Sec: JR.

IIT_*COSC(MODEL-A) RTA-9 Date: 27-01-25

Time: 3 Hrs 2020_P2 Max. Marks: 198
KEY SHEET
MATHEMATICS
1 1 2 1 3 2 4 7 5 4

6 0 7 ABC 8 ABC 9 AD 10 CD

11 AC 12 BC 13 2.5 14 1.25 15 4.5

16 0 17 8.8 18 0.25

PHYSICS
19 5 20 6 21 8 22 4 23 5

24 4 25 ABC 26 AD 27 ABC 28 ABD

29 AC 30 ABCD 31 288 32 80 33 297

34 500 35 0.875 36 16

CHEMISTRY
37 5 38 5 39 5 40 9 41 5

42 2 43 ABD 44 ABC 45 ABCD 46 ABD

47 AD 48 CD 49 58.32 50 27 51 25

52 6.25 53 94.79 54 50
Narayana IIT Academy 27-01-25_JR.*CO-SC(MODEL-A)_JEE-ADV_RTA-9_KEY&SOL
SOLUTIONS
MATHEMATICS
1. 1

L1  lim x 1

sin n cos 1 x  1  x  lim x 1
n  cos 1 x 
 n
1 x 1 x  1 x 
   lim  
2
1  cos ncos 1x 1
n 2 cos x  1 
L 2  lim x 1  
1  x 1  x  x 1
2 1  x   2 
2
n
 L2 
2
n2 3
Given n 
2 2
 n  2n  3  n 2  2n  3  0   n  3 n  1  0
2

 n  1 or n  3
Since, n  N .
 n  1  Sum  1
2. 1
     
v1  3(a  b), v2  2(b  (a·b)a)
   
v1 ·v2  0  v1  v 2
   
v1  3|a||b|sin   3|b|sin 
  
v2  2 (b  (a·b)a)2
   
 2 |b|2 2(a·b)2  (a·b)2 |a|2
 
 2 |b|2 (a·b)2

 2 |b|2 a2b2 cos2   2|b|sin 
1  
Area  ·3| b|sin ·2| b|sin 
2

3

 | b|4 4
4

1
|b|2 sin2   |b|4 4 
4
 4
  |b| |b|
4sin 2 2
2
4 

4

|b| 2

[|b|]  1
3. 2
Let A  diag.  a, b, c 
1 1 1
 A 1  diag· , , 
a b c
 2 A  B  I
2

 2 A2  4 A 1  I

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 4 4 4
 diag.  2a2  ,2 b2  ,2c2  
 a b c
 ( ,  , )

4
 2x 2     2x 3  x  4  0
x

 a  b  c  0,abc  2
Tr(A)  0 and Det(A)  2
 pq2
4. 7
x2
f(x)  (2lnx  1)  cx  k
4
x2  2  x
f  (x)     (2lnx  1)·  e
4 x 2
x x
  xlnx   e
2 2
 xlnx  e
f  (x)  0  xlnx  e  0
e
 lnx   0
x

f  (x)  0 in (0,e)  f(x) is 

f  (x)  0 in (e, )  f(x) is 
e2 3
f(x) min.  f(e)   e2  k  k  e2
4 4
For f  x  to be defined for all x   0, 
3
f(x)  0  k  e2
4
3e ae2
2
k min.  
4 b
a  b  3  4  7
5. 4
x2  y 2  4x  6y  3  0
(x  2)2  (y  3)2  3  9  4
PT  S1  49  3  16  36  6

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Let ACB  
 
 ABC  
2 2

 BPT 
2

 8 4
tan  
2 6 3
1
Ar. (CAB)   4·4·sin   8sin 
2
1
Ar  ΔCAT    4  4  sin      8sin
2
Ar(CAB)  Ar·(CAT)  16sin 
 4
2tan 16·2·
 16· 2  3  384
 16 25
1  tan2 1
2 9
  15  384   15
 
 19  15  4
6. 0
7. ABC
  
a  b  c 1
   
and a  c  b  c …(1)
                 
a  b  c   b   c  a    a  c  b   a  b  c   a  b c  b  c  a
       
=  a  c  b   b  c  a =  4  x 2  b   4x cos2   a
   
 a  c  4  x 2 , b  c  4x cos2  .
From (1),
4 + x2 = 4xcos2
 4 + x2 = 4x – 4x sin2 (x – 2)2 = – 4x sin2 x = 2 or sin = 0.
8. ABC
9. AD
Tangent at P.
ty  x  at 2
Q   0, at 

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Now, Equation of parabola with vertex  0, at  and  0, 0  as its focus

x 2  4at  y  at 
which passes through  2a, 0 
4a 2  4at   at 
 t 2  1  t  1
Possible equation curve
C2 : x 2  4a(y  a)
or x2  4a(y  a)
Co-ordinates of P are :  a, 2a 
[Extremities of latus rectum of C1 ]. Possible equation of directrix of
C2 : y  a  a  y  2a  0
y  a  a  0  y  2a  0
10. CD
11. AC
12. BC
13. 2.5
14. 1.25
15. 4.5
x  (cos   1)  (cos   1)  (cos   2)  (cos   3)
 x  7  2cos 
xmax  7  2(1)  9
xmin  7  2(1)  5
16. 0
Since point of minima is negative therefore point of maxima is also negative.
Hence, both roots of f   x  must be negative and distinct.
Sum of the roots  0 and D  0
Their intersection is  , hence no values of a .
17. 8.8
If m  2
1 1 2 2  3 4 4  2n1 2n1 
A  , then A 2
 2 2  ,A  4 4  , ,A n
  n1 n1 
1 1     2 2 

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m n 1
m n 1
 m n 1 
 
 If m  m , then An   m n 1 m n 1  m n 1 
 m n 1 m n 1  m n 1 
 
 An  mn1 A  1617 A  268 A
Factors of 68 are 1,2,4,17,34,68.
If n  1  1  n  2, then m  268
If n  1  2  n  3, then m  234
If n  1  4  n  5, then m  217
If n  1  34  n  35, then m  4
If n  1  68  n  69, then m  2
 Sum of all n  132.
18. 0.25
b  0 and c  1
Note that both x3  2 x 2  x  c and e x are differentiable in their domain.
So make the function differentiable at x  b .
Since f is differentiable at x  b .
L.H.D.  R.H.D.  at x  b 
3b 2  4b  1  eb
b is an integer, so LHS of the equation will always be an integer. However RHS will an integer only
if b  0 .
If b  0 , LHS  RHS, so b  0 is the solution to this equation.
Since f is differentiable at x  b , it is implied that it is also continuous at x  b .
lim f(x)  f(b)  lim f(x)
x b x b

when b  0 , we get c  e 0  1
so the answer is 0  1  1
PHYSICS
19. 5

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20. 6

21. 8

22. 4

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23. 5

24. 4

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25. ABC

26. AD

27. ABC

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28. ABD

29. AC
30. ABCD
31. 288

32. 80

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33. 297

34. 500

35. 0.875

36. 16

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Narayana IIT Academy 27-01-25_JR.*CO-SC(MODEL-A)_JEE-ADV_RTA-9_KEY&SOL

CHEMISTRY
37. 5
Suppose the lower oxidation number of metal is a
Metal  H2SO 4 
 H2
0.1 g 43.9 ml at NTP
Eq. of metal = Eq. of hydrogen
0.1 43.9
 a2
51/ a 11200
Metal changes from lower oxidation number 2 to higher oxidation number, say b
51 51
Eq. of the metal  
change in oxidation number b  2
Eq. of metal = Eq. of KMnO4
0.1 0.1 58.8
 b5
51/ b  2 1000
38. 5
SO3, Cl2O7, SO2, N2O5, Br2O5
39. 5
H3C CH3
NH2
N
CH2 NH2

, , , H3C CH2 CH2 CH2 NH2

,
N

OMe
40. 9

41. 5
COOH SO 3H OH COOH
O 2N NO2

, , ,

NO2 NO2

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HO O

HO O

42. 2
A  aq.  mB  g
Kc (RT)m  KP
m
 2
 2  R×  = 8
 R
2 =4
m

m=2
So, for 1 mole of A(aq.) reacted, two moles of the gaseous product molecules are formed.
43. ABD
A 
 B  3C
1 0.1  0.1  0.3 

PT  1  3 0.1  1.3 atm

ΔP = 0.2, atm or 760×0.3 mm Hg = 228 mm of Hg
44. ABC
 2Ke2  Z
v     , so, atomic no. (Z)  slope of the graph.
 h  n
So, statement (1) is True.
h 1
  , slope of the graph 
2qVm m
So, statement (2) is True.
From, PV = nRT
 nR  1
V  T , so, slope of graph 
 P  P
So, statement (3) is also correct.
1
 P  nRT  , so, slope  T
V
45. ABCD
46. ABD
  
In (A) CH2=CH–CH2  CH2–CH=CH2 ; whereas CH2=CH–CH2–CH2 shows no resonance effect.
  +
In (B) CH3–NH–CH2  CH3–NH=CH2. Although CH2–OH also shows resonance; but, oxygen
being less basic contributes to a lesser extent than nitrogen.
 + 
In (C) CH3–O–CH2  CH3–O=CH2 ; whereas no resonance occurs in CH3–O–CH2–CH2 .
+
In (D) CH3–CH–CH2–CH2–CH3 has six hyper-conjugative structures; whereas
+
CH3–CH2–CH–CH2–CH3has just five hyper-conjugative structures.
47. AD
48. CD

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Ph
N CH3
(i) H cannot be resolved due to flipping of lone pair.
CH3 COOH

H
H
H
H

CH3
(ii) COOH cannot be resolved due to center of symmetry.
49. 58.32
2CH2 = CHCN + 2H+ + 2e- 
 CN – (CH2)4 CN
 108 
   0.8  3750  9.65  3600
 2 
m= = 58.32 kg
96500
50. 27
27 mL
3
Co  NH3 6  Cl3  3AgNO3   Co NH3 6   3NO3  3AgCl  s 
0.3
Moles of complex 
267.46
0.3 0.125  V
Moles of AgNO3  3  
267.46 1000
 V = 26.92 mL = 27
51. 25
CuSO2 ·5H2O  CuSO4 ·3H2O(s)  2H2O(g)
p

52. 6.25

Van't Hoff factor .

53. 94.79%

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2  1600
% of tertiary bromide   100%
2  1600  2  82 +12  1
= 94.79%
54. 50
F
F F
F F
F F F
Xe S S
F F F F F
F F
1  6  3  19 F
6  3  18 1  4  3  13
Total lone pairs = 50

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