UTTHAN BATCH

JEE (Main + Adv.) Division

Chemistry
CPS - 9
IONIQ EQUILIBRIUM

Motion Education, 394 - Rajeev Gandhi Nagar, Kota-5 (Raj.)

: 1800-212-1799| url : www.motion.ac.in
 UTTHAN BATCH - CPS
[ JEE ADVANCED ]

[STRAIGHT OBJECTIVE TYPE]

Q.1 to Q.9 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct
1. The range of most suitable indicator which should be used for titration of X– Na+ (0.1 M, 10 ml )
with 0.1 M HCl should be (Given: k b( X  ) =10–6)

(A) 2–3 (B) 3–5 (C) 6–8 (D) 8–10

2 3
2. Silver ions are added to a solution with [Br–] = [Cl–] = [ CO 3 ] = [ AsO 4 ]= 0.1 M. Which
compound will precipitate at lowest [Ag+]?
(A) AgBr (Ksp = 5×10–13) (B) AgCl (Ksp = 1.8×10–10)
(C) Ag2CO3 (Ksp = 8.1×10–12) (D) Ag3AsO4 (Ksp = 1×10–22)
3. A buffer solution was prepared by dissolving 0.02 mole acetic acid & 0.01 mole sodium acetate in
enough water to make 1.0 L of solution ( K a (CH COOH) = 2 ×10–5). If 5 × 10–4 mole NaOH were
3
added to 100 ml of the buffer. The resultant pH of the solution would be [given log 5 = 0.70]
(A) 5 (B) 4.7 (C) 5.3 (D) None
4. What is the aq. ammonia concentration of a solution prepared by dissolving 0.15 mole of
NH4 CH3COO– in 1L H2O.[ K a (CH =1.8×10–5 ; K b ( NH OH) =1.8×10–5]
3COOH) 4
(A) 8.3 ×10–4 (B) 0.15 (C) 6.4 ×10–4 (D) 3.8 × 10–4
5. In which of the following cases will neither pH nor pOH be less than 5 at 298 K.
(A) an aqueous solution of NaOH molarity 10–4 M.
(B) an aqueous solution of ammonium acetate
(C) an aqueous solution of NH3 having concentration 0.1M and Kb = 1.8 × 10–5 for NH3
109
(D) an aqueous solution of CH3COOH having concentration 0.1 M and Kb = for CH3COO– ion.
1 .8
6. Calculate [H+] of 0.01 M A+ B¯ salt solution if Ka HB= 10–12.
(A) 10–2 M (B) 10–7 M (C) 6.2 × 10–3 (D) 1.6 × 10–12 M
7. What will be the concentration of Ag+ in a solution saturated with 0.1 M H2S such that pH of the solution
is maintained at 2 if K a1 , K a 2 of H2S are 10–7, 10–14 and solubility product of Ag2S is 10–50 ?
(A) 10–18 M (B) 10–16 M (C) 10–32 M (D) 2 × 10–18 M

8. When pure water is saturated with CaCO3 and CaC2O4, the concentration of calcium ion in the
solution under equilibrium is 9.0 × 10–5 M. If the ratio of the solubility product of CaCO3 to that
of CaC2O4 is 2.0, what is the solubility product of CaCO3 in pure water?
(A) 3.0 × 10–5 (B) 3.6 × 10–9 (C) 6.0 × 10–5 (D) 5.4 × 10–9
9. 50 ml of 0.02 M NaHSO4 is mixed with 50 ml of 0.02 M Na2SO4. calculate pH of the resulting
solution.

[K a 2 H 2SO 4  10 2 ] .
(A) 2 – log 0.414 (B) 2 + log 1.414 (C) 1.7 (D) 2

[MULTIPLE OBJECTIVE TYPE]

Q.10 to Q.15 has four choices (A), (B), (C), (D) out of which ONE OR MORE THAN ONE is correct.
5 12
10. N2H4 is a weak base, ( K b  3.0 10 and K b  6.0 10 ). Which of the following is / are correct
1 2
equilibrium concentrations of the given species, in 0.3 M N2H4 solution?
(A) [H+] = 3.33 × 10–12 M (B) [N2H5+] = 3.0 × 10–3
2+
(C) [N2H6 ] = 6.0 × 10 –12 M (D) [OH¯] = 6.0 × 10–12 M

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 UTTHAN BATCH - CPS
11. If the vapour pressure of a saturated aqueous solution of salt AB is equal to 299.892 torr and
that of pure H2O at that temperature is 300 torr then select the correct statments. Molar mass
of AB = 50 gm/mole.
(A) Solubility of AB in water at that temperature is 0.5 gm / litre.
(B) Solubility product of AB is 2.5 × 10–4 M2
(C) Solubility product of AB is 10–4 M2
(D) Solubility of AB in a solution of 0.025 M BCl(aq) (Completely soluble salt) will be 4 × 10–3 M

12. A substance A2H4 is dissolved in water to form aqueous solution. If its base dissociation constants
are K b1 = 4 × 10–5 & K b2 = 10–8 respectively then which of the options are correct regarding
approximate concentration of species when 0.1 M aqueous solution of A2H4 is taken
(A) [A2H62+] = 10–8 M (B) [H+] = 5 × 10–12 M
+ –3
(C) [A2H5 ] = 2 × 10 M (D) [OH¯] = 2 × 10–3 M

13. A solution is prepared by mixing 100 ml of 0.5 M hydrazoic acid (HN3) , with 400 ml of 0.25 M
cyanic acid (HOCN) at 25°C. [Given : Ka of HOCN is 5 × 10–6 , Ka of HN3 is 10–5]
Which of the following is/are true?
1
(A) [H+] = 2 × 10–3 M (B) [N3–] =  103 M
2
1 1
(C) [OCN–] =  103 M (D) [OH–] =  1011 M
2 2
14. When 100 ml of 0.2 M - NaOH solution is added in 200 ml of 0.4 M - HA (weak monobasic acid)
solution at 25°C, the pH of resulting solution becomes 6.52. The incorrect statement(s) at 25°C
is/are:
(Given : ln 3 = 0.48)
(A) Ka of HA is 3 × 10–7
(B) pH of 0.1 M - HA solution is 4.0
(C) pOH of 0.1 M - NaA (strong electrolyte) solution is 4.0
(D) A buffer solution may be obtained by mixing 10 ml of 0.2 M - HA solution with 20 ml of
0.15 M - NaOH solution.

15. Which of the following solutions when added to 1L of a 0.1M CH3COOH solution will cause no
change in either degree of dissociation of CH3COOH or the pH of the solution
(Ka for CH3COOH = 10–5)
(A) 1 milli Molar HCl (B) 0.1M CH3 COOH
(C) 0.1M CH3COONa (D) 2M HA (Ka = 5 × 10–7)

[COMPREHENSION TYPE]
Q.16 to Q.21 are based upon a paragraph. Each questions has four choice (A), (B), (C), (D) out of
which ONLY ONE is correct
Paragraph for question nos. 16 to 18
The equilibrium equations and Ka values for three acids are given at 25°C :
HA(aq) + H2O H3O+(aq) + A¯ (aq) ; Ka = 2 × 10–5
HB(aq) + H2O H3O+(aq) + B¯ (aq) ; Ka = 4 × 10–6
HC(aq) + H2O H3O+(aq) + C¯ (aq) ; Ka = 1 × 10–4

16. Which conjugate pair would be best for preparing a buffer with a pH = 5.4 ? (log 2 = 0.3)
(A) HA + A¯ (B) HB + B¯ (C) HC + C¯ (D) H2O + H3O+

17. The pH of 0.2 M aqueous HA solution is

(A) 3.70 (B) 2.70 (C) 1.70 (D) 2.35

18. The pH of 0.1 M aqueous NaC solution is (NaC is sodium salt of acid HC)
(A) 2.5 (B) 11.5 (C) 9.5 (D) 8.5

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 UTTHAN BATCH - CPS
Paragraph for question nos. 19 to 21
'Equivalence point' in an acid-base titration is defined as that point where equivalents of acid
become equal to equivalents of base. In case of monoprotic acids and bases there is a single
equivalence point, where as in case of polyprotic acids and bases there may be multiple equivalence
point. Depending upon type of substances present pH of the solution can be calculated at any
equivalence point.
Given that : Ka1 H3PO4 = 5 × 10–4
Ka2 H3PO4 = 5 × 10–8
Ka3 H3PO4 = 4.5 × 10–11
(Use : log 2 = 0.3, log3 = 0.4)
On the basis of above information answer the questions that follow.

19. The pH of the solution when 100 ml of 0.1M H3PO4 is mixed with 200 ml of 0.1M NaOH solution
at 298K.
(A) 8.9 (B) 1.5 × 10–9 (C) 5.3 (D) 8.5

20. What can concluded about nature of final solution obtained after mixing 50 ml of 0.1 M H3PO4 with
0.1M KOH at 298 K if volume of KOH solution added is less than or equal to 50 ml .
(A) neutral
(B) definitely acidic
(C) definitely basic
(D) Nature cannot be decided unless volume is specified.

21. What can be concluded about the final solution obtained on mixing 200 ml of 0.2 M H3PO4 with 50
ml of 0.3 M NaOH solution at 298 K.
(A) The solution will be acidic and will show buffer properties.
(B) The solution will be acidic but will not show buffer properties.
(C) The solution will be basic and will show buffer properties.
(D) The solution will be basic but will not show buffer properties.

[ MATCH THE COLUMN TYPE ]

Q.22 has matching list. The codes of list have choices (A), (B), (C) & (D) out of which Only one is correct
22. Column I Column II
(Solution) (Formula used to calculate pH)
[salt ]
(A) 10 ml of 0.1 M Na2HPO4 (P) pH = pK3 + log
[acid ]
+ 10 ml of 0.1 M HCl
[salt ]
(B) 10 ml of 0.1 M Na3PO4 (Q) pH = pK2 + log
[acid ]
+ 15 ml 0.2 M HCl

Kw [ H  ]2
(C) 10 ml of 0.1 M H3PO4 (R) 
K1 C  [ H  ]
+ 15 ml 0.1 M NaOH
1
(D) 15 ml of 0.1 M Na3PO4 (S) pH = (pK2 + pK1)
2
+ 40 ml of 0.1 M HCl

[H  ]2
(T) K1 =
C  [H  ]
Select the correct option
(A) (A) R, (B) T (C) S (D) Q (B) (A) T, (B) P (C) Q (D) S
(C) (A) P, (B) Q (C) R (D) S (D) (A) S, (B) T (C) Q (D) P

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