Product information

ANCAREZ AR555
Waterborne Epoxy Resin

DESCRIPTION

Ancarez AR555 resin is a waterborne solid epoxy resin dispersion delivered at 55% solids in water. It is
designed for use in two-component, ambient-cure epoxy systems. Ancarez AR555 resin delivers superior
performance at lower cost when compared to conventional solid resin dispersions. The unique nature of
Ancarez AR555 resin allows film formation without high levels of coalescing solvent, which enables the
formulation of low-odor, zero-VOC systems.

TYPICAL PROPERTIES

Property Value Unit Method

Appearance Milky white liquid
Appearance Film Clear, glossy
Solids Content 55 wt%
Solvent Water (contains no organic solvents)
Viscosity @ 25°C 200 cPs Brookfield viscosity, Spindle #3, 12 rpm
Flash Point > 249 °C Seta flash, closed cup
Specific Gravity @ 25°C 1.08 Specific Gravity, weight per gallon, and EEW reported on
Weight per Gallon 9.1 as delivered basis
Equivalent Wt/{Epoxy} 550 g/eq
Equivalent Wt/{Epoxy} 1300 g/eq *

* Recommended value for use level calculations. In waterborne systems based on solid epoxy resin dispersions, a 60-90% excess
epoxy is recommended for maximum corrosion resistance. When EEW of Ancarez AR555 is assumed 1300, the best overall results
are obtained in the range of 0.8:1 to 1.2:1 (epoxy:amine) stoichiometry.

ADVANTAGES

• Zero VOC capability

• Fast dry speed: < 30 minutes
• Excellent universal colorant acceptance
• Early water resistance: 2 hours
• Long pot life: > 3 hours
• High gloss
• Zero induction time
• Low resin viscosity
• Low odor
• Lower cost-in-use
• High Corrosion Resistance

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 APPLICATIONS

• OEM, industrial maintenance, and transportation coatings

• Anticorrosive primers, mid-coats and topcoats
• Institutional coatings

SHELF LIFE

At least 18 months from the date of manufacture in the original sealed container below 45°C. Store in tightly
closed containers away from excessive heat. Do not freeze.

STORAGE AND HANDLING

Refer to the Safety Data Sheet for Ancarez AR555 Resin.

TYPICAL COATING HANDLING PROPERTIES **

Property Value Unit Method

Pot Life 3+ h
Volume Solids 42 %
Weight Solids 57 %
Formulation Viscosity at 25°C 1100 cPs Brookfield viscosity, Spindle #3, 12 rpm
Clean-Up Warm, Soapy Water

TYPICAL PERFORMANCE **

Property (14-day cure @ 25°C) Value Unit Method

60° Gloss 90
Pencil Hardness 2H
¼ inch Mandrel Bend 180 °
Direct Impact 40 in-lb
Reverse Impact 4 in-lb

** Ancarez AR555 resin formulated with Anquamine 401 curing agent in a high gloss enamel formulation

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 SUPPLEMENTARY DATA

RESIN CHARACTERISTICS
Ancarez AR555 resin is a unique solid epoxy Dispersion stabilized in water with a nonionic surfactant. It is
zero-VOC as supplied, and can be formulated to produce high-performance, zero-VOC, low-odor,
two-component epoxy topcoats and ultra-low-VOC two-component epoxy primers for metal and concrete.
These coatings exhibit excellent corrosion, weathering and chemical resistance.

Because of its unique nature, Ancarez AR555 resin allows the formulation of waterborne epoxy
maintenance primers and topcoats that have the rapid dry characteristics and long pot life of conventional
solid waterborne epoxy resin emulsions, without the need for high levels of coalescing solvent typical of
these systems. Ancarez AR555 resin formulations accept universal tints readily, providing for easy
incorporation of waterbased epoxy coatings into existing product lines.

Evonik offers three waterborne hardeners currently for use in systems based on Ancarez AR555 resin.
Those hardeners should be used as follows:

Hardener Recommended Applications

®
Anquamine 419 curing agent Low odor/ Ultra-low VOC metal primers
Anquamine® 401 curing agent Zero-VOC/ Low-odor concrete primers and pigmented metal and concrete topcoats
®
Anquamine 100 curing agent Wall and floor coatings and institutional coatings

FORMULATING GUIDELINES

CURING AGENT SELECTION

Anquamine 401 curing agent is recommended where zero-VOC, high-gloss and gloss retention are
required. Anquamine 401 curing agent can be thinned with water to retain zero VOC in the finished
formulation.

Anquamine 419 curing agent is recommended for Optimum humidity and corrosion resistance. Anquamine
419 curing Agent can be thinned with a mixture of water and propyleneglycol monomethyl ether.

Anquamine 100 curing agent is recommended when low color, stain resistant (good acid and food stain
resistance) are required. It provides long pot life, and offers high yellowing resistance.

Both Anquamine 401 and 419 curing agents can be modified with acetic acid to improve water solubility
and to extend pot life. Typical use levels are 0.5-2.0% glacial acetic acid based on curing agent weight.
Acetic acid levels should be kept to a minimum to avoid negative impact on water resistance.

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 STORAGE AND STABILITY
Ancarez AR555 resin should be stored between 35 and 105°F (2 and 41°C) for best package stability.
Freeze-thaw stability can be enhanced through the addition of glycol ether solvents such as
propyleneglycol monomethyl ether or ethyleneglycol monopropyl ether.

STOICHIOMETRY
Best overall results have been obtained in the range of 0.8:1 to 1.2:1 (epoxy:amine). The best corrosion
resistance has been observed at 1:1 stoichiometry or with a slight excess of curing agent.

PIGMENTS/PIGMENT DISPERSION
Ancarez AR555 resin can be readily pigmented through the use of pigment dispersants. Best results have
been obtained by preparing a resin-free grind in water utilizing Disperbyk 190 (2.5-3.5% based on pigment
weight) and Surfynol® 420 surfactants (0.1-0.2% based on pigment weight). Ancarez AR555 resin is then
added during the let down.

When formulating gloss white enamels, good results have been obtained using a variety of titanium
dioxides including: Ti-Pure R-706, Tioxide TR-92, Tronox CR-826, Tronox CR-828, Kronos 2102, Kronos
2310 and Tiona RCL-535. Tronox CR-826 in particular, exhibits good yellowing resistance. Ti-Pure R-960
should be avoided due to reduced gloss in enamels made with this product. Typical PVCs are 15-20%.
Gloss can be reduced through the addition of 0.25-0.75 pounds per gallon of low oil absorption talc such
as Mineral Technology’s P 40-27 or LVT 400.

When formulating primers, PVC should be targeted at and no higher than 32% for optimum corrosion and
humidity resistance. Extender pigments such as barytes, talc, Wollastonite and ceramic microspheres
should be selected for low oil absorption and good packing characteristics. Calcium Carbonate and zinc
oxide should be avoided due to possible interactions with the curing agent. Anticorrosive pigments such
as Halox SW 111 or SZP 391 have been effective at boosting corrosion resistance. Typical use levels are
0.5-1.0 lb/gal.

TINTING
Tinted coatings exhibit excellent compatibility and color stability throughout the pot life. Colorant
dispersions can be added to the curing agent or the epoxy side, or to the mixed paint without exhibiting
pigment flooding, floating or color drift during pot life. Systems found to be effective include: Creanova M
888, M 803, COVON and Elementis WD, UL colorants.

RHEOLOGY MODIFIERS
Rheology modifiers should be pre-diluted in water prior to addition to Ancarez AR555 resin. Diluted
rheology modifiers should be added slowly with good mixing to avoid agglomeration.

Associative thickeners such as Rheolate 310, Drewthix 6050 and Acrysol RM 8W are effective at
increasing sag resistance and storage stability while maintaining good flow and leveling. Associative
thickeners can be added to either the epoxy or the curing agent side of the formulation. When adding to
Ancarez AR555 resin, the thickener should be pre-diluted in water and added slowly with good mixing.
Typical use levels are 0.5- 1.5% based on total formulation weight.

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 FOAM CONTROL
Surfynol DF 75, an organic based, 100% active silicone free defoamer, has proven effective as both a
grind defoamer and an application defoamer. It should be incorporated into the formulation with high
shear. A typical use level is 0.25-0.5% based on total formulation weight. Surface cratering associated
with Surfynol DF 75 defoamer can be avoided through the addition of Surfynol 420 surfactant at 0.1-0.2%
based on total formulation weight.

FLASH RUST PREVENTION

Flash rusting may occur under conditions of high humidity. Flash rust can be eliminated by the addition of
a 10% aqueous solution of sodium nitrite (NaNO2), or equivalent, to the Part B (curing agent) side in the
amount of 2 pounds of solution per 100 gallons of paint.

MIXING AND APPLICATION

Thoroughly mix the A and B side components for 1-2 minutes until a uniform consistency is achieved. For
high-gloss finishes, no induction time is needed. However, for maximum humidity and corrosion
resistance, allow the mixed paint to induct for 15-30 minutes.

For conventional spray, the mixed paint can be reduced to application viscosity with water.
- A maximum wet film thickness of 8 mils is recommended to allow for water evaporation from the paint
film.
- Good air flow across freshly painted areas will assist in water evaporation and improve dry speed.

Typical pot life is 3-6 hours. In gloss enamels, end of pot life is signaled by a visible loss of gloss in the
dried film. Paint remains fluid beyond the pot life but loses coalescence and should be discarded. Do not
mix expired paint with fresh paint.

To help avoid shocking the system, formulated A and B components should be free flowing liquids of
similar viscosity.

CLEAN UP
Application tools can be cleaned with warm soap and water.

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 STARTING POINT FORMULATIONS

ANCAREZ AR555 EPOXY RESIN/ ANQUAMINE 419 CURING AGENT —

TABLE 4: STARTING POINT FORMULATION 4:1 ANTICORROSIVE METAL PRIMER

Nb. Part A Pounds Gallons

1. Water 123.56 14.80
2. Disperbyk 190 13.51 1.48
3. Surfynol DF75 Defoamer 4.13 0.52
4. Surfynol 420 4.99 0.64
Mix at slow speed, then add:
5. Red Iron Oxide 72.40 1.68
6. Zeeospheres G400 62.74 3.42
7. Sparwite Barytes 62.74 1.71
8. Wollastocoat 10ES 62.74 2.59
9. Halox SW111 96.53 4.00
10. Mica White 325 9.65 0.41
High speed disperse to Hegman 6+ Reduce speed then add:
11. Ancarez AR555 Epoxy Resin 415.08 45.62
12. Rheolate 310 (15% in water) 32.18 3.82
955.0 80.0
Nb. Part B
1. Anquamine 419 Curing Agent 113.43 12.52
2. Propylene glycol methyl ether 32.82 3.75
3. De-ionized Water 31.08 3.72
177.33 20.0

TABLE 5: FORMULATION ATTRIBUTES

Property Value Unit

Weight Solids 60.53 %
Volume Solids 46.74 %
PVC 30 %
VOC 137 g/l
Resin Stoichiometry 0.8 : 1 (Epoxy : Amine)
Part A Viscosity 63 KU
Part B Viscosity 80 KU
Mix Viscosity 65 KU
Pot life >6 h

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 ANCAREZ AR555 EPOXY RESIN/ ANQUAMINE 401 CURING AGENT —
TABLE 6: STARTING POINT FORMULATION ULTRA-LOW-VOC 4:1 CLEAR CONCRETE PRIMER

Part A Pounds Gallons

Ancarez AR555 Epoxy Resin 655.76 72.06
Add at slow speed a premix of:
Rheolate 310 15.48 1.75
De-ionized Water 51.53 6.19
722.8 80.0
Part B
Anquamine 401 Curing Agent 108.54 11.91
De-ionized Water 58.99 7.08
Surfynol DF-75 Defoamer 3.87 0.49
Surfynol 420 3.11 0.40
Glacial Acetic Acid 1.00 0.11
Mix at medium speed:
175.5 20.0

TABLE 7: FORMULATION ATTRIBUTES

Property Value Unit

VOC Trace g/l
Mix Viscosity 850 cP
Weight Solids 50.3 %
Volume Solids 41.8 %
Resin Stoichiometry 0.90 : 1 (Epoxy : Amine)
Part A Viscosity 63 KU
Part B Viscosity 60 KU
Mix Viscosity 77 KU
Pot life >3 h

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 ANCAREZ AR555 EPOXY RESIN/ ANQUAMINE 401 CURING AGENT —
TABLE 8: STARTING POINT FORMULATION ULTRA-LOW-VOC 2:1 HIGH-GLOSS ENAMEL

Part A Pounds Gallons

Ancarez AR555 Epoxy Resin 546.50 60.05
Add at slow speed a premix of:
Rheolate 310 12.90 1.46
De-ionized Water 42.94 5.15
602.3 66.7
Part B
De-ionized Water 62.15 7.46
Surfynol DF-75 Defoamer 4.01 0.51
Anquamine 401 Curing Agent 64.29 7.06
Glacial Acetic Acid 0.86 0.10
Mix until curing agent is incorporated, then add:
TiPure R-706 Titanium Dioxide 230.03 6.90
Grind to Hegman 7+, then add:
De-ionized Water 47.43 5.70
Anquamine 401 Curing Agent 26.35 2.89
Surfynol 420 2.75 0.35
Mix for 15 min. at slow speed, then add at slow speed a premix of:
De-ionized Water 15.35 1.84
Rheolate 310 4.61 0.52
457.8 33.3

TABLE 9: FORMULATION ATTRIBUTES

Property Value Unit

VOC Trace g/l
Mix Viscosity 1100 cP
Weight Solids 57.2 %
Volume Solids 41.9 %
PVC 16.5 %
Resin Stoichiometry 0.93 : 1 (Epoxy : Amine)
Part A Viscosity 64 KU
Part B Viscosity 81 KU
Mix Viscosity 83 KU
Pot life >3 h
60° Gloss 101.8

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 ANCAREZ AR555 EPOXY RESIN/ ANQUAMINE 100 CURATIVE —
TABLE 10: CLEAR COAT FORMULATION

Part A Pounds Gallons

Ancarez AR555 Epoxy Resin 606.57 66.67
Part B
Anquamine 100 curative 265.37 30.28
De-ionized Water 23.05 2.76
Surfynol DF 110D 2.43 0.29
Total B 290.85 33.33
Total A + B 897.42 100.0

TABLE 11: FORMULATION ATTRIBUTES

Property Value Unit

Pencil Hardness H
60° Gloss 90
Impact
Gardner Impact Direct 36 in/lb
Gardner Impact Reverse 20 in/lb
Dry Time
Set to touch 20 min
Dry to touch 1¾ h
Hard dry 6 h

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 ANCAREZ AR555 EPOXY RESIN/ ANQUAMINE 100 CURATIVE —
TABLE 12: WHITE GLOSS ENAMEL FORMULATION

Part A Pounds Gallons

Ancarez AR555 Epoxy Resin 413.63 45.05
Acrysol RM8W 41.36 4.96
Part B
Anquamine 100 curative 144.77 16.52
De-ionized Water 188.20 22.55
Disperbyk 190 10.34 1.17
Surfynol DF110 4.14 0.50
TiO2 – R960 289.54 8.89
Surfynol 420 3.1 0.37
640.09 50.00

TABLE 13: FORMULATION ATTRIBUTES

Property Value Unit

Pencil Hardness 2H
60° Gloss 63
Impact
Gardner Impact Direct 12 in/lb
Gardner Impact Reverse 100 in/lb
Dry Time
Set to touch ¼ h
Dry to touch ¾ h
Hard dry 4 h

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 MAINCOTE AE-58/ ANCAREZ AR555 RESIN —
TABLE 14: STARTING POINT FORMULATION ACRYLIC-EPOXY CLEAR COAT

Acrylic Component A Parts by Weight

Add the following in the order listed and mix thoroughly:
Methyl Carbitol 5.7
Maincote AE-58 72.0
NH4OH (28% NH3) 0.5
Ektasolve EEH 7.0
Patcote 550 0.3
Acrysol RM-1020 1.2
Acrysol RM-8 0.2
Sodium Nitrite (15% aqueous solution) 1.3
TOTAL ACRYLIC COMPONENT A 88.2
Acrylic Component B
Ancarez AR555 (Evonik) 11.8
TOTAL ACRYLIC / EPOXY TOPCOAT 100.0

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 MAINCOTE AE-58/ ANCAREZ AR555 —
TABLE 15: STARTING POINT FORMULATION ACRYLIC-EPOXY TOPCOAT

Acrylic Component A Pounds Gallons

Grind the following materials using a high speed dissolve for 20 minutes:
Methyl Carbitol 39.34 4.56
Tamol 165 13.99 1.59
NH4OH (28% NH3) 1.01 0.12
Triton CF-10 1.62 0.19
Patcote 519 0.41 0.06
TiPure R-900 196.39 5.74
Add the following and continue to grind for 2-3 minutes at lower speed:
Water 20.18 2.42
Total Grind 272.94 14.69
Letdown Preparation
Add the following in the order listed and mix thoroughly:
Maincote AE-58 499.85 58.05
Water 59.31 7.10
NH4OH (28% NH3) 2.43 0.29
Grind (from above) 272.94 14.60
Ektasolve EEH 48.87 6.59
Patcote 531 2.03 0.28
Water 14.40 1.73
Acrysol RM-1020 8.11 0.91
Acrysol RM-8 1.22 0.14
Sodium Nitrite (15% aqueous solution) 8.92 1.07
Total Acrylic Component A 918.08 90.86
Epoxy Component B
Ancarez AR555 83.14 9.14
Total Acrylic-Epoxy Topcoat 1000.91 100.0

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 MAINCOTE AE-58/ ANCAREZ AR555 —
TABLE 16: ACRYLIC-EPOXY TOPCOAT COATING TEST RESULTS

Test 1/2 h induction — 21-Day Cure Clear Topcoat

Substrate Cold Rolled Steel, Zinc Phosphate, B952
Primer None
Color Clear White
Pot Life/Gel Time (h) >12 >12
Thickness (mil) 2.0 2.0
Drying Time (h) Set-to-Touch 0.25 0.25
Tack-Free 0.50 0.50
Dry-Hard 1.00 0.80
Dry-Through 3.75 3.00
Film Appearance Gloss (20°) 67.3 33.8
Gloss (60°) 96.6 77.3
Gloss (85°) 96.2 93.2
Adhesion Dry Scrape (kg) >10.5 kg >10.5 kg
Wet Scrape (kg) (24 h/21°C) 3 kg 2 kg
Immersion Water Immersion (24 h/21°C) Pass Pass
MEK Immersion (r/21°C) Fail Soft-Edge Lift
Solvent Resistance MEK Double Rubs Pass 200 Slight Pass 200 Slight
mar mar
Spot Tests 5% sol. Hydrochloric Acid No Effect No Effect
4-h Exposure 5% sol. Sodium Hydroxide No Effect No Effect
4-h Recovery 5% sol. Sulfuric Acid No Effect No Effect
5% sol. Nitric Acid No Effect No Effect
Chlorox No Effect No Effect
Mustard No Effect No Effect
Ketchup No Effect No Effect
Impact Gardner Impact (in/lb) Direct 12 96
Gardner Impact (in/lb) Reverse 4 60
Flexibility Mandrel Bend 1/8“ 1/8“
Hardness Pencil HB 2H
Persoz 179 165

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 TABLE 17: RESIN, PIGMENT AND ADDITIVE SUPPLIERS

Product Supplier
Acrysol RM-8 Dow Chemical
Ancarez AR555 Evonik
®
Anquamine 401 Evonik
Anquamine 419 Evonik
Colortrend 800-series Colorants Colortrend
Disperbyk 190 BYK Chemie
Drewthix 6050 Ashland
Elementis WD, UL Elementis
Glacial Acetic Acid Hoechst Celanese
Halox SW 111 Halox Pigments
Mica 325 KMG
P 40-27 Talc Baretts Minerals Inc.
Red Iron Oxide Elementis Pigments
Rheolate 310 Elementis
Sparwite Barytes Mountain Minerals
Surfynol® Surfactants Evonik
TiPure R-706 Titanium Dioxide DuPont
TR-92 Titanium Dioxide Huntsman
Wollastocoat 10ES Nexeo
Zeeospheres 400 3M Company

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 Ancarez is a registered trademark of Evonik Industries AG or one of its subsidiaries.

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This information and any recommendations, technical or otherwise, are presented in good faith and believed to be correct as of the date prepared. Recipients of this
information and recommendations must make their own determination as to its suitability for their purposes. In no event shall Evonik assume liability for damages or losses
of any kind or nature that result from the use of or reliance upon this information and recommendations. EVONIK EXPRESSLY DISCLAIMS ANY REPRESENTATIONS
AND WARRANTIES OF ANY KIND, WHETHER EXPRESS OR IMPLIED, AS TO THE ACCURACY, COMPLETENESS, NON-INFRINGEMENT, MERCHANTABILITY
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product, and does not imply that similar products could not be used. Evonik reserves the right to make any changes to the information and/or recommendations at any time,
without prior or subsequent notice.

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