Sec: OSR.

IIT_*CO-SC Date: 12-05-24

Time: 3HRS Max. Marks: 180

Name of the Student: ___________________ H.T. NO:

12-05-24_OSR.STAR CO-SUPER CHAINA_JEE-ADV_GTA-13(P1)_SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

MATHEMATICS: TOTAL SYLLABUS

Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
TIME:3hrs IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 1 – 3) +4 -2 3 12
(partial marking scheme) (+1,0)
Sec – II (Q.N : 4 – 7) Questions with Single Correct Options +3 -1 4 12
Sec – III (Q.N : 8 – 13) Questions with Non-Negative Integer type +4 0 6 24
Sec – IV (Q.N : 14 – 17) Questions with MATRIX MATCH +3 -1 4 12
Total 17 60

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 18 – 20) +4 -2 3 12
(partial marking scheme) (+1,0)
Sec – II (Q.N : 21 – 24) Questions with Single Correct Options +3 -1 4 12
Sec – III (Q.N : 25 – 30) Questions with Non-Negative Integer type +4 0 6 24
Sec – IV (Q.N : 31 – 34) Questions with MATRIX MATCH +3 -1 4 12
Total 17 60

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 35 – 37) +4 -2 3 12
(partial marking scheme) (+1,0)
Sec – II (Q.N : 38 – 41) Questions with Single Correct Options +3 -1 4 12
Sec – III (Q.N : 42 – 47) Questions with Non-Negative Integer type +4 0 6 24
Sec – IV (Q.N : 48 –51) Questions with MATRIX MATCH +3 -1 4 12
Total 17 60

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
MATHEMATICS MAX.MARKS: 60
SECTION - I (Maximum Marks : 12)
This section contains THREE (03) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. Let S be set of all complex numbers z satisfying z 2  3 z  3  1 then which of the
following is/are FALSE
3 1
A) z   z  S
2 2
B) z  2  2z  S

3 1
C) z   z  S
2 2
D) All elements of S lies on a unit circle having centre  2, 0 

2. For a non-zero complex number z , let arg  z  denote the principal argument with
  arg  z    . Then, which of the following statements) is (are) TRUE?

A) arg  1  i   , where i  1
4

B) The function f :     ,   , defined by f  t   arg  1  it  for all t   , is

continuous at all points of   0 , i  1

z 
C) For any two non-zero complex numbers z1 and z2 , arg  1   arg  z1   arg  z2 
 z2 
is an integer multiple of 2
D) For any three given distinct complex numbers z1 , z 2 and z3 , the locus of the point z
  z  z1  z2  z3  
satisfying the condition arg     may lie on a straight line
  z  z3  z 2
 z 
1 

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
3. Let S1   i, j , k  : i, j and are distinct elements in1,2,3,....,10

S2   i, j , k  : i +3  j  k  3, i, j, k  1, 2,3,., 20

S3   i, j  :1  i  j  2  10, i, j  1, 2,.,10

If the total number of elements in the set Sr is n r , r  1, 2,3 then which of the following
statements is(are) TRUE?
A) n1  720 B) n2  728 C) n3  44 D) n2  n1  n3  50
SECTION–II (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
4. Let S be the circle in the xy plane defined by the equation x 2  y 2  9 . Let P be a point
on circle S with both co-ordinates positive and O be the centre of the circle. Let the
tangent to S at P intersect the co-ordinate axes at the points M and N , then centroid of
triangle OMN must lie on the curve

A) x 2  y 2  x 2 y 2 B) x 2/3  y 2/3  1 C) x 2  y 2  34/3 D) x 2  y 2  4 xy

  
5.   
Let non-zero vectors a, b,c satisfy a.b  0, b  a . b  c  0 and 2 b  c  b  a .

If a   b  4c then number of possible values of  is___________

A) 1 B) 2 C) 3 D) 4

6. Let , ,  be the roots of the cubic x 3  ax 2  bx  c  0, which (taken in given order) are
2 1 2 100 
 a 
r r

in G.P. If  and  are such that 1      0. If S          , then S


r 1     b  
4   3    1 

equals:

1 1  4 1  8 1  2 1 
A) 1  100  B) 1  100  C) 1  100  D) 1  100 
3 2  3 2  3 2  3 2 

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
7. Let A,B and C be 3 square matrices of order 3  3 . If A3  6A 2  7A  B  0 and
1 0 2 
 adj adjB   C, where A  0 2 1  , then sum of elements of C is______
 2 0 3 

A) 16 B) 32 C) 48 D) 64

SECTION-III (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
8. The length of common chord joining the points of intersection of curves y 2  4  x  1

and 4 x 2  9 y 2  36 is________.

5cos  x   4
9. Number of values of x in the interval  11, 2 that satisfy  0 is______
5sin  x   3

10. Let S be the reflection of a point Q with respect to the plane given by

r    t  p  iˆ  t ˆj  1  p  kˆ

where t , p are real parameters and iˆ, ˆj , kˆ are the unit vectors along the three positive

coordinate axes. If the position vectors of Q and S are 5iˆ  10 ˆj  15kˆ and  iˆ   ˆj   kˆ
respectively, then value of      is

11. Let L1 and L2 be the following straight lines

x 1 y z 1 x  4 y 1 z
L1 :   and L2 :   ,
1 1 3 3 1 1

Suppose plane P : ax  by  cz  1 , contains line L , where L passes though point of

intersection of L1 , L2 and lies in the plane containing L1 and L2 ,also bisects the acute
angle between the lines L1 and L2 . Plane P is perpendicular to the plane containing L1
& L2 , then value of a  b  c is_____

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
12. For a polynomial g  x  with real coefficients, let mg denote the number of distinct real

roots of g  x  .

Let f  x  be a cubic polynomial with real coefficients such that f    f     0 and

f   a   f   b   0 , where   a  b   . Suppose S is the set of polynomials with real

coefficients defined by

 
S   f  x   f   x  .  ar xi  : ai  R 
10

  i 0  

For a polynomial h , let h and h denotes first and second order derivatives
respectively. Then minimum value of mh '  mh where h  S , is

1
dx 1
13.   I , value of is__
1  x   1  x 
9
0 2 1/ 4
 x 2 1/ 4 I

SECTION-IV (Maximum Marks : 12)

SECTION 4 (Maximum Marks: 12)
This section contains FOUR (04) Matching List Sets. Each set has ONE Multiple Choice Question
Each set has TWO lists: List-I and List-II. List-I has Four entries (P), (Q), (R) and (S) and
List-II has Five entries (1), (2), (3), (4) and (5).
FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3ONLYif the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: – 1 in all other cases.
14. Consider the given data with frequency distribution
xi yi
550  650 8
650  750 60
750  850 24
850  950 16
950  1050 12

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
Match each entry in List-I to the correct entries in List-II.
List-I List-II
P) The mean of the above data is 1) 736
Q) The median of the above data is  , 2) 620
then value of    is___
(where [.] is G.I.F)
R) Six times of the mean deviation about the 3) 770
mean of the above data is
S) Seven times of standard deviation of the 4) 670
above data is
5) 556
The correct option is:
(A)  P   (3)  Q    2   R    4   S    5 
(B)  P    3  Q    2   R   1  S    5 
(C)  P    2   Q    3  R    4   S   1
(D)  P    3  Q   1  R    5   S    3
15. In the parabola y 2  4  4 x , a chord passing through the point  2, 0  cuts the parabola at
P and Q . If P   5, 4  and the tangents at P and Q meet at R then match the following
:
Column-I Column-II
P) 1)  3
The focus is  0, 
 2
Q) The centroid of the PQR is 2)  2, 0 
R) The circumcentre of the PQR 3)  25 3 
is  , 
 12 2 
S) 4)  25 3 
The orthocentre of the PQR is  , 
 8 2
5)  3 / 2,3 / 2 
The correct option is:
(A)  P   (2)  Q   1  R    4   S    5 

(B)  P    2   Q    3  R   1  S    5 

(C)  P    2   Q    3  R    4   S   1

(D)  P    2   Q    3  R    5   S    5 

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
16. Consider the function f  x   Sin x  Sin x  Sin 1 x
1 1

Match each entry in List-I to the correct entries in List-II.

List-I List-II
P) The number of solutions of the equation f  x   x is 1) 5
Q) Number of integers in the range of f  x  is ______ 2) 4
R)  3) 3
Number of solutions of f  x  
is ____
2
S) 1 4) 2
Number of solutions of f  x   is _____
2
5) 1
The correct option is:
A)  P    5   Q   1  R    4   S    5
B)  P    5   Q   1  R    4   S    4 
C)  P    2   Q   1  R    4   S   1
D)  P    3  Q    3  R    5   S    5 
17. Match each entry in List-I to the correct entries in List-II.
List-I List-II
If the coefficients of (2r  4) th ,(r  2) th terms in the
P) 1) 3
expansion of (1  x)18 are equal then value of r is
Term independent of x in the expansion of
9
 3x 2 1  1
Q) 1  x  2 x   2  3x  is  value of
3
   . 2) 1
 
 denotes greatest integral function.
If P  (8  3 7) n and f  P   P  , where [] denotes greatest
R) 3) 4
integer function. then value of P 1  f  is
Coefficient of x 70 in the expansion of
S)  x  1  x 2  2  x3  3.  x12  12  is 4) 5

5) 6
The correct option is:
A)  P    5   Q    3  R   1  S    4 
B)  P    3  Q    2   R   1  S    5 
C)  P    2   Q    3  R    4   S   1
D)  P    5   Q   1  R    2   S    3

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
PHYSICS MAX.MARKS: 60
SECTION - I (Maximum Marks : 12)
This section contains THREE (03) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
18. The queen is put at the center of a perfectly smooth carom board (square with side  ).
The striker strikes the queen with a speed Vo as shown in the figure. Radius of the queen

is 10 cm and that of the striker is 2 10 cm . Coefficient of restitution for the collision

between the queen and the striker is 1/ 2 and that for the collision between the queen and
the walls of the board is 1 .
(Assume   radius of queen)

A) The value of ' d ' for which the queen gets in the hole A is 3cm.
B) The value of ' d ' for which the queen gets in the hole A is 2cm.
C) The value of ' d ' depends on the coefficient of restitution between the queen and the
striker.
D) The value of ' d ' is independent of the coefficient of restitution between the queen
and the striker.

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
19. A typical fission reaction is
92
U 235  0 n1   92U 236   z X A  z Y A   n1
1
1
2
2

Which of the following statement(s) is/are correct for above reaction?

A) z1  z2  92; A1  A2   236
B) The ratio of masses of X & Y is found experimentally to be roughly 3 / 2
C) The number of neutrons  released in the fission of a particular element will
depend upon the final fragments that are produced.
D) The two decay fragments usually have a neutron proton ratio approximately equal to
that of the original nucleus.
20. A monochromatic light beam enters into a glass prism of vertex angle 75 . The prism is
in water and the angle of incidence of the light beam is 45 . The light beam emerges
from the glass after two refractions.
 3 4 
1 4 2
 1  9  

 gass  ,  water  ,sin    36.1
,sin  sin  38.9    41.5

 2 3  9   8  
A) the wavelength of light emitted from the glass into the water is increased by 12.5%
B) the wavelength of light emitted from the glass into the water is increased by 25%
C) deviation of light beam is 11.5
D) deviation of light beam is 16.5
SECTION–II (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
21. A hemispherical insulating shell is uniformly charged positively, and is fixed. The
charge distribution of the shell is uniform. At a point on the symmetry axis, which is
exactly at a distance of the radius measured from the centre of the hemisphere O , a
small negatively charged bead is released. The speed of the bead is v 0 when it reaches
the centre O . What will the speed of the bead be when it reaches the shell?

V0 V0
A) 2 V0 B) 2 V0 C) D)
2 2
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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
22. The emf of the battery is 9 V . Internal resistance of the battery and resistances of the
metres and resistor is also unknown. When the switch is closed then the measured
current increases to twice of the previous value, and the reading on the voltmeter
decreases to half of the original value. What is the reading of the voltmeter after closing
the switch?

A) 1 V B) 2 V C) 3 V D) 4 V
23. A point source of light is placed directly x distance above an opaque sphere of radius y
placed on a horizontal surface. Which of following statement is/are incorrect?

2y
A) For x  , radius of shadow formed on horizontal surface is 2 y
3
B) For x  y , radius of the shadow formed on horizontal surface is 3y
Point sources
2y
C) For x  and for surrounding medium(remaining space surrounded by sphere)
3
having refractive index 3 , radius of the shadow formed on horizontal surface is 2y .
2y
D) For x  and for surrounding medium(remaining space surrounded by sphere)
3
having refractive index 3 , radius of the shadow formed on horizontal surface is 2y .

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
24. A dipole is placed in uniform electric field of magnitude E such that its potential energy
is minimum. The distance between the charges is ' d '. The charge's ' q ' and ' q ' have
masses ' m ' and ' 3m ' respectively. IF magnitude of qE is equal to magnitude of 3md.
All physical quantities mentioned to be taken in their respective S.I. units. Now, this
dipole is placed in the same electric field E, such that its dipole moment makes angle 3
degrees with the electric field and then released at time t  zero. The time after which it

makes angle 1.5 degrees with the electric field for the first time is given as seconds,
k
find the value of k .
A) 6 B) 7 C) 8 D) 9

SECTION-III (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
25. A particle having charge q is thrown in gravity free hall from origin with velocity u and
angle  with positive x -axis as shown in figure. A constant electric field exists in
negative y direction in this region. After some time particle crosses x -axis again. Angle
 so that trajectory of the particle forms maximum area upon x -axis during this

time is (10 K)0 . Find the value of ‘ K ’

26. A small size block carrying positive charge q1 is held at rest on a rough inclined plane.
A negative point charge q 2 is fixed somewhere at point O in the same vertical plane
containing the block. Coefficient of friction between the block and the plane is
  0.375 . When released, the block acquires speed v0  3.0 m / s after sliding down a
height h  1.25 m . If the block were having negative charge of the same magnitude (i.e.,
q1 ), what speed would it acquire after sliding down from rest between the same initial

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
and final points. Acceleration due to gravity is g  10 m / s 2 . (Assume block always in
contact with the plane).

27. A point object is kept at a distance of 2 m from origin on x  axis. A quarter cylinder of
radius R  30 cm and refractive index   1.5 having its axis  , to plane of paper is
placed between the object and the parabolic reflector at a distance of 130 cm from origin
as shown in figure. The position of the image after reflection from the parabolic reflector
y 2  2 x is 25 cm . Find the value of  ?

28. A cylinder of mass M and radius R moves with constant speed v through a region of
space that contains dust particles of mass m which is at rest. There are n number of
particles per unit volume. The cylinder moves in a direction perpendicular to its axis.
Assume m  M , and assume the particles do not interact with each other. All the
collision takes place is perfectly elastic and the surface of the cylinder is smooth. The
drag force per unit length of the cylinder require to maintain the speed v constant for the
K
cylinder is nmRv 2 . Find the value of K ?
3

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
29. In a hydrogen like atom an electron is orbiting in an orbit having quantum number n . Its
frequency of revolution is found to be 13.2  1015 Hz . Energy required to free the
electron from the atom from the above orbit is 54.4eV . In time 7 nano - second the
n
electrons jumps back to orbit having quantum number .  be the average torque acted
2

on the electron during the above process, then find  10 27 in N  m .
5
h
(Given:  2.1  1034 J  s ) Frequency of revolution of electron in the ground state of

H  atom f 0  6.6  10 Hz and ionization energy of H  bond E0  13.6eV
15

30. Consider a closed cylinder whose walls are adiabatic. The cylinder lies in a horizontal
position and is divided into three parts A1 , A2 , A3 by mean of a partition S1 and S 2 which
can move along the length of the cylinder without friction. Piston S1 is adiabatic while
piston S2 is conducting. Initially each part contains one mole of Helium gas at
temperature T0 , pressure P0 , volume Vo (see figure). Now heat is slowly supplied to the
9 T0
gas in part A1 till the temperature in part A3 becomes T3  .
4

13V0
The final volume of A1 is ' x ' times , find the value of ' x '
27
SECTION-IV (Maximum Marks : 12)
SECTION 4 (Maximum Marks: 12)
This section contains FOUR (04) Matching List Sets. Each set has ONE Multiple Choice Question
Each set has TWO lists: List-I and List-II. List-I has Four entries (P), (Q), (R) and (S) and
List-II has Five entries (1), (2), (3), (4) and (5).
FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3ONLYif the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: – 1 in all other cases.
31. Two blocks of masses m and 4m lie on a smooth horizontal surface connected with a
spring in its natural length. Mass m is given initial velocity V0 as shown in figure.

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
COLUMN-I COLUMN-II
A) K.E of the system in ground frame P) Zero
B) K.E of the system in center of mass Q) 1 2
mv0
frame 2

C) Momentum of the system in center R) 2 2

mv0
of mass frame 5

D) P.E stored in the spring S) mv02

10
When velocity of block of mass 4m is maximum in ground frame
A) A-Q, B-Q, C-P, D-R B) A-Q, B-R, C-P, D-P
C) A-S, B-P, C-R, D-Q D) A-R, B-Q, C-P, D-S
32. A uniform solid body of mass m and radius ' R ' is placed on a rough horizontal surface.
When a horizontal force ' F 'is applied to the body at a height ' h ' above the centre level,
the body starts rolling without slipping on the horizontal surface as shown.

List - I gives the four different shapes of the given solid body and corresponding values
of F and h while List -II gives the magnitude of some quantities.

LIST-I LIST-II
I) R P)
For a ring, F  2mg, h  1
2
II) 3R Q) 1
For a disc, F  mg, h 
4 3
III) 5mg R R) 7
For a hollow sphere, F  , h
8 3 9
IV) mg 3R S) 8
For a solid sphere, F  , h
2 5 21
T) 1
4
U) 1
7

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
If the magnitude of frictional force acting on the ring is ' f0 ' then the frictional force
acting on the different shapes of the body in ' f0 ' units will be
Options
A) I  P, II  Q, II  R, IV  S B) I  Q, II  P, III  S, IV  U
C) I  P, II  Q, III  T, IV  U D) I  T, II  Q , III  R, IV  U
33. Match each entry in List-I to the correct entries in List-II.
LIST-I LIST-II
P)  1 1 1  1) 4
Magnitude of electric field (in V/m) at  , ,  if
 6 8 10 
1 1 1
electric potential is given by V    
x y z volt, is
Q) The charge flowing through a resistance 6varies with t as 2) 10
Q  4t  2t 2 . The total heat produced (in joules) across the
resistance from t=0 till the instantaneous power is minimum
is
R) 3) 5

Wire PQ has negligible resistance the current through PQ

(in amperes) is
S) 4) 10 2

Value of R (in ) for which maximum power is generated

across R when switch is closed will be
5) 32
The correct option is:
A) (P)  (4) (Q)  (1) (R)  (5) (S)  (2)
B) (P)  (4) (Q)  (3) (R)  (5) (S) (1)
C) (P)  (4) (Q)  (5) (R)  (3) (S)  (1)
D) (P)  (4) (Q)  (5) (R)  (1) (S)  (3)
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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
34. From an insulating solid hemisphere (radius R) carrying a charge Q, a part of it is
removed in the possibilities shown in Column I. Column II gives the magnitude of
electric field at the centre (O) of the original solid hemisphere for the four combinations
1
shown. Match column I with Column II. (given K )
4 0

LIST-I LIST-II

P) 1) 0

3KQ
Q) 2)
4R2

11KQ
R) 3)
18 R 2

KQ
S) 4)
2R2

25 KQ
5)
18 R 2

A) (P)-(4), (Q)-(3), (R)-(2), (S)-(1) B) (P)-(1), (Q)-(4), (R)-(2), (S)-(3)

C) (P)-(4), (Q)-(3), (R)-(1), (S)-(2) D) (P)-(1), (Q)-(3), (R)-(2), (S)-(4)

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
CHEMISTRY MAX.MARKS: 60
SECTION - I (Maximum Marks : 12)
This section contains THREE (03) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
35. The correct relation between the products formed the following set of reactions is(are):
1. AgCN
1. KCN Cl [Q]
Cl [P] ; 2. LiAlH 4
[I] Me 2. LiAlH 4 Me

1. Br2/ Red P
OH 1. NH3/  OH 2. NaOH +CaO, 
Me [R] Ph [S]
;
[II] 2. Br2/NaOH 3. NH3
O O
3. PhCOCl/NaOH
4. (CH3CO) 2O, pyridine

Me
HI
Me [U]
[III] O Me HI ; Me O Me
[T]
Me Me

1. HBr/ R2O 2
1. HBr
2. KCN 2. Mg, Et2O
; [W]
[IV] Me [V] Me +
+ 3. CO 2 then H 3O
3. H3O /

A)[P] and [Q] are functional isomers B) [R] and [S] are metamers
C) [U] and [T] are positional isomers D) [V] and [W] are chain isomers
36. Among the following, the correct statement(s) is (are):
A) Cytosine and Uracil are purine nucleobases.
B) Nucleotide in DNA contains   N-glycosidic bond between   2-deoxy ribose and
nucleobase.
C) Necleotides in DNA are joined together by phosphodiester linkage.
D) Adenine and Thymine are held together by two hydrogen bonds in a DNA double
helix.
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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
37. Aluminium and Copper are extracted from their oxide and sulphide ores respectively.
Which of the following statement(s) is (are) correct?

A) Copper is extracted by the auto reduction of copper oxide by copper sulphide.

B) Aluminium cannot be obtained by chemical reduction method due to its strong

affinity for oxygen

C) In electrometallurgy of Al, graphite is used as cathode to avoid re-oxidation of Al into

Al2O3 by preventing formation of O2.

D) Sulphide ores of copper are difficult to be reduced than oxide ores

SECTION–II (Maximum Marks: 12)

This section contains FOUR (04) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
38. Consider the following statements related to dimethylpolysiloxane, [(CH3)2SiO]n:

(I) It is extremely hydrophilic

(II) It is prepared by a KOH catalysed ring-opening reaction of [Me2SiO]4

(III) It is thermally highly stable due to silica like skeleton.

(IV) It has high dielectric constant.

The option with the correct set of statements is:

A) (I) and (II) B) (II) and (III) C) (I) and (IV) D) (II) and (IV)

39. In an ionic solid AB2O4, the oxide ions form CCP. 'A' and 'B' are metal ions in which
one is bivalent and another is trivalent (not necessarily in given order). If all the bivalent
ions occupy octahedral holes and the trivalent ions occupy tetrahedral and octahedral
voids in equal numbers, then the fraction of octahedral voids unoccupied is:

1 3 1 7
A) B) C) D)
2 4 4 8

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
40. The rate of solvolysis of [P]- [S] follows:
Me Br Me Br
Me Br

Br
[P] [Q] [R] [S]

A) [P] > [Q] > [R] > [S] B) [R] > [P] > [Q] > [S]

C) [R] > [Q] > [P] > [S] D) [S] > [P] > [Q] > [R]

41. The following diagram shows the kinetic energy of the ejected photoelectrons against the
energy of incident radiation for two metal surfaces M1 and M2. If the energy of the
incident radiation on M1 is equal to the work function of M2, the de Broglie wavelength
of the ejected photoelectron is _______ pm.

[Given: Planck’s constant = 6.6210−34J s ; Mass of electron = 9.0  10−31 kg

1 eV = 1.6 10−19 J ]
A) 2580 B) 3590 C) 1580 D) 4670

SECTION-III (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
42. For a van der Waals gas, the critical temperature is 150 K and the critical pressure is 500
bar. If the volume occupied by each gas molecule is X 1029 dm3 , the value X is _____.

[R = 0.08 L bar, NA = 6.0×1023]

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43. The weight (mg) of PbS that get precipitated from a 1.0 L saturated PbSO4 solution if the
solution is made saturated with H2S (0.1 M) and pH adjusted to 0 is_______.

(Round off to the nearest integer).

[Ksp of PbSO 4  1.6  108 and Ksp of PbS  2.5  1027 . For H2S; K a1  107 and

K a2  1014 Atomic weight Pb=206 and S=32]

44. The decomposition reaction


2 Cl 2O7 (g) 2 Cl 2 (g) + 7O2 (g)

is started in a closed cylinder under isothermal isochoric condition at an initial 10 moles .

The chlorine(Cl2) produced after Y s, reacts completely with 12 moles of hot NaOH
solution. If the rate constant of the reaction is 2 × 10-3 s-1,the value of Y is_____.

(use : ln10  2.3,ln 2  0.7)

45. Consider the following data (all values are in kilocalories per mol at 25° C).
C(s) C(g)  H= 172

H2 (g) 2H(g)  H= 104

H2 (g) + 1/2 O2(g) H2O (l)  H= -68

C (s) + O2(g) CO 2(g)  H= -94

C2H6 (g)+ 7/2 O2 (g) 2CO 2(g) +3H2O(l)  H= -372

bond Enthalpy of C-C bond = 82

The bond energy of C-H bond (kcal/mol) is_____.

46. The magnitude of crystal field stabilization energy (CFSE) of octahedral [Ti(H2O)6]3+

complex is 7500 cm-1. The wavelength at the maximum absorption (  max ) of this
complex is____nm

(Round off to the nearest integer).

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47. The total number of monobromo products formed, including stereo isomers, in the
following reaction
is_________.
Cr 2O3 - Al 2O3 Excess H 2 /Ni Br 2/ UV light
n- heptane [P] [Q] isomeric monobromo
773 K, 20 atm 
products

SECTION-IV (Maximum Marks : 12)

SECTION 4 (Maximum Marks: 12)
This section contains FOUR (04) Matching List Sets. Each set has ONE Multiple Choice Question
Each set has TWO lists: List-I and List-II. List-I has Four entries (P), (Q), (R) and (S) and
List-II has Five entries (1), (2), (3), (4) and (5).
FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3ONLYif the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: – 1 in all other cases.
48. Match the indicted C-H bonds in List-I with their BDE (kJ/mol) given in List-II and
choose the correct option.

List-I List-II

P) H 1) 110.9

Q) 2) 71.1

R) H 3) 132.0

S) Me C C H 4) 90.6
A) P  3, Q  4, R  1, S2 B) P  1, Q  3, R  2, S4

C) P  3, Q  1, R  4, S2 D) P  4, Q  1, R  2, S3

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
49. Match the species given in List-I with their characteristics in List-I I and choose the
correct option.
List-I List-II

P) Li 2 1) LUMO is gerade

Q) O2 2) bond order  2

R) N 2 3) HOMO is gerade

S) F2 4) diamagnetic

5) Mixing of ‘s’ and ‘p’ orbitals

A) P  3, 4,5 Q  1,3 R  2,3,5 S  1, 4
B) P  1, 4,5 Q  2,3 R  1,3,5 S  3, 4
C) P  3, 4,5 Q  2,3 R  2,3,5 S  3, 4
D) P  1, 4,5 Q  1,3 R  1,3,5 S  1, 4
50. Match the complexes formed in the reactions given in List-I with their characteristics in
`List-II and choose the correct option.

List-I List-II
1. dil. H2SO 4
P) Malachite 1) tetrahedral
2. Exc. KCN
1. O 2/ 

Q) 2. dil. H2SO 4 2) octahedral

Sphalerite
3. Exc. KCN
1. dil. H2SO 4
R) Haematite 3) square planar
2. Exc. KSCN
1. dil. H2SO 4
S) Azurite 4) paramagnetic
2. Exc. NH 3

5) diamagnetic
A) P  3,4; Q  1,5; R  3,4; S  3,4
B) P  1,5; Q  1,5; R  2,4; S  3,4

C) P  3, 4; Q  2,5; R  2,5; S  1, 4

D) P  1,5; Q  1,5; R  1,4; S  1,4

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Narayana IIT Academy 12-04-24_OSR.IIT_*CO-SC_JEE-Adv_GTA-13(P1)_Q’P
51. Match the products formed on gentle heating the compounds given in List-I with their
characteristics in List-II and choose the correct option.

List-I List-II
HOOC COOH
P) Me Me 1) optically pure enantiomer

Me COOH
Q) 2) mixture of diastereomers
Me COOH

HOOC COOH
R) Me Me 3) mixture of enantiomers

O
COOH
S) 4) achiral compound(s)
Me
`

5) meso compound(s)

A) P  2,5; Q  3; R  3; S  1

B) P  2,4,5; Q  3; R  1; S  3

C) P  2,5; Q  4,5; R  1; S  3

D) P  2,4,5; Q  4; R  3; S  1

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