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STPM 2013 Sem 3u Real Ans

The document outlines a marking scheme for the STPM Sem 3 2013 Chemistry exam, detailing the evaluation criteria for various sections including chemical reactions, reagents, observations, and equations. It includes specific examples of compounds and reactions, as well as comparisons between different chemical processes. Additionally, it provides information on polymers and their properties and uses.

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FARAH BINTI JAAFAR Moe
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1K views1 page

STPM 2013 Sem 3u Real Ans

The document outlines a marking scheme for the STPM Sem 3 2013 Chemistry exam, detailing the evaluation criteria for various sections including chemical reactions, reagents, observations, and equations. It includes specific examples of compounds and reactions, as well as comparisons between different chemical processes. Additionally, it provides information on polymers and their properties and uses.

Uploaded by

FARAH BINTI JAAFAR Moe
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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REAL MARKING SCHEME

STPM SEM 3 2013 962 / U 3 (CHEMISTRY)


Section B and C
16 a) i. Any 2 structures = [2] 19. (a) A : CH3CH=CH2 in H3PO4 / (CH3)2CHX in AlX3 or FeX3
B : Br2 ; UV / hv / sunlight C : ethanolic KCN or CN-
D :LiAlH4 / H3O+ H2 in Ni/Pt/Pd E : conc. HNO3 in conc. H2SO4
F : same as A G : HCl in Sn
ii. KMnO4 / H+ ; Bromine water / Br2 in CCl4 / Br2 in CH2Cl2 [1] b) (reagent [1] ; observation ( + and - ) [1] ; equation [1]
b) i. CH3CH2Cl / AlCl3 or CH3CH2Br / AlBr3 or AlX3 / FeX3. [1] Set 1 : use Br2 (aq)
ii. CH3CH2Cl + AlCl3 → CH3CH2+ + AlCl4- [1] Brown colour decolourised by (G) while (D) will not

iii. [2]
17. a) i. Reagent [1] Observation [1]
Set 1 : Br2 Brown colour decolourised and formed white
water precipitate by 4-methylphenol but not for c) (G) : 3-isopropylaniline / 3-(1-methylethyl)aniline /
4-methylbenzoic acid (or no changes) 3-(1-methylethyl)phenylamine (or use position m)
Set 2 :FeCl3 4-methylphenol give purple colouration 4- (D) : 2-methyl-2-phenylpropylamine.
(aq) methylbenzoic acid give orange-brown ppt (or
d) Must use correct set of answer
said does not form purple colouration)
r : no observable changes (D) is more basic than (G) [1]
- present of CH3 increase basicity [1] due to inductive effect [1]
ii. Reagent [1] Observation [1] (G) is less basic than (D)
Set 1 : KMnO4 Purple colour of KMnO4 decolourised by - delocalisation of e- [1] between -NH2 and aromatic ring [1]
/ H+ methanoic acid
Set 2 :Tollen's Silver mirror will formed by methanoic acid but 20. a) i. catalyst made by mixing titanium tetrachloride, TiCl4 with
reagent (or ethanoic acid will not trialkyl aluminium. [1]
formula) ii. - higher density / enhance strength / resistant to heat / tough [2]
- carpet fibres / upholstery / thermal pants and shirts / car battery
container / waste basket / cooler container [1]

iii. repeating unit :


b) i. - polymer : nylon 6,6 [1] (rej : nylon - 6,6)
- hexane-1,6-dioic acid (accept w/o -1,6-) [1] -
18. a) each isomer = 1 m [4] - hexane-1,6-diamine [1]
ii. each step = 1 mark

b) Compare and contrast


SN1 SN2
2-chloro-2-methylpropane [1] 1-chlorobutane [1]
1-chloro-2-methylpropane [1]

c) - Properties : strong / durable / high tensile strength / tough [1]


- Uses : fishing line / tow ropes / stocking / string for rackets or musical
instrument / house or industrial brushes [1]
c) insist : m3 : dotted line with square bracket.

Section A 1 D 2 C 3 A 4 D 5 C 6 B 7 B
8 C 9 D 10 B 11 D 12 B 13 B 14 A 15 D

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