Chemence Cyanoacrylate Adhesive - SI grades

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 09/18/14 Revision date: 09/18/14 Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product name : Chemence Cyanoacrylate Adhesive - SI grades
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Surface Insensitive Cyanoacrylate Adhesive
1.3. Details of the supplier of the safety data sheet
Chemence, Inc.,
185 Bluegrass Valley Parkway,
Alpharetta, GA 30005 - United States
T 770-664-6624; F 770-664-6620
[email protected] - http://www.Chemence-US.com
1.4. Emergency telephone number
Emergency number : 1-800-424-9300; CHEMTREC® International Emergency number: 703-527-3887

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 4 H227
Skin Irrit. 2 H315
Eye Irrit. 2A H319
STOT SE 3 H335
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US) :

GHS07
Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : H227 - Combustible liquid
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
Precautionary statements (GHS-US) : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray
P271 - Use only in a well-ventilated area
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P302+P352 - IF ON SKIN: Wash with plenty of soap and water
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P337+P313 - If eye irritation persists: Get medical advice/attention
P501 - Dispose of contents/container to local, regional, national, and international regulations.

Precautionary phrases Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Contact through clothing (cotton) may
cause burns. Keep out of the reach of children.
2.3. Other hazards
This product is not identified as a PBT substance.
WARNING: Cyanoacrylate. Eye irritant. Bonds skin and eyes in seconds. This adhesive gives a virtually immediate, strong bond: apply only to
surfaces to be bonded. Do not get adhesive on your skin or other parts of your body, or that of others. In case of body contact, flush with water. Seek
medical attention for any eye or internal contact. Keep out of the reach of children.

SECTION 3: Composition/information on ingredients

3.1. Substances
Full text of H-phrases: see section 16
3.2. Hazardous components

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Chemence Cyanoacrylate Adhesive - SI grades
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Name Product identifier % GHS-US classification

ethyl-2-cyanoacrylate (CAS No) 7085-85-0 > 90 Flam. Liq. 4, H227
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
STOT SE 3, H335

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : If you feel unwell, seek medical advice (show the label where possible). Never give anything by
mouth to an unconscious person.
First-aid measures after inhalation : Overexposure may be irritating to the respiratory system. If breathing is difficult, remove victim to
fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical
advice.
First-aid measures after skin contact : Do not pull bonded skin apart. Gently wash with plenty of soap and water. If skin irritation or rash
occurs: Get medical advice/attention. Do not remove clothing if it sticks to the skin. Contact
through clothing can cause immediate polymerization, exothermic reaction and burning.
Removal of clothing can remove bonded skin. Submerge with water and soak affected area.
Wear a plastic (not cotton) apron for added protection. Get immediate medical advice/attention.
If the lips are accidentally bonded, apply warm soapy water, encourage maximum wetting and
pressure from saliva inside the mouth and peel or roll lips apart. DO NOT TRY TO PULL LIPS
APART. Burn: should be treated normally after the lump of cyanoacrylate is released from the
tissue.
First-aid measures after eye contact : Immediately flush with warm water for at least 15 minutes, get prompt medical attention and
apply gauze patch. Cyanoacrylate will bond to eye protein and cause a lachrymatory effect which
will help de-bond the adhesive. Keep eye covered until de-bonding is complete (usually with 1-4
days). Get immediate medical attention.
First-aid measures after ingestion : This route is not likely. Material will rapidly polymerise in the mouth prior to ingestion. Ensure
breathing passages are not obstructed. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Irritation of the eye tissue. Causes skin and eye irritation. Not expected to present a significant
hazard under anticipated conditions of normal use.
Symptoms/injuries after inhalation : May cause drowsiness or dizziness. May cause respiratory irritation.
Symptoms/injuries after skin contact : May cause irritation to skin. Cyanoacrylate bonds skin and eyes in seconds. In the case of large
spills on the skin, superficial burns may occur. Contact through clothing can cause immediate
polymerization, exothermic and burning.
Symptoms/injuries after eye contact : Causes eye irritation. Bonds eyes in seconds. Goggles or safety glasses are recommended.
Symptoms/injuries after ingestion : Ingestion unlikely. Material will rapidly polymerise in the mouth prior to ingestion.
4.3. Indication of any immediate medical attention and special treatment needed
If exposed or concerned, get medical advice and attention.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Alcohol-resistant foam. Dry powder. Carbon dioxide. Water spray or fog.
Unsuitable extinguishing media : Solid water jet ineffective as extinguishing medium. Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Combustible liquid.
Explosion hazard : In combustion emits toxic fumes of carbon dioxide, carbon monoxide and nitrogen oxides.
Reactivity : No dangerous reactions known under normal conditions of use.
5.3. Advice for firefighters
Firefighting instructions : Exercise caution when fighting any chemical fire. Use a water spray to cool exposed surfaces
and to protect fire-fighters. In case of major fire and large quantities: Evacuate area. Fight fire
remotely due to the risk of explosion. Use water spray or fog for cooling exposed containers.
Avoid (reject) fire-fighting water to enter environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Other information : Do not allow run-off from fire fighting to enter drains or water courses.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Evacuate the area immediately. Ensure adequate ventilation. Avoid all contact with skin, eyes,
or clothing. Handle in accordance with good industrial hygiene and safety practice.

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Chemence Cyanoacrylate Adhesive - SI grades
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

6.1.1. For non-emergency personnel

Protective equipment : Use appropriate personal protection equipment (PPE).
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Evacuate unnecessary personnel. Use appropriate personal protection equipment (PPE).
Ventilate area.
6.2. Environmental precautions
Do not allow water (or moist air) contact with this material. Avoid release to the environment. Prevent entry to sewers and public waters. Notify
authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Absorb excess liquid spillage on inorganic adsorbent material such as fine sand, brick dust etc.
Place spent adsorbent in sealed packages and contact specialist waste disposal contractor.
Collect spillage.
Methods for cleaning up : Clear up spills immediately and dispose of waste safely. Take up liquid spill into absorbent
material, e.g.: sand, earth, vermiculite. Use only non-sparking tools. Notify experts. Collect
spillage. Or flood with water slowly to complete polymerization (~10:1, adhesive : water). Scrape
off floor. Cured material can be disposed of as non-hazardous waste.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact of substance with water. Do no eat, drink or smoke when using this product. Do
not get in eyes, on skin, or on clothing. Do not handle until all safety precautions have been read
and understood. Observe very strict hygiene - avoid contact. Use only in a well-ventilated area.
Use personal protective equipment as required. Wash hands and other exposed areas with mild
soap and water before eating, drinking or smoking and when leaving work. Provide good
ventilation in process area to prevent formation of vapour.
Hygiene measures : Do not eat, drink or smoke in areas where product is used. Handle in accordance with good
industrial hygiene and safety practice. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Keep away from direct sunlight. Keep container tightly closed. Keep cool. Keep in fireproof place.
Store in a dry place. Keep container closed when not in use.
Incompatible products : Amines. Oxidizing agents. Alkali metals. Water. Alcohols. Strong bases. Strong acids.
Storage temperature : Refrigerated storage (2°C to 8°C) is recommended for optimum shelf life.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
ethyl-2-cyanoacrylate (7085-85-0)
USA ACGIH ACGIH TWA (ppm) 0.2 ppm
USA ACGIH ACGIH STEL (ppm) 0.2 ppm

8.2. Exposure controls

Appropriate engineering controls : Ensure all national/local regulations are observed. Avoid all unnecessary exposure.
Personal protective equipment : Protective clothing. Protective goggles. Gloves. Full protective flameproof clothing. Respiratory
protection of the dependent type. Avoid all unnecessary exposure.
Materials for protective clothing : Keep suitable chemically resistant protective clothing readily available for emergency use.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is
recommended. Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.

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Chemence Cyanoacrylate Adhesive - SI grades
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Colorless liquid.
Colour : Colourless.
Odour : Irritating. sharp.
Boiling point : > 300 °F
Flash point : > 176 °F
Self ignition temperature : > 450 °C
Vapour pressure : < 0.5 mmHg @75°F
Specific gravity : 1.06
Solubility : Reacts with water. Soluble in Acetone.
Evaporation rate : Negligible
VOC : <=20 g/l [California SCAQMD method 316B]

SECTION 10: Stability and reactivity

10.1. Reactivity
No dangerous reactions known under normal conditions of use.
10.2. Chemical stability
Stable under normal conditions. Polymerises rapidly with water.
10.3. Possibility of hazardous reactions
Hazardous reactions will not occur under normal conditions. Polymerization may occur on exposure to conditions or materials listed below.
Polymerization can be rapid.
10.4. Conditions to avoid
Direct sunlight. Heat, high temperature. Moisture, humidity.
10.5. Incompatible materials
Amines. Water. Alkalis. Oxidizing agent. Alcohols.
10.6. Hazardous decomposition products
Toxic fume. Carbon monoxide. Carbon dioxide. Nitrogen oxides.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity : Negligible ecotoxicity.
ethyl-2-cyanoacrylate (7085-85-0)
LD50 oral rat > 5000 mg/kg bodyweight (Rat; Experimental value,Rat; Experimental value)
LD50 dermal rabbit > 2000 mg/kg bodyweight (Rabbit; Experimental value,Rabbit; Experimental value)

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Negligible ecotoxicity.
12.2. Persistence and degradability
Chemence SIgrade
Persistence and degradability No data available.
ethyl-2-cyanoacrylate (7085-85-0)
Persistence and degradability No data available.
12.3. Bioaccumulative potential
Chemence SIgrade
Bioaccumulative potential No bioaccumulative potential
ethyl-2-cyanoacrylate (7085-85-0)
Bioaccumulative potential No bioaccumulation potential
12.4. Mobility in soil
Considered very low due to rapid polymerization with water.
12.5. Other adverse effects
Other information : Negligible ecotoxicity.

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Chemence Cyanoacrylate Adhesive - SI grades
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste treatment methods : Remove waste in accordance with local and/or national regulations.
Sewage disposal recommendations : Do not discharge into drains or the environment.
Waste disposal recommendations : Transfer to a suitable container and arrange for collection by specialized disposal company. Or
polymerize adhesive slowly with water (~10:1, adhesive : water). Hardened product can be
disposed of as non-hazardous waste by licensed contractors. Dispose in a safe manner in
accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

In accordance with DOT
Transport document description : NA1993 Combustible liquid, n.o.s., 9, III
UN-No.(DOT) : UN3334
DOT NA no. : NA1993
DOT Proper Shipping Name : Combustible liquid, n.o.s.
Department of Transportation (DOT) Hazard : 9 - Class 9 - Miscellaneous hazardous material 49 CFR 173.140
Classes
DOT Symbols : D - Proper shipping name for domestic use only, or to and from Canada,G - Identifies PSN
requiring a technical name
Packing group (DOT) : III - Minor Danger
DOT Special Provisions (49 CFR 172.102) : IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids
with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55
C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table
2 for UN2672).
T1 - 1.5 178.274(d)(2) Normal............. 178.275(d)(2)
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Packaging Non Bulk (49 CFR 173.xxx) : 203
DOT Packaging Bulk (49 CFR 173.xxx) : 241
DOT Quantity Limitations Passenger aircraft/rail : 60 L
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 220 L
CFR 175.75)
DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel.
Marine pollutant : No
Additional information
Other information : No supplementary information available.

ADR
Transport document description : UN UN3334 aviation regulated liquid, n.o.s., 9
Class (ADR) : 9 - Miscellaneous dangerous substances and articles

Transport by sea
Proper Shipping Name (IMDG) : Not regulated

Air transport
UN-No.(IATA) : UN3334
Proper Shipping Name (IATA) : aviation regulated liquid, n.o.s.
Class (IATA) : 9 - Miscellaneous Dangerous Goods
Packing group (IATA) : III - Minor Danger

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Chemence Cyanoacrylate Adhesive - SI grades
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 15: Regulatory information

15.1. US Federal regulations
Chemence SIgrade
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Delayed (chronic) health hazard
ethyl-2-cyanoacrylate (7085-85-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
Chemence SIgrade
WHMIS Classification Hazard Class B.3, D.2B

EU-Regulations
EUH202: Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin Irrit. 2 H315
Eye Irrit. 2A H319
STOT SE 3 H335
15.2.2. National regulations
No additional information available

15.3. US State regulations

Proposition 65 No Significant Risk Levels (NSRLs): This product contains no ingredient under Proposition 65 that is classified as a significant risk.

ethyl-2-cyanoacrylate (7085-85-0)
U.S. - New Jersey - Right to Know Hazardous Substance List

SECTION 16: Other information

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixturejs, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-phrases:
------ H227 Combustible liquid
------ H315 Causes skin irritation
------ H319 Causes serious eye irritation
------ H335 May cause respiratory irritation

WARNING: Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Contact through clothing (cotton) may cause burns. Keep out
of the reach of children.

HMIS III Rating

Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 2 Moderate Hazard
Physical : 1 Slight Hazard

SDS US (GHS HazCom 2012)

This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200.

Information presented herein has been compiled from sources considered to be accurate and reliable, but is not guaranteed to be so. Nothing herein shall be considered as recommending practices or
products in violation of any patent, law or regulation. It is the user's responsibility to determine the suitability of any material for a specific purpose and to adopt such safety precautions as may be
necessary. WE MAKE NO WARRANTIES REGARDING THE PRODUCTS AND DISCLAIM ALL EXPRESS OR IMPLIED WARRANTIES, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE.

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