(&}) HER.
AN"BA
lOJ INDUSTRIES LIMITED
A Govt. Recognised * Export House
H.O. : 101 / 102, Kanchanganga, Factory Lane, Borivali (W), Mumbai - 400 092. INDIA. Tel. : +91-22-2898 7912 I 2898 7914,
2898 2133 I 44, 5070 5050, 5070 5101 Web : www.heranba.com CIN NO : U24231 GJ1992PLC017315
Branch Off. : 301, 3rd Floor, Soni Shopping Center, L. T. Road, Opp - Dwarka Hotel, Borivali (W), Mumbai-400 092. INDIA
Email : [email protected] I [email protected]
ANNEX20
MATERIAL SAFETY DATA SHEET ALPHACYPERMETHRIN 10% SC
(Trade name- ALPHA-GUARD)
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
( 1.1 Product ldenti{ier-
Product Name: ALPHACYPERMETHRIN 10% SC (Trade name- ALPHA-GUARD)
CAS No.: 67375-30-8
IUPAC Name: a racemic mixture of: (S)-a-cyano-3-phenoxybenzyl-(1R,3R}-3-(2,2- d
ichlorovinyl)-2,2-dimethylcyclopropanecarboxylate and (R)-a-cyano-3-
phenoxybenzyl-(lS,35)-3-(2,2-dichlorovinyl)-2,2- dimethylcyclopropanecarboxylate
1.2 Relevant identified uses of the substance or mixture and uses advised aqainst-
PRODUCT USE: Insecticide.
1.3 Details of Manufacturer/Supplier-
Company name: HERANBA INDUSTRIES LIMITED
Address: 101/102, Kanchanganga, Factory Lane,
Borivali (w), Mumbai- 400092, INDIA
Phone number: +91-22-28987912/14
Web site address: www.heranba.co.in
1.4 Emergency phone number-
+91-22-28987912/14
Unit-1 : Plot No: 1504/1505/1506, lllrd Phase, G.l.D.C., Vapi, Dist: Valsad, Gujarat - 396195.
Board: 0260 - 2401970, 2401971 , 2401646, 2400536, 6639999 Fax: 0260 - 6639918
(ijJ l~D~~~~~~
A Govt. Recognised • Export House
H.O. : 101 I 102, Kanchanganga, Factory Lane, Borivali (W), Mumbai - 400 092. INDIA. Tel.: +91-22-2898 7912 I 2898 7914,
2898 2133 I 44, 5070 5050, 5070 5101 Web: www.heranba.com CIN NO : U24231GJ1992PLC017315
Branch Off.: 301 , 3rd Floor, Soni Shopping Center, L. T. Road , Opp - Dwarka Hotel, Borivali (W), Murnbai-400 092. INDIA
Email : [email protected] I [email protected]
SECTION 2: HAZARDS IDENTIFICATION
2.1 Classification of the Substance or Mixture:
Acute toxicity: Cat. S (oral}
Hazardous to the aquatic environment - acute: Cat. 1
Hazardous to the aquatic environment - chronic: Cat. 1
2.2 Lobel Element (GHS) or Precautionary Symbols:
(
Hazard Pictoqram(s}
Signal Word Warning
GHSHealth
H400 -Very toxic to aquatic life.
Statements
H410- Very toxic to aquatic life with long lasting effects.
P262 Do not get in eyes, on skin, or on clothing.
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P273 - Avoid release to the environment
Precautionary
statements P280: Wear protective gloves/protective clothing/eye protection/face
P361: Take off immediately all contaminated clothing
P363 - Wash contaminated clothing before reuse
P391 Collect spillage.
P403 +P233: Store in a well-ventilated place. Keep container tightly closed.
P501 - Dispose of contents/ container to an approved
Unit-1 : Plot No: 1504/1505/1506, lll rd Phase, G.l.D.C., Vapi, Dist: Valsad, Gujarat -396195.
Board : 0260 - 2401970, 2401971, 2401646, 2400536, 6639999 Fax: 0260 - 6639918
®l~D~~~~~~ A Govt. Recognised • Export House
H.O.: 101/102, Kanchanganga, Factory Lane, Borivali (W), Mumbai - 400 092. !NOIA. Tel.: +91-22-2898 7912 / 2898 7914,
2898 2133 / 44, 5070 5050, 5070 5101 Web: www.heranba.com CIN NO: U24231GJ1992PLC017315
Branch Off.: 301, 3rd Floor, Soni Shopping Center, L. T. Road, Opp - Dwarka Hotel, Borivali (W), Mumbai-400 092. INDIA
Email : [email protected] I [email protected]
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Component Content ( %w/w)
Alphacypermethrin a.i. 10.00
Sodium salt of polymeric carboxylic acid 0.500
Tetrabutyl ammonium bromide 0.020
Xanthan gum 0.550
1-2 Propaneldiol 15.000
( Proprietary mixture of 1,2 benzisothiazolin-3-one 0.150
Sodium hydroxide and Di propylene glycol in· 0.020
aqueous media
Orthophosphoric acid 0.100
Mixture of mineral oils and Alkyl Aryl ether(non- ionic QS
surfactant)
TOTAL 100.00
SECTION 4. FIRST AID MEASURES
4.1. Description of first aid measures
lnhalatlon-
Keep patient calm. Move the exposed person to fresh air.
lnqestion-
Rinse mouth immediately and then drink plenty of water, induce vomiting. Get medical attention immediately.
Skin contact-
( Remove contaminated clothing immediately and wash skin with soap and water.
Eye contact-
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
4.2. Indication of any immediate medical attention and special treatment needed
Treat according to symptoms (decontamination, vital functions), no known specific antidote.
SECTION 5. FIRE FIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media:
Water spray, foam, dry powder and carbon dioxide.
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Unit-1 : Plot No: 1504/1505/1506, lllrd Phase, G.1.D.C., Vapi, Dist: Valsad, Gujarat - 396195.
Board : 0260 - 2401970, 2401971 , 2401646, 2400536, 6639999 Fax: 0260 - 6639918
®~D~~fs~M~foA Govt. Recognised • Export House
H.O. : 101 I 102, Kanchanganga, Factory Lane, Borivali (W), Mumbai - 400 092. INDIA. Tel. : 91-22-2898 7912 I 14, 2898 2133 I 44,
2898 4439 Fax : 91-22-2899 3948 Web : www.heranba.com CIN NO : U24231GJ1992PLC017315
Mkt. Off.: A-201/202, Dwarkesh, Above Dwarka Veg. Restaurant, Opp. Om Jeweller.s, L.T. Road, Borivali (W), Mumbai-92. INDIA
TEL. : 91-22-2833 8443 I 44 Fax : 91 -22-2833 8445 Email : [email protected] I [email protected]
5.2. Special hazards arising from the substance or mixture
Carbon monoxide, hydrogen chloride, hydrogen cyanide, carbon dioxide, nitrogen oxides, organochloric
compounds, carbon oxides The substances/groups of substances mentioned can be released in case of fire.
5.3. Advice for firefighters
Wear self-contained breathing apparatus and chemical-protective clothing.
SECTION 6. ACCIDENTALRELEASE MEASURES
6.1. Personal precautions, protective equipment and emergencv procedures
Take appropriate protective measures. Wear protective clothing as described in Section 8 of this safety data
sheet Do not breathe vapour/spray. Avoid contact with the skin, eyes and clothing. Provide adequate ventilation.
6.2. Precautions for the protection of the environment
Do not discharge into drains, surface water or ground water.
If contamination of drains, streams, watercourses, etc. is unavoidable, warn the local water authority.
6.3. Methods and material for containment and cleaning up
For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr).
For large amounts: Dike spillage. Pump off product.
Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be
labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing
environmental regulations.
Unit-1 : Plot No: 1504/1 505/1 506, lllrd Phase. G.l.D.C., Vapi 396195, Dist: Valsad · Telefax: 0260- 2401646/2400536
®~o~~~DM~foA Govt. Recognised * Export House
H.O. : 101 I 102, Kanchanganga, Factory Lane, Borivali (W), Mumbai - 400 092. INDIA. Tel. : 91-22-2898 7912I14, 2898 2133 I 44,
2898 4439 Fax: 91-22-2899 3948 Web: www.heranba.com CIN NO : U24231GJ1992PLC017315
Mkt. Off. : A-201/202, Dwarkesh, Above Dwarka Veg. Restaurant, Opp. Om Jewellers, LT. Road, Borivali (W) , Mumbai-92. INDIA
TEL. : 91-22-2833 8443 I 44 Fax: 91-22-2833 8445 Email : [email protected] I [email protected]
SECTION 7. HANDLING AND STORAGE
7.1. Precautions for safe handling:
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work
areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the
end of the shift.
7.2. Requirements to be met by storerooms and receptacles:
Store in original container in a cool, well -ventilated area away from sources of heat or ignition and out of
direct sunlight.
Keep containers tightly closed. Keep away from children.
Information about storage In one common storage facility:
Do not store together with incompatible materials and foodstuffs.
Further information about storage conditions: Store in cool, dry, well ventilated location.
SECTION 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
B.1 Control parameters example: Occupational exposure limit values, Biological limit values.
Not available
8.2 Exposure controls
Engineering measures: Provide adequate ventilation
Eye Protection : Wear appropriate protective eyeglasses or chemical safety goggles
Protective Gloves: Wear appropriate protective gloves and clothing to prevent skin exposure.
Other Protective Clothing: Wear appropriate clothing to prevent any possibility of skin contact.
Respiratory Equipment: Respiratory protection not required.
Hygiene measures:
No specific hygiene procedures noted, but good personal hygiene practices are always advisable,
especially when working with chemicals.
Environmental Exposure Controls:
Do not release into the environment.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties:
Colour: Off white
Odour: Odourless
Physical state: Liquid
Unit-1 : Plot No: 1504/1505/1506, Ill rd Phase, G.1.0.C., Vapi 396195, Dist: Valsad · Telefax : 0260 - 2401646/2400536-''
®l~D~~~~M~~ A Govt. Recognised • Export House
H.O. : 101 / 102, Kanchanganga, Factory Lane, Borivali (W), Mumbai - 400 092. INDIA. Tel. : +91-22-2898 791212898 7914,
2898 2133 / 44, 5070 5050, 5070 5101 Web : www. heranba.com CIN NO : U24231GJ1992PLC017315
Branch Off. : 301, 3rd Floor, Soni Shopping Center, L. T. Road, Opp - Dwarka Hotel, Borivali (W), Mumbai-400 092. !NOIA
Email : [email protected] I [email protected]
Flammability: Not flammable
Explosivity: Non-explosive
Viscosity: Not available
Corrosivity: Non-corrosive
Density: 1.015 g/ml
Wettability: Not applicable
Suspensibility: M in. 60%
Persistent foam: M ax. 60 ml after 1 minute
( Wet sieve test: Max. 2.00% retained on a 75 µm test sieve
Flash point: Non flammable
SECTION 10. STABILITY AND REACTIVITY
10.1 Reactivity: No hazardous reactions if stored and handled as prescribed/Indicated.
10.2 Chemical Stability: Stable under normal temperature conditions and recommended use.
10.3 Possibility of hazardous reactions :
No hazardous reactions if stored and handled as prescribed/indicated
10.4 Conditions to Avoid:
Avoid excessive heat and direct sunlight.
10.5 Incompatible materials:
Materia ls to Avoid: strong bases, strong acids, strong oxidizing agents.
10.6. Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
Unit-1: Plot No: 1504/1505/1506, lllrd Phase, G.l.D.C., Vapi, Dist: Valsad, Gujarat - 396195.
Board : 0260 - 2401970, 2401971 , 2401646, 2400536, 663~999 Fax: 0260 - 6639918
®l~D~~~~M~~ A Govt. Recognised • Export House
H.O. : 101 I 102, Kanchanganga, Factory Lane, Borivali (W), Mumbai - 400 092. !NOIA. Tel. : +91 -22-2898 7912 I 2898 7914,
2898 2133 I 44, 5070 5050, 5070 5101 Web : www.heranba.com CIN NO : U24231GJ1992PLC017315
Branch Off. : 301, 3rd Floor, Soni Shopping Center, L. T. Road, Opp - Dwarka Hotel, Borivali (W), Mumbai-400 092. !NOIA
Email : [email protected] I [email protected]
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
(Data on Alphaeypermethrin 10% SC}
Acute Oral LDso (Rat) : 500 mg/kg
Acute Dermal LDso(Rabbit): > 2,000 mg/kg
Acute Inhalation LCso (Rat): >1.01 mg/l/4 hr
Primary Irritant effect:
(Data on Alphacypermethrin 10% SC}
(
Eye Irritation (Rabbit): Non irritant
Skin Irritation (Rabbit): Non irritant
Dermal Sensitization (Guinea pig): Non irritant
(DATA ON ALPHACYPERMETHRIN TECHNICAL}
Germ cell mutagenicity:
Mutagenicity tests revealed no genotoxic potential.
Carcinogenicity:
The results of various animal studies gave no indication of a carcinogenic effect.
Reproductive toxicity:
The results of animal studies gave no indication of a fertility impairing effect.
Developmental toxici ty:
Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental
animals.
Repeated dose toxicity and Specific target organ toxicity :
Repeated oral exposure may affect certain organs. Damages the peripheral nerve system.
SECTION 12. ECOLOGICAL INFORMATION (DATA ON ALPHA·CYPERMETHIN TECHNICAL)
Alpha-cypermethrin is considered highly toxic to fish and aquatic arthropods. The aquatic arthropods
tended to be some of the more sensitive species. Care should be taken to avoid contamination of the
aquatic environment.
12.1. Toxicity
Cyprinus carpio : LCso: 0.00084 mg/I
Daphnia magna, 24 hours: ECso: 0.14 µg/I water
Chlorella vulgaris, 72 hours: ECso: 15.26 µg/ml
Bees, 24 hours (oral) : LDso: 0.06 µg/bee
~
Unit-1 : Plot No: 1504/1505/1506, lllrd Phase, G.1.D.C., Vapi, Dist: Valsad, Gujarat - 396195.
Board : 0260 - 2401970, 2401971 , 2401646, 2400536, 6639999 Fax: 0260 - 6639918
(LI') HEKANi3A
lOJ INDUSTRIES LIMITED
A Govt. Recognised • Export House
H.O. : 101 I 102, Kanchanganga, Factory Lane, Borivali (W). Mumbai - 400 092. INDIA. Tel. : +91-22-2898 7912 I 2898 7914,
2898 2133 / 44, 5070 5050, 5070 5101 Web: www.heranba.com CIN NO : U24231GJ1992PLC01 7315
Branch Off. : 301 , 3rd Floor, Soni Shopping Center, L. T. Road, Opp - Dwarka Hotel, Borivali (W). Mumbai-400 092. INDIA
Email : [email protected] I [email protected]
12.2. Persistence and deqrodability:
Under aerobic conditions of alpha-cypermethrin half-lives were 27 and 13 weeks for sandy clay loam and
clay loam respectively.
12.3 Bioaccumulation factor:
Bio concentration factor: 155 - 910 (73 d), Cyprinus carpio (OECD Guideline 305 C) Accumulation in
organisms is not to be expected.
12.4 Mobility in soil:
No Indication of a build-up of alpha-cypermethrin residues in the surface soil layers, or any evidence to suggest
( significant leaching into sub-surface soil layers.
12.5. Results of PBT and vPvB assessment:
This product does not contain any PBT or vPvB substances.
12.6 Other adverse effects:
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
WASTE: Do not empty into drains or waterways. Disposal of product would usually be by incineration in an
appropriate licensed commercial incinerator. Advice may be obtained from local waste regulation authorities
CONTAINER: Puncture container to avoid re-use. Dispose of empty container in a sanitary landfill or by
incineration, or, if allowed by local authorities, by burning. If burned, stay out of smoke. Follow advice on
product label and/or leaflet.
SECTION 14. TRANSPORT INFORMATION
Alr{IATA):
UN number: 3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains
ALPHA-CYPERMETHRIN)
Transport hazard class{ es): 9
EHSM Packing group: Ill
Marine Pollutant: Yes
Environmental hazards: Yes
......._.
Unit-1: Plot No: 1504/1505/1506, lllrd Phase, G. l.D.C., Vapi , Dist: Valsad, Gujarat - 396195.
Board : 0260 - 2401970, 2401971 , 2401646, 2400536, 6639999 Fax : 0260 - 6639918
®l~D~~~~M~~ A Govt. Recognised • Export House
H.O. : 101 / 102, Kanchanganga, Factory Lane, Borivali (W), Mumbai - 400 092. INDIA. Tel. : +91-22-2898 791212898 7914,
2898 2133 / 44, 5070 5050, 5070 5101 Web : www.heranba.com CIN NO : U24231GJ1992PLC017315
Branch Off. : 301, 3rd Floor, Soni Shopping Center, L. T. Road, Opp - Dwarka Hotel, Borivali (W) , Mumbai-400 092. INDIA
Email : [email protected] I [email protected]
SECTION 15. REGULATORY INFORMATION
Hazard plctograms : Please refer section 2
Signal word : Please refer section 2
Hazard statements : Please refer section 2
Precautionary statements : Please refer section 2
Chemical Safety Assessment
~ • Advice on product handling can be found in sections 7 and 8 of this safety data sheet.
SECTION 16. DISCLAIMER
The information contained herein {including data and statements) are accurate as of the date hereof. No
warranty of fitness for any particular purpose, warranty of merchantability, or any other warranty, expressed or
implied, is made concerning the information provided herein. The information provided herein relates only to the
specific product designated and may not be applicable where such product is used in combination with any other
materials or in any process.
--
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Unit-1 : Plot No: 1504/1505/1506, lll rd Phase, G.l.D.C., Vapi , Dist: Valsad, Gujarat - 396195.
Board : 0260 - 2401970, 2401971 , 2401646, 2400536, 6639999 Fax : 0260 - 6639918
