SR.IIT_*CO-SC(MODEL-A& APEX) GTM-14 Date: 08.01.

2025
Time: 3.00Hrs. JEE MAINS -2025 Max. Marks: 300
KEYSHEET
PHYSICS
1 2 3 4 5 6 7 8 9 10
C D A C C C C A A D
11 12 13 14 15 16 17 18 19 20
A C C A D B C B A A
21 22 23 24 25
3 49 2 12 2

CHEMISTRY
26 27 28 29 30 31 32 33 34 35
C B D A B C C C A D
36 37 38 39 40 41 42 43 44 45
B C C A D B C B C B
46 47 48 49 50
20 5 50 416 446

MATHEMATICS
51 52 53 54 55 56 57 58 59 60
C B A B C D C B C C
61 62 63 64 65 66 67 68 69 70
B A C D A D C B A A
71 72 73 74 75
2 4 10 2 25

1
For More Material Join: @JEEAdvanced_2025
 HINTS
PHYSICS
IV
01. Energy present in volume V 
c
IV  100  10  2640  10 
9 10

So, number of photons in that volume N  2 

ch 9  1016  6.626  1034
 N  442.7
10
02. Both the Diodes act like short. Thus, i1  0 and i2   5mA
2000

R A C B
03.  100   100  3  100  2  100
R A C B
R
%  0.25%  0.2%  0.75%  1.2%
R
E2
04. Pavg  rms cos 
Z
PV
05. PV  nRT  n
RT
n1 
 2V  2 P  and n2 
V  P 
R  2T  R T 
So, n1  2n2
06. v   A2  x 2
2
  50   10  10  x 2
Or x  8.66cm
Therefore distance between those two points,
d  2 x  17.32cm
O
R 53 37

07. A C
v
E
D 37

In figure
3R 4R
OC = R cos 53º = ; OE = R cos 37º =
5 5
R
So CE =
5
From A to B,
1 2 R
mv = mg [Energy conservation]
2 5
2 gR
v=
5

2
For More Material Join: @JEEAdvanced_2025
 Let radius of curvature at B is r
v2
g cos 37º =
r
2
v 2 gR R
r= = =
g cos37º 5  10  4 / 5 2
08. 1/v+1/u=1/f
m
09. r
q
10.
dT
H   kA
dx
L T0 15T0 2
  Hdx   aA TdT  HL  aA
0 4T0 2
L
2
T HL 16T0 2  T 2
  Hdx   aA TdT   aA
0 4T0 2 2
15T0 2 17
  16T0 2  T 2  T  T0
2 2

1 4 3 2  R3 
11.   R  v  4 T   R2 
2 3  r 
1 3 2 1 1 
R   TR3   
6 r R
2
  1 1 
T   
6 r R
6T  1 1 
2  
  r R 
6T  1 1 
  
  r R 
12. If A moves down by a1 w.r.t B and B moves to the right by a2 then the constraint
relation gives a1  a2  a .
For A : N  ma; mg  T  ma
For B : T  N  ma  T  2ma
g
a
3
   g g
 a AO  aBO  a AB  iˆ  ˆj
3 3

WL
13. Elongation  
E

3
For More Material Join: @JEEAdvanced_2025
 L
On either side of the wire, tension is W and length is
2
 WL 
 
 2 
 
AE
WL

2 AE
L
2
14. Geo-satellite means whose time period is
T = 24 hr & from law
T22 ( R  2.5 R ) 3
=
(24) 2 ( R  6 R )3
24  24
T2 = = 6 2 hr.
8
15. 0  2 mm, u  20 cm
R 40
f    20 cm
2 2
From mirror formula,
1 1 1
 
f v u
1 1 1
 
20 v 20
1 1 1
 
v 20 20
 v  10 cm
I v
 
0 u
I 10

2 20
 I  1mm
Height of image = 1 mm

10 R
16. 2
500
dx d
17. v t   
dt dt
 u t  2    t  2
2

Using the product and chain rules:
u  t   u  2a  t  2 
To find the initial velocity at t=0:
v(0)=u+2a(0−2)=u−4a
a(t)=dv/dt=d/dt((u+2a(t−2)))=2a
4
For More Material Join: @JEEAdvanced_2025
 18. Q  nC T  C  2T0  T0 
P R 3R R
2
 constant  PV 2  constant  C  CV   R
T 1 2 2 2
RT0
Q .
2
r (n  1) 2 r0 n 2 r0 ( n  1) 2
19. rn1  rn  rn1  0 2  2  n4
Z Z Z2
Z2
E4  13.6 2  0.85 Z 2 .
4
20. When light ray goes from denser to rarer medium ( . ., more to less ) it deviates
away from the normal while if light ray goes from rarer to denser medium ( . . less
more ) it bend towards the normal.
This property is satisfied by the ray diagram (i) only
21. Applying COAM about the centre of the plate:
  5a  2   2 a 2   a 2   3u
mua  m    m      
  2  12  5a
  
22. B=0.2 T,
q=1.0×10 −5 C,
m=0.01 g=1×10 −5 kg
Force due to magnetic field = Gravitational force of attraction
So, qVB=mg
⇒1×10−5 V×2×10−1=1×10−5×9.8
V=4.9×10=49m/s

23. T1 
6

T2 
3
24. A fully charged capacitor draws no current. If the capacitor is removed from the
circuit, we can distribute the current and find the potential difference across each
resistance.

V  V 
25. n1    n2    4
 4l   2l 
4
It l is doubled, beat frequency will remain  2 Hz
2

CHEMISTRY
26. Conceptual
2.303 100 2.303 100
27. K log : K log
20 90 t19% 81
2
2.303 10 2.303  10 
log  log  
20 9 t19%  9
5
For More Material Join: @JEEAdvanced_2025
 1 10 2 10
log  log
20 9 t19% 9
t19%  40min

5 4
28. No of spectral lines given by H =  10
2
43
No of spectral lines given by He+ = 6
2
3 2
No of spectral lines given by Li2+ = 3
2
However 21 ( H )  42 ( He2 )
Total no of spectral lines = 10 + 6 + 3 – 1 = 18
102  V
29. Ca 2    5  103
final 2V
3
10  V
 F     5  104
final 2V
2
K I P  Ca 2   F  
2
 5  103  5  10 4 
 125  10 11
K I P  1.25  109
K I P  K SP  ppt will form 

30. Only a, c, d correct

31. Mn2O7 : multiple bonds

AgNO3   Ag   NO2  O2 
 5   6   7 
V O2  Cr 2 O72  MnO4 When I  is oxidized by MnO4 in alkaline medium, I 
converts into IO3
32. Atomic radius of noble gas is highest in the respective period
33. Conceptual
34. All are not isotonic to each other.
35. Benzoic acid is stronger than phenols
36. No. of chiral centre =2
No. of optical isomers = 22=4
37. Clemmenson reduction acid sensitive group OH may undergo effect

6
For More Material Join: @JEEAdvanced_2025
 38.
Br
Hbr
 Br2
 
R2 O2
Br
1) 2)
O
CH 3  C  NH 2 CH 2  NH 2
Br2 / hv Br2  NaOH
 
Br
3) 4)

39. cal  q  d
 1.60  10 19 C 1.41  10 10 m 
 2.26  10 29 Cm
2.60  1030 Cm
The percentage ionic character   100  11.5%
2.26  1029 Cm

40.

41. The intermediate is

42.
Ph H Ph
Y 
X  Br2 H Br
Ph  C  C  Ph 
Na / NH3   
 C C  
CCl4 H Br
H Ph
Ph
43. Kjeldahl’s method is not applicable for nitro, nitro so compounds and for
compounds is which N is present in the ring
44.
Ag C  N :
CH3CH 2  Cl   CH3CH 2  N  C  X 

K CN 
CH 3CH 2  C  N  Y 

45. H 2 S is a week acid, its dissociation controlled by HCl and NH 4OH .

46. Conceptual

47. Pressure, p1  20 atm

7
For More Material Join: @JEEAdvanced_2025
 Pressure, p2  50atm
Temperature, T1  27C  273C  300 K
Temperature, T2  327C  273C  600 K
Reaction,
2 NH 3 g   N 2 g   3H 2 g 
 3
After dissociation 1  
2 2
Total moles  1  
Ideal gas equation,
 PV  nRT
20V 1 R 300
 
50V n R 600
 n  1.25
   0.25
 %  25
i.e., x  5

48. gr.Eq of Fe 2  grEq of KMnO4

wt 50
 1  0.1 
393 1000
1.0  50  392
wt 
1000
 1.96
1.96
 100  50%
3.92
49. CH 4 g   C g   4 H  g  ; H  ?
From the given information on solving we get
CH 4 g   C g   4 H  g  ; H  1665 kJ / mol
1665
Then C  H bond energy  kJ / mol
4
 416 kJ / mol
50. When Hg is used as the cathode, Na  will be reduced to form sodium amalgam,
Na-Hg.
At cathode: Na   1e  Hg  Na  Hg
2.0 moles of NaCl presence in the solution contains 2 moles of Na  in 0.5 liters of
4 M solution. Hence two moles of Na-Hg are formed.
The mass of 2 moles of Na-Hg=2(23+200)=446g.

MATHEMATICS
51. lim  1
n 
n 1
sin  
c n 2  0.5n  1 ; n  N
n 1
sin  n      1 sin 
8
For More Material Join: @JEEAdvanced_2025
 
 limsin n   n 2  0.5n  1
n 

 
  n  n2  0.5n  1 n  n 2  0.5n  1

 limsin   
  
n   n  n2  0.5n  1 
   
 
  n 2  n 2  0.5n  1  
 limsin      dividing by n
n    n  n 2  0.5n  1  
  
  1 
  0.5  
 limsin    n 
n   1 
 1  1  0.5 / n  n 2  
 

  1  1
 sin       
  4  2

52. Clearly, f  x  in decreasing just before x  3 and increasing after x  3 . For x  3

to be the point of local minima, f  3  f  3  .
or 15  12  27  ln  a 2  3a  3
or a 2  3a  3  1
or a   ,1   2,  

15 r r
15 5 3
53. Tr 1  Cr .2 .5
r  0,15
23.50  20.55

 32 3

 sin   cos   d
2

54.  
 sin 3  cos3  sin    
 32 
 tan   1 d
 
 sin 3   sin  cos  cos sin  
 32 
 tan   1 d
 
 cos2  tan  tan   cos tan   sin  
Let a  cos  , b  sin 
9
For More Material Join: @JEEAdvanced_2025
 Put tan   t  sec 2  d  dt
 32 
 t  1  dt
   2 at  b  dt
3 1
a 3 1
t 2  at  b  2 t 2  at  b  2
b b
Put t  tan 2 y  dt  2 tan y sec 2 y dy
a a
1
2
2 2a cos y
 at  b   sin
2
dy
a b y
1
2
2 2a 1
 at  b  c
a b sin y
2 2 a a tan   b
 a tan   b  c
a b a tan 
2 2
 a tan   b  a  b cot   c
a b
2 2
 cos  tan   sin   cos   sin  cot   c
cos  sin 

55. Equation of line parallel to 3 x  y  7 is 3x  y  

 1,2  is on it.
  1
Now, point of intersection of 3x  y  1 and x  y  5  0 is  1, 4  .
 Distance between 1,2  and  1, 4   2 2  6 2  40

3
56. Eccentricity of ellipse = , Focii   3,0 
4
1  12 144   
Eccentricity and Foci of hyperbola be 144   and   ,0 
12  5 12 

1 2b 2 27
Since foci coincide  3  144      81 , Length of latus rectum = 
5 a 10
  
57. OC  mOA  nOB
  
c  ma  nb
  
Given a  1, b  1, c  2, tan   7
 
Now take dot of equation (1) with a and b to get
m  5 / 4; n  7 / 4
m  n  3

10
For More Material Join: @JEEAdvanced_2025
 58. P ''  x  is constant  P  x  is quadratic

59. x 2 x  2 x x cot y  1  0 when x  1


1  2cot  y 1   1  0  cot  y 1   0; y 1 
2
Now, we have x2 x  2 x x cot y  1  0
Differentiate both sides with respect to x . when x  1
dy
2  ln x  1 x 2 x  2 x x  ln x  1 cot y  2 x x cosec 2 y 0
dx

2  0  cosec2 . y  '1  0
2
y 1  1

dy
60. 2 xy  y 2 dx   x 2  1 dx
dx
x.d  y 2   y 2 .d  x   x 2  1 dx

x2 x2
 y2   1 
d     1  2  dx
 x   x 
y2 1
 x
x x
2 2
y  x 1
x2  y 2  1

61. Required no.of ways = coeff of

5
 x 2 1  x7  
8 5
x30 in  x 2  x 3  ....  x  30
 coeff of x in  
 1 x 
 
5 5
 coeff of x 20 in 1  x 7  1  x   24 C20  5 17C13  10 10C6  826

62. 8b 3  a 3  c 3  6abc
3
a3  c 3   2b   3ab  2b 
 a  c  2b  0 (or) a  c  2b

1 3
63. Let A is 1,0  , B is  ,  and P is  x, y 
2 2 
  
 OP   2  t  OA  tOB, t  R

11
For More Material Join: @JEEAdvanced_2025
  iˆ 3 ˆj 
 xiˆ  yjˆ   2  t  iˆ  t   
2 2 
t 3t
x  2  ; y 
2 2
 2 3
AP   x  1 iˆ  yjˆ   x  1  y 2  t 2  t  1 
2

64. x   , 1

 2x 
f  x   sin 1  2 
 2 tan 1 x
1 x 
   2tan x  2tan 1 x
1

   4 tan 1 x
2
1  1  x 
g  x   sin  2 
 4 tan 1 x
1 x 
2
 1  1  x 
  cos  2 
 4 tan 1 x
2 1 x 

   2 tan 1 x   4 tan 1 x
2

  6tan 1 x
2
3
Now, f  x   g  x    10 tan 1 x
2
   
x   , 1 , tan 1 x   ,
 2 4 
 7 
So,  f  x   g  x     , 
 2 

65. Let A   x1 , y1  , B   x2 , y2  , C   x3 , y3  , D   x4 , y4 
Given x12  x22  x32  x42  y12  y22  y32  y42  2 x1 x3  2 x2 x4  2 y2 y3  2 y1 y4  0
2 2 2 2
or  x1  x3    x2  x4    y2  y3    y1  y4   0
x x x x y  y2 y4  y3
or 1 2  3 4 and 1 
2 2 2 2
Hence , AB and CD bisect each other .
Therefore , ABCD is a parallelogram , Also
2 2
AB 2   x1  x2    y1  y2 
2 2
  x3  x4    y4  y3 
 CD 2
Thus, ABCD is a parallelogram AB = CD . Hence , it is a rectangle.

12
For More Material Join: @JEEAdvanced_2025
 66. 1,0,1
R   x, y  : x, y  z , x 2  3 y 2  8
8
3

 8 8



8

3
For domain of R 1
Collection of all integral of y’s
For x  0,3 y 2  8
 y  1,0,1

9 9
2
67. We have,   x1  5   9 and
i 1
 x  5
i 1
1  45

9 2
2  9 
 x
i 1
1  5    x1  5  
SD    i1 
9  9 
 
 
2
45  9 
 SD   
9 9
 SD  5  1  4  2

1 2 3 10
68. Given integral   0dx  1 x dx   2  x dx .........   93  xdx3

0 1 2 9
1 2
 9  10  1 2025
 13  23  ........93    x dx     0 xdx 
0  2  2

8 8
69. z  1  cos  i sin
5 5
4 4 4
 2cos 2  i 2sin cos
5 5 5
4  4 4 
 2cos  cos  i sin 
5  5 5 
  
 2cos   cos  i sin 
5 5 5

13
For More Material Join: @JEEAdvanced_2025
   
 2cos  cos  i sin 
5 5 5
     
 2cos  cos     i sin    
5  5  5 
 
Thus , z  2cos and arg  z   
5 5

70. Let Ak be the of positive integers from 1 to 1000, which are divisible by k.
If . denotes the greatest integer function, then
1000 
n  A2     500
 2 
1000 
n  A3     333
 3 
1000 
n  A5     200
 5 
1000 
Also n  A2  A3     166
 6 
1000 
n  A3  A5     66
 15 
1000 
n  A2  A5     100
 10 
1000 
and n  A2  A3  A5     33
 30 
So, n  A2  A3  A5   500  333  200  166  66  100  33  734

71. Let iˆ, ˆj , kˆ be the unit vectors along OA,OB,OC. CN,BM are diagonals skew to OA
   
Let 1 be the S,D between OA and CN let OA  xiˆ, OB  yjˆ, OC  zkˆ  ON  xiˆ  yjˆ

 
Equation of OA and CN are r  xiˆ and r̂  zkˆ  p xiˆ  yjˆ  zkˆ respectively.
The shortest distance between those two lines.
yz 1 1 1
  2 2 2
2
y z 2  y z
1 1 1 1 1 1 1 1 1  1 1 1 
Similarly  2  2 , 2  2  2 ,  2  2  2  2   2 
m 2
z x n x y  m n 2 2
 OA OB OC 

3
72. A   2k  1 , B  0 (since B is a skew – symmetric matrix of order 3)
2
 det  adj A  A
n 1

  2k  1
3
  106
 2k  1  10 or 2k  9

14
For More Material Join: @JEEAdvanced_2025
  k   4 .

73. Area of the shaded region is

1 2
  8  8   32
2 3
1
  32
3
32
 
3
    10

74. The equation of the line through P(x,y) making an angle with the x-axis which is
suplementary to the angle made by the tangent at P(x,y) is
dy
Y  y    X  x  ........1
dx
At the point where it meets the x-axis
y y
Y  0, X  x   OA  x  ............ 2 
dy dy
dx dx
The line through P(x,y) and perpendicular to (1) is
dx
Y  y   X  x.
dy
At the point where it meets the y-axis
x x
X  0, Y  y   OB  y 
dy dy
dx dx
Sin ce OA  OB ,
y x yx dy y  x
x  y   y  x   
dy dy dy dx y  x
dx dx dx
Writing y = vx this equation becomes
dv 1  v dv 1  2v  v 2
vx  x 
dx v  1 dx v 1

1  v  dv  dx  0
1  2v  v 2 x
 n 12v  v 2   n X 2  constant
 x 2  2 xy  y 2  c
Since the curve passes through 1,1 , c  2
Hence , the required curve is x 2  y 2  2 xy  2 .
x
75. m
y

15
For More Material Join: @JEEAdvanced_2025
 Let x  my be the tangent Applying
3  4m
2
1  m2
12 m 2  24 m  5  0
2
2  24  5
 m1  m2   2m1m2     2 
 12  12
19

6

16
For More Material Join: @JEEAdvanced_2025