REVISION PRE-MEDICAL 2025

ASSIGNMENT LEADER COURSE

ASSIGNMENT#06 [COORDINATION, D & F BLOCK, SALT] INORGANIC CHEMISTRY

1. Reddish brown (chocolate) PPt. are formed with : 6. Amongst Ni(CO)4, [Ni(CN)4]2 – and NiCI42 – :
(1) Cu+2 and [Fe(CN)6] – 4 (1) Ni(CO)4 and NiCI42– are diamagnetic and
[Ni(CN)4]2– is paramagnetic
(2) Ba+2 and SO4 – 2
(2) NiCI42 – and [Ni(CN)4]2 – are diamagnetic
(3) Pb+2 and I – 1 and Ni(CO)4 is paramagnetic.
(4) None of these (3) Ni(CO)4 and [Ni(CN)4]2 – are diamagnetic
and NiCI42 – is paramagnetic
2. Ammonia forms the complex ion
(4) Ni(CO)4 is diamagnetic and NiCI42 – and
[(Cu(NH3)4]2+ with copper ions in alkaline
[Ni(CN)4]2 – are paramagnetic
solutions but not in acidic solution. What is the
reason for it: - 7. In the flame test of a mixture of salts, a green
flame with blue centre was observed. Which one
(1) In acidic solutions hydration protects of the following cations may be present?
copper ions (1) Cu2+ (2) Sr2+ (3) Ba2+ (4) Ca2+
(2) In acidic solutions protons coordinate with 8. Cu+ ion is not stable in aqueous solution because
ammonia molecules forming NH4+ ions and
(1) Second ionisation enthalpy of copper is less
NH3 molecules are not available
than the first ionisation enthalpy
(3) In alkaline solutions insoluble Cu(OH)2 is
precipitated which is soluble in excess of (2) Large value of second ionisation enthalpy
any alkali of copper is compensated by much more
negative hydration energy of Cu2+(aq)
(4) Copper hydroxide is an amphoteric substance
(3) Hydration energy of Cu+(aq) is much more
3. Group reagent for analytic group IV is negative than that of Cu2+(aq)
(1) NH4Cl + NaOH (4) Many copper (I) compounds are unstable in
(2) H2S is basic medium aqueous solution and undergo
(3) NH4OH + (NH4)2CO3 disproportionation reaction
(4) HCl + H2S 9. Assertion : Transition metals are good catalysts.
4. Which alum is a double salt made up of two salts : Reason : V2O5 or Pt is used in the preparation of
H2SO4 by contact process.
(1) Salt of a (SA + WB) + Salt of a (WA + WB)
(1) Assertion is correct, reason is correct;
(2) Salt of a (SA + SB) + Salt of a (SA + WB) reason is a correct explanation for assertion
(3) Salt of a (SA + SB) + Salt of a (WA + WB) (2) Assertion is correct, reason is correct;
(4) Salt of a (SA + WB) + Salt of a (WA + WB) reason is not a correct explanation for
5. Isomerism shown by complex
assertion
(3) Assertion is correct, reason is incorrect
[Co(NH3)5(ONO)]SO4 :-
(1) Ionisation isomerism (4) Assertion is incorrect, reason is correct
(2) Linkage isomerism 10. The hybridisation and unpaired electrons in
(3) Geometrical isomerism [Fe(H2O)6] 2+] ion are :
(4) Optical isomerism (1) sp3d2 ; 4 (2) d2sp3 ; 3
(1) 1, 2 (2) 2, 3 (3) 3, 4 (4) 1,4 (3) d2sp3 ; 4 (4) sp3 d2 ; 2

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11. The silver UK coins are alloy of 17. List I – (Cations) List – II(Group reagent)
(1) Cu/Fe (2) Cu/Ni
(3) Cu/Sn (4) Fe/Hg
12. Which is the strongest oxidising agent ?
(1) KMnO4 in acidic medium Code:
(2) Mn+2 in acidic medium
(3) K2Cr2O7 in acidic medium
(4) Cr+3 in acidic medium
13. 0
For which of the following element, EM 3+ /M 2+ is
(1) 1 (2) 2 (3) 3 (4) 4
positive ?
(1) Sc (2) Cr
18. Nitrate is confirmed by ring test. The brown
colour of the ring is due to formation of
(3) Ti (4) Co (1) ferrous nitrite
14. Which is incorrect for primary valency &
(2) nitroso ferrous sulphate
(3) ferrous nitrate
secondary valency, as mentioned infront of the
(4) FeSO4NO2
compound ?
(S = Secondary Valency, P = Primary Valency) 19. Select the correct statement among the
followings :-
(1) [Cr(NH3)6]Cl3, P = 3, S = 6 (a) KMnO4 does not acts as oxidising agent in
alkaline medium.
(2) K2[PtCl4], P = 2, S = 4 (b) Ferrous compounds are relatively more ionic
than the corresponding ferric compound.
(3) [Pt(NH3)2Cl2], P = 2, S = 4 (c) The degeneracy of d-orbitals is lost if a
(4) [Cu(NH3)4]SO4, P = 4, S = 4 spherically symmetrical field of negative charges
surrounds the metal atom/ion.
15. Two test tubes containing a nitrate and a (d) Red colour of ruby is due to incorporation of
octahedral chromium (III) complexes into the
bromide are treated separately with H2SO4 ; alumina lattice.
brown fumes evolved are passed in water. The (e) On substitution of water in [Ni(H2O)6]+2 by
ethylenediammine (en) then spin magnetic
water will be coloured by vapours evolved from moment is decreased.
the test tube containing :- (1) a, b, c only (2) b, d only
(1) Nitrate (2) Bromide (3) b, e only (4) a, b, e only
(3) Both (1) and (2) (4) None of these
20. Assertion :- The fluorine has ability to stabilise
the highest oxidation state as in the case of CoF3.
16. Which of the following statement is not correct Reason :- Due to higher lattice energy.
for Brown Ring complex ? (1) Both Assertion and Reason are true and the
Reason is a correct explanation of the Assertion.
(1) EAN of Fe = 37
(2) Both Assertion and Reason are true and but
(2) Hybridisation state of Fe = sp3d2 Reason is not a correct explanation of the
Assertion.
(3) Spin magnetic moment μ = 15 B. M.
√
(3) Assertion is true but Reason is false.
(4) Brown ring complex is highly stable. (4) Both Assertion and Reason are false.
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21. Which of the following order of given property 28. Which is correct :-
is correct :- Complex No. of Chilate rings
(1) V > Ti > Ni > Co : Enthalpy of atomisation (1) [Co(ox)2Cl2] – 3 4
(2) [Ni(dmg)2] 4
(2) Ti > V > Mn > Cr : Reducing character (3) [Ca(EDTA)] – 2 6
(4) Brown ring complex 1
EMo 2+/M )
29.
(
Colour of Nickel chloride solution is
(3) Sc < Ti < V < Zn < Cr : Density (1) Pink (2) Black
(4) Cr+3 > Ti+3 > V+3 > Fe+3 > Mn+3 : (3) Colourless (4) Green
Oxidising character
30. The oxidation no and coordination no. of Pt in
22. K2Cr2O7 on heating with aqueous NaOH gives [Pt(C2H4)Cl3] – :-
(1) CrO2− (2) Cr(OH)3 (1) +1, 3 (2) +2, 4 (3) +3, 6 (4) +2, 5
4

(3) Cr2 O2− (4) Cr(OH)2

31. Which of the following complex is not a chelate
7 complex ?
23. In dilute alkaline solution MnO−4 changes to- (1) bis(dimethylglyoximato)nickel(II)
(1) MnO2− (2) potassium
4
(2) MnO2 ethylenediaminetetrathiocyanatochromate (III)
(3) Mn2O3 (4) MnO (3) tetramminediazidocobalt(III) nitrate
24. Which one of the following is an amphoteric (4) trans-diglycinatoplatinum(II)
oxide? 32. Match List-I with List-II
(i) Mn2O7 (ii) CrO
List-I List-II
(iii) V2O4 (iv) Cr2O3 Species Electronic distribution
(1) (i) and (ii) (2) (ii), (iii) and (iv) (A) Cr+2 (I) 3d8
(3) (iii) and (iv) (4) (ii) and (iv)
(B) Mn+ (II) 3d34s1
25. Red azo compound is formed in which ion. (C) Ni+2 (III) 3d4
(1) SO4 – 2 (2) NO2 – (3) Br – (4) S – 2 (D) V+ (IV) 3d54s1
26. On shaking H2O2 with acidified potassium Choose the correct answer from the options given below :
dichromate and ether, ethereal layer becomes- (1) (A) – (I), (B)-(II), (C) – (III), (D) – (IV)
(1) Green (2) Red (2) (A) – (III), (B)-(IV), (C) – (I), (D) – (II)
(3) Blue (4) Black (3) (A) – (IV), (B)-(III), (C) – (I), (D) – (II)
27. Match the column- (4) (A) – (II), (B)-(I), (C) – (IV), (D) – (III)
Catalyst Process 33. List-I List-II
Vanadium (V) (Basic Radical) (Group)
(A) oxide (P) Haber’s process (P) Pb+2 (1) VI group
(Q) Fe+3 (2) IV group
(B) Finely divided (Q) Contact process (R) Ni+2 (3) I group
iron
(C) Nickel (R) Hydrogenation (S) Mg+2 (4) III group
Deacon’s Correct matching is :
(D) CuCl2 (S) process
PQRS
(1) A → Q; B → P; C → R; D → S (1) 1 3 2 4
A → P; B → Q; C → R; D → S
(2) 3 4 2 1
(2)
A → Q; B → R; C → P; D → S
(3) 4 3 2 1
(3)
(4) A → Q; B → P; C → S; D → R
(4) 3 4 1 2
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34. Which among the following match is correct :- 43. Gadolinium has a low value of third ionisation
(1) Trans[Pt(NH3)2Cl2] – Anti cancer enthalpy because of
(2) Carboxy peptidase enzyme – Complex of Mg (1) High electronegativity
(3) [Fe(H2O)5NO+]SO4 – Formed during (2) High basic character
testing of NO2 – ion (3) Small size
(4) Dimethylglyoxime – Used to detect Fe2+ ion (4) High exchange enthalpy
35. A salt which gives CO2 with hot H2SO4 and also 44. Interstitial compounds are formed when small
decolourizes acidified KMnO4 on warming is atoms are trapped inside the crystal lattice of
metals. Which of the following is not the
(1) HCO−3 (2) CO2−3 characteristic property of interstitial compounds ?
(3) Oxalate ion (4) Acetate ion (1) They have high melting points in
36. The number of isomers possible for square comparison to pure metals.
planer complex K2[PdCl Br2(SCN)] is :- (2) They are very hard.
(1) 2 (2) 3 (3) 4 (4) 6 (3) They retain metallic conductivity.
37. The confirmatory test for sulphat ions (SO2− )
(4) They do not retain metallic conductivity.
45.
4
involves which reagent? The colour of Ca in flame test is
(1) AgNO3(2) BaCl2 (3) NaOH (4) NH4Cl (1) Brick Red (2) Crimson Red
38. Which complex is most stable ? (3) Lilac (4) Apple Green
Where kd = Dissociation constant 46. Which one have maximum density ?
(1) [Cu(CN)2] – ; Kd = 1 × 10 – 16 (1) Sc (2) Ti (3) V (4) Cr
(2) [Fe(CN)6] – 4 ; Kd = 1 × 10 – 37 47. Consider the following Complex :
(3) [Fe(CN)6] – 3 ; Kd = 1 × 10 – 44 [CO(NH3)5CO3]ClO4
(4) [Ag(CN)2] – ; Kd = 1 × 10 – 20 The Coordination number, oxidation number, no:
39. Which one of the following transition metal ions
of d-electrons and number of unpaired d-
electrons on the metals are respectively.
shows magnetic moment of 5.92 BM? (1) 6, 2, 7, 3 (2) 7, 2, 7, 1
(1) Mn2+ (2) Ti3+ (3) Cr3+ (4) Cu2+ (3) 5, 3, 6, 4 (4) 6, 3, 6, 0
40. Which one is not an organometallic compound ? 48. Assertion (A) : Aqueous solution of Mohr's salt
exhibits the test for NH4+, Fe2+ and SO42 – ions.
(1) RMgX
(3) (CH3)4Sn
(2) (C2H5)4Pb
(4) C2H5ONa
Reason (R) : Mohr's salt is a double salt.
(1) Both A and R are true but R is NOT the
41. The catalytic activity of the transition metals correct explanation of A.
(2) A is true but R is false
and their compounds is described to:
(3) A is false but R is true
(1) their chemical reactivity.
(4) Both A and R are true and R is the correct
(2) their magnetic behaviour.
(3) their filled d-orbitals. explanation of A.
(4) their ability to adopt multiple oxidation
state and their complexing ability. 49. Which of the following isomerism is not shown
by complex [CoCl2(OH)2(NH3)2]Br ?
42. (1) Ionization (2) Linkage
(A) is. (3) Geometrical (4) Optical
50. Which one used in pigment industry
(1) Fe+2 (2) Zn+2 (3) Fe+3 (4) Ni+2 (1) MnO (2) TiO (3) Cr2O3 (4) ZnO
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