Safety Data Sheet

Revision Number: 006.0 Issue date: 11/26/2018

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: LOCTITE 3705 known as Loctite 3705 IDH number: 1019674
30ml for US EN/ES
Product type: Ultraviolet adhesive Item number: 42257
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: DO NOT SPRAY. DO NOT HEAT.
COMBUSTIBLE LIQUID.
HARMFUL IF SWALLOWED OR IN CONTACT WITH SKIN.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.

HAZARD CLASS HAZARD CATEGORY

FLAMMABLE LIQUID 4
ACUTE TOXICITY ORAL 4
ACUTE TOXICITY DERMAL 4
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
REPRODUCTIVE TOXICITY 2

PICTOGRAM(S)

Precautionary Statements

Prevention:
Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Keep away from heat, sparks, open flames, hot surfaces - no smoking.
Avoid breathing vapors, mist, or spray. Wash affected area thoroughly after handling. Do not
eat, drink or smoke when using this product. Contaminated work clothing should not be allowed
out of the workplace. Wear protective gloves, clothing, eye and face protection.

IDH number: 1019674 Product name: LOCTITE 3705 known as Loctite 3705 30ml for US EN/ES
Page 1 of 6
 Response:
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of
soap and water. Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. IF exposed or concerned: Get medical attention. If skin irritation or rash
occurs: Get medical attention. Take off contaminated clothing. In case of fire: Use foam, dry
chemical or carbon dioxide to extinguish.
Storage:
Store in a well-ventilated place. Keep cool. Store locked up.
Disposal:
Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*
Acrylate monomer Proprietary 30 - 60
N,N-Dimethylacrylamide 2680-03-7 10 - 30
Treated fumed silica 67762-90-7 5 - 10
Substituted silane Proprietary 1-5
Diphenyl-2,4,6-trimethylbenzoyl
75980-60-8 0.1 - 1
phosphine oxide

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.

Skin contact: Remove contaminated clothing and footwear. Immediately flush skin with
plenty of water (using soap, if available). Get medical attention. Wash clothing
before reuse. Thoroughly clean shoes before reuse.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel.

Never give anything by mouth to an unconscious person. Give a conscious
person several glasses of water. Get medical attention.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear. In case of fire, keep containers cool with water spray.

Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in
explosions or rupture of storage containers.

IDH number: 1019674 Product name: LOCTITE 3705 known as Loctite 3705 30ml for US EN/ES
Page 2 of 6
 Hazardous combustion products: Oxides of carbon, oxides of nitrogen, irritating organic vapors. Oxides of
silicon. Formaldehyde. Collect contaminated fire extinguishing water
separately. This must not be discharged into drains.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to
prevent entry into water system; wear full protective equipment during clean-
up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Scrape up spilled material and place in a closed
container for disposal. Store in a closed container until ready for disposal.
Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up.

7. HANDLING AND STORAGE

Handling: Use only with adequate ventilation. Keep away from heat, spark and flame.
Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling. Do not taste or swallow. Keep container
closed. Refer to Section 8. DO NOT heat or spray.

Storage: For safe storage, store between 2 °C (35.6 °F) and 8 °C (46.4 °F)
Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

Acrylate monomer None None None None
0.1 mg/m3 TWA
(Skin)
N,N-Dimethylacrylamide None None None
0.025 ppm TWA
(Skin)
10 mg/m3 TWA 15 mg/m3 TWA Total
Inhalable dust. dust.
Treated fumed silica None None
3 mg/m3 TWA 5 mg/m3 TWA
Respirable fraction. Respirable fraction.
Substituted silane None None None None
Diphenyl-2,4,6-trimethylbenzoyl
None None None None
phosphine oxide

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below
exposure limits.

Respiratory protection: If personal exposure cannot be controlled below applicable limits by

ventilation, wear a properly fitted organic vapor/particulate respirator approved
by NIOSH. If this material is handled at elevated temperature or under mist
forming conditions, a NIOSH approved respirator must be used.

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety
showers and eye wash stations should be available.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact. Neoprene gloves.

IDH number: 1019674 Product name: LOCTITE 3705 known as Loctite 3705 30ml for US EN/ES
Page 3 of 6
 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid, Paste
Color: Beige
Odor: Mild
Odor threshold: Not available.
pH: Not applicable
Vapor pressure: < 5.0 mm hg (20 °C (68°F))
Boiling point/range: Not available.
Melting point/ range: Not available.
Specific gravity: 1.12
Vapor density: >1
Flash point: 84 °C (183.2 °F) Closed cup
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Flammability: Not applicable
Evaporation rate: Not available.
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available.
VOC content: 0 %; 0 g/l (calculated)
Viscosity: Not available.
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions of storage and use.

Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the
presence of incompatible materials.

Hazardous decomposition Oxides of carbon. Oxides of nitrogen. Oxides of silicon. Formaldehyde. Irritating organic
products: vapours.

Incompatible materials: Strong oxidizing agents. Strong acids and strong bases. Moisture. Peroxides. Free radical
initiators. Reducing agents.

Reactivity: Not available.

Conditions to avoid: Store away from incompatible materials. Heat, flames, sparks and other sources of ignition.
Exposure to moisture. Exposure to sunlight.

11. TOXICOLOGICAL INFORMATION

Product toxicity data: Modified acrylamide: LD50 (oral, rat) 316 mg/kg LD50 (dermal, rabbit) 518 mg/kg LC50 (vapor,
1hour, rat) greater than 776 ppm.

Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

IDH number: 1019674 Product name: LOCTITE 3705 known as Loctite 3705 30ml for US EN/ES
Page 4 of 6
 Potential Health Effects/Symptoms

Inhalation: Modified acrylamide is harmful if inhaled. Inhalation of vapors or mists of the product may be
irritating to the respiratory system. Vapors and mists will irritate nose and throat and possibly
eyes. DO NOT heat or spray as this increases the inhalation hazard.
Skin contact: Harmful in contact with skin. Causes skin irritation. May cause allergic skin reaction. Modified
acrylamide may be absorbed through skin in harmful amounts.
Eye contact: Causes serious eye damage.
Ingestion: Harmful if swallowed. Symptoms can include sore throat, abdominal pain, nausea, vomiting and
diarrhea.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Acrylate monomer None Irritant, Allergen
Irritant, Eyes, Mutagen, Kidney, Less weight
N,N-Dimethylacrylamide None
gain and food intake.
Treated fumed silica None Irritant
Substituted silane None Allergen, Irritant
Diphenyl-2,4,6-trimethylbenzoyl
None No Records
phosphine oxide

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Acrylate monomer No No No
N,N-Dimethylacrylamide No No No
Treated fumed silica No No No
Substituted silane No No No
Diphenyl-2,4,6-trimethylbenzoyl
No No No
phosphine oxide

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.

Hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Combustible liquid, n.o.s. (N,N-Dimethylacrylamide)
Hazard class or division: Combustible Liquid
Identification number: NA 1993
Packing group: III

International Air Transportation (ICAO/IATA)

Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Isobornyl acrylate)
Hazard class or division: 9
Identification number: UN 3082
Packing group: III

IDH number: 1019674 Product name: LOCTITE 3705 known as Loctite 3705 30ml for US EN/ES
Page 5 of 6
 Water Transportation (IMO/IMDG)
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Isobornyl
acrylate)
Hazard class or division: 9
Identification number: UN 3082
Packing group: III
Marine pollutant: Isobornyl acrylate

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.

CERCLA/SARA Section 311/312: Fire, Immediate Health, Delayed Health
CERCLA/SARA Section 313: None above reporting de minimis.

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other
components are listed on or are exempt from listing on the Domestic Substances List.
Components listed on the NDSL must be tracked by all Canadian Importers of Record as
required by Environment Canada. They may be imported into Canada in limited quantities.
Please contact Regulatory Affairs for additional details.

16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: 2,3

Prepared by: Product Safety and Regulatory Affairs

Issue date: 11/26/2018

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

This Safety Data Sheet has been generated based on OSHA Hazard Communication Standard (29 CFR 1910.1200) and provides
information in accordance with U.S. federal law only. No warranty or representation of any kind is given with respect to the
substantive or export laws of any other jurisdiction or country. Please confirm that the information provided herein conforms to the
substantive export or other law of any other jurisdiction prior to export. Please contact Henkel Product Safety and Regulatory
Affairs for additional assistance.

IDH number: 1019674 Product name: LOCTITE 3705 known as Loctite 3705 30ml for US EN/ES
Page 6 of 6