Sec: SR.

IIT _*CO-SC(MODEL-A) Date: 09-02-25

Time: 3 Hrs Max. Marks: 180
09-02-25_SR.IIT_STAR CO-SC(MODEL-A)_JEE ADV_GTA-6(P-1)_SYLLABUS

MATHEMATICS: TOTAL SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP

TIME:3hrs IMPORTANT INSTRUCTIONS Max Marks: 180

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
Questions with Comprehension Type With
Sec – II (Q.N : 5 – 10) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Multiple Correct Choice
Sec – III (Q.N : 11 – 16) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – IV (Q.N : 17 – 19) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 20 – 23) Questions with Single Correct Options +3 -1 4 12
Questions with Comprehension Type With
Sec – II (Q.N : 24 – 29) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Multiple Correct Choice
Sec – III (Q.N : 30 – 35) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – IV (Q.N : 36 – 38) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 39 – 42) Questions with Single Correct Options +3 -1 4 12
Questions with Comprehension Type With
Sec – II (Q.N : 43 – 48) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Multiple Correct Choice
Sec – III (Q.N : 49 – 54) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – IV (Q.N : 55 – 57) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
MATHEMATICS MAX.MARKS: 60
SECTION – 1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
n
sin kx
1. For non-negative integers n, define the function h n  x  as h n  x    , where
k 1 k  cos kx
x     2m  1 , m   . Let h 'n  x  denote the derivative of h n  x  . Which of the
following statement is INCORRECT?

A) There exists    0, 2  such that h 'n     0 , for all n  1

 2
B) h 3   
2 3

C) for all n,h n  x  is an odd function

2
D) h n  x  periodic with period .
n 1

1
2. If the area of region    x, y      : 0  x  2;0  y  1 and  xy  1 is  square
3
unit. Then  is equal to

2 2 1 3 3
A)  ln2  ln3 B)  ln2  3ln3
3 3 3 2 2

2 2 1
C)  ln2  ln3 D) none of these.
3 3 3

Cn  2  x 2 
n n
C1 2 n  2
n n
C2 2 n 4
3. n
C0 x 
2n
x 2  x  
2
x  2  x   .... 
2 2

2 3  n  1
2n  x 2 n  2 2n  x 2 n
A) B)
 n  1  2  x 2   n  1  2  x 2 
2n 1  x 2 n  2 2n 1  x 2 n
C) D)
 n  1  2  x 2   n  1  2  x 2 
SR.IIT_*CO-SC Page. No. 3
Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
4. Let a 1 ,a 2 ,a 3 ,...........,a n be real numbers different from 1 and let n be a natural number
such that

a 12 a 22 a 32 a 2n
a 1  a 2  a 3  .............  a n  1000 and
2 2 2 2
   ........   100 . Let
1  a1 1  a 2 1  a 3 1 an

a13 a 32 a 33 a 3n
S    .........  . Then the number of ways in which S can be
a1  1 a 2  1 a 3  1 an 1
expressed as a product of two integers is

A) 15 B) 18 C) 28 D) 36

SECTION - 2 (Maximum Marks : 12)

This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 5 and 6:
Suppose f(x) is a function satisfying the following conditions:

1 13
(i) f  0   ,f  3   ;
2 4

(ii) f(x) has a maximum value at x = -1;

2px 2px  1 2px  q  1

(iii) f '  x   q2 q 1 1 . If p1  f 1 and range of f(x) as
2px  q  3 2px  q  1 2px  q  2

 , p  ,then
2

5. p1 is equal to

6. p 2 is equal to

Question Stem for Question Nos. 7 and 8:

f ,g : R  R are functions such that

 x   x 
f  x   3x  sin   ,g  x   x 3  2x  sin  
 2   2 
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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
 d 1 1  2
7. The value of 
 dx
 
f  g  x    is equal to
 x 12 3k
then k is equal to

8. The area bounded by y  f 1  x  , y  g 1  x  is

Question Stem for Question Nos. 9 and 10:

Let ,  be real numbers such that the system of linear equations

xyz2

x  2y  3z  5

x  3y  z  

has infinitely many solutions. Let M represent the determinant of the matrix

 2 3   sin   2 

M  1 sin   2  
 
  2sin   1  sin   2  2  

Where   R,   0, 2 and minimum value of determinant of M is 8 and foot of

perpendicular from the point P    4,   10,1 to the plane x  2y  2z  10  0 is

F  a,b,c  , then


9. The value of is ___________________.
5

3
10. The value of  a  b  c  is ___________.
2

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
11. Consider the equation 3 x  x  30 x  10 x 2  3 x 3  1  0 then
7 4 5


A) The minimum real root of equation is  3  2 
B) The minimum real root of equation is   3  2 

C) The maximum real root of equation is  3  2 

D) The number of positive roots of equation is 3

12. For all real values continuous, differential and strictly increasing function f on the real
x

line for all x satisfy the condition f  x     f  t     f '  t    dt  2025 . Then the area
2 2
2

0
 

f x
bounded by curve y  and lines x = 0 and y = e is/are
2025
 1
3 x2
A)  1  sin x  1  sin 2 x dx B) e2025   ex dx
3  0
2025 e
e
C)  In ydy D)  In  e  1  y  dy
1 1
13. Let f :  0, 2    be a differentiable function such that

f  x  cos t  f  t  cos x cos 2 x 1

lim  ; x  0, 2   . If f      , then which of the
t x
tx x2 
following statement(s) is/are TRUE?
 
A) f  x  has local minimum in the interval  ,  
2 
 
B) f  x  is increasing for x   0, 
 3
1

 x f ' x  dx  0
3
C)
1/2
1
7 1
D)   x 3f  x  dx 
30 0 3
14. The integers from 1 to 1000 are written in order around a circle. Starting at 1, every
fifteenth number is marked (i.e. 1, 16, 31, …..). This process is continued until a number
is reached which has already been marked, then marked numbers are

A) 11 B) 17 C) 986 D) 996
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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
15. Let a, b, c be distinct non zero complex numbers with a  b  c and each of the
equations az 2  bz  c  0 and bz 2  cz  a  0 has a root having modulus 1, then

A) b 2  ac B) c 2  ab

C) a  b  b  c  c  a D) a 2  bc

16. Consider the system of equations ax  by  0 and cx  dy  0 where a,b,c,d  1,2 .

Then the probability that the system of equations has

1 5
A) unique solution is B) unique solution is
2 8
3 1
C) non trivial solutions is D) non trivial solutions is
8 2
SECTION - 4 (Maximum Marks : 12)
This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
n 2  n 14

17. If the coefficient of x 2

in  x  1  x 2  2  x 3  3 x 4  4  .... x n  n  , n  30 is equal

 3k 
to k, then   is ? (where [.] is the greatest integer function)
4

18. Let f :    and g :    be given

f  x   X 2  3X  2  3 and g  x   x 3  3x 2  3x  1 define

max f  x  ,g  x  , x  1
h  x  as : h  x    .If   number of point(s) where h(x) is
 min f  x  ,g  x  , x  1

discontinuous and m = number of point(s) where h(x) is not differentiable. Then find
m

36 x 2  3x  2 dx ____


19. Number of integral values of x in the interval  0,5 which satisfy

cos 9 x  sin 9 x  5  sin 5 x  cos 5 x  is ______________

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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
PHYSICS MAX.MARKS: 60
SECTION – 1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
20. Two wires of same length l  1 m and same cross-sectional area A  10 mm 2 are welded
together and their ends are rigidly clamped between two walls as shown in the figure.

Given 1  2 105 C 1 , Y1  11010 N/m 2 , 1  0.4 kg/m

 2  1 105 C 1 , Y2  2  1010 N/m 2 , 2  0.1 kg/m

The tension in the wires is produced by reducing the temperature of system by 20°C.
Find the first overtone frequency (in Hz) of transverse vibration of the system with joint
'O' as a node.

A) 10 B) 20 C) 30 D) 40

21. The pitch of a screw gauge is 1 mm and its circular scale is divided into 100 divisions.
When nothing is placed between its studs, the zero of the circular scale lies 6 divisions
below the reference line, and the zero of main scale is visible. When a wire is placed
between its studs, the main scale reading is 2 mm and 56th division of circular scale
coincides with the reference line of the main scale. Find the radius of the wire in cm.

A) 0.250 cm B) 0.125 cm C) 0.256 cm D) 0.128 cm

22. Suppose a uniform steel ring (mass M and radius R) is kept on a smooth horizontal
surface with its plane horizontal. It is hinged about a point O on the perimeter & is made
to rotate in a horizontal plane as shown (A, B, & C are points on the ring). The angular
velocity  is constant in time. The tension developed in the ring at point B is:

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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP

1 2  1 2 
A) M  2 R   1 B) M  2 R   1
2   4  

1 1
C) M2R D) M2R
2 4

23. Two springs, each of unstretched length 20 cm but having different spring constants
K1  1000 N/m and K 2  3000 N/m are attached to two opposite faces of a block of mass

m  100 g kept on a smooth horizontal surface as shown in the figure. The outer ends of

the two springs are now attached to two pins P1 & P2 whose locations are shown in the
figure, as a result of this, the block acquires a new equilibrium position. The block has
been displaced by small amount from its equilibrium position and released to perform
simple harmonic motion, then

A) new equilibrium position is at 35 cm from P1 and time period of simple harmonic


motion is sec.
100
B) new equilibrium position is at 25 cm from P1 and time period of simple harmonic

motion is sec.
100
C) new equilibrium position is at 35 cm from P1 and time period of simple harmonic

motion is sec.
200
D) new equilibrium position is at 30 cm from P1 and time period of simple harmonic

motion is sec.
200
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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
SECTION - 2 (Maximum Marks : 12)
This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 24 and 25:
A bulb (purely resistive of resistance 100 ) is connected in a circuit using a DC battery
of 12 V as shown:

The inductor has an inductance of 0.5 mH & resistance of 100 . Based on this, answer
the following two questions

24. The magnitude of rate of change of current in the inductor, just after closing the switch
measured in kA/s is___:

25. The bulb stops glowing if current passing through it becomes any less than 50 mA. Then
for what time interval (in  s), after closing the switch, will the bulb glow for?
(Take ln 2  0.69 )

Question Stem for Question Nos. 26 and 27:

A conducting rod of mass 'm' and length 'l' is placed on a pair of smooth horizontal
conducting parallel rails connected at one end by an inductor of inductance L and by a
capacitor of capacitance 'C' at the other end as shown in the figure. A uniform vertical
magnetic field 'B' exists in the region perpendicular to the plane of rails. The conductor
starts from rest at t  0 from the left end of the rails due to constant external horizontal
force F  2mg applied to it. Considering CB 2l 2  m , choose the CORRECT option(s):

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The maximum horizontal displacement of the rod is x  2 2  . Find the value of x .

mgL
26.
B l 

Bl
27. The angular frequency of the oscillations of the rod is . Find the value of y .
y  mL 

Question Stem for Question Nos. 28 and 29:

Two uncharged thin concentric spherical conducting shells 'A' and 'B' of radii R and 3R
are connected through a resistance 'r' and switch 'S' initially opened as shown in the
figure. A positive point charge 'Q' is fixed at a distance 2R from the centre of the shells.

At t  0 , the switch 'S' is closed till the steady state is reached. The charge on the outer
surface of shell 'A' after steady state reached is  xQ . The charge on the inner surface of
shell ‘B’ after steady state is reached is  yQ

28. Find value of x .

29. Find value of y .

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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
30. The magnitude of angular momentum, kinetic energy, velocity and frequency of an
electron in a hydrogen atom corresponding to the quantum number n are L, K, V and f
respectively. Then according to Bohr's theory of hydrogen atom:
A) K 1Lf is constant for all orbits. B) Kvf 1 is constant for all orbits.
1
C) K 1 Lv is proportional to n 2 . D) K 1 f is proportional to .
n
31. A small sphere is charged uniformly and placed at some point A( x0 , y0 ) so that at point

B (9m, 4m) electric field strength is E  (54iˆ  72 ˆj ) NC 1 and potential is 1800 V. Then
A) The magnitude of charge on the sphere is 4  C
B) The magnitude of charge on the sphere is 2  C
C) Coordinates of A are: x0  3 , y0  12
D) Coordinates of A are x0  4 , y0  1
32. Figure shows cross-sectional view of a long solid cylinder of radius 'R'. Current 'I' flows
 
along outward direction along length of cylinder. Then, find possible value(s) of 
BA
B.dl

along BA.
Given: OB = ( 3  1)R , OA  2R , OBA  45 . Where 'O' is point of axis of cylinder.

0 I 0 I 0 I 7  0 I
A) B)  C) D)
6 6 6 12

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33. Figure shows cross-sectional view of solid semi cylinder of radius 'r' rigidly attached
with solid triangular prism. It floats on a liquid having density 'p'. It is in contact with
smooth vertical wall. Part BC is not in contact with liquid and the part AB is entirely
inside the liquid.

The length of object is 'l'. Given (AC = CD = DA). The atmospheric pressure is P0 .

A) Buoyant force acting on object is independent of atmospheric pressure.

pgr 2l
B) Normal force exerted by vertical wall is .
2

C) The force exerted by liquid on slant surfaces ADC of prism is Po  2rl    2  3  r 2 plg .


D) Weight of object is  3   r 2l  g .
 2

34. A uniform wire of mass m, length L and cross-sectional area 'A', made of a material of
Young's modulus Y, is pulled by a constant force F on an inclined plane such that it
moves up the inclined plane as shown in figure.

Choose the CORRECT option(s).

Fl
A) The extension in the wire is
2YA
L F
B) The tension in the rod at a distance from the lower end of the rod is
4 4
1 F 2L
C) The elongation potential energy (elastic) in the rod is
6 YA
1 F 2L
D) The elongation potential energy (elastic) in the rod is
4 YA
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35. Potential energy of a system is given by U ( x)  ( x  1)( x  2) . Then:

3
A) Point x   corresponds to equilibrium position of the system.
2

B) Point x  1 and x  2 corresponds to equilibrium position of the system.

3
C) System is in stable equilibrium position at x   .
2

3
D) System is in unstable equilibrium position at x   .
2

SECTION - 4 (Maximum Marks : 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
36. The surface mass density (mass per unit area) of a semi circular disc of radius 'R' varies
 
as  |   r | , where  is a constant vector along positive x-axis and r is positive vector
with respect to origin. It is kept on smooth horizontal surface with flat surface in contact
with surface. Now, force 'F' is applied in such a way that it moves translationally without
K R
any rotation. The value of h is , then find value of k.
16

37. There is spherical symmetric charge distribution around origin. The electrostatic
1
potential at a distance 'r' from origin is given as V  e  Kr , where K is a positive
4

constant. The charge present in a spherical volume of radius r is given as  x   r  y  K  o e Kr .

Find the value of  x  y  .
38. A uniform horizontal rod of length L and mass m is placed with its two ends on two
supports A and B. The rod breaks suddenly at length L/10 measured from the support B.
x
The reaction at support A immediately after the rod breaks is mg . Find the value of x
40

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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
CHEMISTRY MAX.MARKS: 60
SECTION – 1 (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
39. An acyclic diyne [P] with molecular formula C11H16 gives H2 gas with sodium metal
and also gives undecane on complete hydrogenation. Identify the major product in given
reaction

A) B) C) D)

40. Identify the most stable conformer of [T] in the given sequence

A) B) C) D)

41. For an electrolytic cell undergoing following balanced reaction:

NO3  3H 3O   Hg 22  2 Hg 2  HNO2  4 H 2O

Under standard state conditions E 0 cell = 0.02 V. If an average current of 10 amp. passes
through the cell, how long will it take to produce 0.3mole of HNO2 by this reaction?

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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
    2.303RT 
Given NO3  3H 3O  2e  HNO2  4 H 2O, E  0.94V and  0.06 
0

F 

A) 1.6 hours B) 16 hours C) 3.2 hours D) 32 hours

42. At 298 K, E o OP of the following reaction is

Ag  s   2 NH 3  aq   Ag  NH 3 2  aq   e



Given: K f Ag  NH 3 2

  10
16
; Eo
Ag  / Ag
 0.80V

A) 0.144 V B) 1.744 V C) –0.144 V D) –1.744 V

SECTION - 2 (Maximum Marks : 12)

This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 43 and 44:
Consider the major organic product in each case

43. Position of –NH2 in [P] as per IUPAC is

44. Number of carbon atoms present in parent chain (as per IUPAC) in [R] is

Question Stem for Question Nos. 45 and 46:

Consider following reagents with given codes:

Code 1: dil. HCl Code 2: NH 3  aq 

Code 3: KI  aq  Code 4: KCN  aq 

Code 5: Na2 S2O3  aq  Code 6: NaOH  aq 

Let the sum of codes of reagents in which AgCl is soluble be x .

Let the sum of codes of reagents in which Zn  OH 2 is soluble be y .

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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
x
45. Find
2

y
46. Find
4

Question Stem for Question Nos. 47 and 48:

Cadmium oxide crystallises in NaCl type structure. The compound is however non-
stoichiometric with the formula CdO0.95 . The defect arises due to some cationic positions

occupied by neutral Cd atom in place of Cd 2 ions and equivalent numbers of anion

sites are vacant.  Cd  112, N A  6  1023 

47. What percent of anion sites are vacant?

48. If the edge length of the unit cell is 400 pm, what would be the density  in gm / cm3  of

this non – stoichiometric solid?

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
49. Treatment of D-glucose with aqueous NaOH results in a mixture of monosaccharides,
identify the monosaccharide(s) present in the mixture

A) B) C) D)

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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
50. Considering the following reaction sequence, the CORRECT statement(s) is(are) (note
in every stage consider major organic product

A) Compounds [Q] and [R] both give effervesces with NaOH

B) Compounds [R] and [S] both react with hydroxyl amine gives corresponding oxime

C) Degree of unsaturation in [T] is 9

D) Compound [P] can give neutral FeCl3 test

51. 0.5 moles of sodium chloride is dissolved in 150 moles of water. The solution is cooled
to a temperature 'T' K below the freezing point of solution so that some ice is formed.
After separating the ice formed, the remaining solution is heated to normal boiling point
of water, where the vapour pressure of solution is found to be 750 torr. Identify
CORRECT option(s) on basis of this information  K f for water  2 K kg mol 1 

A) Mass of ice formed at ‘T’ K is 1.350 kg

 40 
B) Temperature T is  273   K
 27 

 20 
C) Freezing point of original solution is  273   K
 27 

1
D) Relative lowering of vapour pressure of resulting solution is
76

52. Which of the following complex is/are optically inactive and as well as diamagnetic:
 3
A) Co  NH 3 4 Cl2  B) Cr  H 2O 6 

3
C) cis  Co  NH 3 2  en 2  D)  PtCl2  NH 3 2 

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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP
53. The fixation of N 2 by certain bacteria is a biological reduction reaction of great interest.
Very few nonbiochemical systems are known which will react with N 2 at room
temperature and atmospheric pressure. One such compound is the titanium (II)
compound titanocene,  C5 H 5 2 Ti sometimes also abbreviated as Cp2Ti , a sandwich

compound like ferrocene. Select the CORRECT statement(s) about titanocene (I) & its
dinitrogen complex (II) [Bond length of free N 2 109.8pm]

A) The IUPAC name for the complex (II) would be bis(cyclopentadienyl)

bis (dinitrogen) titanate (II)

B) N-N bond lengths in the complex will be greater than 109.8 pm

C) The N-N bond length in the complex is less than 109.8 pm

D) Of the two complexes, only complex (II) follows Sidgwick EAN rule

54. Which of the following plot(s) is/are CORRECT for a sample of ideal gas in given
conditions?

A) B)

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Narayana IIT Academy 09-02-25_ SR*CO-SC_JEE-ADV_(MODEL-A)_GTA-6(P-1)_ QP

C) D)

SECTION - 4 (Maximum Marks : 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
55. The number of Sp3 hybridized carbon atoms in [S]
Hg2+ / H+ NaOCl 1. NaOH, Electrolysis
C5H8 [Q] [R] [S]
[P] 333 K -CHCl3 2. V2O5, 770K, 20 atm
[Q] gives 2-pentanol
[P] liberates up on hydrogenation
H2 gas with Na

56. The total number of different organic molecules formed from one molecule of P on
complete ozonolysis (O3, Zn/H2O) is
OH OH

HO HO OH

[P]

57. How many of these reaction gives N 2 as product

 i  NH 4 NO3 

  ii  NO 
red hot copper


 iii  Ba  N3 2 
heating
  iv  NH 4Cl  NaNO2 



 v  NH 2CONH 2  HNO2   vi 
o
NaNO3 
heating ,800 C


 vii  NH 3excess   Cl2   viii   NH 4 2 Cr2O7 

heating


 ix  NH 4Cl  CaOCl2 

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