Sri Chaitanya IIT Academy., India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office, Madhapur – Hyderabad
Sec: Jr.Super60_NUCLEUS WTA-32 Date: 01-12-2024
Time: 09:00AM to 12:00PM JEE-ADV_(2023-P1) Max. Marks: 180

2023_PAPER-I
01-12-2024_Jr.Super60_NUCLEUS BT JEE-ADV-2023-P1_WTA-32_Syllabus
MATHEMATICS : Rolle's Theorem, Lagrange Mean value Theorem, Cauchy's Mean Value Theorem,
Intermediate Value Theorem
CHEMISTRY : BENZENE AND EAS: Preparations of benzene, General mechanism of EAS, directive
influence of functional group in mono substituted benzene , Eletrophilic aromatic
substitution, mechanism of halogenations, nitration, sulphonation, nitrosation,
alkylation and acylation, Blanc Chloromethylation, Gattermann Koch reaction,
Gattermann reaction,Effect of directing groups (monosubstituted benzene) in these
reactions, Side chain reactions of alkyl toluene - halogenation & oxidation, Birch
reduction
PHYSIC : Superposition of Waves: Organ Pipes, Normal Modes of Vibration in an open Organ
Pipe, Normal Modes of Vibration in a Closed Organ Pipe, Vibration In Rods, Beats,
Applications of Beat Phenomenon, Doppler Effect, Doppler Effect in Sound Waves
(Deleted pertaining to JEE MAINS but still in JEE ADV Syllabus), Application of Doppler
Effect, Consequences of Doppler Effect (Deleted pertaining to JEE MAINS but still in
JEE ADV Syllabus), Miscellaneous Problems

Name of the Student: ___________________ H.T. NO:

 Sri Chaitanya IIT Academy 01-12-2024_Jr.Super60_NUCLEUS BT_Jee-Adv(2023-P1)_WTA-32_Q.P
JEE-ADVANCE-2023-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 1 – 3) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 4 – 7) +3 -1 4 12
Choice
Sec – III(Q.N : 8 – 13) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 14 – 17) Matching Type +3 -1 4 12
Total 17 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 18 – 20) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 21 – 24) +3 -1 4 12
Choice
Sec – III(Q.N : 25 – 30) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 31 – 34) Matching Type +3 -1 4 12
Total 17 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 35 – 37) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 38 – 41) +3 -1 4 12
Choice
Sec – III(Q.N : 42 – 47) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 48 – 51) Matching Type +3 -1 4 12
Total 17 60

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MATHEMATICS Max Marks: 60

SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

1. If Rolle’s theorem is applicable for the function f defined by :


lx 2  m if | x | 1

f ( x )  1 if | x | 1

 if | x | 1
 | x |
In interval [-2,2], then

A) 3l  m  0 B) m  3 / 2 C) l  m  1 D)   l  m

2. Lagrange’s mean value theorem can be applied for the following?

1
A) f ( x)  x 2 in [-1,1] B) f ( x)  x  in [1,3]
x
C) f ( x)  x 2  4 in [2,4] D) f ( x) | x | in [-1,2]

3. For which of the following function Rolle’s theorem is applicable?

x 2
A) f ( x)   , x  [1,4] B) f ( x)  x  1  x 3/2 , x  [0,1]
2 x
 5 1 
C) f ( x) | x  1|3 , x  [2,0] D) f ( x)  sgn( x)  sgn( x), x   ,  (sgn ( x )
 2 2
denotes signum functions of x )
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
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Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases

4. If the function f ( x)  2 x 2  3 x  5 satisfies LMVT at x  3 on the closed interval

[1,k] then the value of k
A) 1 B) 3 C) 4 D) 5

5. Given n is a positive integer for the function f ( x)  5 x ( x  2) n , x  [0,2] by Rolle’s

1
theorem the value of c is then n is equal to
5
A) 10 B) 9 C) 6 D) 3
x

6. The function f ( x)  x( x  3)e satisfies all the conditions of Rolle’s theorem on [-3,0].
2

The value of c which verifies Rolle’s theorem is

3
A) -2 B) -1 C) 0 D)
2
7. The value of ‘c’ in Lagrange’s mean value theorem for f ( x)  lx 2  mx  n,(l  0) on
[a,b] is
ab ab a b
A) B) C) D)
2 2 2 2

SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.

8. Suppose Rolle’s theorem holds in [1,2] for the function f ( x)  x 3  px 2  qx, at the
4
point x  then p  q  _______.
3
9. Let f (1)  2 and f ' ( x)  4.2 for 1  x  6 . Then the possible value of f (6) lies in
the interval   ,   . Then   15  ________.
2  x 3 if x 1
10. Value of ‘c’ of Lagrange’s mean value theorem for f ( x )   on [-1,2]
3 x if x 1
 3 
is  m  then | m |  __________ . is GIF  .
 5 

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11. For the function f ( x)  ( x  1)( x  2)( x  3) in [0,4], value of ‘c’ in Lagrange’s mean
q
value theorem is p  then p  q  k  _________.
k
12. Let f ( x ) and g ( x) be two differentiable functions in R and
f (2)  8, g (2)  0, f (4)  10 and g (4)  8 and for at least one x  (2, 4) ,
g ' ( x)  n f ' ( x) then n  ________.
13. The value of ‘c’ by Rolle’s theorem for which f ( x)  1  3 x 4 in [-1, 1] is ______.
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.

14. Let f ( x)  ax3  bx 2  11x  6 and g ( x)  x3   x 2   x . Now match the following

Column –I Column-II
I) 1 P) -5
Rolle’s theorem holds for f ( x ) in [1,3] at 2  ,
3
Then a=
II) 1 Q) 1
Rolle’s theorem holds for f ( x ) in [1,3] at 2  ,
3
Then b=

III) 4 R) 8
, Then  =
Rolle’s theorem holds for g ( x) in [1,2] at
3
IV) 4 S) 6
Rolle’s theorem holds for g ( x) in [1,2] at , Then  =
3
T) 2

A) I - Q, II –S, III – P, IV – R B) I - S, II –Q, III – P, IV – R

C) I - P, II –S, III – Q, IV – R D) I - R, II –S, III – Q, IV – R

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15. Match the following

Column –I Column-II
I) If f ( x)  x3  bx 2  ax satisfies the conditions of Rolle’s P) 17
1
theorem on [1,3] with c  2  then a  b 
3
II)  x log x, x  0 Q) 1
If f ( x)   and Rolle’s theorem is
 0 , x  0
Applicable to f ( x ) for x  [0,1] then  may be
not equal to
III) Value of ‘c’ Rolle’s theorem for R) 0
f ( x)  log( x 2  2)  log3 on [1,1] is

IV) Value of ‘c’ Rolle’s theorem for f ( x)  x 2 on [-1,1] S) 0.5

T) 7

A) I - Q, II –S, III – S, IV – S B) I - S, II –P, III – P, IV – P

C) I - P, II –R, III – R, IV – R D) I - R, II –Q, III – Q, IV – Q

16. Match the value of c (column II) of Lagrange’s mean value theorem with the functions
given in column-I:

Column –I Column-II
I) f ( x)  x 3  2 x 2  x  3 in [0,1] P) 1
II) f ( x)  e x in [0,1] Q) 0.5
III) 1 R) (e  1)
f ( x)  x  in [1/2,2]
x
IV) f ( x)  log x in [1, e] S) log(e  1)
T) 1/3

A) I - R, II –S, III – Q, IV – Q B) I - S, II –Q, III – P, IV – R

C) I – T, II –S, III – P, IV – R D) I - Q, II –S, III – P, IV – R

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17. Match the statements of Column –I with values of Column –II.

Column – I Column-II
A) If the functions f ( x ) and g ( x) are continuous in [a,b] P) 1
and differentiable in (a, b) then the value of c, for 3
1
the pair of functions, f ( x)  x , g ( x) 
x
B) If the functions f ( x ) and  ( x ) are continuous in [a,b] and Q) ab
differentiable in (a, b) then the value of c for the
pair of functions f ( x)  e x , ( x)  e  x is
C) The value of c in Lagrange’s mean value theorem for R) ab
f ( x)  log x on [1,e] is 2
D) The value of c in LMVT for f ( x)  x 3  2 x 2  x  4 in S) e-1
[0,1] is
T) 2
3

A) I - R, II –S, III – Q, IV – Q B) I - S, II –Q, III – P, IV – R

C) I - Q, II –R, III – S, IV – P D) I - Q, II –S, III – P, IV – R

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PHYSICS Max Marks: 60
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

18. In the figure an observer O1 floats (static) on water surface with ears in air while another
observer O2 . Is moving upwards with constant velocity v1  v / 5 in water. The source
moves down with constant velocity vs  v / 5 and emits sound of frequency f. The
velocity of sound in air is v and that in water is 4v. For the situation shown in figure .

A) The wavelength of the sound received by O1 is 4v / 5 f

B) The wavelength of the sound received by O1 is v / f
C) The frequency of the sound received by O2 is 21 f / 16
D) The wavelength of the sound received by O2 is16v / 5 f
19. In a stationary wave system, all the particles of the medium
A) Have zero displacement simultaneously at some instant
B) Have maximum displacement simultaneously at some instant
C) Are at rest simultaneously at some instant
D) Reach maximum velocity simultaneously at some instant

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20. A stationary observer receivers a sound of frequency f 0  2000 Hz . The apparent
frequency f varies with time as shown in figure. Speed of sound = 300 m/s. Choose the
correct alternative (s)?

A) speed of source is 66.7 m/s

B) f m shown in figure cannot be greater than 2500 Hz
C) speed of source is 33.33 m/s
D) f m shown in figure cannot be greater than 2250 Hz
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
21. A turning fork of frequency 480 Hz produces 10 beats per second when sounded with a
vibrating sonometer string. What must have been the frequency of the string if a slight
increase in tension produces lesser beats per second than before:
A) 460 Hz B) 470 Hz C) 480 Hz D) 490 Hz
22. A siren placed at a railway platform is emitting sound of frequency 5 kHz. A passenger
sitting in a moving train. A records a frequency of 5.5 kHz while the train approaches the
siren. During his return journey in a different train B the records a frequency of 6.0 kHz
while approaching the same siren. The ratio of the velocity of train B to that of train A is
242 5 11
A) B) 2 C) D)
252 6 6
23. In the resonance tube experiment for determining the speed of sound in air using a
tuning fork of frequency 480 Hz, the first resonance was observed at 17.7 cm of air
column and the second at 53.1 cm. The maximum possible error in the speed of sound in
air is
A) 192 cm s 1 B) 96 cm s 1 C) 64 cm s 1 D) 48 cm s 1
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24. An organ pipe P1 , closed one end containing a gas of density 1 is vibrating in its first
harmonic. Another organ pipe P2 , open at both ends and containing a gas of density  2 is
vibrating in its third harmonic. Both the pipe are in resonance with a given tuning fork. If
the compressibility of gases is equal in both pipes, the ratio of the lengths of P1 and P2 is
1 1 1 1 2
A) B) 3 C) D)
3 6 2 6 1
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases..
25. An ambulance sounding a horn of frequency 256 Hz is moving towards a vertical wall
with a velocity of 5 ms 1 . If the speed of sound is 330 ms 1 , how many beats per second
will be heard by an observer standing a few metres behind the ambulance ?
26. There are three sources of sound of equal intensities with frequency 400,401 and 402 Hz.
What is the beat frequency heard if all are sounded simultaneously ?
27. Two wires are fixed on a sonometer wire. The tensions are in the ratio 8 : 1, the lengths
in the ratio 36 :35, the diameter are in the ratio 4: 1 and the densities in the ratio 1:2.
Find the frequency of the beats produced if the note of the higher pitch has frequency of
360 Hz. ( in Hz)
28. A tuning fork having a frequency of 340 Hz is vibrated just above a cyclindrical tube.
The height of the tube is 120 cm. Water is slowly poured in it. What is the minimum
height ( in cm) of water required for resonance? Velocity of sound in air = 340 m/s
29. A metal wire of diameter 1 mm is held on two knife edges separated by a distance of 50
cm. The tension in the wire is 100 N. The wire vibrating with its fundamental frequency
and a vibrating tuning fork together produces 5 beats per second. The tension in the wire
is then reduced to 81 N. When two are excited, beats are heard at the same rate.
Calculate the frequency ( in Hz) of the fork .
30. A train approaching a railway crossing at a speed of 120 km/h sounds a short whistle at
frequency 640 Hz when it is 300m away from the crossing. The speed of sound in air is
340 m/s. What will be the frequency ( in Hz) heard by a person standing on a road
perpendicular to the track through the crossing at a distance of 400 m from the crossing?

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SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
31. Column I shows four systems, each of the same length L, for producing standing waves.
The lowest possible natural frequency of a system is called its fundamental frequency,
whose wavelength is denoted as  f . Match each system with statements given in
column-II describing the nature and wavelength of the standing waves.
Column-I Column-II

I) Pipe closed at one end (p) Longitudinal waves

II) Pipe open at both ends (q) Transverse waves

III) Stretched wire clamped (r) f  L

at both ends

IV) Stretched wire clamped (s)  f  2L

to both ends and at mid-
point

(t)  f  4L

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A) I- q, r ; II – q, s ; III – p, s; IV- p, t
B) I- p, t ; II – p, s ; III – q, s ; IV- q, r
C) I- q ,r ; II – p, s ; III – q, s; IV- p, t
D) I- p, t; II – q, s ; III – p, s; IV- q, r
32. Source has frequency f source and observer both have same speed. For the apparent
frequency observed match the following
Column-I Column-II
I) Observer is approaching the source but (p) more than f
source is Receding from the observer
II) Observer and source both approaching (q) less than f
towards each other
III) Observer and source both receding from (r) equal to f
each other
IV) Source is approaching but observer is
receding
A) I- r ; II – q ; III – p, s; IV- r B) I- p ; II – q ; III – r; IV- p
C) I- q ; II – r ; III – r; IV- p D) I- r; II – p ; III – q; IV- r
33. Match the Column-I and Column-II
Column – I Column –II

I) Consider a string that is fixed at (p) These are longitudinal stationary

both ends If the string is plucked, waves.
stationary waves will be setup in the
string.
II) In organ pipes, stationary waves can (q) Fundamental frequency of the
be setup In the air column vibrations will also depend on
temperature
III) Frequency of the first overtone in a (r) Fundamental frequency of the
pipe of Length 40 cm, that is open vibrations will also depend
at both ends, will Be (take speed of on humidity.
sound in air =330 m/s)
IV) On the surface of moon, frequency (s) 825 Hz
Of the fundamental note emitted by
a length 20 cm that is open at both
ends, will be
t) none

A) I- q ; II – pqr ; III – s; IV- t B) I- q ; II – qrs ; III – p; IV- pqr

C) I- q ; II – qrs ; III – s; IV- pqr D) I- q ; II – s ; III – pqr ; IV- t

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34. In closed organ pipe at one end ….

Column –I Column –II

P) Third overtone frequency is x time (1) 3
Fundamental frequency, then x is
Q) Number of nodes is second overtone (2) 4
R) Number of antinodes in second overtone (3) 5
S) nth harmonic does not exists, where n is (4) 7
(5) 6

A) P -5 Q -1 R -1 S -5

B) P -4 Q -1 R -1 S -2,5

C) P -4 Q -2 R -3 S -2

D) P -3 Q-2 R -4 S -2,5

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CHEMISTRY Max Marks: 60
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

35. Among the following, reaction (s) which gives (give) tert-butyl benzene as the major
product is (are)
Br
Cl
NaOC2H5 AlCl3
A) B)

OH

H
H2SO4
C) D)

36. Isopropyl benzene can be obtained by:

CH3 CH CH2 CH3 CH2 CH2 Cl

H
 AlCl3
A) B)

H3 C
CH Cl
H3 C
CH3CH2OCH3

Al Cl3
C) D)

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37. What is the intermediate(s) of the following reaction is/are
CH2 CHCH3, H

Heat

 
A) CH 3  CH  CH 3 B) CH 2  CH 2  CH 3
 
C) CH 3  CH  CH 3 D) CH 3  CH  CH 3
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
38. Decreasing order of rate of EAS (Electrophilic Aromatic Substitution)reaction is :

(1) (II)

(III)

A) I>II>III B) I>III>II C) II>III>I D) III>I>II

 HF

X (Major product). 'X' is :

39.

A) B) C) D)
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40. What is the major mono bromination product in the following reaction?

C H2 C H2 N O2 h 
Br 2

 li ght

A)

B)

C)

D)

41. The major product in the following reaction is:

 i SOCl2

 ii Anhyd, AlCl3

COOH
 iii ZnHg / HCl
 A  iv Se , 6000 C
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A) B)

C) D)
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
42. One mole of benzene ozonolysis _________number of moles of glyoxals are formed.
43. Examine the structural formulas shown below and find out how many compounds
will show oxidation reaction with acidic KMnO4.

i. ii.

iii. iv.
44. Identify the number of products (excluding stereoisomers) in the following reaction.

H3 C C H3
NBSh
Product

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45. Among the given organic compounds, the total number of aromatic compound is _____

i. ii.

iii. iv.
46. How many isomeric structures with M.F C6 H 3 Br3 are possible with benzene ring.

47. Each of the compounds shown below has two aromatic ring, labeled as A and B.
Identify number of compounds in which ring B is more active than ring A for
electrophonic aromatic substitution reaction.

ii. A C N B
i. A C B
H

iii. iv.

SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases..

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48. Match the following
COLUMN-I COLUMN-II
C H3
A) C6 H 6  CH 3 Cl 
 AlCl3
P)

B) C6 H 6  CH 3 CH 2Cl 
AlCl3
 Q)

Al O
C) CrO
2 3

3/

 R)

D) C6 H 6  CH 3COCl 
AlCl3
 
N2H 4
NaOH / 
 S)

A) A-PRS, B-Q, C- QRS, D-Q B) A-S, B-PQRS, C-PQ, D-S

C) A-QS, B-PQS, C-RP, D-QR D) A-Q, B-P, C-PR, D-QS
49. Match the following
COLUMN-I COLUMN-II
OH

A) H3 CCCl
P) O, P-directing compound for ArSE
AlCl3

NH2

B) CH3 Cl Q) Activated compound for ArSE

AlCl3

H3 C CH3
N
Given AES not possible
C) R) AES= aromatic electrophilic
substitution

N O2

Deactivated compound for aromatic

D) S)
electrophilic substitution

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A) A-PRS, B-PRS C-PR, D-PQS B) A-PQRS, B-PQRS, C-PQ, D-S
C) A-RS, B-PQR, C-PQ, D-S D) A-QS, B-PS, C-PR, D-QS
50. Match the following
COLUMN-I COLUMN-II

Ph  CF3 Less reactive than benzene towards

A) P)
nitration
Nitration give meta isomer
B) Ph-NO2 Q)
as the major product
Arenium carbocation formed when
C) Ph  O  COCH 3 R) an electrophile attacks is stabilized
by +R effect
D) Ph-NHCOCH3 S) Doesn’t react with MeCl / AlCl3
More reactive than benzene
T)
towards bromination
A) A-PRS, B-PRS C-PR, D-PQS B) A-PQS, B-PQS, C-RT, D-RT
C) A-PQS, B-PRS, C-RT, D-RT D) A-QS, B-PS, C-PR, D-QS

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51. Match the following
COLUMN-I COLUMN-II
H 5 C2 O O
C

A) P) Ortho and para substitution.

C l2
F eC l3

CH CH C H

B) Q) Meta substitution.
Conc. H 2 SO4

NH C CH3
Substitution is faster than
C) R)
N2 O 5 benzene.

C F3

Substitution is slower than

D) S)
C o n c. H N O 3 benzene.
 Co n c. H 2 S O4

A) A-PRS, B-PRS C-PR, D-PQS B) A-PQS, B-PQS, C-RT, D-RT

C) A-PQS, B-PQS, C-RT, D-RT D) A-QS, B-PS, C-PR, D-QS

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