11.3.
Class Notes
Announcements
Mock #4:
Saturday February 22
Chapters 1 - 11
Cumulative quiz:
chapters 7 + 8 + 10
Please put your questions in the Q/A window
not the chat
11.3. Rusting
-
S
What are the two necessary chemicals needed for rusting?
Air : O of H2O moisture
variable
/
21 % .
+3
Fe -
Word equation
rust
iron + oxygen + water hydrated iron (III) oxide
>
-
Fe + 02 +
H > Fe,0 xH
- ·
L
-
& water
dissolved
water
How did scientists know that we need both O2 and H2O?
Experiment 1 Experiment 2 Experiment 3
/I I
W
W
Only air
Only H2O Air
No H2O
No O2 & H2O
No rusting No rusting Rusting
Boiled water Drying agent 2-3 weeks
Anhydrous salt
anhydrous Callz
Cas
Conc . HISOn
Pure iron Rust heavily
Mild Steel Less rusting
High carbon steel Less rusting
Stainless steel
$ No rusting
E
as
↑ &
r
W
water
---
-
&------
air
-
&
==
of
volme
shrinks
· &
water
2
W &
--
How to prevent the suck-back problem?
Remove delivery tube from water
f
-
= -
a
M
-
↑ &
water
0 . 000 - 00 .
E
· 80 . 80 - 8 ⑧
O O
&
⑧oa &
⑧
000 O
· o
O
&
&
O O O
& & ·
...
I
&
. &
①
U
o ⑧
& O ①
&
a 00 &
⑧
O
&
&
O Zum
·
& &
Sum
&
&
·
must be &
replaced
&
&
& O O
G
·
N2 appea pure
02 >
-
Fe
·
H20
↓
warer
rust
How did scientists know it’s O2 in air that’s responsible for rusting?
O2 in air reacts
Air will be 21% of air will be gone
displaced by
7
-A
&
water ·
&
2 1 an
- .
W
- 02
80%
-02
no
dextra
-
change
20
% ↓
-Heaction
wag
no reaction ↑
All
&
no
change
·
no ·
M
↑
:.
① What is % of Oz
84-69 15 mm
0
YS9
[
=
=
2 S
O
-
· => % Of =
total
5 x100
= 17 86 %
.
-> not should be 21 %
W if I day
all o reat
enough Fe
not have
LL - 79 %
am air remaining
10
Final volume
ad -h 3
300 16 an
84 am
Y -rust flaste syringe
wet Fe filings
21 % of 400 = 84 an
106 27 Calculate % & Oz
- used up
02
=
=
100-27
73 am
↓
OZExo
%
&
total 380
=
%= 19 2 %
.
T
O
How to prevent attack?
& options :
02 00 nide
F guards Nisreen
⑥
·
Body
O Lina
H80 - Malak
-
I -
I Berry
>
- Q O
-
Ayter
# -
&
How to prevent rusting?
① Prevents
Cover iron with a barrier ② Sacrificial protection
O2 in H2O from reaching iron
⑨ Paint, e.g. cars
② Grease, e.g. machines
· &
J
W
*
⑤ Plastic, e.g. fridge, buckets, chairs -
Fa Another less reactive matal, e.g. tin cans
-
Es Cover with zinc = galvanization
g
Blocks of more reactive metal: Zn, Mg
# De En-2e >
-
Ent
· * ①
Popular Exam Question
How does zinc blocks protect iron from rusting?
T
*
Zinc is more reactive than iron.
Therefore zinc loses electrons and gets
oxidized more readily than iron.
Thus, zinc corrodes in preference to iron.
d
This is called sacrificial protection.
A B
En
[ & Etta
neither
Fe
will rust - barrier
* +20 -neverS
Exc
2 2
En&
C D
Not rust
Sactfidial protection
③ Cathodic protection
-
=
---
power
↓
E
now a cathed
Plan an investigation to compare the effectiveness of painting versus galvanization for the protection from
rusting. You are provided with:
-
• uncoated steel nails
• steel nails coated with paint
• steel nails coated with zinc
• common lab apparatus
I
measure mass
beakers
① we mass ② Put in 3
all
same water
in
an water
③ Add 50 , water
Wait for 2-3 weeks ⑤ Decant : pour
off
①
⑤ Dry Gut final mas
& Rust-final-initial (Conclusion
9 & most in mas ,
rusted most
Zinc-
corrode
&
L
>
-
no
rusting
· same
painted
o
·
Nails will rust because both
oxygen and water are present
Nails will not rust because
agat there’s no water
Dril Nails will not rust because
there’s no oxygen
Nails will not rust because
the paint acts as a barrier
Nails will not rust because
stainless steel is resistant to
corrosion
Questions?
Remember to take the pop quiz
On a scale of 1 to 10, how do you rate your
understanding of 11.3?
