A Review of Secondary Alumina Products Its Byproducts
A Review of Secondary Alumina Products Its Byproducts
Submitted by:
SUDEEP KUMAR SINHA
Enrolment No.: K0126
MBA (Dual)3rd Semester
Guided by:
Submitted by:
SUDEEP KUMAR SINHA
Enrolment No.: K0126
MBA (Dual)3rd Semester
Guided by:
Dr. Bhavna Prajapati
Assistant Professor, Management Department
Submitted to:
This is to declare that this report has been written by me. No part of the report is
plagiarized from other sources. All information included from other sources has
been duly acknowledged. I aver that if any part of the report is found to be
plagiarized, I shall take full responsibility for it.
This is to certify that the project A Review of Secondary Aluminum Products & Its
byproducts submitted by Sudeep Kumar Sinha.
Roll No.: 131230122020
Enrolment No.: K0126 has been examined by the undersigned as a part of the
examination for the award of Master of Business Administration degree of ITM
University, Raipur (C.G.).
Date:
Acknowledgement
This project consumed huge amount of work, research, and dedication. Still,
implementation would not have been possible if I did not have a support of my
company mentor Mr. Hukum Chand Yadav and Mr. Aditya Tiwari and my
faculty guide Dr. Bhavna Prajapati. Therefore, I would like to extend my
sincere gratitude to them.
I extend my heartily thanks to Dr. Yasin Sheikh Head and all other faculty
members of School of Commerce, Management & Research, ITM University
for their support and valuable suggestions in one or other occasions to complete
the project.
This report is prepared as part of the curriculum and as a partial MBA requirement. The report
is on A Review of Secondary Aluminum Products & Its byproducts The research report
has two sections, in its first section company and industry profile is being described, whereas
in the second section, research methodology is described which includes, analysis and
interpretation.
The main purpose of this study is to understand the growth And Various uses of Aluminum
market in the next five years, identifying the major players of the market and its growth
drivers, the Growth in the Flame Retardant.
The study is done on the global basis and the data was collected through primary and
secondary mode. MS Excel was used for prediction. The result in this report is shown via
charts and graphs.
TABLE OF CONTENTS
CHAPTER
TITLE PAGE NO.
NO.
I Introduction 1-15
IX Annexure 54-65
CHAPTER I
INTRODUCTION
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INTRODUCTION:
ATH stands for Alumina Trihydrate, which serves as the filler in solid surface. ATH is found in its
physical form as a powder. This powder, as previously mentioned, is similar to the dry ingredients in
a cake mix that are held together by the eggs and oil, or, in solid surface, by the resin. ATH is made
from bauxite ore, a natural material that is the main source of aluminum. The ore, it is refined to a
powder using the Bayer Process. From there, the powder is used to create a variety of alumina
chemicals. Alumina trihydrate (also known as ATH and alumina Tri hydroxide, chemical formula
(Al2o3. 3h2o), initially derived from bauxite ore, before being refined into a fine white powder.
Alumina Trihydrate is the most widely used flame retardant in the world due to its versatility and
low cost. Available in different particle sizes, Alumina Trihydrate can be used in a wide range of
polymers at processing temperatures below 220°C.
Alumina Trihydrate is non-toxic, halogen-free, chemically inert, and has low abrasiveness.
Additional benefits are arc and track resistance in plastics exposed to electrical arcing, acid
resistance, and smoke suppression.
Alumina trihydrates thermodynamic properties, endothermic dehydration cools the plastic 6 rubber
parts and dilutes the combustible gases with water vapours that is generated in case of fire. ATH
widely use in Paper Industries as a whitening agent in place of titanium dioxide. Alumina trihydrate
is also use in Paints Industries. Alumina trihydrate can replace up to 25% of the Titanium dioxide
pigment & therefore is an economical extender reducing production cost. Ideal for the manufacture
of mortars used for floors with epoxy resins, polymer concrete parts, decorative resin parts, etc.
Alumina trihydrate is an inorganic white fine crystalline, non-hygroscopic powder. Alumina
trihydrates solubility in water and organic solvents is very low.
By volume, Alumina trihydrate is the largest flame retardant (FR) used in diverse end applications.
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Production:
Virtually all the Aluminum hydroxide used commercially is manufactured by the Bayer process which
involves dissolving bauxite in sodium hydroxide at temperatures up to 270 °C (518 °F). The waste
solid, bauxite tailings, is removed and Aluminum hydroxide is precipitated from the remaining solution
of sodium aluminate. This Aluminum hydroxide can be converted to Aluminum oxide or alumina
by calcination. The residue or bauxite tailings, which is mostly iron oxide, is highly caustic due to residual
sodium hydroxide. It was historically stored in lagoons; this led to the Ajka alumina plant accident in 2010
in Hungary, where a dam bursting led to the drowning of nine people. An additional 122 sought treatment
for chemical burns. The mud contaminated 40 square kilometres (15 sq. mi) of land and reached
the Danube. While the mud was considered non-toxic due to low levels of heavy metals, the associated
slurry had a pH of 13.
1.1Bauxite Mining
Bauxite is used as the main raw material in the manufacture of Aluminum. The bauxite is often
mined from only a few metres below the ground level. 3 tonnes of bauxites are required for 1 tonne of
Aluminum. To extract pure alumina, the Bayer process is used.
➢ Bayer process: The Bayer process is the principal industrial means of refining bauxite to
produce alumina (Aluminum oxide) and was developed by Carl Josef Bayer. Bauxite, the
most important ore of Aluminum, contains only 30–60% Aluminum oxide (Al2O3), the rest
being a mixture of silica, various iron oxides, and titanium dioxide.[1] The Aluminum oxide
must be further purified before it can be refined into Aluminum metal. The Bayer process is
also the main source of gallium as a byproduct despite low extraction yields.
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1.2 Bauxite grinding
The bauxite mineral is transported to refineries where the clay is washed off and the bauxite
Passes through a grinder to produce a more consistent material.
1.4. Settling
The sodium aluminate solution is then passed through into lower pressure settling tanks.
The solution at the top of the tanks is directed downwards through a series of filers to remove
excess red mud. The remaining alumina is then passed through huge “leaves” or cloth filters to
remove any solids in the solution.
1.5. Precipitation
The sodium aluminate solution is then cooled and pumped into large precipitators (sometimes
as tall as a 6-story building). Aluminum hydroxide seed crystals added to the solution to start the
precipitation process. At this point, large Aluminum crystals are formed.
1.6. Calcination
The crystals are then heated in rotary kilns to temperatures over 960°C. This extracts the last
impurities and creates a white powder, known as alumina or Aluminum oxide. The refined alumina
is transformed into Aluminum through the smelting or Hall–Héroult process.
1. 7. Smelting process
The alumina is poured into a reduction cell with 950°C molten cryolite. 400kA electrical
currents are passed through the mixture to break the bond between the Aluminum and oxygen.
The result is 99.8% pure Aluminum.
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Application of ATH:
Non-Ferric Alum:
Flame Retardant:
Alumina Trihydrate (Al₂O3.3H₂O) is the most widely used flame
retardant in the world due to its versatility and low cost. Available in
different particle sizes, it can be used in a wide range of polymers at
processing temperatures below 220°C. ATH is non-toxic, halogen-free,
chemically inert, and has low abrasiveness. Additional benefits are arc
and track resistance in plastics exposed to electrical arcing, acid
resistance, and smoke suppression. At about 2200C, ATH begins to
decompose endothermically releasing approximately 35% of its weight as
water vapor.
Al203.3H20 + HEAT
Alumina Trihydrate acts as heat sink thereby retarding pyrolysis and reducing
the burning rate. The water vapor released has an added effect of diluting
combustion gases and toxic fumes.
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Sheet moulding compound (SMC):
Industrial grade ATH for SMC Compounds is known for its high
flame-retardant properties. Available in white powder form, the
offered Aluminum trihydrate easily dilutes in alkali and acid.
Known for its low organic content, the offered ATH is appreciated
for its long shelf life, moisture free content, high efficacy rate,
impure composition, competitive price and easy handling method.
It can be accessed in different packaging standards.
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Manufacturing process:
This manufacturing process is the most commonly used as bauxite is a
ubiquitous material.
It involves reacting liquid sulfuric acid with either bauxite ore containing
Aluminum hydroxide
(Al (OH)3) and hydrated Aluminum (Al2O3 ∙ 3H2O), or synthetic hydrated
Aluminum previously refined from bauxite. Bauxite ore is the main source of
aluminium for the world and contains various aluminium minerals and two
iron minerals). The process creates hydrated aluminium sulphate per the
following reactions:
From bauxite: 3 H2SO4 + 2 Al (OH)3 + 8 H2O → Al2(SO4)3 ∙ 14 H2O
Adding 3 molecules of sulfuric acid to 2 molecules of aluminum hydroxide and
8 molecules of water results in 1 molecule of aluminum sulphate and 14 molecules of water.
From hydrated aluminum: 3 H2SO4 + Al2O3 ∙3H2O + 8 H2O → Al2(SO4)3 ∙ 14 H2O
Adding 3 molecules of sulfuric acid to 1 molecule of hydrated aluminium and 8 molecules of
water results in 1 molecule of aluminium sulphate and 14 molecules of water.
➢ Uses
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• Treatment Printing of clothes: Another one of the
many uses of aluminum sulphate is in dyeing and
printing on cloth. When dissolved in a large amount of
water that has a neutral or slightly alkaline pH, the
compound produces a gooey substance, aluminum
hydroxide. The gooey substance helps dyes stick to
the cloth fibres by making the dye water insoluble.
The role of aluminum sulphate, then, is as a dye
“fixer,” which means that it combines with the
molecular structure of the dye and the fabric so the dye
doesn’t run out when the fabric gets wet.
• PAC 9% HB: high-basicity liquid PAC, containing 9 ± 0,5% AL2O3, specific for
potable waters.
PAC 9 is based on highly charged Aluminum which results in lower dosage and
therefore reduces sludge volume and pH adjustment demand. It also improves solids
and/or phosphorous removal over conventional coagulants.
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➢ Uses
• Water treatment - The Poly Aluminum chloride (PAC) is used for settling of solid particles
present into drinkable waters and for the flocculation of
civil and industrial effluents. It has also a high ant
bactericide effect, due to the presence of chlorine into
the product formula, and can be utilized for large range
of pH and with higher turbidity.
❖ Manufacturing Process:
high-density aluminum fluoride through the “dry process” according to the following
reactions:
1. dry acid grade fluorspar (CaF2) reacts with sulphuric acid (H2So4) in externally heated
rotary kilns, generating gaseous hydrogen fluoride (HF) and calcium sulphate (CaSO4 ),
4
2. the gaseous HF reacts with dry aluminum hydrate Al (OH) in fluidised bed reactors to
produce high density aluminum fluoride.
3. The addition of aluminum fluoride to the raw materials used in the aluminum smelting
process reduces the temperature and improves the conductivity of the molten bath,
reducing the electric power consumption.
9|Page
➢ Uses
• Used as an additive for the production of Aluminum by electrolysis:
Aluminum fluoride sees its primary use as an additive in aluminum
production and by electrolysis. Aluminum manufacturing must include
extracting the aluminum from its ore, in which the ore is covered in pure
aluminum oxide and is then electrolyzed by a solution of aluminum fluoride
and cryolite.
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ACTIVATED ALUMINA:
Activated alumina is used for a wide range of adsorbent and catalyst applications including the
adsorption of catalysts in polyethylene production, in Hydrogen peroxide production, as a selective
adsorbent for many chemicals including Arsenic, fluoride, in Sulphur removal from fluid streams
(Claus catalyst process).
Available in white balls form, the offered Activated Alumina has wide applications in semiconductor,
fertilizer and metal processing industries. This chemical is an effective fluoride and arsenic remover for
waste water. It is also required for re circulation of cooling tower. Due to its large surface area, its
adsorption capacity is higher than other chemicals. Due to its stable chemical properties, it easily integrates
with solid materials. As a good desiccant, Activated Alumina is useful for quick drying of moisture enriched
gases.
❖ Manufacturing Process:
A method of making activated alumina including the steps of dissolving a double salt of
aluminum in a solution of pure water at 85°C., recrystalizing the double salt at a pressure about
250 psi and temperature ranging from 200°C. to 250°C., precipitating out the purified basic
double salt, drying the precipitated double salt to drive off water and roasting it at 850°C. to
950°C to drive off the sulphate, washing to remove the potassium sulphate and then drying the
remaining alumina to yield activated alumina for use as a high-grade catalyst. A method for
producing activated alumina suitable for use as a catalyst, comprising the steps of:
(a) dissolving a double salt of aluminum potassium sulphate Al2 K2 (SO4)4 in a
solution;
(b) heating and pressurizing the resulting solution in a pressure vessel to crystallize
and precipitate out a crystal material from said solution;
(c) drying and calcining said crystal material to produce a combination of alumina
and potassium sulphate;
(d) washing with water to remove said potassium sulphate from said combination of
alumina and potassium sulphate;
(e) drying said alumina remaining after the step of washing to produce an activated
alumina.
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PROPERTIES OF ALUMINUM TRIHYDRATE:
-Physical Form: Powder
-Particle Morphology: Hexagonal
-Colour: White
-Specific Gravity:2.42 g/cm3
-pH Value: 9 - 10
-Hardness, Mohs: 2.5 – 3.5
-Refractive Index: 1.57
-Temperature of Decomposition: 220°C / 428°F
-Heat of Decomposition, Cal/g: 280
-Theoretical loss on ignition: % 34.6
PHYSICAL PROPERTIES:
-Powdery substance
-Odourless
-Non-carcinogenic
-Contains thermal characteristic that provides translucency and whiteness to
-Solid surface material
-Non-smoking
-Low-toxicity
-Halogen-free
-Flame retardant
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CHAPTER II
COMPANY PROFILING
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2.1 Minning:
Mining is the process of extracting useful materials from the
earth. Some examples of substances that are mined include coal,
gold, or iron ore. Iron ore is the material from which the metal
iron is produced.
The two major categories of modern mining include surface mining and underground mining. In surface
mining, the ground is blasted so that ores near Earth’s surface can be removed and carried to refineries to
extract the minerals. Surface mining can be destructive to the surrounding landscape, leaving huge open
pits behind. In underground mining, ores are removed from deep within the earth. Miners blast tunnels
into the rock to reach the ore deposits. This process can lead to accidents that trap miners underground.
Along with accidents, a career in mining can also be dangerous since it can lead to health problems.
Breathing in dust particles produced by mining can lead to lung disease. One of the most common forms is
black lung disease, which is caused when coal miners breathe in coal dust. Many other types of mining
produce silica dust, which causes a disease similar to black lung disease. These are incurable diseases that
cause breathing impairment and can be fatal.
Extraction:
Metal extraction can occur when the thermodynamics Favors it, or when the Gibbs free energy for the
associated reaction is negative as discussed previously. Pourbaix diagrams utilize Gibbs free energy
information to provide useful insights into the conditions needed for extraction. Thermodynamics
feasibility must be accompanied by reasonable reaction rates to make extraction viable on a commercial
scale.
Commercial extraction of metals from minerals is usually practiced by dump leaching, heap leaching, tank
leaching, or pressurized leaching. Dump leaching is performed by percolating a leaching solution through
mined ore that contains low concentrations (low grade) of desired elements. Heap leaching is
accomplished by applying solution to a bed of crushed ore of low to medium grade that is often
agglomerated prior to leaching. Tank leaching utilizes stirred tanks containing leaching solution with
medium to high grade ore that is crushed and ground to fine particles. Pressurized leaching is often
practiced on crushed and ground sulphides concentrates and aluminum ore to accelerate dissolution at
elevated temperatures of 110–230 °C, which is only possible for aqueous solutions in pressurized vessels.
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Founded in the year 1985 by Shri Anil Agrawal and Shri Sunil Agrawal. The group has
come a long way from Taking contracts from PWD
to Setting up a calcined Bauxite Unit from Owned
Bauxite Mines. The group expanded in iron steel,
Food Processing and Trading in between. About the
groups objective is to be one of the most cost group
efficient producers of Ferrous and Non-Ferrous
Metals along with continuous nurturing of human as
well as natural resources. Till Date the group has
achieved a topline of over Rs 1,500 Cr. and provides
direct employment to over 900 strong taskforces
across all verticals.
Vision:
“To Become one of the most respected and admired Global Metal and Food Processing
Company from India, Focused on technology, innovation & Imaginative treatment of Natural
Resources”.
Mission:
“To Become the most cost-efficient processors of Minerals & Metals and to be Agri one of the
prominent commodity players in India carefully nurturing the Natural available Human and
Resources in the region.”
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Maa Kudargarhi Energy & Ispat Pvt Ltd: Maa Kudargarhi Energy and Ispat Private
Limited is in the business of Integrated Steel Plant. The Proposed plant is
coming at district Jashpur, state of Chhattisgarh with capacity of 4 Lakh TPA
finished steel. Plant will have DRI, melting facility for rolling mill of the same
capacity.150 MW captive solar power plant is part of the project. Land has already been
acquired and procedings of environmental clearance is in process.
Maa Kudargarhi Power & Ispat Pvt Ltd: Maa Kudargarhi Power and Ispat Private
Limited is a company to support backward integration of Maa Kudargarhi
Steels Private Limited. Plant will have DRI, melting facility for existing
rolling mill.150 MW captive solar power plant is part of the project. Land has
already been acquired and proceedings of environmental clearance is in process.
Maa Kudargarhi Alumina Refinery Pvt Ltd: Maa Kudargarhi Minerals and
Refractory Private Limited is in the business of Mining and Processing of
Bauxite in Ambikapur region of Surguja district in Chhattisgarh, India. We mine
Bauxite and produce our own calcined bauxite and also supplies to aluminum
industries, cement plants, etc. The plant is equipped with state-of-the-art facilities, with
full- fledged calciner along with a crushing and grading facility. The company is led by
efficient and highly skilled manpower.
We have the capacity to supply any grades required by the customer. Today, the Indian
mineral industries are in scarcity of Calcined bauxite and we at MAA Kudargarhi is here
to bridge this gap to a possible extent. Our mining capacity is 4 Lacs Tonnes per annum
and we have raw materials in abundance which is one of our greatest strengths. Our
products are used in Refractories, Mortars, Emery, Castable & Allied Products, Welding
flux and as an Anti- Skid for Roads and Runways.
Maa Kudargarhi Minerals and Refractories Pvt Ltd: Maa Kudargarhi Minerals
and Refractory Private Limited is in the business of Mining and Processing of Bauxite
in Ambikapur region of Surguja district in Chhattisgarh, India. We mine Bauxite and
produce our own calcined bauxite and also supplies to aluminum industries, cement
plants, etc. The plant is equipped with state-of-the-art facilities, with full-fledged
calciner along with a crushing and grading facility. The company is led by efficient and
highly skilled manpower. We have the capacity to supply any grades required by the
customer. Today, the Indian mineral industries are in scarcity of Calcined bauxite and
we at Maa Kudargarhi is here to bridge this gap to a possible extent.
Our mining capacity is 4 Lacs Tonnes per annum and we have raw materials in
abundance which is one of our greatest strengths. Our products are used in Refractories,
Mortars, Emery, Castables & Allied Products, Welding flux and as an Anti- Skid for
Roads and Runways. Our product has been approved by leading names in the industry
like Carborundum, Premier Refractories, Maithan Ceramics etc.
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The future products in our basket are brown fused alumna, white fused alumna,
calcined alumna, pink fused alumina, mullite, etc. These minerals are well in demand
in the Indian industry now. Our technical team is working in these projects to bring
these products into the market by 2022.
BM Foods: The Firm also has two operational Rice mill at Ambikapur and
Ramanuganj, one of the major Rice hubs of Chhattisgarh. Capacity of both the rice
mills is of 400 TPD. The Firm is also engaged in trading of various qualities of rice,
Grains and Pulses We foresee a major upsurge in Agri commodity business in near
future.
Mahamaya Food and Grains Pvt Ltd: Company is involved in processing of Wheat
Flour, Semolina, Gram Flour, Refined Flour Etc. Unit is located at
Ambikapur with capacity of 200 TPD. Major supplies are made in market
under the brand "Chetak”. The company wants to expand this business by
adding few values added products in FMCG sector by capitalizing its brand.
Farmer Bridge Food Park Pvt Ltd: This segment includes packaging materials,
packaging and allied, packaging equipment, processes and technology, labels and tags.
Maa Kudargarhi Biofuels Pvt Ltd: Maa Kudargarhi Biofuels Private Limited is in the
business of production and/or processing of various biofuels from agro based products
and also in trading of byproducts made out of such biofuels.
Helio Renewable Power Pvt Ltd: Helio Renewable Power Private Limited will be
nodal company for setting up Solar Power Plant from concept to commissioning for total
captive demand of the group companies. Manufacturing of solar PV panels is also
proposed in the same company.
Kawatiya Steels: The firm is in the business of steel and cement trading around
Ambikapur through own network of traders and distributors.
Capitalising on group's strength in TMT bars, the firm has strengthened its position in
supply to construction sector in the region.
This trading business has enabled better understanding of TMT rod Market in the area.
Justifying expansion of group's steel manufacturing plant around Ambikapur.
The firm has big plans to expand the trading of steel rods to prepare ground for the
upcoming TMT rod facilities in the new plant, we foresee a major upsurge in trading
business in immediate future.
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Group Milestones
Plant of 1000
PWD Oil Mill TPM Raipur Flour Mill
Acquistion of Acquistion of
New Rice Mill at 1 more
2 Bauxite
Ramanujganj and Bauxite Mines
Mines at
Rice Mill and Raw Rice Plant Pulses Refining unit at Chhatisgarh
Chhatisgarh
Bauxite
Calcination 2020
at Ambikapur
Chhatisgarh
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Corporate Management Team
Managing Director
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2.2.4 CLIENTS:
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CHAPTER III
REVIEW OF LITRATURE
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1. Research Paper-1 Sonthalia, Behara& Kumaresan (2013) states that:
The Bayer process used for refining bauxite to smelting grade alumina serves as the
linchpin of the Aluminum production industry worldwide. Even though the process is well
established, the presence of impurities in the liquor affects the quality of product and
imposes a major economic cost on the industry. This review article focuses on the issues
pertaining to Gibbsitic (Al2O3.3H2O) precipitation. The comprehensive review provides a
basic understanding of the aluminum trihydrate precipitation and agglomeration
phenomena. Crystal growth rate and agglomeration play a significant role in determining
the output particle size distribution (PSD) of agglomerates. Hence, the effect of certain
thermodynamic and hydrodynamic parameters along with the impact of natural impurities
and additives (artificial impurities) on hydrate growth has been reviewed.
Aluminum is the third abundant element in the earth crust. It never occurs as a free
element. It is a silvery white metal with a wide range of application in the transport,
construction, packaging industry, electronic production, household appliances, etc., and
consequently the economic activities of these industrial sectors determine the overall
demand for aluminum.
A model is designed to be a flexible tool in accommodating certain factors that impacts
the metal ‘s growth and its subsequent production in India. Consumption of Aluminum
goes hand in hand with production. So, a future prediction of Aluminum production is
projected considering the Gross Domestic Product, Population, Power and Automobiles.
The aluminum model simulates the technology evolution of the industry from 1980 to
2030, prior to primary Aluminum production. Several future projections have also been
portrayed and correlated in the model to illustrate the technology dynamics of the
sector ‘s future.
4. Research Paper-4 Khattab, Sadik, F Feteha& Elsayed Abdel Bary (2016) describes in
their paper that:
In this work, different concentrations, per hundred rubbers (phr), of aluminum trihydrate
(ATH) were added to thermoplastic rubber nanocomposite based on ethylene propylene
diene monomer and linear low-density polyethylene. The effect of the added compound
on the flammability, rheological, mechanical properties, and electrical conductivity of
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the composite was studied. The results of the cone calorimeter showed a significantly
reduction in the flammability of the composites occurred when the composite was
treated with ATH. The peak heat release rate was reduced by about 66% when the
composite was loaded with 180 phr of ATH. Moreover, the time to ignition prolonged up
to 160%. The total smoke released decreased significantly as the concentrations of the
ATH were increased. A reduction of about 69% in the total smoke released was observed
when the composite was treated with 180 phr. The thermogravimetric analysis showed a
reduction in the overall weight loss as the concentrations of ATH were increased. A
reduction of about 50% of the original weight was observed when 180 phr of ATH was
used. An appreciable decrease in tensile stress and strain with increasing ATH contents
had been observed. The addition of ATH markedly reduced the conductivity of the
thermoplastic rubber nanocomposite
5. Research Paper-5 Li, Franco, Yang, Zhu, Zhang, yhao, Zhang and J Zhu. (2019)
states that:
Aluminum trihydrate (ATH) is one of the most widely used fillers in solvent-borne
coatings and polymer industries. To investigate its performance in powder coatings, four
different pigments to binder ratios (P/B) were used in respect to different ATH
concentrations in four most widely used resin systems (epoxy, epoxy-polyester,
polyurethane and polyester). The angle of repose (AOR) and specific gravity of powder
paints increase accordingly with ATH concentration. The mechanical properties,
corrosion and UV resistance performances of coating films are enhanced or only slightly
decreased with the addition of ATH. Pencil scratch hardness increase significantly with
the increase of ATH content. Impact resistance decreases within 5% of the initial
resistance at the maximum ATH loading. There is a slightly decrease in corrosion
resistance performances of less than 2 mm of failure at scribe in all formulations. The
incorporation of ATH has slight effect on the UV resistance performance of all the
samples. Moreover, the matting effect of ATH is observed for all the resin systems,
especially epoxy, with the specular gloss decreasing more than 70% at P/B of 0.75.
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7. Research Paper-7 Wang, F Guo, & J Chen (2006) describes that:
Wet surface modification of nano-Al (OH) 3 has been carried out with a silane coupling
agent; the optimum results were obtained with a silane coupling agent dosage of 1.5%
(by weight) and a pH of the Al (OH) 3 slurry of 5-6. The modified composite particles
have been studied by means of FTIR spectroscopy, settlement tests and mechanical
testing. Settlement tests show that the sedimentation rate of the modified particles in
liquid paraffin is markedly below that of the unmodified particles. IR spectroscopy
confirms that the organic groups are chemically grafted to the Al (OH)3 surface. The
mechanical properties of the composite with the modified ATH were significantly
enhanced. When the modified ATH was used as a flame retardant with EVA, the
mechanical properties and the flame-retardant properties of the composite with 55%
inorganic filler (mostly ATH) were shown to meet national standards.
8. Research Paper-8 Xiang-yang, -lin, -wei, Jie, Shang-yuan (2008) states that:
The thermal stability, particle size and morphology and oil absorption of aluminum
hydroxide (ATH) treated by dry modification with three different modifiers were
investigated. The experimental results show that the thermal stability of ATH powder is
markedly improved by dry modification technology with the following modifiers such as
phosphoric acid, polyacrylic acid and the mixture of phosphoric acid and polyacrylic acid.
The best effect comes from pure phosphoric acid, and the initial temperature for the loss
of crystal water of ATH powder modified with pure polyacrylic acid can reach about 202
°C that is approximately 10 °C higher than that of ATH powder before modification. The
phenomena of agglomeration and macro-aggregate badly exist in ATH powder modified
with the modifiers containing phosphoric acid. The growth of particles and
agglomerations of powders are not evident in ATH powder modified with pure polyacrylic
acid. The oil absorption of ATH powder modified with the modifiers containing
phosphoric acid is apparently larger than that of original ATH powder and ATH powder
modified with pure polyacrylic acid. The oil absorption of the ATH powder modified with
pure polyacrylic acid is slightly smaller than that of original ATH powder.
Low soda or high purity hydrates/alumina with less than 0.1% Na2O by weight are
high-tech materials having extremely special and versatile high-tech applications.
When calcined, they are used especially in electronics applications for making high-
end refractories and ceramics and are precursor materials for activated alumina used
for catalysts supports. Caustic soda is one of the main impurities in alumina and has
an undesirable effect on alumina properties when used in specific applications
The paper thoroughly explains the origin, mechanism, and factors affecting the
formation of caustic soda in alumina hydrate. It gives an overview of the special
hydrate/alumina and reviews comprehensively the manufacturing processes,
properties, and vast applications of these special products. It also gives an insight into
a process developed by JNARDDC for its production of 3N (99.9%) purity alumina.
The paper would largely help in identifying the existing knowledge gap and surely
assist in the production of these advanced materials.
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CHAPTER IV
RESEARCH METHODOLOGY
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4.1 OBJECTIVE
The following objectives have been developed based on the review of literature and the
identified research gap:
• To analyse the different aspects of Aluminum industry.
• To identify the top players of the industry.
• To identify the major regions in which top players have significant presence.
• To identify the growth drivers of the market.
• To forecast the global market share of industry and production of alumina up to 2030.
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4.2.3 SECONDARY DATA
Secondary data is any information collected form pre-existing sources. In-depth surveys and
trade publications are used to collaborate on technical facts and trends. The dynamics of the
industry and market trends are assessed from reliable sources. Data is accumulated through
government sources and corporate filings including annual reports, investors presentations,
white papers, news releases, and others.
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CHAPTER V
ANALYSIS AND DATA INTERPRETATION
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5.1 MAJOR PLAYERS AND THEIR MARKET SHARES
MARKET SHARE
24%
27%
2%
3%
21%
7%
16%
Given the Big players controlling the majority of market shares, the market is fairly
concentrated. Major players are using a variety of tactics to enter, create, test, and introduce
more efficient products.
The top six players of Aluminum Tri Hydrate market are, Aluminum Corporation of China
Limited, J.M. Huber Corporation, Sumitomo Chemical Co. Ltd, Aditya Birla Management
Corporation Pvt Ltd, Alcoa Corporation, Nabaltec AG.
These players hold 73% of the global Aluminum Tri Hydrate market. The major market
participants have adopted a number of contracts, partnerships, agreements, acquisitions, joint
ventures, and new product launches as significant strategies.
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5.2 GLOBAL SEGMENT MARKET SHARE
5.2.1 Application Type:
MARKET SHARE
40.00% 36.76%
35.00%
30.00% 25.00%
PERCENTAGE
25.00%
20.00%
14.70% 13.23%
15.00% 10.29%
10.00%
5.00%
0.00%
Non Ferric Flame FRP SMC DMC
alum Retardent
APPLICATION
Five types of ATH (On basis of application) are considered for this study, they are, Non-Ferric
Alum, Flame Retardant, FRP (Fibre-reinforced polymer), SMC (Sheet moulding compound),
DMC (Dimethyl carbonate). FRP (Fibre-reinforced polymer) is the dominated ATH type in
the global market with 36.76%. Flame Retardant is the second largest ATH type in the global
market. DMC (Dimethyl carbonate) has the least market share with 10.29%.
MARKET SHARE
40.00%
35.00%
35.00%
30.00%
25.00%
PERCENTAGE
25.00% 23.00%
20.00% 17.00%
15.00%
10.00%
5.00%
0.00%
ALUMINIUM POLY ALUMINIUM ALUMINIUM ACTIVATED
SULPHATE CHLORIDE FLUORIDE ALUMINA
BYPRODUCTS
Aluminum Sulphate, Poly Aluminum Chloride, Aluminum Fluoride, Activated Alumina are
some of the Biproducts application types. Activated Alumina is the major Biproducts
application type of holding 35.28% of the market followed by Aluminum Fluoride with 24.25%
and Aluminum Sulphate capturers minor sector of Biproducts application type with 17.21%.
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5.2.3 ATH Market Share (Global):
MARKET REGION
OCEANIA
1% AFRICA
1%
N.AMERICA
23%
ASIA
S.AMERICA 45%
4%
EU 27
22% OTHER EUROPE
4%
Asia has shown the largest annual increase in consumption of ATH, driven largely by the
increased industrial consumption especially in China and India with 45% market share global.
Whereas Africa and Oceania have the least market share with 1-1% each.
Iceland
United States
Norway
Australia
COUNTRY
Bahrain
United Arab Emirates
Canada
Russia
India
China
0 5 10 15 20 25 30 35 40 45
MILLIOM (MT)
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5.2.5 State-wise ATH consumer in India:
MADHYA PRADESH
others(south
2% UTTAR PRADESH CHHATTISGARH
telangna,hyderabad,
3% 3%
bihar)
17% WEST BENGAL
5%
ODISHA
1%
DELHI(PUNJAB&HARYANA)
7%
PERCENTAGE
MAHARASHTRA GUJRAT
21% 40%
RAJASTHAN
1%
For ATH, Gujrat is dominant in India of all other state with 40% customer, whereas Rajasthan
and Odisha have least dominant with 1% customer in India.
5.2.5 Top 5 Company Market capture in percentage (ATH) in India:
Market capture
40%
35% 38%
30%
PERCENTAGE
25%
27%
20%
15%
17%
10%
12% 3%
5% 2%
0%
NALCO HINDALCO CREDO PIONEER ALUMINIUM OTHERS
CHEMICAL
COMPANY
In India Nalco has the highest market capture with 38% and other players has the lowest market
capture with 2%.
ATH market
2.29 2.38
2.5 2.2
2.11
1.93 2.02
2 1.75 1.84
1.66
BILLION(USD)
1.5
0.5
0
2022 2023 2024 2025 2026 2027 2028 2029 2030
YEAR
ATH market
Alumina Trihydrate (ATH) Market Size was valued at USD 1.57 billion in 2021. The
aluminum trihydrate (ATH) market industry is projected to grow from USD 1.66 Billion in 2022
to USD 2.38 billion by 2030, exhibiting a compound annual growth rate (CAGR) of 4.58%
during the forecast period (2023 - 2030). Growing demand for flame retardants across major
industries and surging use of the product in the paints and coatings industry are driving the
market growth. The inclusion of ATH in FRP production helps to minimize smoke generation
rate as it tends to absorb maximum amount of heat as a result of endothermic reaction. Nontoxic
formulation, precise content, long storage life, white powder form, free flow quality and low
price are the key attributes of this chemical.
The global demand for alumina has witnessed significant growth over the years, driven by its
widespread use in industries such as transportation, construction, packaging, and electrical
engineering. As a result, assessing the adequacy of bauxite reserves and identifying potential
supply constraints are crucial for meeting the escalating demand. In addition to bauxite reserves,
market reserves for aluminum also include existing inventories of refined aluminum. These
inventories play a crucial role in balancing supply and demand fluctuations and act as a buffer
during periods of disruption or volatility in production. Tracking the levels of refined aluminum
inventories and understanding their distribution across regions provide valuable insights into
market stability and the potential for short-term adjustments in supply. Factors such as economic
growth, technological advancements, environmental regulations, and geopolitical developments
significantly influence the market reserves for aluminum. Economic growth, particularly in
emerging markets, drives the demand for aluminum, necessitating the evaluation of bauxite
reserves to support future production capacities. Technological advancements, such as improved
extraction techniques and recycling technologies, impact the availability and utilization of
aluminum reserves.
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5.4 GROWTH DRIVERS
5.4.1 Driver 1: GROWING DEMAND FOR FLAME RETARDANTS ACROSS MAJOR
INDUSTRIES
14
12
10
BILLION(USD)
6 11.4 12
10.4 10.8
9.2 9.8
4 8.1 8.5
7.6
0
2022 2023 2024 2025 2026 2027 2028 2029 2030
YEAR
The Global Flame-Retardant Market size was valued at USD 7.6 Billion in 2022 and is expected
to reach USD 12 billion in 2030 growing at a CAGR of 5.21% during the forecast period of
2023-2032. Chemicals called flame retardants are added to combustible materials like textiles,
plastics, and coatings to either stop a fire from starting or slow it down. They are a variety of
chemicals with various physical and chemical properties and molecular structures. Growing
demand for non-halogenated flame retardants over halogenated flame retardant across industries
is a factor driving the growth of the alumina trihydrate market. The increasing incidence of fire
accidents drives the demand for alumina trihydrate as a flame retardant.
5.4.2 DRIVER 2: INCREASED IN FIBRE-REINFORCED POLYMER (FRP):
50 53.5
51.2
48.66
40 46.3
BILLION(USD)
44.6
39.2 41.3
37.6
30 35.2
20
10
0
2022 2023 2024 2025 2026 2027 2028 2029 2030
YEAR
Fiber Reinforced Polymer (FRP) Market Size was valued at USD 35.2 Billion in 2022.
The Fiber Reinforced Polymer (FRP) Market industry is projected to grow from USD
37.6 Billion in 2023 to USD 53.8 Billion by 2030, exhibiting a compound annual growth
rate (CAGR) of 4.83% during the forecast period (2023 - 2032).
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5.4.3 DRIVER 3: INCREASE IN UTILIZATION AND RISING DEMAND FOR
CATALYSTS
35
30 33.4
32.2
30.1 30.9
29.1
BILLION(USD)
25 27.8
25.4 26.4
24.4
20
15
10
0
2022 2023 2024 2025 2026 2027 2028 2029 2030
YEARS
There is a growing demand for catalysts in many eases of application, including chemical
synthesis, petroleum refinery, polymers, petrochemicals, and environmental, and drives the need
for process optimization, yield improvement, and cost savings. Furthermore, ecological catalysts
can help manufacturers comply with all mandates regarding NOx and Sox, as well as carbon
dioxide emissions. The global catalyst market size was valued at USD 24.4 Billion in 2022, and
it is expected to grow to USD 33.4 Billion in the forecast period 2023-2030 with an anticipated
CAGR of 3.5%.
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CHAPTER VI
RESULTS AND FINDINGS
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RESULTS AND FINDINGS OF THE STUDY
• The finding of the study id that the market is highly concentrated with major 6 players.
• Aluminum Tri hydroxide (ATH) is a low-cost, inert, odourless filler powder than can be
used to bulk-out, reduce shrinkage, add weight and add fire retardancy to casting resins
including polyurethane, epoxy and polyester.
• Most of the consumer in India for ATH is in Gujrat with 40% of customer.
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CHAPTER VII
CONCLUSION
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CONCLUSION
The purpose of this study is to understand the past, present, and future scenario of ATH and
Products developed from ATH to sell in the market. The study provides information on the
major industry growth factors and key market drivers for ATH global market. Also, depicts
the current trends and future estimations.
The aim of studying different products developed by aluminum and aluminum trihydrate can
vary depending on the specific research objectives and context. However, the general aims of
such studies can include the following:
3. Application Development: The aim is to explore and develop new applications for
aluminum-based products and aluminum trihydrate compounds. This involves studying their
unique properties and characteristics and identifying potential areas where these materials can
be utilized effectively. The aim is to expand the range of applications, improve existing
processes, and explore innovative solutions in industries such as construction, transportation,
packaging, electronics, and fire safety.
4. Sustainability and Environmental Impact: The aim is to evaluate the sustainability and
environmental impact of aluminum-based products and aluminum trihydrate compounds
throughout their life cycle. This involves assessing factors such as raw material sourcing,
energy consumption, greenhouse gas emissions, recyclability, and waste management. The
aim is to identify opportunities to reduce the environmental footprint and promote sustainable
practices in the production, use, and disposal of these materials.
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CHAPTER VIII
LIMITATIONS
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LIMITATIONS OF THIS STUDY
• Limited period is taken for this study leading to inaccuracy of data.
• The outcome if this study may be inaccurate as it is dependent on the opinion of the
industry players and representatives, the results based on their opinion may be
ambiguous.
• This study is not backed by any state of art tools or software and the results are only
derived by using MS Excel. Data outsourcing partner Want Stats Research and media
Pvt Ltd., Source: https://www.marketresearchfuture.com.
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CHAPTER IX
BIBLIOGRAPHY AND REFERENCES
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BIBLIOGRAPHY AND REFRENCES
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CHAPTER IX
ANNEXURE
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Weekly Progress Report IIP
Week Number: 1
Monday Training
Tuesday Training
Wednesday Training
Guide
Remarks from the Company Guide:
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Weekly Progress Report IIP
Week Number: 2
Guide
Remarks from the Company Guide:
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Weekly Progress Report IIP
Week Number: 3
Signature of Student
Seal & Signature of Company
Guide
Remarks from the Company Guide:
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Weekly Progress Report IIP
Week Number: 4
Signature of Student
Seal & Signature of Company
Guide
Remarks from the Company Guide:
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Weekly Progress Report IIP
Week Number: 5
Preparation of
Wednesday
excel sheet
Preparation of
Thursday
excel sheet
Discussion with
Friday
guide
Guide
Remarks from the Company Guide:
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THIS PROJECT REPORT IS THE PROPERTY OF
SCHOOL OF COMMERCE, MANAGEMENT & RESEARCH,
ITM UNIVERSITY, RAIPUR (CHHATTISGARH), INDIA.
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