PU II Chemistry

Chemistry Passing &

Scoring Package
Chapter-wise Questions from
PU Board
Model Question Papers

By-
Mr. Shivalingayya Hiremath M.Sc. B.Ed. K-SET
Chemistry NEET-JEE Expert @
Konnur’s College of Science, Yallatti
 Unit-1
Solutions
MQP PART-A PART-B PART-C PART-D PART-E TOTAL
24-25 MCQ FIB 2M INORG PHY ORG PROBLEMS MARKS
MQP-1 10,15 19 - - 34 - 42,44 12
MQP-2 4 - 21 - 33 - 41,42 12
MQP-3 1 - 23 - 33 - 41,42 12

Solutions
PART-A(1M) MCQs
1. In a solution containing non-volatile solute, the mole fraction of solvent is 0.9. The
relative lowering of vapour pressure is (MQP-1)
a) 1 b) 0.1 c) 0.9 d) 1.1
2. During osmosis, the solvent molecules are moving from (MQP-1)
a) Hypotonic solution to hypertonic solution
b) Hypertonic solution to hypotonic solution
c) Higher concentrated solution to lower concentrated solution
d) Higher osmotic pressure solution to lower osmotic pressure solution.
3. The tanks used by most of scuba divers are filled with air diluted with helium of around
(MQP-2)
a) 88.3% b) 56.2% c) 32.1% d) 11.7%
4. The concentration term depends on temperature is (MQP-3)
a) ppm b) mole fraction c) molality d) molarity
5. When a non-volatile solute is added to the pure solvent, the freezing point of
Solvent Ans: decreases (MQP-1)

PART-B(2M)
6. Draw a graph to show variation of vapour pressure of solvent and solution with respect to
temperature. (MQP-2)
7. Write the expression to relate cryoscopic constant and change in enthalpy of fusion.
Explain the terms involved in it. (MQP-3)

PART-C(3M)
8. Name the two components present in binary solution. Which component determines the
physical state of binary solution? (MQP-1)
9. Write three reasons to justify that osmotic pressure method has the advantage over other
colligative methods for the measurement of molar mass of proteins and polymers.(MQP-2)
10. Give any three differences between ideal and non -ideal solutions. (MQP-3)
 PART-E (NUMERICAL PROBLEMS)
11. Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105 mm
of Hg. Calculate the mole fraction of methane in benzene at 298 K under 760 mm Hg.
(MQP-1)
12. A 5% solution (w/w) of cane sugar (C12H22O11) in water has freezing point of 271K.
Calculate the freezing point depression constant. Given freezing point of pure water is
273.15 K. (MQP-1)

13. Calculate the mass of Vitamin C (ascorbic acid, C6H8O6) to be dissolved in 78 g of acetic

acid to lower its melting point by 1.5°C.Given: Kf of acetic acid is 3.9 K kg mol-1.
(MQP-2)
14. Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two
liquid components are 105.2 KPa and 46.8 KPa respectively. Calculate the vapour
pressure of a solution containing of 26.0 g of heptane and 35 g of octane. (MQP-2)
15. Vapour pressure of water at 293K is 17.535 mm Hg. Calculate the vapour pressure of
water at 293K when 25 g of glucose is dissolved in 450 g of water. (MQP-3)
16. Calculate the molality of 20% (w/v) aqueous solution of KI. Given density of aqueous
–3 -1
solution of KI = 1.2gcm . Molar mass of KI = 166 g mol . (MQP-3)

Unit-02
Electrochemistry
MQP PART-A PART-B PART-C PART-D PART-E TOTAL
24-25 MCQ FIB 2M INORG PHY ORG PROBLEMS MARKS
MQP-1 8 - - - 31,33 - 43,45 13
MQP-2 6 - - - 32,34 - 43,44 13
MQP-3 5 - - - 32,34 - 43,44 13

PART-A(1M) MCQs
2+ 2+ 2+
1. The Eoof Fe /Fe, Zn /Zn and Sn /Sn are –0.44 V, –0.76 V and –0.14 V respectively.

Which metal/s is/are act as sacrificial electrode to protect iron from rusting? (MQP-1)
a) Both Zn and Sn b) Zn only c) Sn Only d) neither Zn nor Sn.
2. A galvanic cell has electrical potential of 1.1 V. If an opposing potential of 1.1V is applied
to this cell, what will happen to the cell reaction and current flowing through the cell?
(MQP-2)
a) The reaction stops and no current flows through the cell.
b) The reaction continuous but current flows in opposite direction.
c) The concentration of reactants becomes unity and current flows from cathode to anode.
d) The cell does not function as a galvanic cell and zinc is deposited on zinc plate

PART-C(3M)
3. Direct measurement of conductivity of ionic solutions by Wheatstone bridge is not
 possible. Give reasons. Suggest a remedy to resolve it. (MQP-1)
4. State Faraday’s II law of electrolysis. Mention any two factors which determines the
product of electrolysis. (MQP-1)
5. Plot a graph of molar conductivity v/s √c for strong and weak electrolytes in solution. For
strong electrolytes, Write the equation that represent the variation of molar conductivity
with dilution. (MQP-2)
6. During working of Leclanche cell, Write the anodic and cathodic reaction. What is the role
of produced ammonia during cell reaction? (MQP-2)
7. Name the fuel cell used in Apollo space programme and write its anodic and cathodic
reaction. (MQP-3)

8. Mention any three thermodynamic properties determined by using electrochemical

cells. (MQP-3)
PAET-E (NUMERICAL PROBLEMS-3M)
9. The molar conductivity of 0.025 mol L–1 methanoic acid is 46.1 S cm2 mol–1. Calculate
2 -1
its degree of dissociation. Given λo(H+)349.6Scm mol = and λo (HCOO ) = 54.6Scm2mol-1.
(MQP-1)

10. Two electrolytic cells A and B containing solutions of AgNO 3 and CuSO4 respectively are
connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g
of silver is deposited at the cathode of cell A. How long did the current flow and what mass
of copper was deposited? [Atomic mass of copper = 63.5 and silver = 108]. (MQP-1)
–1
11. The electrical resistance of a column of 0.05 mol L NaOH solution of diameter 1 cm and

length 50 cm is 5.55 × 103 ohm. Calculate its resistivity, conductivity and molar

conductivity. (MQP-2)
12. Calculate the Gibbs free energy change and equilibrium constant for the cell reaction
3+ - +2
2Fe (aq) + 2I → 2Fe + (aq) + I2. (MQP-2)

13. Calculate the emf of the following cell and state whether the cell is feasible or not?

- 2 -
14. Calculate the limiting molar conductivity of Cl by the data λo for CaCl2 = 271.6 Scm mol
2 -1
and λo for Ca+2 = 119.0 Scm mol (MQP-3)

Unit-3
Chemical Kinetics
MQP PART-A PART-B PART-C PART-D PART-E TOTAL
24-25 MCQ FIB 2M INORG PHY ORG PROBLEMS MARKS
MQP-1 11 - 23 - 32 - 41,46 12
MQP-2 2,10 20 - - 31 - 45,46 12
MQP-3 6,13 17 - - 31 - 45,46 12
 PART-A(1M) MCQs
1. All natural and artificial radioactive decay of unstable nuclei take place by (MQP-1)
a) zero order kinetics b) half order kinetics
c) first order kinetics d) second order kinetics
2. Order of a reaction in which unit of rate of reaction and rate constant are same (MQP-2)
a) 0 b) 1 c) 1/2 d) 2
3. Compounds A and B react according to the following chemical equation
2A(g) +B(g) ——→ 2C (g) concentration of either A or B were changed by keeping the
concentrations of one of the reactants constant and the rates were measured as a function
of initial concentration. Following results were obtained. Choose the correct option for
the rate equation for this reaction.(MQP-2)

a) Rate= k[A]2 [B] b) Rate= k[A] [B]2

c)Rate= k[A] [B] d) Rate= k[A]2
4. The radioactive substance reduced to 1/4 TH of initial concentration in 20 min, then time
taken to reduce to 1/16th of the initial concentration is (MQP-3)
a) 60 min b) 120 min c) 40 min d) 15 min
5. The following factor which does not affect the rate of reaction is (MQP-3)
a) molecularity b) temperature
c) catalyst d) concentration of reactant
6. Change in standard Gibbs free energy (∆G °) of a reaction is does not altered by the
addition of Ans: catalyst (MQP-2)
7. The rate at a particular moment of time is expressed as rate of reaction.
Ans: instantaneous (MQP-3)
PART-B(2M)
8. Define half-life period of a reaction. Write the relationship between half-life period and
initial concentration of zero order reaction.
PART-C(3M)
9. For the reaction R(s) → P(g), the potential energy diagram is given below: (MQP-1)

By observing the above diagram, answer the following.

 a) What is the value of activation energy of the reaction?
b) What is the value of ΔH of the reaction?
c) Draw potential energy diagram for the reaction P(g) → R(s).
10. What is the effect of temperature on the rate constant of reaction? How can this
temperature effect on rate constant be represented quantitatively? (MQP-2)

11. What does P and ZAB represent in the equation: Rate= P Z AB e–Ea /RT= ? Name a factor on
which Z depends. (MQP-3)
PART–E (NUMERICAL PROBLEMS-3M)
12. Show that in a first order reaction, time required for completion of 99.9% is 10 times of
half-life (t1/2) of the reaction. (MQP-1)
13. The rate constant of a reaction is given by:

.
Calculate the activation energy and pre-exponential factor (A).(MQP-1)
14. The rate of a reaction quadruples when the temperature changes from 293 K to 313 K.
Calculate the energy of activation of the reaction assuming that it does not change with
temperature. (MQP-2)
15. A reaction is first order in A and second order in B. (MQP-2)
(i) Write the differential rate equation.
(ii) How is the rate affected on increasing the concentration of ‘B’ three times and
decreasing the concentration of ‘A’ by 2 times?
(iii) How is the rate affected when the concentrations of both ‘A’ and ‘B’ are tripled?
16. The rate constant for a reaction is 60 S–1. How much time will it take to reduce the
initial concentration of the reactant to its 1/16th value? (MQP-3)
–2 -1 -1
17. In the given reaction A→B, the rate constant k is 2.0 x 10 lit mol s , find initial rate
of reaction when [A]= 0.5 M at 298K. (MQP-3)

Unit-04
The d and f-Block Elements
MQP PART-A PART-B PART-C PART-D PART-E TOTAL
24-25 MCQ FIB 2M INORG PHY ORG PROBLEMS MARKS
MQP-1 5 16 25 26,28 - - - 09
MQP-2 2,10 - - 26,28,30 - - - 11
MQP-3 2 18 21 27,30 - - - 09

PART-A (1M) MCQs

1. The most stable manganese compound is (MQP-1)

a) Mn2O7 b) MnF4 c) MnO2 d) MnSO4

2. The correct order of melting point is. (MQP-2)
a) Cr > Mn > Fe b) Fe > Mn > Cr c) Cr > Fe > Mn d) Mn > Fe > Cr
3. Identify the correct sequence of number of unpaired electrons of the following ions.(MQP-3)
a) Ti+3 > Cr3+ > Fe3+ > Ni2+ b) Fe3+ > Ni2+ > Ti+3 > Cr3+
c) Fe3+ > Cr3+ > Ni2+ > Ti+3 d) Fe3+ > Cr3+ >Ti+3 > Ni2+
4. The melting point of interstitial compound is than the pure metal.(MQP-1)
Ans: greater

5. The diamagnetic lanthanoid ion is (MQP-3) Ans: Yb2+

PART-B (2M)
6. Iron (III) catalyses the reaction between iodide and persulphate ions in the reaction

Explain the catalytic action of catalyst iron (III) by using chemical reactions. (MQP-2)
7. Name an important alloy, which contains maximum percentage of the lanthanoid metals.
Mention one of its use. (MQP-3)
PART-C (3M)
8. Study of actinoids elements is more difficult? Give any three reasons. (MQP-1)
9. A student of 2nd PU performs two trails of reactions between KI and KMnO4. In first trail
student add small amount of acid to reaction mixture and in second trail student forgot
to add acid to reaction mixture. Then student observed that different colour was obtained
in first and second trail. Give reason for above observation. Write the possible chemical
reactions to both the trails. (MQP-1)
10. When a chromite ore ‘A’ is fused with sodium carbonate in free excess of air and the
product is dissolved in water, a yellow solution of compound ‘B’ is obtained. After
treatment of this yellow solution with sulphuric acid compound ‘C’ can be crystallize
from the solution. When compound ‘C’ is treated with KCl orange crystals of compound
‘D’ is crystallizes out. Write all the reactions involved in the conversion of ‘A’ to ‘D’.
(MQP-2)

11. Fluorine has ability to stabilize most of transition metal in higher oxidation states. Give
two reasons with an example. (MQP-2)
12. What is lanthanoid contraction? Name two elements of actinoids which exhibits +7
oxidation state in their compounds. (MQP-2)
13. Write the equations for the preparation of potassium permanganate from pyrolusite ore,
what is the colour of KMnO4 crystals? (MQP-3)
14. Transition elements have higher enthalpy of atomization. Give two reasons. Among 3d
and 4d series of transition elements, which series has higher enthalpy of atomization?
(MQP-3)

Unit-05
Coordination Compounds
MQP PART-A PART-B PART-C PART-D PART-E TOTAL
24-25 MCQ FIB 2M INORG PHY ORG PROBLEMS MARKS
MQP-1 3,7 - - 27,29,30 - - - 11
MQP-2 1,14 17 23 27,29 - - - 11
MQP-3 10 - - 26,28,29 - - - 10

PART-A (1M) MCQs

1. The complex PtCl2.4NH3Br2 is treated with excess of AgNO 3 solution, two mole of AgBr is
precipitated. The primary and secondary valence of this complex is (MQP-1)
a) 6 and 1 b) 6 and 2 c) 4 and 6 d) 3 and 6
2. An ambidentate ligand is (MQP-1)
– +
a) Cl– b) CN c) OH– d) NO2

3. Square planar complex of the type [MABXL] (where A, B, X, L are unidentate) shows (MQP-2)
a) Two Cis and one Trans b) Two cis and Two trans
c) One Cis and two Trans d) one Cis and One Trans
4. The magnitude of CFSE (crystal field splitting complex, ∆o ) can be related to the
configuration of dorbitals in a coordination entity is (MQP-2)

3 1
Ans: a) if ∆o< P, the configuration is t 2g ,e g

5. The geometry of the complex Fe(CO)5 is (MQP-3)

a) octahedral b) tetrahedral c) trigonal bipyramidal d) square pyramidal
6. Vitamin B12 is a coordination compound of metal (MQP-2) Ans: cobalt

PART-C(3M)
7. What are heteroleptic complexes? What is the co-ordination number in complex
+
[Co(ox)2Cl2] (MQP-2) .
8. For the complex, Mercury (I) tetrathiocyanato-S-cobaltate (III)
a) What is coordination number of Co.
b) Identify the ligand present in this complex.
c) Does ionization isomer for the following compound exist? (MQP-2)
9. Define Crystal field splitting. Sketch the energy level diagram for the crystal field
splitting of d-orbital in a tetrahedral complex. (MQP-2)
10. What is the significance of synergic effect in metal carbonyls? How many bridged and
non-bridged CO (carbonyl) ligands are present in octacarbonyldicobalt (0) complex
compound? (MQP-2)
+1
11. Write the IUPAC name of [CoCl2(en)2] . Draw the geometrical isomers for this
complex.(MQP-2)
12. Write any three limitations of Valence Bond Theory (VBT) of coordination compounds.(MQP-2)
13. Using abbreviations of following ligands, identify the number of donor sites and write the
formula of each ligand. (MQP-3)
a) en b) EDTA c) PPh3
14. Using Valence Bond Theory [VBT], explain geometry, hybridisation and magnetic property
3–
of [CoF6] ion. [Atomic number of Cobalt is 27]. (MQP-3)
15. Give any three applications of coordination compounds. (MQP-3)

Unit-06
Haloalkanes and Haloarenes
MQP PART-A PART-B PART-C PART-D PART-E TOTAL
24-25 MCQ FIB 2M INORG PHY ORG PROBLEMS MARKS
MQP-1 4,9 - 21 - - 38 - 09
MQP-2 5 - 24 - - 40 - 08
MQP-3 3 16 22 - - 36 - 09

PART-A(1M) MCQs
1. Statement I: Enantiomers are non-superimposable mirror images on each other.
Statement II: A racemic mixture shows zero optical rotation.
Identify the correct statement (MQP-1)
a) Both statement I and II are correct
b) Both statement I and II are incorrect
c) Statement I is correct and statement II is incorrect.
d) Statement I is incorrect and statement II is correct.
2. The chemical name of phosgene is (MQP-1)
a) chromyl chloride b) triphenylphosphine
c) phosphorusoxychloride d) carbonyl chloride.
3. 1,2-dichloroethane is an example of (MQP-2)
a) alkylene dihalides b) alkylidene halides
c) vinyl dihalides d) gem-dihalides.
4. Four haloalkane compounds represented by the letters M, N, O and P having boiling point
are 24.2°C, 38°C, 3.56°C and 101.6°C respectively. Among the four compounds N most
likely to be (MQP-3)

a) CH3Cl b) CH3Br c) C2H5Br d) C3H7I

5. During Surgery, _____________ was used as anesthesia. (MQP-3) Ans: CHCl3

PART-B(2M)
6. Explain Swart’s reaction with an example. (MQP-1)

7. Chlorobenzene cannot be prepared by reacting phenol with SOCl2. Give reasons. (MQP-2)
8. Explain Fittig’s reaction. (MQP-3)
PART-D(5M)
9. a) Complete the following equation. (MQP-1)
 b) Explain Saytzeff rule with an example.(MQP-1)

10. a) Write any three differences between SN1 and SN2 reaction mechanisms. (MQP-2)
b) Identify A and B in the given reaction

11. a) Write the mechanism involved in the conversion of 2-bromo-2-methyl propane to

2-methyl propane-2-ol. (MQP-3)
b) What are enantiomers? Name one Physical Property which differs enantiomers.

Unit-07
Alcohols,Phenols and Ethers
MQP PART-A PART-B PART-C PART-D PART-E TOTAL
24-25 MCQ FIB 2M INORG PHY ORG PROBLEMS MARKS
MQP-1 1,14 18 24 - - 40 - 10
MQP-2 3,9 19 22 - - 39 - 10
MQP-3 7,8 19 25 - - 37 - 10

PART-A(1M) MCQs
1. The role of CO2 in Kolbe’s reaction is (MQP-1)
a) acts as catalyst b) act as nucleophile
c) act as weak electrophile d) act as strong electrophile.
2. The chemicals used to convert commercial alcohol into denatured alcohol are (MQP-1)

a) CuSO4 and Pyrolidine b) Cu2S and Pyrolidine

c) CuSO4 and Pyridine d) Cu2S and Pyridine.

3. Statement I: Tertiary alcohols heated with copper at 573 K yields 2-methyl propene.(MQP-2)
Statement II: Tertiary alcohols undergo dehydration when heated with Cu /573K.
Identify the correct statement
a) Both statement I and II are correct
b) Both statement I and II are incorrect.
c) Statement I is correct and statement II is incorrect.
d) Statement I is in correct and statement II is correct.
o o, o
4. The C–O– bond angles of P, Q and R are found to be 111.7 , 109 108.9 respectively,
compound P, Q and R are (MQP-2)
a) P= Phenol, Q =Methanol, R = Methoxy Methane.
b) P = Methoxy Methane, Q =Methanol, R = Phenol.
c) P= Methanol, Q =Phenol, R = Methoxy Methane.
d) P= Methoxy Methane, Q =Phenol, R = Methanol.
5. The product/s formed when phenol is treated with excess of bromine water is/are (MQP-3)
(i) o-bromophenol (ii) p- bromophenol
(iii) picric acid (iv) 2,4,6- tribromophenol
a) only (iii) b) only (iv)
c) both (i) and (ii) d) only (ii)

6. Which of the following observation is shown by 2–methylpropan-2-ol with Lucas reagent? (M-3)
a) Turbidity will be observed after five minutes.
b) No turbidity will be observed at room temperature.
c) Turbidity will be observed immediately.
d) Turbidity will be observed at room temperature but will disappear after five minutes.

7. The simplest hydroxy derivative of benzene is (MQP-1) Ans: phenol

8. The chemical name of wood spirit is (MQP-2) Ans: methanol
9. Williamson’s synthesis of preparing dimethyl ether involves reaction for the attack

of a methoxide ion on methyl chloride. (MQP-3) Ans: SN2

PART-B(2M)
10. Write the reactions involved in preparation of phenol from cumene. (MQP-1)
11. Explain the preparation of methoxyethane by Willamson’s synthesis.Give equation.(MQP-2)
12. Complete the following reaction and name the reaction.

PART-D (5M)
13. a) Write the reaction involved in the mechanism of acid catalyzed dehydration of alcohol
to alkene. (MQP-1)
b) Explain the preparation of anisole by Williamson synthesis. (MQP-1) (3+2)

14. a) Give the mechanism involved in the acid catalyzed hydration of C2H4 to C2H5OH.(MQP-3)
b) Name the enzyme involved in fermentation of glucose into ethanol and write its
chemical equation. (MQP-3)

15. a) An alkene X (C3H6) reacts with H2O/H+ to give compound Y, compound Y further

undergo reaction with CrO3-H2SO4 to produce compound Z. Write the IUPAC name of

compounds X, Y and Z. (MQP-2)

b) Which among the following compounds have lowest and highest pKa value? (3+2)
p-nitrophenol, phenol, ethanol and o-cresol (MQP-2)
 Unit-08
Aldehydes,Ketones and Carboxylic Acids
MQP PART-A PART-B PART-C PART-D PART-E TOTAL
24-25 MCQ FIB 2M INORG PHY ORG PROBLEMS MARKS
MQP-1 6 20 - - - 36,39 - 12
MQP-2 7,11 - - - - 36,38 - 12
MQP-3 11,12 - - - - 35,40 - 12

PART-A (1M) MCQs

1. Among the following alkyl benzenes which one will not give the benzoic acid on oxidation
with acidic KMnO4 solution. (MQP-1)

2. As the size of the aldehyde molecule increases, the odour becomes (MQP-2)
a) more pungent b) more fragrant c) less fragrant d) no change in the odour.
3. The reagent useful for separation and purification of aldehydes is (MQP-2)
a) silver nitrate solution b) sodium hydrogen sulphite
c) Fehling’s solution d) sodium sulphate.

4. Match the following given in List I with List II (MQP-3)

a) A-(iv), B- (iii), C-(ii), D-(i) b) A-(iii), B-(i), C-(iv), D-(ii)

c) A-(iii), B-(i), C-(ii), D-(iv) d) A-(iii), B-(ii), C-(iv), D-(i)
5. Ozonolysis of alkenes followed by reaction with zinc dust and water gives (MQP-1)
Ans: aldehydes

PART-D(5M)
6. a) Between methanal and ethanal, which would undergo aldol condensation? Write the
chemical reaction involved in it. (MQP-1)
b) Although phenoxide ion has more number of resonating structures than carboxylate
ion, carboxylic acid is a stronger acid than phenol. Why? (3+2) (MQP-1)
7. a) Give the chemical equation for the Conversion of propane nitriles into corresponding
 ketones by using phenyl magnesium bromide.Write the IUPAC name of the product .(M-1)
b) Explain Hell-Volhard-Zelinsky (HVZ) reaction with an example. (3+2) (MQP-1)
8. a) Write the mechanism for the addition of HCN to carbonyl compound in the presence of
base. (MQP-2)
b) Aromatic carboxylic acid does not undergo Friedel crafts reaction.Give reasons.(2) (M-2)
9. a) Write the reactions involved in the conversion of toluene to m-nitrobenzoic acid.(M-3)
b) The pKa values of acetic acid, benzoic acid and trifluoroacetic acid are 4.76, 4.19 and
0.23 respectively. Arrange them in the increasing order of acid strength. Justify the
arrangement. (3+2) (MQP-3)

10. An organic compound (X) with molecular formula C 8H8O forms an orange-red precipitate
with 2,4- DNP reagent and gives yellow precipitate on heating with iodine in the presence
of sodium hydroxide. It neither reduces Tollens reagent nor does it decolourise bromine
water. On oxidation with chromic acid, ‘X’ gives a carboxylic acid (Y) having molecular

formula C7H6O2. Identify the compounds (X) and (Y) and write all the reactions involved.

Unit-09

Amines
MQP PART-A PART-B PART-C PART-D PART-E TOTAL
24-25 MCQ FIB 2M INORG PHY ORG PROBLEMS MARKS
MQP-1 13 17 - - - 35 - 07
MQP-2 13 18 - - - 37 - 07
MQP-3 14,15 - - - - 39 - 07

PART-A (1M) MCQs

1. p-Aminoazobenzene is prepared from benzenediazonium chloride and aniline in (MQP-1)
a) acidic medium b) basic medium
c) neutral medium d) both acidic and basic medium.
2. The product formed from the following reaction sequence is (MQP-2)

3. The correct order of basic strength in case of ethyl substituted amines in aqueous solution
is (MQP-3)
a) (C2H5)2NH > (C2H5)3N > C2H5NH2 > NH3
b) (C2H5)3N > (C2H5)2NH > C2H5NH2 > NH3
c) (C2H5)3N > C2H5NH2 > (C2H5)2NH > NH3
 d) NH3 > (C2H5)2NH > (C2H5)3N > C2H5NH2
4. N-Ethylbenzenesulponamide soluble in alkali because (MQP-3)
a) It does not contain any hydrogen atom attached to nitrogen atom and is not acidic.
b) It contains hydrogen atom attached to nitrogen atom and is strongly acidic.
c) It contains hydrogen atom attached to nitrogen atom but is not acidic.
d) It does not contain any hydrogen atom attached to nitrogen atom but is acidic.
5. Benzenediazonium fluoroborate on heating decomposes to give (MQP-1)
Ans: fluorobenzene
6. Primary aliphatic amines convert into aliphatic alcohols on reacting with
solution. (MQP-2) Ans: HNO2

PART-D(5M)
7. a) How do you distinguish between primary, secondary and tertiary amines by using
Hinsberg’s reagent with chemical equations involved? (MQP-1)
b) Give the preparation of p-hydroxyazobenzene. (3+2) (MQP-1)
8. a) Explain Hoffmann bromamide degradation reaction by taking butanamide as an example.
Give the IUPAC name of the product. (MQP-2)
b) pKb of aniline is more than that of methanamine. Give reasons.(MQP-2)
9. a) Identify the product A, B and C.(MQP-3)

b) Name any one biologically active amino compound used in the following: .(MQP-3)
(i) to increase blood pressure (containing secondary amino group)
(ii) as an anaesthetic in dentistry (a synthetic amino compound)
 Unit-10
Biomolecules
MQP PART-A PART-B PART-C PART-D PART-E TOTAL
24-25 MCQ FIB 2M INORG PHY ORG PROBLEMS MARKS
MQP-1 2,12 - 22 - - 37 - 09
MQP-2 8,12 16 25 - - 35 - 10
MQP-3 4,9 20 24 - - 38 - 10

PART-A (1M) MCQs

1. In DNA, the linkage between different nitrogenous bases is (MQP-1)
a) phosphate linkage b) glycosidic linkage
c) peptide linkage d) hydrogen bonding.
2. Match the following (MQP-1)

a) A-(iv), B- (v), C-(ii), D-(i) b) A-(iii), B-(v), C-(iv), D-(i)

c) A-(ii), B-(i), C-(v), D-(iv) d) A-(iii), B-(ii), C-(iv), D-(i)

3. Sulphur containing amino acid is; (MQP-2)

a) cysteine b) tyrosine c) histidine d) proline
4. Match the following given in column I with Column II (MQP-2)

a) i-C, ii-D, iii-B, iv -A b) i-C, ii-A, iii-B, iv -D

c) i-D, ii-B, iii-C, iv -A d) i-A, ii-B, iii-C, iv –D
5. Glycine is an optically inactive α-amino acid due to (MQP-3)
a) presence of asymmetric carbon atom b) absence of asymmetric carbon atom
c) α-carbon attached to 4 different groups d) its acidic nature.
9. The transition metal present in red pigment of blood haemoglobin is (MQP-3)
a) cobalt b) nickel c) iron d) copper.

FIB
10. Storage polysaccharide present in animals is Ans: glycogen (MQP-2)
11. Nucleotides are joined together by linkage between and carbon atoms of pentose
 sugar. Ans: phosphodiester (MQP-3)
PART –B (2 M)
12. Write the reactions show that glucose contains
a) Five hydroxyl groups
b) Aldehyde group. (MQP-1)
13. What are hormones? Name a hormone that mediate responses to external stimuli. (MQP-2)
14. Give an example for female sex hormone and write its function. (MQP-3)
PART-D (5M)
15. a) What is peptide bond? Give an example for dipeptide. (2+2+1) (MQP-1)
b) What are oxidoreductase enzymes? Name the enzyme that catalyses hydrolysis of
maltose into glucose. (MQP-1)
c) Give any one main natural source of Vitamin K? (MQP-1)
16. a) Give any two differences between amylose and amylopectin. (2+2+1) (MQP-2)
b) Name any two main forces which stabilize the secondary and tertiary structures of
proteins. (MQP-2)
c) Which vitamin deficiency causes the increased fragility of RBC’s and muscular
weakness. (MQP-2)
17. a) What does tertiary structure of proteins represent? Give its two major molecular
shapes. (MQP-3)
b) Write the Haworth structure of α – D – (+)-Glucopyranose. (MQP-3)