FIRST YEAR HIGHER SECONDARY EXAMINATION
Part – III
CHEMISTRY
Maximum : 60 Scores
Time: 2 Hours
Cool-off Time : 15 Minutes
General Instructions to Candidates:
There is a ‘cool-off time’ of 15 minutes in addition to the writing time.
Use ‘cool-off time’ to get familiar with questions and to plan your answers.
Read questions carefully before carefully before answering.
Calculations, figures and graphs should be shown in the answer sheet itself.
Give equations wherever necessary,
Malayalam version of the questions is also provided.
Electronic devices except non programmable calculators are not allowed in the
Examination Hall.
Answer any 4 questions from 1 to 5. Each carries 1 score.
1) Law of multiple proportion was proposed by ______________
2) Atoms with the same atomic number and different mass number is known as _________
3) The IUPAC name of the compound with atomic number 114 is ____________
4) Who synthesized the frist organic compound from an inorganic compound?
5) Dipole moment of BF3 is ____________
Answer any 8 questions from 6 to 15. Each carries 2 score.
6) Define the term molarity and molality?
7) States Modern Periodic Law?
8) Chlorin has more electron affinity than Flurine. Why?
9) Write first law of Thermodynamics and its mathematical expression?
10) Distinguish between intensive and extensive properties. Give two examples for each?
11) State the Le-Chateliers Principle?
12) Define oxidation and reduction in terms of oxidation number?
13) Write stocks notation for below compound:
a) HgCl2 b) SnO2 c) Cr2O3 d) NiSO4
14) Write IUPAC name for below compound.
a) CH 3 CH 2 CH CH 2 CH 3 b) CH 3
CH 2 CH 2 CH 3 CH 3 C CH 3
CH 3
15) State Huckel Rule?
Answer any 8 questions from 16 to 26. Each carries 3 scores.
16) 3g of hydrogen react with 30g of oxygen to yield H2O.
a) Which is the limiting reactant?
b) Calculate the maximum amount of H2O that can be formed?
c) Calculate the amount of reactant which is unreacted?
17) What are the spectral lines shown by hydrogen atom? What is the maximum number of
emission lines when the excited electron of hydrogen atom in n=6 drops to the ground
state?
18) Rutherford proposed Nuclear Model of atom:
a) Explain Rutherford α Ray scattering experiment?
b) Write the drawback of Rutherford model of atom?
19) Removal of electron becomes easier on moving down the group.
a) Comment on the above statement based on ionization enthalpy?
b) Define ionization enthalpy?
20) Sodium and chlorine combine to form sodium chloride. Write Born Haber cycle?
21) Polar molecules having dipole momentum.
a) Dipole moment of NH3 more than that of NF3. Explain?
b) H2O is liquid while H2S is gas. Give the reason?
22) Pcl5 Pcl3 Cl2
a) What is the change in hybridization state of phosphorus in this reaction?
b) Discuss the shape of PCl5 molecule?
c) Why PCl5 decompose easily?
23) Ideal gas obeys PV=nRT
Write the relationship between Cp and Cv for an ideal gas.
24) Water behaves as Amphoteric in nature.
a) What is meant by Amphoteric substance.
b) Write conjugate acid and base pair of HSO4 , NH 3
25) Estimation of Halogen is done by Carius method. Explain Carius method?
26) Match the following:
1) 2CH 3 Br 2 Na CH 3 CH 3 2 NaBr Addition
O3 Elemination
2) CH 3COONa CH 4
H 2O
O3 Wurtz Reaction
3) CH 2 CH 2 2 HCHO
H 2O /2 n
4) n(CH CH ) CH CH Ozonolysis
2 2 2 2 n
5) CH 3CH 2 Br Al.KOH CH 2 CH 2 Polymarisation
6) CH 2 CH 2 HBr CH 3CH 2 Br Decarboxylation
Answer any 4 questions from 27 to 31. Each carries 4 scores.
27) Quantam Numbers are the address of an electron. explain four quantum numbers?
28) Draw the molecular orbital diagram for O2 molecules? Predict the bond order and
magnetic behaviour?
29) a) Explain ionic product of water?
b) Predict the nature of a solution having H 3O OH
c) Define P of the solution.
H
d) Calculate the P H of a 0.01M solution of HCI?
30) Explain the following electron displacement effect.
a) Inductive effect.
b) Hyper conjugation effect.
c) Arrange primary, secondary tertiary carbocation in the order of increasing stability.
Give the reason?
31) a) Illustrate Anti Markonikov rule taking the example of propene?
b) Write geometrical isomers of But-2-ene?
