TR84746

Safety Data Sheet

according to the Hazardous Products Regulation (February 11, 2015)
Date of issue: 04/12/2017 Revision date: 10/12/2018 Supersedes: 07/24/2017 Version: 1.2

SECTION 1: Identification
1.1. Product identifier
Product form : Mixtures
Product name : TR84746
Product code : T84746
1.2. Recommended use and restrictions on use
Recommended use : Scale and Corrosion Inhibitor

1.3. Supplier
Manufacturer
Dober Chemical Corp
333 W. 195th Street
60425 Glenwood, IL - US
T 630-410-7300 - F 630-410-7444
[email protected] - www.dober.com

1.4. Emergency telephone number

Emergency number : 1-800-255-3924 / 1-813-248-0585
ChemTel

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture
Classification (GHS-CA)
Acute Tox. 3 (Oral) H301
Skin Corr. 1C H314
Carc. 1B H350
Repr. 1B H360
STOT SE 3 H335
Aquatic Acute 1 H400
Full text of hazard classes and H-statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS-CA labeling
Hazard pictograms (GHS-CA) :

GHS05 GHS06 GHS07 GHS08 GHS09

Signal word (GHS-CA) : Danger

Hazard statements (GHS-CA) : H301 - Toxic if swallowed

H314 - Causes severe skin burns and eye damage
H335 - May cause respiratory irritation
H350 - May cause cancer
H360 - May damage fertility or the unborn child
H400 - Very toxic to aquatic life
Precautionary statements (GHS-CA) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P261 - Avoid breathing dust.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water .
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
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TR84746
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

P310 - Immediately call a POISON CENTER or doctor.

P312 - Call a POISON CENTER or doctor if you feel unwell.
P363 - Wash contaminated clothing before reuse.
P391 - Collect spillage.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation

2.3. Other hazards

No additional information available
2.4. Unknown acute toxicity (GHS-CA)
1.87% of the mixture consists of ingredient(s) of unknown acute toxicity (Oral)
82.87% of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal)
43.36% of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Dust/Mist))

SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Chemical name / Synonyms Product identifier % Classification (GHS-CA)
Sodium Nitrite Diazotizing salts / Nitrous acid, (CAS-No.) 7632-00-0 30 - 60 Ox. Sol. 3, H272
sodium salt / Nitrous acid, sodium Acute Tox. 3 (Oral), H301
salt (1:1) / SODIUM NITRITE Eye Irrit. 2A, H319
Aquatic Acute 1, H400
Disodium Trioxosilicate Disodium metasilicate / Silicate, (CAS-No.) 6834-92-0 21 - 31 Met. Corr. 1, H290
disodium / Silicic acid (H2SiO3), Acute Tox. 4 (Oral), H302
disodium salt / Sodium metasilicate, Skin Corr. 1B, H314
anhydrous / Silicic acid, disodium STOT SE 3, H335
salt / Disodium metasilicate
(Na2SiO3) / Disodium trioxosilicate /
Silicic acid (H2SiO3), sodium salt
(1:2) / Sodium silicate / Silicic acid,
sodium salt (1:2) / SODIUM
METASILICATE
Tolyltriazole 1H-Benzotriazole, 4(or 5)-methyl- / (CAS-No.) 29385-43-1 8-13 Acute Tox. 4 (Oral), H302
1H-Benzotriazole, methyl- / Methyl- Eye Irrit. 2A, H319
1H-benzotriazole / Tolyltriazole / 1H- Aquatic Acute 3, H402
Benzotriazole, 4 (or 5)-methyl- / 1H- Aquatic Chronic 3, H412
Benzotriazole, 6(or 7)-methyl- /
Tolytriazole / 1H-Benzotriazole, 4(or
5)-methyl-, sodium salt
Disodium Tetraborate, Anhydrous disodium tetraborate, anhydrous, (CAS-No.) 1330-43-4 4-7 Eye Irrit. 2A, H319
boric acid, disodium salt Repr. 1B, H360
Anhydrous borax / Boric acid
(H2B4O7), disodium salt / Boric acid,
disodium salt / Boron sodium oxide /
Boron sodium oxide (B4Na2O7) /
Disodium tetraborate, anhydrous /
Sodium borate / Sodium tetraborate /
Sodium borate, anhydrous / Sodium
tetraborate (anhydrous) / Sodium
tetraborate anhydrous / Borates,
tetra, sodium salts, anhydrous /
Disodium tetraborate anhydrous /
Sodium tetraborate, anhydrous /
SODIUM BORATE / Sodium borate
anhydrous / Borates tetrasodium
salts, anhydrous / Borates, (tetra)
sodium anhydrous / Tetraborates,
sodium salts, anhydrous /
Tetraboron disodium heptaoxide
Phenolphthalein 3,3-Bis(p-hydroxyphenyl)phthalide / (CAS-No.) 77-09-8 0.1 - 1 Muta. 2, H341
1(3H)-Isobenzofuranone, 3,3-bis(4- Carc. 1B, H350
hydroxyphenyl)- / 3,3-Bis(4- Repr. 2, H361
hydroxyphenyl)phthalide / 3,3-Bis(4-
hydroxyphenyl)isobenzofuran-1(3H)-
one / Phenolphtalein

Full text of hazard classes and H-statements : see section 16

SECTION 4: First-aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison
center/doctor/physician if you feel unwell.

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Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Call a
physician immediately.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Call a physician immediately.
First-aid measures after ingestion : Rinse mouth. Call a physician immediately. Do not induce vomiting.
First-aid measures general : Call a physician immediately.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Burns.
Symptoms/effects after eye contact : Serious damage to eyes.
Symptoms/effects after ingestion : Burns.
4.3. Immediate medical attention and special treatment, if necessary
Other medical advice or treatment : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Foam.

5.2. Unsuitable extinguishing media

No additional information available

5.3. Specific hazards arising from the hazardous product

No additional information available

5.4. Special protective equipment and precautions for fire-fighters

Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
No additional information available
6.2. Methods and materials for containment and cleaning up
For containment : Collect spillage.
Methods for cleaning up : Mechanically recover the product. Notify authorities if product enters sewers or public waters.
Other information : Dispose of materials or solid residues at an authorized site.
6.3. Reference to other sections
For further information refer to section 8: "Exposure controls/personal protection"

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Ensure good ventilation of the work station. Obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Take all necessary
technical measures to avoid or minimize the release of the product on the workplace. Limit
quantities of product at the minimum necessary for handling and limit the number of exposed
workers. Provide local exhaust or general room ventilation. Wear personal protective
equipment. Floors, walls and other surfaces in the hazard area must be cleaned regularly.
Avoid contact with skin and eyes. Do not breathe dust.
Hygiene measures : Separate working clothes from town clothes. Launder separately. Do not eat, drink or smoke
when using this product. Always wash hands after handling the product. Wash contaminated
clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Disodium Tetraborate, Anhydrous (1330-43-4)
USA - ACGIH ACGIH TWA (mg/m³) 2 mg/m³ (inhalable particulate matter)
USA - ACGIH ACGIH STEL (mg/m³) 6 mg/m³ (inhalable particulate matter)
Canada (Quebec) VEMP (mg/m³) 1 mg/m³
Alberta OEL STEL (ppm) 3 ppm

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Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

Disodium Tetraborate, Anhydrous (1330-43-4)

Alberta OEL TWA (mg/m³) 1 mg/m³
British Columbia OEL STEL (mg/m³) 6 mg/m³ (inhalable)
British Columbia OEL TWA (mg/m³) 2 mg/m³ (inhalable)
Manitoba OEL STEL (mg/m³) 6 mg/m³ (inhalable particulate matter)
Manitoba OEL TWA (mg/m³) 2 mg/m³ (inhalable particulate matter)
New Brunswick OEL TWA (mg/m³) 1 mg/m³
Newfoundland & Labrador OEL STEL (mg/m³) 6 mg/m³ (inhalable particulate matter)
Newfoundland & Labrador OEL TWA (mg/m³) 2 mg/m³ (inhalable particulate matter)
Nova Scotia OEL STEL (mg/m³) 6 mg/m³ (inhalable particulate matter)
Nova Scotia OEL TWA (mg/m³) 2 mg/m³ (inhalable particulate matter)
Nunavut OEL STEL (mg/m³) 6 mg/m³ (inhalable fraction)
Nunavut OEL TWA (mg/m³) 2 mg/m³ (inhalable fraction)
Northwest Territories OEL STEL (mg/m³) 6 mg/m³ (inhalable fraction)
Northwest Territories OEL TWA (mg/m³) 2 mg/m³ (inhalable fraction)
Ontario OEL STEL (mg/m³) 6 mg/m³ (inhalable)
Ontario OEL TWA (mg/m³) 2 mg/m³ (inhalable)
Prince Edward Island OEL STEL (mg/m³) 6 mg/m³ (inhalable particulate matter)
Prince Edward Island OEL TWA (mg/m³) 2 mg/m³ (inhalable particulate matter)
Saskatchewan OEL STEL (mg/m³) 6 mg/m³ (inhalable fraction)
Saskatchewan OEL TWA (mg/m³) 2 mg/m³ (inhalable fraction)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure good ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment

Hand protection:
Wear Protective gloves.

Eye protection:
Chemical goggles or safety glasses

Skin and body protection:

Wear suitable protective clothing

Respiratory protection:
Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator
selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : No data available
Color : White to yellowish
Odor : slight
Odor threshold : No data available
pH : 10.5 at 1% solution
Relative evaporation rate (butyl acetate=1) : No data available
Relative evaporation rate (ether=1) : No data available
Melting point : No data available
Freezing point : Not applicable
Boiling point : No data available
Flash point : Not applicable
Auto-ignition temperature : Not applicable
Decomposition temperature : No data available

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Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

Flammability (solid, gas) : Non flammable

Vapor pressure : ≤ 0.013 kPa
Vapor pressure at 50 °C : No data available
Relative vapor density at 20 °C : ≤1
Relative density : Not applicable
Specific gravity / density : 0.881 g/ml
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : Not applicable
Viscosity, dynamic : Not applicable
Explosion limits : Not applicable

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity : The product is non-reactive under normal conditions of use, storage and transport.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reactions : None under normal use.
Conditions to avoid : None under recommended storage and handling conditions (see section 7).
Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be
produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity (oral) : Oral: Toxic if swallowed.
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

ATE CA (oral) 147.82600279 mg/kg body weight

Unknown acute toxicity (GHS-CA) 1.87% of the mixture consists of ingredient(s) of unknown acute toxicity (Oral)
82.87% of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal)
43.36% of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation
(Dust/Mist))

Sodium Nitrite (7632-00-0)

LD50 oral rat 85 mg/kg
LD50 oral 77 mg/kg
LC50 inhalation rat (mg/l) 5.5 mg/l/4h
LC50 inhalation rat (Dust/Mist - mg/l/4h) 5.5 mg/l/4h
Disodium Trioxosilicate (6834-92-0)
LD50 oral rat 1153 mg/kg
LD50 oral 600 mg/kg
Tolyltriazole (29385-43-1)
LD50 oral rat 675 mg/kg
LD50 dermal rabbit > 4000 mg/kg
LC50 inhalation rat (mg/l) > 1.73 mg/l (Exposure time: 1 h)
Disodium Tetraborate, Anhydrous (1330-43-4)
LD50 oral rat 2660 mg/kg
LD50 oral 1200 mg/kg
LD50 dermal rabbit > 2000 mg/kg
LC50 inhalation rat (mg/l) > 2 mg/m³ (Exposure time: 4 h)
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 10.5 at 1% solution
Serious eye damage/irritation : Eye damage, category 1, implicit
pH: 10.5 at 1% solution
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified

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Safety Data Sheet
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Carcinogenicity : May cause cancer.

Reproductive toxicity : May damage fertility or the unborn child.

Specific target organ toxicity – single exposure : May cause respiratory irritation.
Specific target organ toxicity – repeated : Not classified
exposure

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Very toxic to aquatic life.

Sodium Nitrite (7632-00-0)

LC50 fish 1 0.19 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])
LC50 fish 2 0.092 - 0.13 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])
Disodium Trioxosilicate (6834-92-0)
LC50 fish 1 210 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [semi-static])
LC50 fish 2 210 mg/l (Exposure time: 96 h - Species: Brachydanio rerio)
Tolyltriazole (29385-43-1)
LC50 fish 1 65 mg/l (Expsoure time: 96h - Species: Brachidanio rerio)
EC50 Daphnia 1 35.4 mg/l (Expsoure time: 48h - Species: Daphnia Magnia)
ErC50 (algae) 62 mg/l (Expsoure time: 72h - Species: Scenedesmus subspicatus)
Disodium Tetraborate, Anhydrous (1330-43-4)
LC50 fish 1 340 mg/l (Exposure time: 96 h - Species: Limanda limanda)
EC50 Daphnia 1 1085 - 1402 mg/l (Exposure time: 48 h - Species: Daphnia magna)
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
Sodium Nitrite (7632-00-0)
Log Pow -3.7 (at 25 °C)
Disodium Tetraborate, Anhydrous (1330-43-4)
BCF fish 1 (no evidence of bioaccumulation)
12.4. Mobility in soil
Sodium Nitrite (7632-00-0)
Log Pow -3.7 (at 25 °C)

12.5. Other adverse effects

GWPmix comment : No known effects from this product.

SECTION 13: Disposal considerations

13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.

SECTION 14: Transport information

14.1. Basic shipping description
In accordance with TDG
Transportation of Dangerous Goods

UN-No. (TDG) : UN2923

Packing group : III - Minor Danger
TDG Primary Hazard Classes : 8 - Class 8 - Corrosives
TDG Subsidiary Classes : 6.1
Transport document description : UN2923 CORROSIVE SOLID, TOXIC, N.O.S. (Disodium Trioxosilicate, Sodium Nitrite), 8 (6.1),
III
Proper Shipping Name (Transportation of : CORROSIVE SOLID, TOXIC, N.O.S. (Disodium Trioxosilicate, Sodium Nitrite)
Dangerous Goods)

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Safety Data Sheet
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Hazard labels (TDG) : 8 - Corrosive substances

6.1 - Toxic substances

TDG Special Provisions : 16 - (1) The technical name of at least one of the most dangerous substances that
predominantly contributes to the hazard or hazards posed by the dangerous goods must be
shown, in parentheses, on the shipping document following the shipping name in accordance
with clause 3.5(1)(c)(ii)(A) of Part 3 (Documentation). The technical name must also be shown,
in parentheses, on a small means of containment or on a tag following the shipping name in
accordance with subsections 4.11(2) and (3) of Part 4 (Dangerous Goods Safety Marks). (2)
Despite subsection (1), the technical name for the following dangerous goods is not required to
be shown on a shipping document or on a small means of containment when Canadian law for
domestic transport or an international convention for international transport prohibits the
disclosure of the technical name: (a)UN1544, ALKALOID SALTS, SOLID, N.O.S. or
ALKALOIDS, SOLID, N.O.S; (b)UN1851, MEDICINE, LIQUID, TOXIC, N.O.S; (c)UN3140,
ALKALOID SALTS, LIQUID, N.O.S. or ALKALOIDS, LIQUID, N.O.S; (d)UN3248, MEDICINE,
LIQUID, FLAMMABLE, TOXIC, N.O.S; or (e)UN3249, MEDICINE, SOLID, TOXIC, N.O.S. An
example in Canada is the “Food and Drugs Act”. (3) Despite subsection (1), the technical name
for the following dangerous goods is not required to be shown on a small means of
containment: (a)UN2814, INFECTIOUS SUBSTANCE, AFFECTING HUMANS; or (b)UN2900,
INFECTIOUS SUBSTANCE, AFFECTING ANIMALS. SOR/2014-306
Explosive Limit and Limited Quantity Index : 5 kg
Excepted quantities (TDG) : E1
Passenger Carrying Road Vehicle or Passenger : 25 kg
Carrying Railway Vehicle Index

14.2. Transport information/DOT

Department of Transport

DOT NA no. : UN2923

UN-No.(DOT) : 2923
Packing group (DOT) : III - Minor Danger
DOT Symbols : G - Identifies PSN requiring a technical name

Transport document description : RQ, UN2923 Corrosive solids, toxic, n.o.s. (Disodium Trioxosilicate, Sodium Nitrite), 8 (6.1), III
RQ of 180 lb due to Sodium Nitrite
Proper Shipping Name (DOT) : Corrosive solids, toxic, n.o.s. (Disodium Trioxosilicate, Sodium Nitrite)

Class (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136

Division (DOT) : 8
Hazard labels (DOT) : 8 - Corrosive
6.1 - Poison

Dangerous for the environment : Yes (ADR 5.2.1.8.1 derogation applies (quantity of liquids < 5 liters or net mass of solids < 5
kg))
Marine pollutant : Yes

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Safety Data Sheet
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DOT Special Provisions (49 CFR 172.102) : IB8 - Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid
plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1,
21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1,
13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).
IP3 - Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and
water-resistant liner.
T1 - 1.5 178.274(d)(2) Normal............. 178.275(d)(2)
TP33 - The portable tank instruction assigned for this substance applies for granular and
powdered solids and for solids which are filled and discharged at temperatures above their
melting point which are cooled and transported as a solid mass. Solid substances transported
or offered for transport above their melting point are authorized for transportation in portable
tanks conforming to the provisions of portable tank instruction T4 for solid substances of
packing group III or T7 for solid substances of packing group II, unless a tank with more
stringent requirements for minimum shell thickness, maximum allowable working pressure,
pressure-relief devices or bottom outlets are assigned in which case the more stringent tank
instruction and special provisions shall apply. Filling limits must be in accordance with portable
tank special provision TP3. Solids meeting the definition of an elevated temperature material
must be transported in accordance with the applicable requirements of this subchapter.
DOT Packaging Exceptions (49 CFR 173.xxx) : 154
DOT Packaging Non Bulk (49 CFR 173.xxx) : 213
DOT Packaging Bulk (49 CFR 173.xxx) : 240
DOT Quantity Limitations Passenger aircraft/rail : 25 kg
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 100 kg
CFR 175.75)
DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
DOT Vessel Stowage Other : 40 - Stow ‘‘clear of living quarters’’,95 - Stow ‘‘separated from’’ foodstuffs

Emergency Response Guide (ERG) Number : 154

Other information : No supplementary information available.

14.3. Air and sea transport

IMDG
UN-No. (IMDG) : 2923
Proper Shipping Name (IMDG) : CORROSIVE SOLID, TOXIC, N.O.S. (Disodium Trioxosilicate, Sodium Nitrite)
Transport document description (IMDG) : UN 2923 CORROSIVE SOLID, TOXIC, N.O.S. (Disodium Trioxosilicate, Sodium Nitrite), 8
(6.1), III, MARINE POLLUTANT
Class (IMDG) : 8 - Corrosive substances
Packing group (IMDG) : III - substances presenting low danger
IATA
UN-No. (IATA) : 2923
Proper Shipping Name (IATA) : Corrosive solid, toxic, n.o.s. (Disodium Trioxosilicate, Sodium Nitrite)
Transport document description (IATA) : UN 2923 Corrosive solid, toxic, n.o.s. (Disodium Trioxosilicate, Sodium Nitrite), 8 (6.1), III
Class (IATA) : 8 - Corrosives
Packing group (IATA) : III - Minor Danger

SECTION 15: Regulatory information

15.1. National regulations
TR84746
Canada DSL & NDSL Flags All substances contained in this product are listed on the Canadian Domestic Substance List (DSL) or are not
required to be listed.

15.2. International regulations

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Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

Sodium Nitrite (7632-00-0)

Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Japanese Poisonous and Deleterious Substances Control Law
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
Disodium Trioxosilicate (6834-92-0)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
Tolyltriazole (29385-43-1)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
Disodium Tetraborate, Anhydrous (1330-43-4)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Japanese Pollutant Release and Transfer Register Law (PRTR Law)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
Phenolphthalein (77-09-8)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Japanese Pollutant Release and Transfer Register Law (PRTR Law)
Listed on INSQ (Mexican National Inventory of Chemical Substances)

SECTION 16: Other information

SDS Major/Minor : None
Date of issue : 04/12/2017
Revision date : 10/12/2018
Supersedes : 07/24/2017

Indication of changes:

10/12/2018 EN (English US) 9/10

TR84746
Safety Data Sheet
according to the Hazardous Products Regulation (February 11, 2015)

Modified. Hazards identification. Composition/Information on ingredients. Handling and storage. Exposure controls/personal protection.
Toxicological information. Ecological information.
Other information : None.
Full text of H-phrases:
------ Acute Tox. 3 Acute toxicity (oral) Category 3
(Oral)
------ Acute Tox. 4 Acute toxicity (oral) Category 4
(Oral)
------ Aquatic Acute Hazardous to the aquatic environment - Acute Hazard Category 1
1
------ Aquatic Acute Hazardous to the aquatic environment - Acute Hazard Category 3
3
------ Aquatic Hazardous to the aquatic environment - Chronic Hazard Category 3
Chronic 3
------ Carc. 1B Carcinogenicity Category 1B
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Met. Corr. 1 Corrosive to metals Category 1
------ Muta. 2 Germ cell mutagenicity Category 2
------ Ox. Sol. 3 Oxidizing solids Category 3
------ Repr. 1B Reproductive toxicity Category 1B
------ Repr. 2 Reproductive toxicity Category 2
------ Skin Corr. 1B Skin corrosion/irritation Category 1B
------ Skin Corr. 1C Skin corrosion/irritation Category 1C
------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3
------ H272 May intensify fire; oxidizer
------ H290 May be corrosive to metals
------ H301 Toxic if swallowed
------ H302 Harmful if swallowed
------ H314 Causes severe skin burns and eye damage
------ H319 Causes serious eye irritation
------ H335 May cause respiratory irritation
------ H341 Suspected of causing genetic defects
------ H350 May cause cancer
------ H360 May damage fertility or the unborn child
------ H361 Suspected of damaging fertility or the unborn child
------ H400 Very toxic to aquatic life
------ H402 Harmful to aquatic life
------ H412 Harmful to aquatic life with long lasting effects
Abbreviations and acronyms:
------ ATE Acute Toxicity Estimate
------ EC50 Median effective concentration
------ IATA International Air Transport Association
------ IMDG International Maritime Dangerous Goods
------ LC50 Median lethal concentration
------ LD50 Median lethal dose

SDS Canada Dober

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy
or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be
used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

10/12/2018 EN (English US) 10/10