1

Series :W2YXZ SET ~ 3

Roll No.
Q.P. Code 56/2/3

iCandidates must write the Q.P. Code

!on the title page of the answer-book.

NOTE
()
Please check that this question paper contains 23 printed pages.
(I)
Please check that this question paper contains 33 questions.

hand side of the question paper should be

Q.P. Code given on the right answer-book by the candidate.
written on the title page of the

the question in the answer

Please write down the serial number of
attempting it.
book at the given place before

read this question paper. The question

15 minute time has been allotted toa.m. From 10.15 a. m. to 10.30 a.m.. the
paper will be distributed at 10.15 and will not write any answer
candidates will read the question paper only
this period.
on the answer-book during

CHEMISTRY (Theory)
Retta g44: 3 U
3feba4 3% : 70
Time allowed : 3 hours
Maximum Marks: 70

56/2/3 731-3 1 P.T.0.

General Instructions :
Read the following instructions carefully and follow them :
(i) This question paper contains 33 questions. All questions are
compulsory.
- Section A, B, C. D
(ü) This question paper is divided into FIVE sections
and E.
multiple choice type
(iii) Section A - questions number l to 16 are
questions. Each question carries l mark.
short answer type
(iv) Section B - questions number 17 to 21 are very
questions. Each question carries 2 marks.
number 22 to 28 are short answer type
(v) Section C - questions
questions. Each question carries 3 marks.
and 30 are case-based questions.
(vi) Section D - questions number 29
Each question carries 4 marks.
long answer type questions.
(vii) Section E- questions number 31 to 33 are
Each question carries 5 narks.
the question paper. However, an
(viiü)There is no overall choice given in
questions in all the sections
internal choice has been provided in few
except Section -A,
separate question paper for Visually
(ix) Kindly note that there is a
Impaired candidates.
(*) Use of calculator is NOT allowed. necessary:
may use the following values of physical constants wherever
You
c=3x 10 m/s
h=6.63 × 10-34 Js
e=1.6 x 10-19 C
TmA-1
Ho = 4 X 10-7
(2 N-1m-2
Ep = 8.854 x 10r12
1
=9x 109 N m² C-2
4TE0
10-81 kg.
Mass of electron (m) =9.1 x
x 10-27 kg.
Mass of neutron = 1.675
10-27 kg.
Mass of proton=1.673 x
1028 per gram mole
Avogadro's number = 6.023 x
JK-1
Boltzmann's constant = 1.38 x 10-28
P.T.0.
3
56/2/3
 SECTION- A 16 x1= 16

Question No. 1 to 16 are Multiple Choice type questions carrying 1 mark each.
1. Which among the following is a false statement ?
(A) Rate of zero order reaction is independent of initial concentration of
reactant.

(B) Half-life of a zero order reaction is inversely proportional to the rate

Constant.

ey Molecularity of a reaction may be zero.

(D) For a first order reaction, ty2 =0.693/k.

2. The charge required for the reduction of 1 mol of MnO4 to Mn0, is

(A) 1F (B) 3F
(C) 5 F (D) 6F

3 The element having [Ar]3d104s' electronic configuration is

AY Cu (B) Zn
(C) Cr (D) Mn

4. The number of molecules that react with each other in an elementary

reaction is a measure of the :
(A) activation energy of the reaction (B) stoichiometry of the reaction
e molecularity of the reaction (D) order of the reaction

5. The diamagnetic species is :

(A [Ni(CN),) (B) [NiCL
(C) (Fe(CN)I (D) [CoFJ
28]
[At. No. Co = 27, Fe = 26, Ni=
(Co(NH),(ONO)2* are called
6 The complex ions [Co(NH), (NO,))* and
(A) Ionization isomers B Linkage isomers
(C) Co-ordination isomers (D) Geometrical isomers

P.T.0.
56/2/3
7. What will be formed after oxidation reaction of secondary alcohol with
chromic anhydride (Cr0,) ?
(A) Aldehyde LB Ketone
(C) Carboxylic acid (D) Ester

Which is the correct IUPACname for

CH,

Cl
(A) Methylchlorobenzene (B) Toluene
(C) 1-Chloro-4-Methylbenzene (D) 1-Methyl-4-Chlorobenzene

9. Which of the following is/are examples of denaturation of protein ?

(A) Coagulation of egg white (B) Curdling of milk
(C) Clotting of blood A D Both (A) and (B)

10. The conversion of phenol to salicylic acid can be accomplished by

(A) Reimer-Tiemann reaction (B) Friedel-Crafts reaction
o Kolbe reaction (D) Coupling reaction

11. Scurvy is caused due to deficiency of

(A) Vitamin Bl (B) Vitamin B2
I c Ascorbicacid (D) Glutamic acid

12. Nucleotides are joined together by

(A) Glycosidic linkage (B) Peptide linkage
(C) Hydrogen bonding LeY Phosphodiester linkage
56/2/3 7
P.T.0,
 For questions number 13 to 16, two statements are given - one labelled as
Assertion (A) and the other labelled as Reason R). Select the correct
answer to these questions from the codes (A), (B), (C) and (D) as given
below :

(A) Both Assertion (A) and Reason (R) are true and Reason (R) is
the
correct explanation of the Assertion (A).
(B) Both ASsertion (A) and Reason (R) are true, but Reason (R) is
not the
correct explanation of the Assertion (A).
(C) Assertion (A)is true, but Reason (R) is false.
(D) Assertion (A) is false, but Reason (R) is true.

13.Assertion (A) : Cu cannot liberate H, on reaction with dilute

mineral
acids.

Reason (R): Cu has positive electrode potential.

14.Assertion (A) : In a first order reaction, if the

concentration of the
reactant is doubled, its half-life is also doubled.
Reason (R):The half.-life of a reaction does not depend upon the initial
concentration of the reactant in a first order reaction.

15. ASsertion (A) : Vitamin D cannot be stored in our body.,

Reason (R) : Vitamin D is fat soluble vitamin and is not excreted from
the body in urine.

16. Assertion (A) :Aromatic primary amines cannot be prepared by Gabriel

Phthalimide synthesis.
Reason (R) : Aryl halides donot undergo nucleophilic substitution
reaction with the anion formed by phthalimide.
56/2/3
P.T.0.
 SECTION B
17. Name the following coordination compounds according to IUPAC norms: 2 x 1
(a) [Co(NH),(H,0)CIjC,
(6) [CrCl, (en),]Cl

18. What is meant by the Rate law and Rate constant of a reaction. Identify
the order of a reaction if the units of its Rate constant are : 2
(a) s
(b) mol-1 Ls-1

19. Complete and balance the following chemical equations : 2 x 1

(a) 8MnO + 38,032 + H,0’

b) Cr,0 + 3Sn2t + 14H+

20. (A) The rate constant for a zero order reaction A ’ P is 0.0030
molL-'s-l.
How long will it take for the initial concentration of A to fall from
0.10 M to 0.075 M?
2
OR
(B) The decomposition of NH, 0n platinum surface is zero order reaction.
What are the rates of production of N, and H, if k=2.5 x 10 mol L-l sl? 2

21. Give reasons for the following observations : 1+1

(a) p-Chloronitrobenzene reacts with (aq)NaOH at 443 K to give
p-nitrophenol whereas chlorobenzene reacts with the same reagent
at 623Kand 300 atm.
b) Main product obtained when chloroethane reacts with
KCN is
propane nitrile while with Ag CN it is ethyl isocyanide.
56/2/3 11
P.T.0.
 SECTION -C
22. Henry's law constant for C0,in water is 1.67 x108 Pa at 298 K. Calculate
the number of moles of CO, in 540 g of soda water when packed under
3.34 × 105 Pa at the same
temperature.
23. Give reasons : 3x 1= 3
(a) Fuel cells are preferred for production of electrical energy than
thermal plants.
(b) Iron does not rust even if zinc coating is broken in a galvanized pipe.
(c) In the experimental determination of electrolytic conductance, Direct
Current (DC) is not used.

24. (a) E
(Mn2+/Mn) is -1.18 V. Why is this value highly negative in
comparison to neighbouring d-block elements ? 3x 1=3
(b) What is lanthanoid contraction ?
(c) Zn, Cd and Hg are soft metals. Why ?

25. (a) Using valence bond theory, explain the hybridization and magnetic
behaviour of the following: 2+1= 3
1) (Co(NH)|C,
(ii) K,[NiCI]
[At. no. : Co = 27, Ni= 28]
(b) Write the electronic configuration of d ion when 4, >P.

26. (a) Define the following: 2+1=3

1) Enantiomers
(ii) Racemic mixture
b) Why is chlorobenzene resistant to nucleophilic substitution reaction ?
56/2/3 13 P.T.0.
27. (A) Explain the following reactions and write chemical equation involved :
3 x la3
(a) Wolff- Kishner reduction
(b) Etard reaction
(c) CannizZaro reaction
OR
(B) Write the structures of A, B andCin the following sequence of
reactions : 2 x 1%=3

(a) CH,COOH SOCl, H,N-NH,,,

A
H,, Pd-BaSO, ’ B

1.(DIBAL-H) Dil. NaOH

(b) CH,CN A B C
2. H,0

28. Define the following terms : 3

(a) Native protein
(b) Nucleotide
(c) Essential amino acid

SECTION-D
29. The spontaneous flow of the solvent through a semipermeable membrane
from a pure solvent to a solution or from a dilute solution to a
concentrated solution is called osmosis. The phenomenon of osmosis can
be demonstrated by taking two eggs of the same size. In an egg, the
membrane belowthe shell andaround the egg materialis semipermeable.
The outer hard shell can be removed by putting the egg in dilute
hydrochloric acid. After removing the hard shell, one egg is placed in
distilled water and the other in a saturated salt solution. After some time,
the egg placed in distilled water swells-up while the egg placed in salt
solution shrinks The external pressure applied to stop the osmosis is
termed as OBmotic pressure (a colligative property). Reverse osmosis takes
place when the applhed external pressure becomes larger than the osmotic
pressure.

56/2/3 15
P.T.0.
 (a) Define reverse osmosis. Name one SPM which can be used in the
process of reverse osmosis. 2

(b) ) What do you expect to happen when red blood corpuscles

(RBC's) are placed in 0.5% NaCl solution ? 1

OR

(6) (i) Which one of the following willhave higher osmotic pressure in
1 MKOl or 1 M urea solution. Justify your answer. 1

(c) Why osmotic pressure is a colligative property ? 1

30. Amines have a lone pair of electrons on nitrogen atom dåe to which they
behave as Lewis base. Greater the value of K, or smaller the value of pK,
stronger is the base. Amines are more basic than alcohols, ethers, esters,
etc. The basic character of aliphatic amines should increase with the
increase of alkyl substitution. But it does not occur in a regular manner as
a secondary aliphatic amine is unexpectedly more basic than a tertiary
amine in aqueous solutions. Aromatic amines are weaker bases than
ammonia and aliphatic amines. Electron releasing groups such as -CH,
-0CH, -NH, etc., increase the basicity while electron-withdrawing
substituents such as -NO, -CN, halogens etc., decrease the basicity of
amines. The effect of these substitute is more at p than at mposition.
(a) Arrange the following in the increasing order of their basic character.
Give reason : 2
NH, NH, NO2
224)

NO2 CH,
(b) Why pk, of aniline is more than that of methylamine ?
1

56/2/3 17
P.T.0.
 (c) (i) Arrange the following in the increasing order of their basic
character in an aqueous solution: 1

(CH),N, (CH),NH, NH, CH,NH,

OR
(c) (ii) Why ammonolysis of alkyl halides is not a good method to
prepare pure amines ? 1

SECTION - E
31. (A) (a) Calculate the standard Gibbs energy (A,G) of the following
reaction at 25°C: 3+2

Au(s) + Ca2t(1M) ’ Aus(1M) + Ca(s)

E
Au/Au =+ 1.5 V, E,2+/Ca -2.87 V
Predict whether the reaction will be spontaneous or not at 25 °C.
[1 F=96500 C mol-]
-(b) Tarnished silver contains Ag,S. Can this tarnish be removed by
placing tarnished silverware in an aluminium pan containing
an inert electrolytic solution such as NaCi ? The standard
electrode potentialfor half reaction:
Ag,S(s) + 2e- -’ 2Ag(s) + $2 is -0.71 V and for
Aj8+ + 3e’2Als) is -1.66 V
OR
31. (B) (a) Define the following: 2+3
(i) Cell potential
(iü) Fuel cell
(b) Caleulateemf of the following cell at 25 °C:
2+
Zn(s) |Zn
(0.1M) (o.01M) | Cd(s)
Given :
Eca2*/ca =-0.40 V
=-0.76 V
Zn2*1Zn
[log 10 = 1]

56/2/3 ~ 19 P.T.O.
32. (A) An organic compound 'A, molecular formula C,H,0 oxidises witn
CrO, to form a compound 'B. Compound B on warming with iodine
and aqueous solution of NaOH gives a yellow precipitate of
compound 'C. When compound 'A' is heated with conc. H,S0, at 413
K gives a compound D', which on reaction with excess HI gives
compound 'E. Identify compounds 'A', B, C, D' and E and write
chemical equations involved. 5

OR

32. (B) (a) Write chemical equations of the following reactions : 3+1+1=5

(i) Phenol is treated with conc. HNO,

Ai) Propene is treated with B,H, followed by oxidation by
H,0,0H.
(ii) Sodium t-butoxide is treated with CH,CI.
(b) Give a simple chemical test to distinguish between butan-1-ol
and butan-2-ol.
(c) Arrange the following in increasing order of acid strength :
phenol, ethanol, water

33. (A) (a) Give IUPAC name of CH, CH= CH- CH0. 1

(b) Give a simple chemical test to distinguish between propanal

and propanone. 1

(c) How willyou convert the following : 3

(i) Toluene to benzoic acid

(ii) Ethanol to propan-2ol

(ii) Propanal to 2-hydroxy propanoic acid
OR

56/2/3 ~ 21
P.T.0.
33. (B) Complete each synthesis by oiving missing
starting matera
reagent or products : 5 x1= 5

(a) + HO NH, H+

(b) ? ()O3
(ii) Zn - H,0

OH SOCl,
(c)

OH

CHO NaCNHCI
(d)
-COOH

CH3
(e)

5612/3 ~ 23