Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60, Elite,Target & LIIT BT's Paper -1(2022-P1-Model) Date: 16-02-2025
Time: 09.00Am to 12.00Pm GTA-20 Max. Marks: 180*

KEY SHEET
MATHEMATICS
1 3 2 512 3 11 4 71 5 4 6 1275

7 1677 8 141 9 ABD 10 AB 11 AB 12 AC

13 AB 14 BCD 15 A 16 C 17 B 18 D

PHYSICS
19 100 20 0 21 0.91 22 6.4 23 1 24 4.50

25 2 26 2 27 AC 28 ABD 29 ACD 30 AC

31 AD 32 AD 33 B 34 B 35 D 36 A

CHEMISTRY
1.66
37 361.50 38 6.10 39 7.50 40 - 41 131.33 42 1.15
1.67
43 90 44 1400 45 ABCD 46 ABD 47 AC 48 AC

49 D 50 AD 51 D 52 A 53 C 54 D
 Sri Chaitanya IIT Academy 16-02-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2022 -P1)_GTA-20_Key& Sol’s

SOLUTIONS
MATHEMATICS
1. Conceptual
1
Ir  
 2  x   1  x  dx  1 dx  1 dx 21 r  1 1  21 r
2.
0 1  x   2  x 
2 0 1  x  0 1  x  1  2  x 
2 r
I r  I r 1 
1 r

r 1
1  2 9 1  2 8 1
I10  I 9  & I9  I8   9 I10  I 9  8 I 8  9
9 8 2
4 2
3. S .D  1  1,3 ,  3,5  5,7  7,9   5 
2  6 13
4. 6  3  4  1  1  72  1 =71
5. Minimum will occur at   1,   R
50  51
6. 1+2+3+………+50 =  1275
2
7. p  x    x  1 x  2  x  3  x  4  x     2007 x
p 10   p  5   9.8.7.6  10      5      20070  10035 = 75465
8. tan   tan  60     tan  60     3tan 
tan  tan  60     tan  60    tan  60     tan  tan  60     3
 tan 2   tan 2  60     tan 2  60      3tan 3   2  3  9 tan 2 3  6
2

a  9, b  33, c  63  36 3  a  b  c  105  36 3
9. A   tan  A  A  I  0 , A  tan  A I  A  0  tan  A   0 , A2  A I  0 A2   I A   A
2 T

k2  2  k2  4 k2  2  k2  4
10. f ' x   0  x  x , point of real maximum
2 2
k2  2  k2  4
x , point of local minimum
2
4
  e  sin at  cos 6 at  dt
t 6
11.
0
 2 3
  e  sin at  cos at dt 
t 6 6
e
t
 sin at  cos at dt 
6 6
 e
t
 sin 6 at  cos 6 at dt
0  2
4
  et sin 6 at  cos 6 at dt
3
 2 
  e sin at  cos at dt 
t 6 6
 e
t 
sin 6  a  t      cos 6  a  t     dt
0  

3  2
  e t  2
sin 6  a  t  2    cos 6  a  t  2   dt
 
2 2
4
 e t 3
sin 6  a  t  3    cos 6  a  t  3   dt
3

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 Sri Chaitanya IIT Academy 16-02-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2022 -P1)_GTA-20_Key& Sol’s
 t  e 4  1 e4  1
 1  e  e
 2
 e    e  sin 6 at  cos 6 at  dt 
3
  L 
0  e 1 e 1
12. Conceptual
13. They intersect at four concylic points, they are orthogonal curves. Equations of the circle,
passing through these four points, is x 2  y 2  a 2  b 2  k 2
14.
3, x   4, 2 

2, x  2
, x  0

g  x   0, x  0
, x  0,2
  
2, x  2

3, x   2, 4 
16. Let the plane be x  z  1  0
1 1
Pass through 1,0,1 ;  3,2, 1    ;    (I)  : x  z  2
2 2

Both A and B are on same side of .

Reflection of A in plane is A '  2,0, 2 

Equation of line A ' B  r  6iˆ  2kˆ    4iˆ 

1
For P : 6  4  0  2  2      P  4, 2, 2  | 4 x0  y0  2 z0  12
2
(II) Now PA  PB min  0 PA  PB min will approach

AB  4  0  4  8  PA  PB  0, 8 . 
x2 y  z 
(IV) Also, A ' will lie on  
1 0 1
22 0 2
      0,   2  4  4  16
1 0 1
17. (I) Clearly, number of solutions is 2.
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 Sri Chaitanya IIT Academy 16-02-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2022 -P1)_GTA-20_Key& Sol’s
 x2   1 
(II) f  x   cos  1
2 
 cos 1 1  2 
1 x   1 x 

1  
t 1  t   0,1  cos 1 t   0,    a, b    a  b   1
1  x2  2

 
(III) 12 tan 2  tan 1    tan 2  tan 1    12   2  2 


 12       2
2
 9 
 12   2.1  3
4 
 
(IV) sin  cos 1 x   sin   sin 1 x   cos  sin 1 x   t
2 

f  x   sin  cos 1 t  sin 1 t   sin 1
2
18. (I) The given parabolas are symmetric about the line y  x

(II) Area of the given triangle  x03

a 2  ab 2
(III) Probability (required)    a  3b
a 2 3
(IV) Here, roots are 1, 2,  2

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 Sri Chaitanya IIT Academy 16-02-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2022 -P1)_GTA-20_Key& Sol’s

PHYSICS
19. 2 2  PV
PV 1 1

V1  20000CCP1  105 Pa

Kx
v2  Ax P2  P0 
A
 1000 x 
4  
 105  20000  106  105  100 x 10 4
 100  10 
 2000  1000  x 1  x   x2  x  2  0 x  100cm
1
20. Least count of both instruments is mm.
6
21. Focal length for upper half is,
 
  1   1.5  1 
f1    f air   1.5  28  56cm
  / 1  1   1
 1.2 
Focal length for lower half is,
  1  1.5  1
f2    f air  1.5  28  35cm
  / 1  1  1
2.5
If the object is at infinity, two will form at corresponding focuses. So, the required
separation is x  f1  f 2  56  35  91cm  0.91m
22. Let R be the radius of the circular layer of water.
Then, R 2 d    m …..(1)
2T
Pressure at A  0  …..(2)
d

Thus pressure between the plates is less than the atmospheric pressure and so the plates
are pressed together as though attracted towards each other.
2T
F , force of attraction    area  F   R 2
d

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 Sri Chaitanya IIT Academy 16-02-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2022 -P1)_GTA-20_Key& Sol’s
2T m 2Tm 2  0.4  10 3  0.08
F      6.4 N
d d . d 2 . 0.012  104  1000
23.

1 R / h
1h tan   2 R 
 1
2 tan 
24. When the ball A leaves the horizontal surface

T  mg …..(i)
m  2v 
2
4mv 2 gl
T  mg  2mg  v ……(ii)
l l 2
Now, using Conservation of Energy
1 2 1
mu  2  mv 2  mgl
2 2
u  2v  2 gl
2 2
u 2  gl  2 gl  umin  3 gl  3  10  0.675  4.50m / s
Ldi
25. E  iR  0
dt
27. B & D are equipotentials
28. When the vessel starts accelerating then the sphere gets completely immersed in the
liquid of density 20 .

5
So, T  V0  20  0  a 2  g 2  V00 g .
3

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 Sri Chaitanya IIT Academy 16-02-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2022 -P1)_GTA-20_Key& Sol’s
29. P  weight of the vertical part + force required to provide momentum to the part which is
being lefted per unit time. Hence, P  gx 
 vdt  v P    gx  v 2 
dt  
30. Due to symmetrically placed cavities field at center will be zero and potential at
equidistant points from center on y  z plane would be equal.
31. Consider the bug at point P at any time t , moving with speed v along the stick, so
L  mvh  mvl sin  cos   Angular momentum of bug about point O

dL dv dv
   ml sin  cos    mg  l  x  cos    ml sin  cos  
dt dt dt

dv g  x dv g g
  1     x  Equation of SHM with mean position at
dt sin   l dt l sin  sin 
l sin  T  l sin 
point A  T  2 . Time required  
g 4 2 g
v
32. If a  0  g , then the distance covered by the object relative to train
t
 a  g  t 2  vo  gt 
2 2
1 v0t 1 v02 vt
l   a  g  t 
2
  gt 
2
  0
2 2g 2 2 2g 2g 2
If the wagon long enough, distance moved by the small body relative to train is
v02 vt
l  0
2g 2
33. When the strip is y below the mid plane its acceleration is given by

a 

buyant force-weight V0  1  4 y   V0 g 0 
g  4 gy
mass V0 g 0
Similarly when strip is y above mid plane a  4 gy clearly its medium is SHM when
2
T  1sec
4g
34. (p) Rays will become parallel to principle axis after reflection. Therefore diameter of spot
will be D.
1 1 1 f
(q)   v
v  f   f  2
y D
If diameter of the spot is y then  or, y  5D
5f   f 
   
 2  2
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 Sri Chaitanya IIT Academy 16-02-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2022 -P1)_GTA-20_Key& Sol’s

1 1 1
 (r)  vf
v  f   f 
 
 2
y D 3D
Diameter of the spot is given by  or, y 
3f  f 2
 
 2 

y D
(s) Diameter of the spot is given by  or, y  3D
3d d

GM gR 2 g
35. Velocity at A in a circular orbit VA  GM  gR 2  R
r1 r1 r1
1 1 
Velocity in elliptical orbit is given by the expression, v 2  2 gR 2    where
 r 2a 
r r 1 1 
a  1 2 , Velocity at Perihelion of the transfer orbit, v A2  2 gR 2   
2  r1 2a 
1 1  2 gr2
 vA   R 2g   R r1v A  r2vB
 r1 r1  r2  r1  r1  r2 
2 gr1
Velocity at aphelion of the transfer orbit  vB   R
r2  r1  r2 

g  2r2 
Velocity increment, va  R   1 
r1  r1  r2 
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 Sri Chaitanya IIT Academy 16-02-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2022 -P1)_GTA-20_Key& Sol’s

CHEMISTRY
37. Gas – 1 = Cl2
Gas – 2 = H 2
Diatomic (X) = I 2
Solution  S1   NaOH
Solution  S 2   KCl
Gas – 3 = NH 3
Gas – 4 = HCl
Salt Y  NH 4Cl
38. Cl  1s 2 2s 2 2p 6 3s 2 3p 41
Zeff  17   6  0.35   8  0.85    2  1   6.10
39.  -bond order in : O 2  1.5,O 2  0.5,O 22  0, NO   2,S2  1,C 2  2, B2  0.5
40. 3Cl2  6NaOH  5NaCl NaClO3  3H 2O
X Y
NaCl AgNO3  AgCl   NaNO 3
X

2 5
Bond order of Cl  O bond  1    1.66or1.67
3 3
1 12  1  127  3 394
41. moleCHI3 formed.wt.of X    131.33g
3 3 3
42.
CH3 CH 3
| |
CH 3  C  CH 3  CH 3  CH 3  CH3  C  CH 2  Cl  CH 3  CH 2  Cl
Cl2 /hv

equimolar ratio neopentyl uhloride

Assume that hydrogens in neopentane are ‘x” times more reactive than the hydrogens in
CH 3  CH3 .
Relative amount of  CH 3 3 CCH 2Clformed  12  x  12x
Relative amount of CH 3CH 2Cl  6  1  6
2.3 12x
  2.3  2x  x  1.15
1 6
h L
43. Lz  ml cos  z
2 L
h
L cos  ml
2

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 Sri Chaitanya IIT Academy 16-02-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2022 -P1)_GTA-20_Key& Sol’s
h h ml
l  l  1 cos   ml .  cos 
2 2 l  l  1
For d z 2 , ml  0  cos  0,    90
44. In 2800 g of 2mCaBr2 solution,800 g CaBr2 and 2000 g water present. In the vapours
solute CaBr2 will not be present. At 110C after stopping of boiling, in the solution
800 g CaBr2 present, xg of H 2O present.
4  1000
Tb  kb .m.i 10  0.5   3  x  600 g
x
 Wt. of water evaporated = 2000  600  1400 g
45. NCERT LINES
46. Self reduction is not applicable for SnO 2 .
Serpeck’s process is not applicable for red bauxite.
NaOH leaching is not applicable for Fe2O3
47. MgAl2O4  spinal 
4
  4
  4
 
3 3 3
4   rO 2   1   rMg 2  2   rAl 
P.F  3 3 3
3
a
3 3 3
4  a  4  a  4  a 
4    1    0.225.   2  3   0.414 
3  2 2  3  2 2 

2 2

a3
4 1
 
3 16 2
 4  0.2253  0.4143  2 

 
  4  0.11  2  0.71   4.153
12 2 12 2
2.23
  4.153  0.7717
12
48.  S 2  in saturated H 2 S  K a2  1014 M
Minimum conc. of S 2 when MS starts precipitation
1027  101  S 2    S 2   1026 M
In H 2 S , S 2 concis10 14 M . Thus MS can be precipitated with H 2 S gas alone
Minimum conc. of S 2 where NS starts precipitation
1021  101  S 2    S 2   1020 M
In H 2 S , S 2 concis10 14 M . This NS can be precipitated with H 2 S alone
Minimum conc. of S 2 when OS starts precipitation
105  10 1  S 2    S 2   104 M
In H 2 S , S 2 concis10 14 M . This OS can be precipitated with H 2 S alone
Conc of H  when MS will be precipitated but not NS

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 Sri Chaitanya IIT Academy 16-02-25_Sr.Super60, Elite, Target & LIIT BT's _Jee-Adv2022 -P1)_GTA-20_Key& Sol’s
2 2
 H    S 2  21
 H   1020
K a1 .K a2   10 
 H 2S  10 1
  H    101
 pH  1

Conc of H where O 2 will start precipitated
2 2
 H    S 2  21
 H   104
K a1 .K a2   10 
 H 2S  106
  H    109
 pH  9
49. Ans: D

∴ In reaction-II, equimdar mixture of Q and R formed.

50. A) C  C is more reactive than benzene ring
B) not possible
C) d - NCERT
51. B2H 6  Electron deficient
CsH  Ionic / salt like hydride
ZrH1.75  Metallic / non stoichiometric hydride
GeH 4  Electron precise
52. Flame Test  Li and K
Amphoteric  Be  OH 2 , Al  OH 3
Evolves CO2 on heating  Li2CO3
Super Oxide  K
0.059   K   R .H.E 
53. E cell  log     
n   K  L.H .E 
  
 0.059 log 20  59  1.3  76.7mV
54. Halogens when attached to C  C , reactivity in electrophitic addition decreases due to
 I  effect.

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