g = 10 ms−2 )
A) 48.4 m B) 84.4 m C) 88.4 m D) 44.8 m
114. When 20J of work was done on a gas, 40J of heat energy was released. If the initial
internal energy of the gas was 70J, what is the final internal energy?
A) 50 J B) 60 J C) 90 J D) 110 J
115. For hydrogen gas Cp − Cv = a and for Oxygen gas Cp − Cv = b , where C p and C v are
molar specific heats. Then the relation between ' a ' and 'b' is
A) a = 16b B) b = 16a C) a = 4b D) a = b

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 116. The H calories of heat is required to increase temperature of one mole of monoatomic
gas from 20 C to 30 C at constant volume. The quantity of heat required to increase
the temperature of 2 moles of a diatomic gas from 20 C to 25 C at constant volume is
4H 5H 7H
A) B) C) 2 H D)
3 3 3
3
117. The volume of 1 kg of hydrogen gas at N.T.P. is 11.2 m . Specific heat of hydrogen at
constant volume is 100.46J kg −1 K −1 . Find the specific heat at constant pressure in
J kg −1 K −1 ?
A) 120.2 B) 142.2 C) 163.4 D) 182.3

118. 3 moles of a monoatomic gas require 60 cal heat for 5 C rise of temperature at constant
volume, then heat required for 5 moles of same gas under constant pressure for 10 C
rise of temperature is (R = 2cal / mole − k)
A) 200 cal B) 400 cal C) 100 cal D) 300 cal
119. One mole of oxygen is heated at constant pressure starting at 0 C . The heat energy that
must be supplied to the gas to double its volume (R is the molar gas constant) is
A) 2.5  273  R B) 3.5  273  R C) 2.5  546  R D) 3.5  546  R
120. The triatomic gas is heated isothermally. What percentage of the heat energy is used to
increase the internal energy?
A) 0 % B) 14 % C) 60 % D) 100 %
CHEMISTRY Max Marks: 40
(SINGLE CORRECT ANSWER TYPE)
This section contains 40 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +1 for correct answer, 0 if not attempted and 0 if not correct.

121. Which pair of names refers to the same compound?

A) Ethyne and Acetylene B) Ethyne and Ethene
C) Ethane and Acetylene D) Ethane and Ethene
122. The structure shown

A) 1o , 2o and 3o Carbon atoms B) 1o and 2o Carbon atoms only

C) 1o and 3o Carbon atoms only D) 2o and 3o Carbon atoms only
123. Which of the following name will be incorrect?

A) B)

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 C) D)
124. The IUPAC name of the following compound is

A) n-propyl ethanoate B) ethyl propanoate

C) pentanoic anhydride D) n-propyl propanoate
125. What is the IUPAC name of the following compound ?

A) o-nitro-m-bromo toluene B) 3-bromo-6-nitro toluene

C) m-bromo-o-nitro toluene D) 5-bromo-2-nitro toluene
126. How many dibromobenzenes are possible?
A) 1 B) 2 C) 3 D) 4
127. Which of the following compound will not show tautomerism ?

A) B)

C) D)
128. Total number of stereoisomers for 2,3-dichlorobutane is:
A) 3 B) 4 C) 5 D) 6

129.

Above Gauche form is stable when Z is

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 A) -F B) -OH C) −OCH3 D) All of these
130. Determine the double bond stereochemistry (E or Z ) for the following
molecules.

A) A: E ; B: E B) A: Z ; B: Z C) A: E ; B: Z D) A: Z ; B: E

131.

Inductive effect of chlorine is minimum on:

A) C1 B) C 2 C) C 3 D) C 4
132. Select the molecule in which  bonds are conjugated?
A)

B)

C)

D) Both A and C

133. Number of  - hydrogens in given compound is

A) 4 B) 5 C) 6 D) 7
134. Which of the following cations is aromatic?

A) b, d B) d C) a, b, d D) b, c, d

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 135. Which of the following aniline derivatives is the strongest base?

A) B)

C) D)
− −
136. C6H13Br + OH → C6H13OH + Br . This reaction is an example of:
A) nucleophilic addition B) nucleophilic substitution
C) electrophilic addition D) electrophilic substitution
137. Which among the following purification methods is based on the principle of
"Solubility" in two different solvents?
A) Column Chromatography B) Sublimation
C) Distillation D) Differential Extraction
138. For the estimation of nitrogen, 1.4 g of an organic compound was digested by Kjeldahl
M
method and the evolved ammonia was absorbed in 60 mL of sulphuric acid. The
10
M
unreacted acid required 20 mL of sodium hydroxide for complete neutralization.
10
The percentage of nitrogen in the compound is:
A) 6 % B) 10% C) 3% D) 5%
139. Match the List-I and List-II
List I List II
(Element detected) (Reagent used/Product formed)
P) Nitrogen I. Na 2  Fe(CN)5 NO
Q) Sulphur II. AgNO3
R) Phosphorous III. Fe 4  Fe(CN)6 3
S) Halogen IV. ( NH 4 )2 MoO 4
Choose the correct answer from the options given below:
A) P-II, Q-IV, R-I, S-III B) P-IV, Q-II, R-I, S-III
C) P-II, Q-I, R-IV, S-III D) P-III, Q-I, R-IV, S-II
140. In Carius method of estimation of halogen, 0.45 g of an organic compound gave 0.36 g
of AgBr . Find out the percentage of bromine in the compound.
(Molar masses: AgBr = 188 g mol−1 : Br = 80 g mol−1 )
A) 34.04 % B) 40.04 % C) 36.03 % D) 38.04 %
141. CH3MgBr + D2O → (A) ; Product (A) of the reaction is:
A) CH 4 B) CH 3D C) CH 2 D2 D) CHD3

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 142. Which of the following alkane will be formed in high yield by Wurtz reaction?

A) B)

C) D)
143. Which of the following reactions is a termination step in the free radical chlorination of
methane?
A) Cl2 + Cl• → Cl • +Cl2 B) Cl2 → 2Cl •
C) •CH3 + Cl• → CH3Cl D) CH 4 + Cl• → HCl + •CH3
144. How many products will formed in the following reaction?
CH3 − Cl + CH3 − CH2 − Cl ⎯⎯⎯⎯ Na
dry ether
→
A) 1 B) 2 C) 3 D) 4
145. How many products are formed from the monochlorination of ethylcyclohexane? Ignore
stereoisomers?

A) 6 B) 8 C) 5 D) 9

146. products. Value of X is:

A) 0 B) 1 C) 2 D) 3
147. Which of the following is the MOST stable carbocation?

A) B)

C) D)
148. Indicate the product resulting from the hydrogenation (excess H 2 / Pd ) of 2-hexyne.
A) (Z)-2-hexene B) (E)-2-hexene C) hexane D) 1-hexene
149. Which of the alkyl chlorides listed below undergoes dehydrohalogenation in the
presence of a strong base to give 2 -pentene as the only alkene product?
A) 1-chloro pentane B) 2-chloro pentane
C) 3-chloro pentane D) 1-chloro-2-methyl butane

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 150. Product (A) is

A) B)

C) D)
151. When iodoform is heated with silver powder, it forms:
A) acetylene B) ethylene C) methane D) ethane
152. The correct order for acid strength of compounds
CH  CH,CH3 − C  CH and CH 2 = CH 2 is as follows:
A) CH  CH  CH 2 = CH 2  CH3 − C  CH
B) CH3 − C  CH  CH  CH  CH 2 = CH 2
C) CH3 − C  CH  CH 2 = CH 2  HC  CH
D) HC  CH  CH3 − C  CH  CH 2 = CH 2
153. The hydration of propyne results in formation of
A) Acetone B) Propanol-1 C) Propene D) Propanal
154. The incorrect statement regarding ethyne is
A) The C − C bonds in ethyne is shorter than that in ethene
B) Both carbons are sp hybridised
C) Ethyne is linear
D) The carbon-carbon bonds in ethyne is weaker than that in ethene
155. Which one of the following has minimum boiling point?
A) 1 -Butene B) 1 – Butyne C) n-Butane D) Isobutane
156. Predict the major product of the following reaction.

A) o-bromonitrobenzene and p-bromonitrobenzene

B) m-bromonitrobenzene
C) o-bromoaniline and p-bromoaniline
D) m-bromoaniline

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 157.

Product (B) is:

A) Ph − D B) Ph − O − D C) Ph − H D) Ph − OH
158. Which of the compound will not undergo Friedel Craft reaction?

A) B)

C) D)
159. The compound X in the reaction,

A) B)

C) D)
160. In electrophilic aromatic substitution (EAS) reactions a chlorine
substituent:
A) is a deactivator and a m-director
B) is a deactivator and an o, p-director
C) is an activator and a m-director
D) is an activator and an o, p-director

***** ALL THE BEST *****

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 JR MPC ALL EAMCET-_KEY SHEET

DATE: 30-12-2024

MATHS KEY:
1) C 2) D 3) B 4) A 5) A 6) B 7) B 8) C 9) A 10) C

11) A 12) B 13) A 14) D 15) C 16) A 17) D 18) C 19) C 20) C

21) C 22) B 23) B 24) C 25) D 26) D 27) D 28) B 29) C 30) D

31) A 32) C 33) D 34) C 35) D 36) A 37) C 38) C 39) D 40) C

41) C 42) C 43) A 44) A 45) D 46) D 47) D 48) D 49) C 50) C

51) B 52) C 53) C 54) C 55) C 56) A 57) D 58) C 59) B 60) B

61) A 62) D 63) B 64) B 65) A 66) B 67) B 68) C 69) C 70) D

71) A 72) C 73) D 74) A 75) B 76) D 77) C 78) A 79) D 80) C

PHYSICS KEY:

81) A 82) C 83) B 84) A 85) B 86) C 87) C 88) C 89) A 90) C

91) B 92) B 93) A 94) D 95) A 96) A 97) A 98) A 99) A 100) A

101) A 102) B 103) A 104) B 105) B 106) B 107) B 108) D 109) A 110) B

111) A 112) A 113) A 114) A 115) D 116) B 117) B 118) D 119) B 120) A

CHEMISTRY KEY:

121) A 122) A 123) C 124) D 125) D 126) C 127) D 128) A 129) D 130) D
131) D 132) C 133) C 134) C 135) B 136) B 137) D 138) B 139) D 140) A
141) B 142) A 143) C 144) C 145) A 146) B 147) D 148) C 149) C 150) D
151) A 152) D 153) A 154) D 155) D 156) B 157) A 158) C 159) B 160) B

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 121)

122)

123)

124)

125)

126)

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 127)

128)

129)

130)

131)

132)

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 133)

134)

135)

136) Nucleophilic substitution

137)

138)

139) Conceptual
140)

141)

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 142)

143)

144)

145)

146)

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 147)

148)

149)

150)

151)

152)

153)

154)

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 155)

156)

157)

158)

159)
160)

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