DEJAZMACH WONDIRAD SENIOR SECONDARY SCHOOL

2017 E.C 1st SEMESTER CHEMISTRY WORK SHEET ONE FOR GRADE 12th
Direction: Read the questions carefully and Choose the correct Answer
1. According to Lewis concept , a base is a substances which :
A. Donates a proton C. donates electron pairs
B. Accepts a proton D. accepts electron pairs
2. Which of the following is NOT true about ACIDS ?
A. An acid is a proton donor C. An acid is electron pair acceptor
B. An acid provides H+ ion in aqueous media D An acid electron pair donor
3. According to Bronsted-Lowry concept an acid is a substances that is
A. Proton donor C. Proton acceptor
B. Electron pair donor D. Electron pair acceptors
4. In the reaction : FeCl3 + Cl- FeCl4- . The Lewis Acid is :
A. FeCl3 B. Cl- C. Cl3 D. FeCl4-
5. Three acids ,HA, HB &HC has the following Ka values 1.0 x10 -5, 2.0 x10-5 and 1.0 x10-6
respectivelly . What is the correct order of increasing acid strength?
A. HA,HB.HC B.HC,HB.HA C. HC,HA,HB D. HB,HA,HC
6. The PKa value of three acid HA, HB and HC are 4.5,3.5 and 6.5 respectively. Which of the
following is the correct order of acid strength?
A. HA>HB>HC B.HB>HA>HC C. HC> HA> HB D. HC>HB> HA
7. All of the following species can act as Bronsted-Lowry bases EXCEPT
A. I- B.NH3 C.HCO3- D.H2CO3
8. All of the following are acid -base conjugate pairs EXCEPT:
A. HS-,S2- B.HNO3, NO3- C. CH3NH2, CH3NH3+ D. H3O- , OH-
9. What is the [H3O+ ]in a 0.05Msolution of Ba(OH)2?
A. 1.0 X10-13M B. 5.0 X10-10M C. 1.0 X10-5M D. 5.0 X10-2M
10. An aqueous solution contains 0.10M NaOH at 250c.The PH of the solution is
A. 0.1 B. 1.0 C. 7.0 D. 13.0
11. An amphiprotic species is a molecule or ion that can _
A. Both accepts and donates a proton C. Donates proton
B. Both accepts and donates electron pairs D. Accepts proton
12. Which of the following substance could be amphiprotic ?
I=NO3- II.H2O III.NH3 IV.HCO3-
A. I&II B.I,II&III C. II&IV D. II,III&IV
13. Which of the following species is NOT amphoteric?
A. SO42- B. HS- C. HSO4- D. HCO3-
14. Which solution below has the highest concentration of hydroxide ions?
A. PH=3.2 B. PH=5.2 C. PH=7.2 D. PH=9.2-
15. Among the following oxi-acid anion which one is the weakest base ?
A. ClO4- B.ClO3- C. ClO2- D. ClO-
16. What is the percent ionization in 1.0M of HCN containing 3.7 x10-2 ?
A. 2.7% B. 3.7% C. 37% D. 27%
17. A0.1M solution of weak monoprotic acid is 4.2%ionized. What is the Ka acid ?
A. 1.8 x10-4 B. 4.2 x10-5 C. 9. 58 x10 -3 D. 5.5 x10-8
-8
18. The Ka of hypochlorous (HClO) is 3.0 x10 at 250c .What is the % ionization of hypochlorous
acid in a 0.015Msolution of HClO at 250C ?

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 A. 2.1 X10-5 B. 1.4 X10-1 C. 1.4 X10-2 D. 3.3 X 10-1

19. For the reaction :HCO3-+H2O ⇋ H2CO3 + OH-.The Bronsted acids are
A. H2O &OH- B. HCO3-&OH- C. H2O & H2CO3 D. HCO3- & H2CO3
20. The PH of a 0.1Msolution of a weak acid is 3.0 What is the ionization constant (ka) of the acid ?
A. 1.0 x10-7 B.1.0 x 10-5 C. 1.0 x10-3 D.1.0 x10-1
21. Which of the following acid dissociation constant(ka)is true for the acid H3PO4 ?
A. Ka3> ka2> ka1 B.. Ka3=ka2=ka1C.Ka3<ka2<ka1 D. ka1 =1/ka2 & ka2= 1/ka3
22. Which solution will be strongly acidic ? A. POH= 4.5 B.POH=13 C.PH= 8.5 D. PH= 7
23. Which of the following solution is basic ?
A. [ H+] =2 X10-5M C.[OH-]-=1 X10-7 M
B. [ OH-]-=3 X 10-9 M D. [H+] =1 X 10-8 M
24. The hydrogen ion concetration in a certain solution at 25 0c is 1.0 x10-6 . What is the POH of this
solution ? A. 2 B.6 C.8 D.10
25. What happens when CH3COONa is added to a solution of CH3COOH ?
A. dissociation CH3COOH decreases C.an increase in PH of the solution
B. Concentration of H+ decreases D. All of the above
26. The PH of a solution is 2.0. What is the concentration of OH – ion in the solution?
A. 1 x 10-12 B.1.0 X 102 C.1.0 X 10-2 D. none
27. Which of the following is TRUE for a 0.1M solution of acid HA ?
A. [H+]= 0.1M B. [A-]=.01M C.[HA]>[H+] D. PH= 1
-
28. What ratio of [F ] to [HF] would you use to make a buffer of PH= 2.15 (Pka=3.15) ?
A. 1:1 B .10:1 C.1:10 D. 1:2
29. How many grams of NaOH must be dissolved in a litter of solution
so that its PH will be 12 ? ( molar mass of NaOH = 40g/mol)
A. 0.01g B. 0.4g C. 40g D. none
30. The PH of a 0.05M Ba(OH)2 solution is A. 5 B. 9 C.11 D. 13
31. The suppression of ionization of weak acid or weak base by adding one of its own ions is
A. Buffer solution B. Common ion effect C. Buffer capacity D. None
32. The salt whose 0.1M solution acidic is A. KNO3 B.CH3COONa C.NaCN D.NH4Cl
33. If 0.365g of HCl is dissolved to make one litter of solution .The PH of solution is
A. 0.001 B.0.01 C.1.0 D.2.0
34. How many ml of 1M H2SO4 is required to neutralize 10 ml of 1M NaOH solution ?
A. 2.5 B.5 C.10 D. 20
35. The PKa of a weak monoproticacidis 4.8. What would be the ratio of [Acid]/[Salt] of a buffer if its
PH is 5.8 ? A. 0.1 B. 1.0 C. 2.0 D. 10. 0
36. Which one of the mixture of the following pairs will NOT give a buffer system ?
A. HCN/NaCN B. NH3/NH4Cl C. H3PO4/KH2PO4 D. HNO3/NaNO3
37. Bromthymol blue has ka= 1.0x10-7.Its acidic form is yellow and its basic form is blue .What is the
color if it is added to a solution with PH =8?
A. Yellow B. Blue C. Yellowish-blue D. Orange
38. 10ml of diprotic acid is titrated with 20ml of 1.0M NaOH .What is the molarity of the acid ?
A. 1.0 B.2.0 C. 4.0 D. 5.0
39. 50 ml of 0.1M HCl is titrated with 0.02M NaOH solution. What is the PHof the acid after the
addition of 50 ml of NaOH?
A. 0.04 B. 0.602 C. 1.4 D.0.301
40. In acid- base titration the PH at equivalence point for SA/SB, SA/WB & WA/SB titration
respectively are
A. PH=7, PH<7 , PH>7 C .PH>7, PH<7 , PH=7
B. .PH=7, PH >7 , PH<7 D. PH< 7, PH< PH>7

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