TARGET-1000(JEE ADV-2025)_CHEMISTRY_Spl Assignment
METALLURGY
MULTIPLE ANSWER CORRECT TYPE
1. Auto reduction process is used in the extraction of (A) Cu (B) Hg (C)Al (D) Fe
2. Which of the following reduction reactions are actually employed in commerical extraction of
metals?
3. Hg and Pb are comercially extracted from their respective sulphide ores by Pyrometallurgy whereas
Pyrometallurgyis not applied in the extraction ofAg fromAg2S because
(A) Roasting of PbS is thermodynamicallyfeasible below its melting point
(B) Roasting ofAg2S is not thermodynamicallyfeasible
(C) Roasting of HgS is feasible at low temperature
(D) Gf ofAg2O becomes positive on normal heating
4. In the extraction of respective metal correct match is/are
Metals Process
(A) Pb Pattinson's Process
(B) Cu Bessemerisation
(C) Ag pyrometallurgy
(D) Zn Carbon Reduction
5. Assertion: Magnesia and quick lime (CaO) are used as basic refractory material.
Reason: MgO and CaO can withstand very high temperatures
6. Assertion: In smelting, roasted ore is heated with powdered coke in presence of a flux.
Reason: Metal oxides are reduced to metals by C or CO and impurities are removed as slag.
1|Page
Paragraph 7 & 8
7. How many moles of Ni(CO)4 could be obtained from the CO produced by the reaction of 75.0 g of
carbon? (Assume 100% reaction and 100% recovery in both steps.)
(A) 6.25 (B) 1.563 (C) 3.125 (D) 25.0
8. Formation of volatile Ni(CO)4 and its subsequent heating gives pure Ni, process is called:
(A) Hall's Process (B) Dow's Process (C) Serpeck 's Process (D) Mond's Process
Match the column
9.
10.
Integer Type
QR
11. Consider following ORES and calculate the value of expression
P S
2|Page
where, P= Number of ores from which metal is commerciallyextracted byHydrometallurgy.
Q = Number of ores from which metal is commerciallyextracted by Self reduction.
R = Number of ores from which metal is commercially extracted byCarbon reduction.
S = Number of ores from which metal is commerciallyextracted byElectrolytic reduction.
12. How manyof the following metals is extracted byself reduction process?
Pb, Au, Mg, Sn, Fe, Al, Ag, Hg, Na, Zn, Cu, Ca
13. For how manymetals carbon reduction method is/are mainlyapplicable.
Sn, Al, Cr, Mn, Pb, Ca, Na, Z
14. In order to concentrate galena (which contains ZnS as impurity) by froth-floatation process, sodium
cyanide is used as depressant. NaCN dissolves ZnS due to formation of water soluble complex(A).
Find the value of w + x + y + z.
where w = coordination number of central metal ion in complex ion of (A)
x = number of unpaired electrons in (A).
y = total number of possible linkage isomers of (A) including (A).
z = maximumnumber of atoms in a single plane in the complex ion of (A)
15. In how manyfollowing ores, during the extraction of metal roasting process is carrying out. Galena,
Chalcopyrite, Casseterite, Haematite, Bauxite, Carnalite
1) AB 2) BC 3) ABCD 4) ABD 5) A 6) A 7) B 8) D 9) (A) PR 10) (A) Q
(B) PR (B) R
(C) Q (C) S
(D) ST (D) P
11) 3 12) 3 13) 3 14) 14 15) 4
3|Page