13-10-2024

9610ZJM801335240010 JM

PART 1 : PHYSICS

SECTION-A

1) A particle is performing simple harmonic motion with time period T. At an instant its speed is 60%
of its maximum value and is increasing. After an interval Δt its speed becomes 80% of its maximum
value and is decreasing. The smallest value of Δt in terms of T will be :-

(A)

(B)

(C)

(D)

2) A particle moves on the x-axis according to the equation x = A + Bsinωt. The motion is simple
harmonic with amplitude :-

(A) A
(B) B
(C) A + B
(D)

3) In the shown arrangement, the coefficient of friction between the blocks is µ and no friction
between ground surface and block 2m. The blocks are displaced slightly and released. They move
together without slipping on each other. The time period will be :-

(A)

(B)

(C)

(D)
4) A particle performing S.H.M. about mean position x = and at t = 0. It has displacement
and moving away from the origin. Then which of the following is its possible graph between position
(x) and time (t)

(A)

(B)

(C)

(D)

5) A particle moves along X axis such that its acceleration is given by a = –β (x – 2). Where β is a
positive constant and x is the position coordinate. The time period of oscillation (in sec) :-

(A) π
(B) 2π

(C)

(D)

6) Both the frequency and the intensity of a beam of light falling on the surface of photoelectric
material are increased by a factor of two. This will:

increase both, the maximum kinetic energy of the photo-electrons, as well as photoelectric
(A)
saturation current by a factor of two.
increase the maximum kinetic energy of the photo-electrons by a factor greater than two and
(B)
would increase the photoelectric saturation current by a factor of two.
increase the maximum kinetic energy of the photoelectrons by a factor greater than two and
(C)
will have no effect on the magnitude of the photoelectric saturation current produced.
 increase the maximum kinetic energy of the emitted photo-electrons by a factor of two but will
(D)
have no effect on the saturation photoelectric current.

7) According to Moseley's law the ratio of the slopes of graph between and Z for Kβ and Kα is:
(where the symbols have their usual meaning).

(A)

(B)

(C)

(D)

8) A radioactive sample disintegrates via two independent decay processes having half lives

and respectively. The effective half-life T1/2 of the nuclei is :

(A) None of the above

(B)

(C)

(D)

9) The binding energies of deutron and α-particle are 1.125 and 7.2 MeV/nucleon
respectively. In the process , Amount of energy transferred is & which nucleus is
more stable ?

(A) 24.3 MeV liberated,

(B) 24.3 MeV liberated,

(C) 24.3 MeV supplied,

(D) 24.3 MeV supplied,

10) A photoelectric material having work-function ϕ0 is illuminated with light of wavelength

. The fastest photoelectron has a de Broglie wavelength λd. A change in wavelength of

the incident light by Δλ results in a change Δλd in λd. Then the ratio is proportional to

(A)
(B)

(C)

(D)

11) If the binding energy of the electron in a hydrogen atom is 13.6 eV, the energy required to
remove the electron from the first excited state of Li2+ is-

(A) 30.6 eV
(B) 13.6 eV
(C) 3.4 eV
(D) 122.4 eV

12) Energy levels A, B and C of a certain atom correspond to increasing values of energy i.e.
EA < EB < EC. If λ1 ,λ2 and λ3 are wave lengths of radiations corresponding to transitions C to B, B to
A and C to A respectively, which of the following relations is correct :

(A) λ3 = λ1 +λ2

(B)

(C) λ1 + λ2 +λ3 = 0
(D)

13) If each fission in a U235 nucleus releases 200 MeV, how many fissions must occurs per second to
produce a power of 1 KW

(A) 1.325 × 1013

(B) 3.125 × 1013
(C) 1.235 × 1013
(D) 2.135 × 1013

14) A mixture consists of two radioactive materials A1 and A2 with half lives of 20s and 10s
respectively. Initially the mixture has 40g of A1 and 160g of A2. The active amount of the two in the
mixture will becomes equal after :

(A) 20s
(B) 40s
(C) 60s
(D) 80s

15) The half-life of a radioactive element A is the same as the mean-life of another radioactive
element B. Initially both substances have the same number of atoms, then :

(A) B will decay at a faster rate than A initially

(B) A and B both decay at the same rate always
(C) A will decay at a faster rate than B initially
(D) A and B will decay at the same rate initially

16) The energy spectrum of β-particles, number N(E) as a function of β-energy E emitted from a
radioactive source is-

(A)

(B)

(C)

(D)

17) A photon of 10.2 eV energy collides with a hydrogen atom in ground state inelastically. After few
microseconds one more photon of energy 15 eV collides with the same hydrogen atom. Then what
can be detected by a suitable detector.

(A) one photon of 10.2 eV and an electron of energy 1.4 eV

(B) 2 photons of energy 10.2 eV
(C) 2 photons of energy 3.4 eV
(D) 1 photon of 3.4 eV and one electron of 1.4 eV

18) The maximum number of emission lines for atomic hydrogen that you would expect to see with
naked eye if the only electronic levels involved are those shown in the figure, is
(A) 6
(B) 5
(C) 21
(D) ∞

19) A particle is travelling 4 times as fast as an electron. Assuming the ratio of de-Broglie
wavelength of a particle to that of electron is 2 : 1, the mass of the particle is :-

(A)
times the mass of e–
(B) 8 times the mass of e–
(C) 16 times the mass of e–

(D)
times the mass of e–

20) Which of the following transitions of He+ ion will give rise to spectral line which has same
wavelength as some spectral line in hydrogen atom ?

(A) n = 4 to n = 2
(B) n = 6 to n = 5
(C) n = 6 to n = 3
(D) None of these

SECTION-B

1) Ratio of debroglie wavelength of electron in third orbit of hydrogen atom to the debroglie
wavelength of electron in first orbit of hydrogen is

2) Given a sample of Radium-226 having half-life of 4 days. If the probability is then what is the
value of N, a nucleus disintegrates within 2 half lives.

3) A hydrogen like atom has one electron revolving around a stationary nucleus. The energy
required to excite the electron from the second orbit to the third orbit is 47.2 eV. The atomic number
of the atom is _____.

4) In an experiment on photoelectric effect, the slope of the cut-off voltage (y-axis) versus frequency
(x-axis) of incident light is found to be 4.12 × 10–15 V s. If the value of Planck's constant is P × 10–15
eV-s then value of 100 × P × 10–15 will be.

5)

The kinetic energy of an α-particle which flies out of the nucleus of a Ra226 atom in radioactive
disintegration is 4.78 MeV. If the total energy evolved during the escape of the α-particle is E then
value of 100E.
6) Radiations of two photons of energies twice and five times the work function of a metal are
incident successively on the metal surface. If the ratio of maximum velocities of photo electrons in
two cases is A then value of 2A will be.

7) A block of mass m is connected to three springs as shown in the figure. The block is displaced
down slightly and left free, it starts oscillating. Find the time period (in sec) of oscillations
(neglecting gravity).
(m = π2kg; π2 =10 ; θ = 60º; k1 = 4N/m; k2 = 23 N/m)

8) A light uniform rod of 3 m length is pivoted at one of its ends and a small sphere of mass 0.5 kg is
attached at the other end as shown in the Figure. The rod with the sphere is at rest in the horizontal
plane with two attached springs S1 and S2 each of spring constant 1000 Nm–1. If angular frequency of
oscillation of the sphere about the pivot O is ω then value of 3ω(Take π = 22/7)

9) The system shown is in equilibrium. The string is cut at t = 0. The spring comes to its natural
length at t = t1 sec. If minimum value of t1 is T then value of 5T will be (Take : π2 = 10)
10) Three SHM in the same direction, having same amplitude and same period, are superimposed. If
each differ in phase from the next by 45°. Then, find the energy associated with resulting motion
taking energy associated with each of given SHM as 1 J. If the calculated energy is E then value of
100E will be.

PART 2 : CHEMISTRY

SECTION-A

1) For the reaction that taking place at certain temperature NH4HS(s) ⇌ NH3(g) + H2S(g),
if equilibrium pressure is X bar, then ΔrG° would be :-

(A) – 2 RT ln X
(B) – RT (ln X – ln2)
(C) – 2 RT (ln X–ln 2)
(D) – 0.5 RT (ln X–ln 2)

2) What is the free energy change (ΔG) when 1.0 mole of water at 100°C and 1 atm pressure is
converted into steam at 100°C and 1 atm pressure ?

(A) 80 cal
(B) 540 cal
(C) 620 cal
(D) zero

3) If ΔG° > 0 for a gaseous reaction then :

(A) KP > 1
(B) KP < 1
(C) The products predominate in the equilibrium mixture
(D) Mole of product must be less than mole of reactant
4) The value of ΔG°f of gaseous mercury is 38 kJ/mole. At what total external pressure mercury start
boiling at 27°C. (R.ln10 = 19 J/K-mol)

(A) 10–6.67
(B) 10–1.67
(C) 10–13.33
(D) 10–3.33

5) ΔfG° at 500 K for substance 'S' in liquid state and gaseous state are + 100.7 kcal mol–1 and + 103
kcal mol–1, respectively. Vapour pressure of liquid 'S' at 500 K is approximately equal to :
(R = 2 cal K–1 mol–1) -

(A) 0.1 atm

(B) 10 atm
(C) 100 atm
(D) 1 atm

6) Concentration of H2SO4 and Na2SO4 in a solution is 1 M and 1.8 × 10–2 M, respectively. Molar
solubility of PbSO4 in the same solution is:
[Given: Solubility product of PbSO4(Ksp) = 1.6 ×10–8. For H2SO4, Ka1 is very large and Ka2 = 1.2 ×
10–2]

(A)

(B)

(C)
(D)

7) The pink colour of phenolphthalein in alkaline medium is due to :-

(A) Negative ion

(B) Positive ion
(C) OH– ions
(D) Neutral form

8) The total number of different kind of acidic buffers obtained during the titration of H3PO4 with
NaOH are :

(A) 3
(B) 1
(C) 2
(D) 0

9) The pH of rain water, is approximately: [JEE (Main)-2019]

(A) 6.5
(B) 7.5
(C) 5.6
(D) 7.0

10) The order of reactivity of the following ester towards hydrolysis is

(A) I > II > III > IV

(B) II > I > III > IV
(C) IV > III > II > I
(D) IV > III > I > II

11) Major product ‘P’ formed in the following reaction is :-

P Major Product

(A)

(B)

(C)

(D)

12) product of given sequence

reaction is

(A) CH3CH2NH2
(B) CH3CH2—OH

(C)

(D)

13) In the following sequence of reactions?

Toluene the product C is

(A) C6H5COOH
(B) C6H5CH3
(C) C6H5CH2OH
(D) C6H5CHO

14) Reaction incorrectly matched with the product is?

(A)

(B)

(C)

(D)

15)

A compound which does not give a positive Lassaigne's test for 'N' is:

(A) Urea
(B) Hydrazine
(C) Phenyl hydrazine
(D) Glycine

16) Carbylamine test is used to detect the presence of primary amino group in an organic compound.
Which of the following compound is formed when this test is performed with aniline?

(A)

(B)

(C)

(D)

17)
In the chemical reactions given above A and B respectively are :

(A) H3PO2 and CH3CH2Cl

(B) CH3CH2OH and H3PO2
(C) H3PO2 and CH3CH2OH
(D) CH3CH2Cl and H3PO2

18) Which one of the following pairs is correctly matched?

(A) Sucrose : reducing sugar

(B) Glucose : mutarotation
(C) Fructose : aldose sugar
(D) Sucrose : monosaccharide

19) Which of the following is basic amino acid?

(A) Glycine
(B) Valine
(C) Histidine
(D) Alanine

20) The correct structure of purple coloured compound formed in the reaction of ninhydrin with
proteins is:

(A)

(B)

(C)

(D)

SECTION-B

1) For the reaction : A(g) 2B(g). The equilibrium pressure of A(g) is 1.0 bar. Now the
equilibrium mixture is compressed reversibly and isothermally such that the final total pressure of
system becomes 8 bar. The partial pressure of A(g) (in bar) at this new equilibrium is

2) Pure gas ‘A’ was taken in a closed container at a initial pressure of 5 atm. The pressure in the
container changed due to following reactions

A(g) B(g) + 2C(g)

C(g) B(g) + D(g)

If the total pressure due to mixture of gases A, B, C and D was found to be 10 atm, in which partial

pressure due to gas C was 3 atm. Find KP for first equilibrium ?

3)
What is the sum of double bond equivalent of final product(s) of above reaction sequence?

4) (P). Number of COOH group present in product “P” is

5) Calculate the minimum mass of AB2 (s) which must be added to 100 ml water (in mg) to form a
saturated solution. Ksp (AB2) = 3.2 × 10–11
Mw.t. [AB2(s)] = 100 g/mole
(Fill your answer as sum of digits till you get single digit.)

6) The pH of ammonium phosphate solution, if pKa of phosphoric acid and pKb of

ammonium hydroxide are 5.23 and 4.75 respectively, is ______.

7) A mixture of 1° amides (benzenoid) having molecular formula (C8H9NO) reacted with Br2/NaOH.
The number of 1° amines products formed will be :

8) Hoffmann reaction is found to follow the path.

The number of moles of NaOH consumed for formation of 1 mole of amine is ____

9)
Number of chiral centre in compound P is

10) The number of groups present in a tripeptide Asp – Glu – Lys is _________ .

PART 3 : MATHEMATICS

SECTION-A

1) The vector is to be written as the sum of a vector parallel to and a vector

perpendicular to , then equals
(A)

(B)

(C)

(D)

2) Vector in the plane of and is such that it is equally inclined to and

where The value of is :-

(A)

(B)

(C)

(D) None

3) If and are non-coplar vectors and is perpendicular to , then the value of

is equal to :-

(A)
(B)
(C)
(D)

4) Given three non-zero, non-coplanar vectors and = and The

vectors and are collinear then (p,q) is :-

(A) (0,0)
(B) (1,–1)
(C) (–1,1)
(D) (1, 1)

5) If and are the position vectors of the vertices A, B and C,

respectively, of triangle ABC, then the position vector of the point where the bisector of angle A
meets BC is :-

(A)

(B)
(C)

(D)

6) The equation of the plane passing through the lines and is

:-

(A) 11x – y – 3z = 35
(B) 11x + y – 3z = 35
(C) 11x – y + 3z = 35
(D) none of these

7)

The cartesian equation of the plane is :-

(A) 2x + y = 5
(B) 2x – y = 5
(C) 2x + z = 5
(D) 2x – z = 5

8) A line segment has length 63 and dr's are 3, –2, 6. If the line makes an obtuse angle with x-axis.
The components of the line vector are :-

(A) 27, –18, 54

(B) –27, 18, –54
(C) –27, 18, 54
(D) 27, –18, –54

9) The equation of a line which passes through point A(1,0,–1) and perpendicular to the straight lines

and and , is :-

(A)

(B)

(C)

(D) None of these

10) The intercepts made on the axes by the plane which bisects the line joining the points (1, 2, 3)
and (–3, 4, 5) at right angles are

(A)
(B)

(C)

(D)

11) If the lines 3x – 4y + 10 = 0 and 3x – 4y –15 = 0 are tangents to a circle, then the radius of
the circle is :-

(A) 5
(B) 25/2
(C) 5/2
(D) None of these

12) A variable circle passes through the fixed point P(a, b) and touches y-axis. The locus of the other
end of the diameter through P is :-

(A) (x – a)2 = 4by

(B) (x – b)2 = 4ay
(C) (y – a)2 = 4bx
(D) (y – b)2 = 4ax

13) The equation of the circle passing through the point (–1, –3) and touching the line 4x + 3y – 12 =
0 at the point (3, 0) is :-

(A) x2 + y2 – 2x + 3y – 3 = 0
(B) x2 + y2 + 2x – 3y – 5 = 0
(C) 2x2 + 2y2 – 2x + 5y – 8 = 0
(D) None of these

14) Let A ≡ (1, 2), B ≡ (3, 4) and let C ≡ (x, y) be a point such that (x – 1) (x – 3) + (y – 2) (y – 4)=0. If
area (ΔABC) = 1 then maximum number of positions of C in the x – y plane is :-

(A) 2
(B) 4
(C) 8
(D) 10

15)

The number of integral values of λ for which x2 + y2 + λx + (1 – λ)y + 5 = 0 is the equation of a circle
whose radius cannot exceed 5, is :-

(A) 14
(B) 18
(C) 16
(D) None of these

16) Tangents are drawn from the point (4, 3) to the circle x2 + y2 = 9. The area of the triangle
formed by them and the line joining their points of contact is :-

(A)

(B)

(C)

(D)

17) y = mx is a chord of a circle of radius 'a' and the diameter of the circle lies along x-axis and one
end of this chord is origin. The equation of the circle described on this chord as diameter is :-

(A) (1 + m2) (x2 + y2) – 2ax = 0

(B) (1 + m)2 (x2 + y2) – 2a(x + my) = 0
(C) (1 + m2) (x2 + y2) + 2a(x + my) = 0
(D) (1 + m2) (x2 + y2) – 2a(x – my) = 0

18) The locus of the mid-points of the chords of the circle , which subtends a

right angle at is :

(A) ax + by = 0
(B)

(C)

(D)

19) If the circles x2 + y2 + 2x + 2ky + 6 = 0 and

x2 + y2 + 2ky + k = 0 intersect orthogonally, then k is -

2 or
(A)

(B)
+2 or

(C)
–2 or –

(D)
–2 or
20) A uni-modular tangent vector on the curve x = t2 + 2, y = 4t – 5, z = 2t2 – 6t at t = 2 is :-

(A)

(B)

(C)

(D)

SECTION-B

1) Let be a vector perpendicular to , where .

If , then (ℓ + m + n) is equal to

2) If and and the projection of on is , then λ is equal to :-

3) Let , , and a vector satisfies ,

, then the value of is:-

4)

If are unit vectors such that and angle between is , if

the value of is k then the value of 1000 k is

5) The radius of the larger circle lying in the first quadrant and touching the line 4x + 3y – 12 = 0
and the coordinate axes is-

6) If the line 3x – 4y – k = 0 (k > 0) touches the circle x2 + y2 – 4x – 8y – 5 = 0 at (a, b) then k + a +

b is equal to :-

7) If the circumference of the circle x2 + y2 + 8x + 8y – b = 0 is bisected by the circle x2 + y2 – 2x +

4y + a = 0, then a + b equals to:-

8) If the circle x2 + y2 + 2ax + 2by + c = 0 and x2 + y2 + 2cx + 2ay + c = 0 where c > 0, have exactly

one point is common, then the value of is :

9) If the line 3x – 4y – k = 0 (k > 0) touches the circle x2 + y2 – 4x – 8y – 5 = 0 at (a, b) then
k + a + b is equal to :-

10) The radius of the larger circle lying in the first quadrant and touching the line 4x + 3y – 12 = 0
and the coordinate axes is-
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-A

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B A D D C A C B A A B B B A C A B D A

SECTION-B

Q. 21 22 23 24 25 26 27 28 29 30
A. 3 3 5 412 487 1 4 100 1 582

PART 2 : CHEMISTRY

SECTION-A

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. C D B A A C A A C C B A D C B D A B C D

SECTION-B

Q. 51 52 53 54 55 56 57 58 59 60
A. 4 9 2 2 2 7 4 4 4 5

PART 3 : MATHEMATICS

SECTION-A

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. A B C D C D C B B A C D A B C C B D B A

SECTION-B

Q. 81 82 83 84 85 86 87 88 89 90
A. 0 2 2 375 6 20 -56 1 20 6
 SOLUTIONS

PART 1 : PHYSICS

1) Ist case → n = 60° of vmax

n = 0.6 Aω

x1 = 0.8A
IInd case → n = 80% of vmax

x2 = 0.6A

α = 53°

β = 37°
θ = ωt

(α + β) = ωt ⇒

2) (x –A) = Bsinωt
SHM of particle about x = A and its amplitude is B.
3)
keff = k1 + k2 Parallel combination
= 2k + k = 3k

4)

Mean position at

at t = 0

at t = 0 it will move towards left extreme (negative displacement)

5) a = –β (x –2) Compares with the standard equatioh of SHM a = –ω2x.

∴ (Equilibrium position x = 2)

6)

The maximum K.E. of ejected photoelectron is (K.E)max = hν – ϕ0

If the frequency of photon is doubled, maximum kinetic energy of photon electron becomes
= 2hν – ϕ0

= >2

Photo current ∝
If intensity and frequency both are doubled, the photocurrent remains same.

7)
k-series, b = 1

for

Ratio of slopes=

8) λeq = λ1 + λ2

9)

10)

11)

12) EC – EB= ...(1)

EB – EA= ...(2)
EC – EA= ...(3)
On add equation (1) and (2)

EC – EA= hc

13)

Let n be number of fissions per second.

Each fission produces 200 MeV.
is produced in one second by n fissions
But
Hence, power produce Joule per second.
Also 1 J/s = 1W and
1000 J/s = 1 kW.
The required power is 1 kW.

Hence,

14) M01 = 40g M02 = 160g

T1 = 20s T2 = 10s
M1 = M2

t = 40s

15)
(N0)A = (N0)B
RA = λ(N0)A
RB = λ(N0)B

16)

The range of β particle lie between zero to some maximum value. During beta decay,
electrons or photons are released. Because a neutron or an antineutron is emitted
simultaneously, there is an emission spectrum of electrons or positions depending on the ratio
or Q reaction energies boron by the large particle. The shape of this energy curve can be
predicted from the Fermi theory of beta decay.

17) A photon of 10.2 eV energy collide with a H -atom in ground state in elastically this will not
case any transition but only sector with its fall energy so we can detect a photon of 10.2 eV.
After few microsound and more photon of energy 15 eV collides with the same H-atom with
cause an ionization of a electron from its ground state. So we can detect another e with
length.
15-13.6 = 1.4 eV

18)

Spectral lines of Balmer series are in visible range.

Balmer series lines are obtained due to transition of an electron to n = 2 state from any higher
state.

19)

20)

must be integer & square terms

n = 4 to n = 2

21)

velocity of an e– in
H– like atom

so (k = constant)
22) N =

Probability of survival =

23) 13.6 Z2 = 47.2

Z2 ≈ 25
Z ≈ 5.00

24) eVS = hf – ϕ

Slope = = 4.12 × 10–15

h = 4.12 × 10–15 eVs

25)

P1 = P2

kTotal = k1 + k2

kT = 4.87 MeV

26)

E1 = 2ϕ, E2 = 5ϕ
Kmax = E – ϕ
27)
Frestoring = 2k1xcos2θ + k2x

So,

28) Let the sphere be given a small displacement x from its equilibrium position. Then, the

spring is compressed by , the spring S2 is elongated by

Equation of motion (torque)

and ℓ = 3m

or

Angular velocity

29) &

30) ynet = y1 + y2 + y3
= a [sinωt + sin(ωt + 45°) + sin(ωt + 90)]

Energy ratio is
 Eresultant = 5.82 J

PART 2 : CHEMISTRY

31)

32) For Rev. phase transition ΔG = 0

33)

34) Hg(ℓ) ⇌ Hg(g)

ΔfGº 0 38
ΔrGº = 38 – 0 = – 2.303RTlog10KºP (T = 300 K)

35) = 103 – 100.7 = – 2.3 × 0.002 × 500 logP

⇒ P1 = 0.1 bar = 0.1 atm

36) Consider following equations

As

37) In alkaline medium, H3O+ gets consumed and reaction

proceeds in forward direction. As a result pink colour appers as extent of Ph– increases.
38) Following three reactions will occurs :
H3PO4 + NaOH → NaH2PO4 + H2O
NaH2PO4 + NaOH → Na2HPO4 + H2O
Na2HPO\ + NaOH → Na3PO4 + H2O
Therefore buffer solution will be :
(i) H3PO4 + NaH2PO4
(i) NaH2PO4 + Na2HPO4
(i) Na2HPO4 + Na3PO4
No. of buffer solutions = 3

39) pH of rain water is approximate 5.6

40)

IV > III > II > I

41)

42)
43)

44)

45) Hydrazine does not have carbon atoms so it does not form NaCN and hence does not give
a positive Lassaigne's test

46) CARBYL amine given by 1° amine

47)

48)

Sucrose : non-reducing sugar

fructose : Ketos Sugar
Sucrose : Diasaccharides

49) Histidine is basic amino acid.

50)

51)
A(g) 2B(g)
EPP 1 bar 2 bar
Pressure on a bar 2a bar
compression
New E.P.P (a + x) for (2a – 2x) for
From question, (a + x) + (2a – 2x) = 8
3a – x = 8 ...(1)

and ...(2)
From (1) & (2) : a = 3, x = 1
∴ PA = a + x = 4 bar

52)

2x – y = 3 .......(i)
5 – x + x + y + 2x + y = 12 .....(ii)
5 + y + 2x = 10
–y 2x = 3
3 – 2y = 7
y = 1, x = 2

Kp = =

53)
54)

55) 4S3 = 3.2 × 10–11

4S3 = 32 × 10–12
S = 2 × 10–4 mole/L
= 2 × 10–4 mole/ml
= .02 mg/ml
= 2 mg per 100 ml

56) Since (NH4)3PO4 is salt of weak acid (H3PO4) & weak base (NH4OH).

pH = 7 + (5.23 – 4.75)
= 7.24 » 7.

57)

58)

59)

60) Structure of Tri peptide Asp – Glu – Lys

PART 3 : MATHEMATICS

61) (a) where

⇒
⇒
⇒ x + y = 0, x – y = 3 and λy = 4

⇒ 2x = 3, i.e., x = ∴

62) Let
is equally inclined to and , where .

=
or λ(4 + 1) + μ(2–1) = λ (1) + μ(–1+2)
or 4λ = 0, i.e., λ = 0

63) Given that and are non-coplanar. Thus,

...(i)
Again
or
or
or
Hence, and are perpendicular (ii)

or

64) Let

⇒
p=q&q=1

65) Suppose the bisector of angle A meets BC at D.

Then AD divides BC in the ratio AB : AC.
So, P.V. of D is given by

But
and
⇒ = 6 and =3
Therefore, P.V. of D is given by

66) Here, the required plane is

a(x – 4) + b(y – 3) + c(z – 2) = 0
Also a + b + 2c = 0 and a – 4b + 5c = 0
Solving, we have

Therefore, the required equation of plane is

–13x + 3y + 5z + 33 = 0

67)

⇒
which is a plane passing through
and parallel to the vectors
 and therefore, it
perpendicular to the vector

Hence, its vector equation is

⇒
so, the cartesian equation is

or 2x + z = 5

68) Let the components of the line segment vector be a, b, c then

a2 + b2 + c2 = (63)2 ...(i)

also. (say)
⇒ a = 3λ, b = –2λ, c = 6λ
from (i) 9λ2 + 4λ2 + 36λ2 = (63)2
⇒ 49λ2 = (63)2

⇒λ=±
∵ a = 3λ < 0
∵ line makes abtuse angle with x-axis
⇒λ=-9
So. reqd. components are –27, 18, –54

69) Let the equation of line passes through

..(1)
It is pependicula to two given lines
∴ 2a + 7b - 3c = 0 ..(2)
and 2a – 2b + 5c = 0 ..(3)
from (2) & (3)

∴ Equation of line

70)

Let plane is ..... (i)

mid point of P(1, 2, 3) and Q(–3, 4, 5)
i.e., –1, 3, 4 lie on Eq. (i)

..... (ii)
Also, PQ is parallel to normal of the plane (i)
 Intercepts are .

71) Given lines are parallel

Hence dist. between lines = diameter of circle

Hence r = (dist. between lines)

= =

72)

centre

radius =
Acc. to condition

⇒ (k – b)2 = 4ah
⇒ (y – b)2 = 4ax

73) Let the equation be x2 + y2 + 2gx + 2fy + c = 0

it passes through (–1, –3) and (3, 0) therefore
10 – 2g – 6f + c = 0 ....(i)
9 + 6g + c = 0 ....(ii)
Slope of tangent = –4/3

⇒ 3g – 4f + 9 = 0 ....(iii)
 solving g = –1, f = 3/2, c = –3

74)
∵ A & B are end's of diameter, diameter = 2
∴ radius =
Let height of ΔABC is h.

Now, .Base × h = 1 {Base=daimeter

⇒ ×2 ×h=1

⇒ h=
∵ h<r
therefore no. of position of C is 4.

75) radius ≤ 5

⇒ 2λ2 – 2λ – 119 ≤ 0

⇒ ≤λ≤
⇒ –7.2 ≤ λ ≤ 8.2 (nearly)
⇒ λ = –7, –6, .... 8

76) Equation of AB is 4x + 3y = 9 ..... (i)

{∵ it is chord of contact}

OQ = [perpendicular distance of AB from origin]

AQ =

AB = 2AQ =

PQ =

Hence the area = × × =

Aliter : Required area= (h2 + k2 – a2)3/2

= (42 + 32 – 9)3/2 =

77) Here the equation of circle is

(x – a)2 + (y – 0)2 = a2 ⇒ x2 + y2 – 2ax = 0

Now the point of intersection of circle and chord i.e.,

Put y = mx in equation of circle and solve it.

O and B are O(0, 0) and B .

Hence the equation of circle (as chord OB as diameter) is (x2 + y2) (1 + m)2 – 2a(x + my) = 0.

78)

79) Given circles will intersect orthogonally,

if 2(1 × 0 + k × k) = 6 + k
[Using : 2(g1g2 + f1f2) = c1 + c2]
⇒ 2k2 – k – 6 = 0
⇒ (2k + 3) (k – 2) = 0

⇒ k = 2, –
80) The position vector of any point at t is

and
Hence, the required unit tangent vector at t = 2 is

81)

.... (i)

.... (ii)

.... (iii)

Add them

82) Given,

⇒ (λ + 3 – 1)

⇒ (λ + 2)
On equating the coefficient of , we get
λ+2=4⇒λ=2

83)

⇒
⇒ (–38)

⇒
 84)

Let θ1 is the angle between , θ2 is the angle between

Here , ,

⇒
⇒ 1000k = 375

85) Let the equation of the circle be

(x – a)2 + (y – a)2 = a2, a > 0,
It touches 4x + 3y – 12 = 0

∴ =a
7a – 12 = ± 5a
take '+' sign take '–' sign
2a = 12 12a = 12
a=6 a=1
∴ radius of larger circle a = 6

86)

Since, the given line touches the given circle, the length of the perpendicular from the centre
(2, 4) of the circle to the line 3x – 4y – k = 0 is equal to the radius of the circle.

∴ =±5
⇒ k = 15

[∵ k > 0]
hence equation of tangent is
3x – 4y – 15 = 0 ..... (1)
Let equation of normal to circle
4x + 3y = λ
It passes through centre (2, 4)
⇒ λ = 20
hence equation of normal is
4x + 3y = 20 .... (2)
Solve (1) & (2)
a = 5,
b=0
k+a+b
= 15 + 5 + 0 = 20
87) Equation of radical axis (i.e. common chord) of the two circle is
10x + 4y – a – b = 0 ...(i)
Centre of first circle is H(–4, –4).
Since second circle bisects the circumference of the first circle, therefore, centre H(–4, –4) of
the first circle must lie on the common chord Eq. (i).
∴ –40 – 16 – a – b = 0
⇒ a + b = –56

88) Radical axis, x – y = 0

Centre of 1st circle is (–a, –b) and .

Now perpendicular distance from center on radical axis = radius of the circle

⇒ a2 + b2 – 2ab = 2[a2 + b2 – c]
a2 + b2 + 2ab = 2c

89) Since, the given line touches the given circle, the length of the perpendicular from the
centre (2, 4) of the circle to the line 3x – 4y – k = 0 is equal to the radius of
the circle.

⇒ k = 15 [ k > 0]
hence equation of tangent is
3x – 4y – 15 = 0 ... (1)
Let equation of normal to circle 4x + 3y = λ
It passes through centre (2, 4) ⇒ λ = 20
hence equation of normal is
4x + 3y = 20 ... (2)
Solve (1) & (2)
a = 5, b = 0 ; k + a + b = 15 + 5 + 0 = 20

90) Let the equation of the circle be

(x – a)2 + (y – a)2 = a2, a > 0,
It touches 4x + 3y – 12 = 0

∴ =a
7a – 12 = ± 5a
take '+' sign take '–' sign
2a = 12 12a = 12
a=6 a=1
∴ radius of larger circle a = 6