Sec: SR STAR & ALL SECTIONS JEE MAIN DATE: 23-01-2025

Time: 03:00 Hrs GRAND TEST Max Marks: 300

SR STAR (GTM-21) & MPC CAT B&C, XII CBSE (GTM-14)

IMPORTANT INSTRUCTIONS: -
JEE MAINS MODEL
MATHEMATICS:
+Ve - Ve No.of
Section Question Type Total marks
Marks Marks Q’S
Sec – I(Q.N : 1 – 20) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 21 – 25) 4 -1 5 20
(+/ - Decimal Numbers)
Total 25 100
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Mark Marks Q’S Marks
Sec – I(Q.N : 26 – 45) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type (+/
Sec – II(Q.N : 46 – 50) 4 -1 5 20
- Decimal Numbers)
Total 20 100
CHEMISTRY:
+Ve - Ve No.of
Section Question Type Total marks
Mark Marks Q’S
Sec – I(Q.N : 51 – 70) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type (+/
Sec – II(Q.N : 71 – 75) 4 -1 5 20
- Decimal Numbers)
Total 30 100

Syllabus:
MATHS : TOTAL SYLLABUS
PHYSICS : TOTAL SYLLABUS
CHEMISTRY : TOTAL SYLLABUS
 MATHS Max Marks: 100
SECTION – A (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. In a certain town 25% families own a cell phone, 15% families own a scooter and 65%
families own neither a cell phone nor a scooter. If 1500 families own both a cell phone
and a scooter, then the total number of families in the town is
A) 10000 B) 20000 C) 30000 D) 40000
2. If R  (x, y) : x, y  Z, x 2  3y 2  8 is a relation on the set of integers Z, then the
domain of R 1 is
A) {2, 1,1,2} B) {0,1} C) {2, 1,0,1,2} D) {1,0,1}
3. If cot   tan   m and sec   cos   n then which of the following is correct
A) m  mn 2   n  nm 2   1 B) m  m 2 n   n  mn 2   1
1/3 1/3 1/3 1/3

C) n  mn 2   m  nm 2   1 D) n  m 2 n   m  mn 2   1
1/3 1/3 1/3 1/3

If  sin 1 x    cos 1 x   a;0  x  1;a  0 , then the value of 2x 2  1 is

2 2
4.

 4a   2a   3a   4a 
A) cos   B) sin   C) sin   D) sin  
          
5. The last two digits of the number 3400 are
A) 81 B) 43 C) 29 D) 01
6. Let z  i 64C0  i 68C1  i 64C2   i64C64 , where i  1 be a complex number. Then
which of the following is correct
A) Re  (z  63) 2022   0 B) Im  (z  60) 2022   0

C) Re  (z  61) 2022   0 D) Im  (z  59) 2022   0

7. The number of positive integers satisfying the equation
x  log10  2 x  1  x log10 5  log10 6 is
A) 0 B) 1 C) 2 D) infinite
8. On a railway route there are 15 stations. The number of tickets required in order that it
may be possible to book a passenger from every station to every other is
A) 105 B) 210 C) 15 ! D) 15!/ 2 !
9. The mean and standard deviation of 50 observations are 15 and 2 respectively. It was
found that one incorrect observation was taken such that the sum of correct and

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 incorrect observations is 70 . If the correct mean is 16, then the correct variance is
equal to :
A) 10 B) 36 C) 43 D) 60
10. A student appeared in an examination consisting of 8 true-false type questions. The
students guesses the answers with equal probability. The smallest value of n, so that
1
the probability of guessing at least 'n' correct answers is less than is
2
A) 5 B) 6 C) 3 D) 4
11. A parabola is drawn with focus at (3, 4) and vertex at the focus of the parabola
y 2  12x  4y  4  0 . If the equation of parabola is x 2  ax  by  c  0 . Then
a  b  c is equal to
A) 8 B) 11 C) 14 D) 17
12. Let f be a real valued function defined as f :
R  R,f (x)  x 2  6x  8 sin((x  2) )  e x  1 sin x  x 2
The number of points of non-differentiability is
A) 4 B) 3 C) 2 D) 0
 3 1 
  1 1
13. If P   2 2 
,A  and Q  PAP T and X  PT Q 2019 P then X 
 1 3  0 1
 
 2 2 
1 2019  1 0  2019 1 1 1 
A)  B)  C)  D) 
0 1  
 2019 1   0 1 
 0 2019
dy
14. The solution of  x 2  y 2 x 2    y 2  x 2 y 2   0 is
dx
1 1 1 1
A) x  y c B) x  y c0
x y x y
1 1 1 1
C) x   y c D) x  y c0
x y x y
15. The set of all values of a for which lim([x  5]  [2x  2])  0 where [] denotes the
x a

greatest integer less than or equal to  is equal to

A) [7.5, 6.5] B) ( 7.5, 6.5] C) [ 7.5, 6.5) D) ( 7.5, 6.5)
dy
16. If (cos x) y  (sin y) x then 
dx
log(sin y)  y tan x log(sin y)  y tan x
A) B)
log(cos x)  x cot y log(cos x)  x cot y
SENIOR MPC ALL SECTIONS GTM Page 3
 log(sin y) log(cos x)
C) D)
log(cos x) log(sin y)
17. A ( 1,2, 3),B(5,0, 6),C(0,4, 1) are the vertices of a triangle. The DC's of the
internal bisector of  BAC are
 25 8 5   5 6 8 
A)  , ,  B)  , , 
 714 714 714   74 74 74 
 25 8 5   5 6 8 
C)  , ,  D)  , , 
 714 714 714   74 74 74 
1
18. The domain of f (x)   x 2  4 is
9x 2

A) ( 4, 2)  (2, 4) B) ( 3, 2]  [2,3)

C) ( , 3)  (2, ) D) (, )
19. The range of values of k , such that the point (0, k) lies on or inside the triangle
formed by the lines 3x  y  2  0, 2x  3y  5  0, x  4y  14  0 is
5 7 5 7 5 7
A) 5  k  7 B) k C) k D) k
3 3 3 2 2 3
20. If the lines x  2y  3  0,3x  ky  7  0 cut the coordinate axes in concyclic points,
then k 
A) 3 / 2 B) 1 / 2 C) 3 / 2 D) 4

SECTION-B (NUMERICAL VALUE ANSWER TYPE)

This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the decimals,
Round off the nearest Integer only
Marking scheme: (+4) for correct answer, (0) if not attempted and (-1) if not correct.

ˆi  2ˆj 2iˆ  ˆj  3kˆ

21. If a and b are vectors in space given by a  and b  then the value
5 14
     
of (2a  b)·[(a  b)  (a  2b)] is
| x  1|
22. The number of critical points of f (x)  is ____
x2
( x )5  xk 
23. If  dx  aln  k   C then the value of "2k" is
( x )7  x 6  x 1

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 sin 2 x
2
24. The value of  dx where [x] is the greatest integer function less than or
2  x  1
    2
equal to x, is ____
25. The Area bounded by y | sin x |, x -axis and the lines | x |  is

PHYSICS Max Marks: 100

SECTION – A (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
 
26. Find the resultant of the following two vectors A and BA : 40 Units due east and

B : 25 units 37o north of west
A) 25 Units 37 o north of west B) 25 units 37 o north of east
C) 40 Units 53o north of west D) 40 units 53o north of east
27. Two resistors R 1  (5  0.2)  and R 2  (10  0.1)  are connected in parallel. What is
% error in effective resistance?
A) 3% B) 5% C) 2% D) None
28. Match the following regarding translational motion of a particle:

List I List II
(A) Rate of change of displacement (P) Magnitude of average velocity
(B) Average speed is always greater (Q) Initial to final position
than or equal to
(C) The direction of displacement is (R) Velocity
(D) Motion under gravity is (S) Uniform acceleration
considered as the case of
A) (A) III, (B) I, (C) II, (D) IV B) (A) I, (B) II, (C) III, (D) IV
C) (A) III, (B) I, (C) IV, (D) II D) (A) I, (B) III, (C) II, (D) IV
29. If a particle is projected with speed u from the ground at an angle  with horizontal.
Radius of curvature of a point where velocity vector is perpendicular to initial velocity
vector is given by
u 2 cos 2  u 2 cot 2  u2 u 2 tan 2 
A) B) C) D)
g g sin  g g cos 

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 30. A bullet is fired normally on an immovable wooden plank. It loses 25% of its
momentum in penetrating a thickness of 3.5 cm . The total thickness penetrated by the
bullet is
A) 8 cm B) 10 cm C) 12 cm D) 14 cm
 
31. A force F  3iˆ  cjˆ  2kˆ acting on a particle causes a displacement d  4iˆ  2ˆj  3kˆ . If
the work done is 6 J then the value of 'c' is:
A) 12 B) 0 C) 6 D) 4
bx
32. A uniform thin rod AB of length L has linear mass density (x)  a  where x is
L
7
measured from A. If the CM of the rod lies at a distance of   L from A , then a and
 12 
b are related as :
A) a  2b B) 2a  b C) a  b D) 3a  2b
33. The angular momentum of a planet of mass M moving around the sun in an elliptical

orbit is L . The magnitude of the areal velocity of the planet is:
4L L 2L L
A) B) C) D)
M M M 2M
34. A man grows into a giant such that his linear dimension increases by a factor of 7.
Assuming that his density remains the same, the stress in the leg will change by a
factor of
A) 7 B) 9 C) 8 D) 6
35. Statement 1: When there is a thin layer of water between two glass plates there is a
strong attraction between them
Statement 2: The pressure between the plates become less than atmospheric pressure
as pressure difference is created due to surface tension.
A) Statement–1 is True, Statement–2 is True ; Statement–2 is a correct explanation for
Statement–1.
B) Statement–1 is True, Statement–2 is True ; Statement–2 is not a correct explanation
for Statement –1.
C) Statement -1 is True, Statement–2 is False
D) Statement–1 is False, Statement–2 is True
36. The isotherms of a fixed mass of an ideal gas at three temperatures TA ,TB and TC ,
then

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 A) TA  TB  TC B) TA  TB  TC C) TB  TA  TC D) TA  TB  TC
37. How much work is done per cycle by a gas following the path shown on the pV -
diagram?

A) 10 J B) 20 J C) 30 J D) 40 J
38. A mixture of two moles of hydrogen and one mole of argon gas is taken in a closed
container at room temperature. Consider the following two statements
Statement -(i): The average kinetic energy of each molecule of H 2 and Ar are the
same.
Statement -(ii): The partial pressure due to argon gas is more than that due to
hydrogen gas.
A) Both statement (i) and (ii) are correct
B) Statement (i) is correct while statement (ii) is incorrect
C) Both statement (i) and (ii) are incorrect
D) Statement (i) is incorrect while statement (ii) is correct

39. The function of time representing a simple harmonic motion with a period of is

 
A) sin(t)  cos(t) B) 3cos   2t 
4 
C) sin 2 (t) D) cos(t)  cos(2t)  cos(3t)
40. A particle B executing S.H.M given by equation y  8sin 6t is sending out waves in a
continuous medium travelling at 200 cm / s . The resultant displacement of the particle
150 cm from B and one second after the commencement of vibration of B is
A) 4 cm B) 8 cm C) -8 cm D) -3 cm

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 41. Two balls of same mass and carrying equal charge are hung by threads of length 1
from a fixed support. At electrostatic equilibrium, assuming that angles made by each
thread is small, the separation, x between the balls is proportional to :
A)  B)  2 C)  2/3 D) 1/3
42. A cube made of an insulating material has uniform charge distribution throughout its
volume. Assuming electric potential due to its charge at infinitely distance place to be
zero, potential at the center is found V0 . What is the electric potential at one of its
corners?
V0 V0 V0
A) V0 B) C) D)
2 4 8
43. Two cylindrical conductors with equal cross sections and different resistivity 1 and
 2 are put end to end. Find the charge at the boundary of the conductors if a current I
flows from 1 to 2 .
10 10
A) B) C)  1  2  /  0 D)  2  1  / 0
2  1 1   2
44. STATEMENT-1: It is not possible for a charged particle to move in a circular path
around a long straight conductor carrying current.
STATEMENT-2: The electromagnetic force on a moving particle is normal to its
plane of rotation.
A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
B) Statement-1 is True, Statement-2 is True; Statement-2 is not a correct explanation
for Statement-1
C) Statement-1 is True, Statement-2 is False
D) Statement-1 is False, Statement-2 is True
45. What will be magnitude of net magnetic field as shown in figure at point P. (Magnetic
4M  M 
moment of small magnets are M and respectively) Given that  0 3  B0 
3 3  4 R 

A) B0 B) 5 B0 C) 3 B0 D) None of these

SENIOR MPC ALL SECTIONS GTM Page 8

 SECTION-B (NUMERICAL VALUE ANSWER TYPE)
This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the decimals,
Round off the nearest Integer only
Marking scheme: (+4) for correct answer, (0) if not attempted and (-1) if not correct.

46. In a coil of resistance 16 , the magnetic flux due to an external magnetic field varies
2
with time as  
3
 9  t 2  . The value of total heat produced in the coil, till the flux

becomes zero, will be ____ J.

47. In an Oscillating LC circuit the maximum charge on the capacitor is 'Q'. The charge on
the capacitor when the energy is stored equally between the electric and magnetic field
Q
is . The value of 'N' is
N
48. In a medium the speed of light wave decreases to 0.2 times to its speed in free space.
The ratio of relative permittivity to the refractive index of the medium is x :1 . The
value of x is ____
(Given speed of light in free space  3 108 ms1 and for the given medium  r  1 )
49. Two plane mirrors A and B are aligned parallel to each other, as shown in the figure.
A light ray is incident at an angle 30o at a point just inside one end of A. The plane of
incidence coincides with the plane of the figure. The maximum number of times the
ray undergoes reflections (including the first one) before it emerges out is

50. A thin glass plate receives light from one side. Each surface of the glass plate reflects
20 percent of light incident on it and rest is refracted. The ratio of the maximum and
minimum intensities in the reflected light due to interference between the first two
x
order reflected beam is x, and in transmitted light the same ratio is y, then if is 6n .
y
Find n

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 CHEMISTRY Max Marks: 100
SECTION – A (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

51. A sample of CaCO 3 and MgCO 3 Weighing 2.21 g is ignited to a constant weight of
1.152 g. The composition of the mixture is :
(Given molar mass in gmol1CaCO3 :100,MgCO3 :84 )
A) 1.187g CaCO 3  1.023g MgCO 3 B) 1.023g CaCO 3  1.023g MgCO3
C) 1.187g CaCO 3  1.187g MgCO 3 D) 1.023g CaCO 3  1.187g MgCO 3
52. An element has successive ionization energies as 940, 2080, 3090, 4140, 7030, 7870,
16000 and 19500KJ Mol1
To which group of periodic table does this element belong?
A) 16 B) 15 C) 14 D) 17
53. Match the following

A) A – P, B – T, C – S, D – Q B) A – P, B – S, C – T, D – Q
C) A – P, B – Q, C – T, D – R D) A – P, B – T, C – S, D– T
54. For a given reaction, H  35.5 kJ mol1 and S  83.6 JK 1 mol1 . The reaction is
spontaneous at (Assume that H and S do not vary with temperature.)
A) T  425 K B) all temperatures
C) T  298 K D) T  425 K
55. Consider the reaction,
CO( g)  3H 2 ( g)  CH 4 ( g)  H 2O( g)
4 moles of gaseous reactants, taken in a ratio to get maximum yield, are allowed to
reach equilibrium (state I) in a cylinder fitted with a piston at constant temperature. It
is compressed to reduce the volume to one half of the volume in state-I. Then new
equilibrium (state-II) is reached. Then
A) State-II can be arrived at different pressures
B) Partial pressure of methane and water increases whereas partial pressures of carbon
monoxide and hydrogen decreases from state-I to state-II
SENIOR MPC ALL SECTIONS GTM Page 10
 C) Transformation from State-I to state-II, generates entropy
D) All are correct
56. 4 mole of NH 4OH and 2 mole of HCl are mixed and diluted to 1 litre solution. P K b
of NH 4 OH the is 4.8. The pH of solution is
A) 4.8 B) 9.2 C) 9.5 D) 10
57. Chlorine undergoes disproportionation in alkaline medium as shown below :
aCl2 ( g)  bOH  (aq)  cClO  (aq)  dCl  (aq)  H 2O(I)
The values of a,b,c and d in a balanced redox reaction are respectively :
A) 1, 2, 1 and 1 B) 2, 2, 1 and 3 C) 3, 4, 4 and 2 D) 2, 4, 1 and 3
58. Statement I : In 'Lassaigne's Test, when both nitrogen and sulphur are present in an
organic compound, sodium thiocyanate is formed.
Statement II : If both nitrogen and sulphur are present in an organic compound, then
the excess of sodium used in sodium fusion will decompose the sodium thiocyanate
formed to give NaCN and Na2S.
Choose the most appropriate answer from the options given below:
A) Both Statement I and Statement II are correct
B) Both Statement I and Statement II are incorrect
C) Statement I is correct but Statement II is incorrect.
D) Statement I is incorrect but Statement II is correct.
59. Addition of HOCl to ethyne gives:
A) ethyl chloride B) vinyl chloride
C) dichloroacetaldehyde D) ethylidene chloride
60. Silicones repel water due to
A) The presence of alkyl group pointed towards surface
B) strong Si – O – Si bonds
C) Low surface area
D) High Vander Waals’ forces
61. The correct geometry and hybridization for XeF4 are
A) octahedral, sp3 d 2 B) trigonal bipyramidal, sp3 d
C) planar triangle, sp3 d3 D) square planar, sp3 d 2
62. Which of the following is not a concentration cell
A) Pt H 2 (patm) H   C1  H   C2  H 2 (patm) Pt

B) Pt H 2  p1 atm  H   C1  H 2  p 2 atm  Pt

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 C) Cu Cu 2  C1  Cu 2  C 2  ,Cu   C3  Pt

D) Zn Zn 2  C1  Zn 2  C 2  Zn
63. Which of the following statements is incorrect about the collison theory of chemical
reaction.
A) It considers reacting molecules or atoms to be hard spheres and ignores their
structural features.
B) Number of effective collisions determines the rate of reaction.
C) Collision of atoms or molecules possessing only proper orientation results into the
product formation.
D) Molecules should collide with sufficient threshold energy and proper orientation
for the collision to be effective.
64. Which of the following pairs of ions will have same spin only magnetic moment
values within the pair?
(A) Zn 2 ,Ti 2 (B) Cr 2 ,Fe 2 (C) Ti3 ,Cu 2 (D) V 2 ,Cu 
Choose the correct answer from the options given below:
A) C and D only B) A and D only C) A and B only D) B and C only
65. According to Einstein's photoelectric equation, the graph between kinetic energy of
photoelectrons ejected and the frequency of the incident radiation is:

A) B)

C) D)
66. Match the following

A) A→p,s ; B→q,r, C→p,s; D→p,r B) A→s; B→p, C→r, D→q

C) A→p,q; B→p,s, C→p; D→r D) A→q,; B→p, C→q, D→r

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 O
||
67. End product of this conversion CH 3  C CH 2  CH 2  CH 2  CO 2 H 
1.NaBH 4
2.H O,H 

2

A) B) C) D)
68. Aniline with bromine water at 0-5° C gives a white precipitate of

A) B) C) D)
69. Which of the following is a steroid hormone?
A) Cholesterol B) Adrenaline C) Thyroxine D) Progesterone
70. Sodium carbonate cannot be used in place of  NH 4 2 CO3 for identification of
Ca 2 ,Ba 2 and Sr 2 ions(in group v) during mixture analysis because
A) Mg 2 ions will also be precipitated
B) Concentration of CO32 ions is very low.
C) Sodium ions will react with acid radicals.
D) Na  ion will interfere with the detection of Ca 2 ,Ba 2 ,Sr 2 ions

SECTION-B (NUMERICAL VALUE ANSWER TYPE)

This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the decimals,
Round off the nearest Integer only
Marking scheme: (+4) for correct answer, (0) if not attempted and (-1) if not correct.

71. When the excited electron of H atom from n  5 drops to the ground state the
maximum number emission lines observed are
72. How many of the following show positive deviation.
CS2  CH 3  CO  CH 3 ;C 6 H 6  C 6 H 5CH 3 ;
CH 3  CO  CH 3  CHCl3;C 2 H 5OH  H 2O;
C 2 H 5 Br  C 2 H 5Cl;C6OH 5  C6 H 5 NH 2 ;
C 2 H 5OH  CH 3  CO  CH 3

73. On adding AgNO3 solution to a solution of  Pt  NH 3 3 Cl  Cl , the percentage of total

chloride ion precipitated is

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 74. Which of the following compound will react with NaHCO 3 or soluble in NaHCO 3 ?

(a) (b) (c) (d)

(e) CH 3  C  CH
75. How many of the following are more reactive than acetaldehyde towards nucleophilic
addition
FCH 2 CHO, NO 2  CH 2CHO,CH 3  CH 2  CHO,CH 3COCH 3 ,PhCHO3 ,PhCOCH 3
________

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 SR STAR (GTM-21) & MPC CAT B&C, XII CBSE (GTM-14)
KEY SHEET
DATE: 23-01-2025

MATHS KEY:

1) C 2) D 3) A 4) B 5) D 6) C 7) B 8) B 9) C 10) A

11) B 12) D 13) A 14) A 15) D 16) A 17) C 18) B 19) C 20) C

21) 5 22) 2 23) 5 24) 0 25) 4

PHYSICS KEY:

26) B 27) A 28) A 29) B 30) A 31) C 32) B 33) D 34) A 35) A

36) B 37) D 38) C 39) B 40) C 41) D 42) B 43) D 44) C 45) C

46) 1 47) 2 48) 5 49) 30 50) 6

CHEMISTRY KEY:

51) A 52) A 53) A 54) A 55) C 56) B 57) A 58) A 59) C 60) A

61) A 62) C 63) C 64) D 65) C 66) A 67) A 68) D 69) D 70) A

71) 10 72) 3 73) 25 74) 2 75) 2

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 MATHS SOLUTIONS

1.

2.

3.

4.

5.

6.

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 7.

8.

9.

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 10.

11.

12.

13. Conceptual

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 14.

15.

16.

17.

18.

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 19.

20.

21.

22.

23.

24.

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 25.

PHYSICS SOLUTIONS

26.

27.

28. Conceptual

29.

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 30.

31.

32.

33.

34.

35. Conceptual

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 36.

37.

38.

39.

40.

41.

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 42.

43.

44.

45.

46.

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 47.

48.

49.

50.

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 CHEMISTRY SOLUTIONS

51.

52. Conceptual

53.

54.

55.

56.

57.

58.

59.

60.

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 61.

62.

63. Rate depends upon molecules having threshold energy and also proper orientation.
Ions having same number of unpaired electrons will have same spin only magnetic moment.

64.

65.
66. Conceptual

67.

68. 2,4,6 tri bromo aniline

69. Progesterone is a steroid harmone which controls the development and maintainance of pregnancy.

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 Thyroxine and Adrenaline are Amine harmones.

70.

71.

72. Conceptual

73. Conceptual

74.

75. Conceptual

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