SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS 2015 (HPR-GHS), European Union CLP EC 1272/2008 and REACH, Australian NOHSC, New Zealand HNSO, the Korean ISHA
(Notice 2009-68), Singapore SS586 - 2: 2008 and SS 586 - 3: 2008 Standards, Chinese GB 20576 ~ GB 20602-2006, Japanese JIS Z7253, Taiwanese Standards and the Global
Harmonization Standard, and requirements under Chemical Control Regulations of Argentina, Chile, Colombia, Costa Rica, Panama, Honduras, Venezuela, Uruguay, Peru and Paraguay.
1. IDENTIFICATION of the SUBSTANCE or PREPARATION
IDENTIFICATION OF SUBSTANCE/PREPARATION:
TRADE NAME (AS LABELED): Tattoo Paint No. BLK
CHEMICAL NAME/CLASS: Water-Based Pigment
SYNONYMS: Not Applicable
PRODUCT USE: Various Uses
U.N. NUMBER: None Allocated
U.N. DANGEROUS GOODS CLASS/SUBSIDIARY RISK: None Allocated
HAZCHEM CODE (AUSTRALIA): None Allocated
POISONS SCHEDULE NUMBER (AUSTRALIA): None Allocated
COMPANY/UNDERTAKING IDENTIFICATION:
MANUFACTURER'S NAME: DYNAMIC COLOR CO.
ADDRESS: PO Box 21083
Ft. Lauderdale, FL 33335, USA
INFORMATION PHONE: + 1-954-462-0261 9 a.m. to 4 p.m. (U.S. East Coast Time Zone)
EMERGENCY PHONE: 1-800-233-8332 9 a.m. to 4 p.m. (U.S. East Coast Time Zone)
(from U.S., Canada, Puerto Rico, U.S. Virgin Islands)
EMAIL:
[email protected]DATE OF PREPARATION: April 12, 2001
DATE OF REVISION: May 09, 2017
NOTE: ALL United States Occupational Safety and Health Administration Standard (29 CFR 1910.1200), U.S. State equivalent Standards, Canadian WHMIS [Controlled Products Regulations],
the European Union CLP EC 1272/2008 and the Global Harmonization Standard, Australian [NOHSC:2012 (2003)], and Japanese Industrial Standard (JIS Z 7250: 2000) required
information is included in appropriate sections based on the Global Harmonization Standard. This product has been classified in accordance with the hazard criteria of the countries listed
above.
2. HAZARD IDENTIFICATION
GLOBAL HARMONIZATION LABELING AND CLASSIFICATION: Classified in accordance with Global Harmonization
Standard under U.S. OSHA Hazard Communication Standard, Canadian WHMIS HPR-GHS 2-15, EU CLP Regulation
(EC) 1272/2008, Japanese JIS Z7253: 2012 and Singapore Standards. For information on Korean ISHA and New
Zealand HSNO classification, see below.
Classification: Eye Irritation Cat. 2A Signal Word: Warning Hazard Statement Codes: H319
Precautionary Statement Codes: P264, P280, P305 + P351 + P338, P337 + P313
Hazard Symbol/Pictogram: GHS07
KOREAN ISHA (Notice 2009-68) LABELING AND CLASSIFICATION: Classified in accordance with ISHA Notice 2009-68.
Under ISHA, the following differences in classification are applicable.
Classification: Eye Irritation Cat. 2 Signal Word: Warning Hazard Statement Codes: H319
Precautionary Statement Codes: P264, P280, P305 + P351 + P338, P337 + P313
Hazard Symbol/Pictogram: GHS07
NEW ZEALAND HAZARDOUS SUBSTANCES and NEW ORGANISMS ACT (HNSO) CHEMICAL CLASSIFICATION:
Product Group Standard: Not Otherwise Classified, Subsidiary Hazard
Classification: 6.4A: Irritating to the eye.
See Section 16 for full text of classification of product and components
TATTOO PAINT NO. BLK SDS
Page 1 of 11
2. HAZARD IDENTIFICATION (Continued)
EMERGENCY OVERVIEW: Product Description: This product is a black liquid that has a mild odor. Health Hazards:
The primary health hazard associated with this product is the potential for mild irritation of contaminated tissue. Eye
contact may cause irritation. The inks may stain skin, eyes, other contaminated tissue, and objects. The Carbon Black
component is a suspect carcinogen by inhalation of respirable particles. Due to the liquid form of this product, this hazard
is not expected to be significant. Flammability Hazards: This product is not flammable. If involved in a fire, the product
may decompose to produce carbon and nitrogen oxides. Reactivity Hazards: This product is not reactive.
Environmental Hazards: Not tested. This product may have adverse effects when released into the environment.
Emergency Recommendations: Emergency responders must wear the personal protective equipment suitable for the
situation to which they are responding.
3. COMPOSITION and INFORMATION ON INGREDIENTS
Chemical CAS # European Japanese Korean New Chinese Taiwan Australian % w/w LABEL ELEMENTS
Name EINECS # MITI/ENC # ECL # Zealand IECSC NESCI AICS GHS under U.S. OSHA, Canadian
NZIoC # Inventory ECS WHMIS HPR-GHS & EU
Inventory Classification (1272/2008),
Japanese, Taiwan, Chinese and
Korean Regulations
Korean ISHA Classification
Hazard Statement Codes
Carbon 1333-86-4 215-609-9 Excepted KE- HSR00284 Listed Listed Listed 10% GHS under U.S. OSHA, Canadian
Black as a 04682 WHMIS HPR-2015, Korean ISHA
(.C.I. Mineral & EU CLP 1272/2008
Number Classification: Carcinogenic
77266) Category 2
Hazard Statement Codes: H351i
Under U.S. OSHA, Canadian
WHMIS HPR-2015 only
Classification: Combustible Dust
Hazard
Isopropyl 67-63-0 200-661-7 2-207 KE- HSR00118 Listed Listed Listed 10% HARMONISED CLASSIFICATION -
Alcohol 29363 0 ANNEX VI of REGULATION (EC)
No 1272/2008 (CLP00)
Classification: Flammable Liquid
Category 2, Eye Irritant
Category 2A, STOT SE 3
Hazard Statement Codes: H225,
H319, H336
GHS under Korean ISHA
Classification: Flammable Liquid
Category 2, Eye Irritant Category
2, STOT (Inhalation-Narcotic
Effect) SE 3
Hazard Statement Codes: H225,
H319, H336
Acrylic Proprietary Not Determined 5% GHS under U.S. OSHA, Canadian
Polymer WHMIS & EU CLP 1272/2008,
KOREAN ISHA
Classification: Not Determined
Water 7732-18-5 231-791-2 Not Identified KE- Excepted Listed Listed Listed Balance GHS under U.S. OSHA, Canadian
in the Listing 35400 WHMIS & EU CLP 1272/2008,
KOREAN ISHA
Classification: Not Classified
See Section 16 for full text of classification. See Section 15 for information on other country inventory listing of components, as applicable
4. FIRST-AID MEASURES
PROTECTION OF FIRST AID RESPONDERS: Rescuers should be taken for medical attention, if necessary. Only trained
personnel should administer supplemental oxygen and/or cardio-pulmonary resuscitation, if necessary.
DESCRIPTION OF FIRST AID MEASURES: Victim(s) must be taken for medical attention. Take copy of label and MSDS
to physician or other health professional with victim(s). Remove victim(s) to fresh air, as quickly as possible.
Skin Exposure: If this product contaminates the skin, begin decontamination with running water. Minimum flushing is for 20 minutes.
The contaminated individual must seek medical attention if any adverse effects occur after flushing.
Eye Exposure: If this product enters the eyes, open contaminated individual's eyes while under gently running water. Use sufficient
force to open eyelids. Have contaminated individual "roll" eyes. Minimum flushing is for 20 minutes. Contaminated individual must
seek medical attention if adverse effect continues after flushing.
Inhalation: If aerosols are inhaled, remove victim to fresh air. The contaminated individual must seek medical attention if any adverse
effects occur.
Ingestion: If swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. If professional
advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to someone who is unconscious,
having convulsions, or unable to swallow. If victim is convulsing, maintain an open airway and obtain immediate medical attention.
IMPORTANT SYMPTOMS AND EFFECTS: See Sections 2 (Hazard Information) and 11 (Toxicological Information) for
information.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin or respiratory conditions may be aggravated by exposure
to this product.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT IF NEEDED: Treat symptoms and
eliminate exposure.
TATTOO PAINT NO. BLK SDS
Page 2 of 11
5. FIRE-FIGHTING MEASURES
FLASH POINT: Not flammable.
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %): Not applicable.
FIRE EXTINGUISHING MEDIA: Unless incompatibilities exist for surrounding
materials, carbon dioxide, water spray, ‘ABC’ type chemical extinguishers,
foam, dry chemical and halon extinguishers can be used to fight fires involving
this product.
UNSUITABLE FIRE EXTINGUISHING MEDIA: None known.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE: When involved in
a fire, this material may decompose and produce irritating vapors and toxic
gases (e.g., carbon and nitrogen oxides).
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS Incipient fire Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate
responders should wear eye protection. Structural firefighters must wear Self- 3 = Serious 4 = Severe
Contained Breathing Apparatus and full protective equipment. Due to the presence of pigment, the runoff water from this
product can discolor contaminated objects. If possible, prevent runoff water from entering storm drains, bodies of water, or
other environmentally sensitive areas. If necessary, rinse fire-response equipment with soapy water before returning it to
service.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS AND EMERGENCY PROCEDURES: Uncontrolled releases should be responded to by
trained personnel using pre-planned procedures. Proper protective equipment should be used. Call CHEMTREC (1-800-
424-9300) for emergency assistance. Or if in Canada, call CANUTEC (613-996-6666). The atmosphere must at least 19.5
percent Oxygen before non-emergency personnel can be allowed in the area without Self-Contained Breathing Apparatus
and fire protection.
PERSONAL PROTECTIVE EQUIPMENT: Proper protective equipment should be used.
Small Spills: Wear rubber gloves, splash goggles, and appropriate body protection.
Large Spills: Minimum Personal Protective Equipment should be rubber gloves, rubber boots, face shield, and Tyvek suit. Minimum
level of personal protective equipment for releases in which the level of oxygen is less than 19.5% or is unknown must be Level B:
triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard hat, and Self-
Contained Breathing Apparatus.
METHODS FOR CLEAN-UP AND CONTAINMENT:
Small Spills: Carefully absorb spill using polypads or other non-reactive absorbent. Place spilled material in appropriate container for
disposal, sealing tightly. Remove all residue before decontamination of spill area.
Large Spills: Access to the spill area should be restricted. For large spills, dike or otherwise contain spill and absorb spill with polypads
or other non-reactive absorbent material. Monitor area for combustible vapor levels.
All Spills: Place all spill residue in a double plastic bag or other containment and seal. Decontaminate the area thoroughly. Do not mix
with wastes from other materials. Dispose of in accordance with applicable Federal, State, and local procedures (see Section 13,
Disposal Considerations). For spills on water, contain, minimize dispersion and collect. Dispose of recovered material and report spill
per regulatory requirements.
ENVIRONMENTAL PRECAUTIONS: Avoid release to the environment. Run-off water may be contaminated by other
materials and should be contained to prevent possible environmental damage.
REFERENCE TO OTHER SECTIONS: See information in Section 8 (Exposure Controls – Personal Protection) and Section
13 (Disposal Considerations) for additional information.
7. HANDLING and STORAGE
PRECAUTIONS FOR SAFE HANDLING: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid
breathing aerosols from the product. Keep away from incompatible materials (see Section 10, Stability and Reactivity).
Containers of this product must be properly labeled. Use in a well-ventilated location. Remove contaminated clothing.
CONDITIONS FOR SAFE STORAGE: Keep container tightly closed when not in use. Store containers in a cool, dry
location, away from direct sunlight, sources of intense heat, or where freezing is possible. Material should be stored in
secondary containers or in a diked area, as appropriate. Inspect all incoming containers before storage, to ensure
containers are properly labeled and not damaged. Have appropriate extinguishing equipment in the storage area (such as
sprinkler systems or portable fire extinguishers). Empty containers may contain residual product; therefore, empty
containers should be handled with care.
SPECIFIC USE(S): This product is for use as an ink. Follow all industry standards for use of this product.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely. Always
use this product in areas where adequate ventilation is provided. Decontaminate equipment thoroughly, before maintenance
begins. Collect all rinsates and dispose of according to applicable Federal, State, or local procedures, or applicable
standards.
TATTOO PAINT NO. BLK SDS
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8. EXPOSURE CONTROLS - PERSONAL PROTECTION
EXPOSURE LIMITS/CONTROL PARAMETERS:
Ventilation and Engineering Controls: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided
in this section. Use local exhaust ventilation. Normal office ventilation conforming to the American Society of Heating, Refrigerating,
and Air Conditioning Engineers (ASHRAE) Standards is adequate under normal circumstances of use. Persons using this material
should consult a qualified Ventilation Engineer and/or Industrial Hygienist if concerns about exposure arise. If necessary, refer to
Australian National Code of Practice for the Control of Workplace Hazardous Substances [NOHSC: 2007 (1994)] for further
information.
Workplace Exposure Limits/Control Parameters:
CHEMICAL CAS # EXPOSURE LIMITS IN AIR
NAME
ACGIH-TLVs OSHA-PELs NIOSH-RELs NIOSH OTHER
TWA STEL TWA STEL TWA STEL IDLH
3 3 3 3 3 3 3 3
mg/m mg/m mg/m mg/m mg/m mg/m mg/m mg/m
Carbon Black 1333-86-4 3 NE 3.5 NE 3.5 (0.1 in presence NE 1750 DFG MAK: As inhalable dust
(C.I. # 77266) (inhal. of PAHs, as PAHs;
fract.) 1-hr TWA)
Isopropyl 67-63-0 492 984 980 500 ppm 980 1225 2000 DFG MAK:
Alcohol (vacated ppm TWA = 500 ppm
1989 (based PEAK = 2•MAK, 15 min.,
PEL) on average value, 1-hr interval, 4
LEL) per shift
DFG MAK Pregnancy Risk
Classification: C
Acrylic Polymer Proprietary NE NE NE NE NE NE NE NE
NE = Not Established. PAHs = Polycyclic Aromatic Hydrocarbons See Section 16 for Definitions of Other Terms Used
International Occupational Exposure Limits: The following international limits are in place for some components of this product. Limits
may have changed since time of preparation of this SDS and should be checked with competent authorities of individual countries.
CARBON BLACK: ISOPROPYL ALCOHOL (continued):
Australia: TWA = 3 mg/m3, JUL 2008 Belgium: STEL = 500 ppm (1248 mg/m3), MAR 2002
Austria: MAK-TMW = 2 mg/m3, resp, 2007 Denmark: TWA = 200 ppm (490 mg/m3), MAY 2011
Belgium: TWA = 3.6 mg/m3, MAR 2002 France: VLE = 400 ppm (980 mg/m3), FEB 2006
Denmark: TWA = 3.5 mg/m3, carc, MAY 2011 Germany: MAK = 500 mg/m3 (200 mL/m3), 2005
Finland: TWA = 3.5 mg/m3, STEL = 7 mg/m3, NOV 2011 Hungary: TWA = 500 mg/m3, STEL = 2000 mg/m3, Skin, SEP 2000
France: VME = 3.5 mg/m3, FEB 2006 Iceland: TWA = 200 ppm (490 mg/m3), skin, NOV 2011
Iceland: TWA = 3.5 mg/m3, NOV 2011 Japan: OEL-C = 400 ppm (980 mg/m3), MAY 2009
Japan: OEL = 1 mg/m3 (resp. dust), 4 mg/m3 (total dust), 2B carc, MAY 2012 Korea: TWA = 400 ppm (980 mg/m3), STEL = 500 ppm (1225 mg/m3), 2006
Korea: TWA = 3.5 mg/m3, 2006 Mexico: TWA = 400 ppm (980 mg/m3); STEL = 500 ppm (1225 mg/m3), 2004
Mexico: TWA = 3.5 mg/m3; STEL = 7 mg/m3, 2004 The Netherlands: MAC-TGG = 650 mg/m3, 2003
The Netherlands: MAC-TGG = 3.5 mg/m3, 2003 New Zealand: TWA = 400 ppm (983 mg/m3); STEL = 500 ppm (1230 mg/m3), JAN
New Zealand: TWA = 3 mg/m3, JAN2002 2002
Norway: TWA = 3.5 mg/m3, JAN 1999 Peru: TWA = 200 ppm (491 mg/m3); STEL = 400 ppm (983 mg/m3), JUL 2005
Peru: TWA = 3.5 mg/m3, JUL 2005 The Philippines: TWA = 400 ppm (980 mg/m3), JAN 1993
The Philippines: TWA = 3.5 mg/m3, JAN 1993 Poland: MAC(TWA) = 900 mg/m3, MAC(STEL) = 1200 mg/m3, JAN 1999
Russia: STEL = 4 mg/m3, JUN 2003 Russia: TWA = 10 mg/m3, STEL = 50 mg/m3, JUN 2003
Sweden: TWA = 3 mg/m3, JUN 2005 Sweden: TWA = 150 ppm (350 mg/m3); STEL = 250 ppm (600 mg/m3), JUN 2005
United Kingdom: TWA = 3.5 mg/m3; STEL = 7 mg/m3, OCT 2007 Switzerland: MAK-W = 200 ppm (500 mg/m3), KZG-W = 400 ppm (1000 mg/m3), DEC
In Argentina, Bulgaria, Colombia, Jordan, Singapore, Vietnam check ACGIH TLV 2006
ISOPROPYL ALCOHOL: Turkey: TWA = 200 ppm (500 mg/m3), JAN 1993
Australia: TWA = 400 ppm (983 mg/m3), STEL = 500 ppm (1230 mg/m3), JUL 2008 United Kingdom: TWA = 400 ppm (999 mg/m3); STEL = 500 ppm (1250 mg/m3), OCT
Austria: MAK-TMW 200 ppm (500 mg/m3); KZW = 800 ppm (2000 mg/m3), 2007 2007
Belgium: TWA =400 ppm (997 mg/m3), MAR 2002 In Argentina, Bulgaria, Colombia, Jordan, Singapore, Vietnam check ACGIH TLV
Biological Exposure Indices (ACGIH): Currently, there are ACGIH Biological Exposure Indices (BEIs) determined for the components of
this product, as follows:
CHEMICAL: SAMPLING TIME BEI
DETERMINANT
Isopropyl Alcohol
• Acetone in urine • End of Shift End of Workweek • 40 mg/L
Workplace Exposure Standards (New Zealand): None established. Refer to the Hazardous Substances (Classes 6, 8, and 9 Controls)
Regulations 2001 (Regulations 29-30).
Exposure Standards Outside the Workplace (New Zealand): Currently, there are no other exposure limits, such as TELS and EELS (See
Section 12 [Ecological Information] for EEL information) established for components of this product.
PERSONAL PROTECTIVE EQUIPMENT: The following information on appropriate Personal Protective Equipment is
provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132,
including Respiratory Protection Standard [29 CFR 1910.134]), equivalent standards of Canada (including CSA including
CSA Respiratory Standard Z94.4-02 and CSA Standard Z94.3-07), standards of EU member states (including EN
529:2005 for respiratory PPE, CEN/TR 15419:2006 for hand protection, and CR 13464:1999 for face/eye protection), or
standards of Australia (including AS/NZS 1715:1994 for respiratory PPE, AS/NZS 4501.2:2006 for protective clothing,
AS/NZS 2161.1:2000 for glove selection, and AS/NZS 1336:1997 for eye protection), or standards of Japan (including JIS
T 8116:2005 for glove selection, JIS T 8150:2006 for respiratory PPE, JIS T 8147:2003 for eye protectors, and JIS T
8030:2005 for protective clothing). Please reference applicable regulations and standards in each jurisdiction for relevant
details.
TATTOO PAINT NO. BLK SDS
Page 4 of 11
8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
PERSONAL PROTECTIVE EQUIPMENT (continued):
Respiratory Protection: Respiratory protection is not generally needed when using this product. Maintain airborne contaminant
concentrations below limits listed in this section, if applicable. In instances where inhalable mists or sprays of product may be
generated, and respiratory protection is necessary, use only respiratory protection authorized in appropriate regulations. Oxygen levels
below 19.5% are considered IDLH by U.S. OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full
facepiece, SAR with auxiliary self-contained air supply is required under OSHA’s Respiratory Protection Standard (1910.134-1998).
Eye Protection: Depending on the use of this product, splash goggles or safety glasses may be worn. Use goggles or safety glasses for
spill response, as stated in Section 6 (Accidental Release Measures) of this SDS. If necessary, refer to appropriate regulations when
selecting eye protection.
Hand Protection: Wear butyl rubber, neoprene, or nitrile rubber or latex gloves for routine use. If necessary, refer to appropriate
regulations for further information.
Body Protection: Use body protection appropriate for task, such as a lab coat. If necessary, use body protection appropriate for task
(e.g., Tyvek suit, rubber apron). If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce
the soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot protection, as described in appropriate
regulations.
9. PHYSICAL and CHEMICAL PROPERTIES
FORM: Liquid. COLOR: Black.
MOLECULAR FORMULA: Mixture. MOLECULAR WEIGHT: Mixture.
ODOR: Mild. ODOR THRESHOLD: Not established.
VAPOR DENSITY (air = 1): Not established. EVAPORATION RATE (n-BuAc = 1): < 1
SPECIFIC GRAVITY (water = 1): Not established. MELTING/FREEZING POINT: Not established.
SOLUBILITY IN WATER: Soluble BOILING POINT: Not established.
VAPOR PRESSURE: Not established. pH: Not established.
OXIDIZING PROPERTIES: Not applicable. EXPLOSIVE PROPERTIES: Not applicable.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established.
HOW TO DETECT THIS SUBSTANCE (identification properties): The odor and color of this product may be distinguishing
characteristics to identify it event of a spill.
10. STABILITY and REACTIVITY
CHEMICAL STABILITY: Stable under conditions of normal temperature and pressure.
DECOMPOSITION PRODUCTS: Combustion: If exposed to extremely high temperatures, this product can decompose to
generate carbon and nitrogen oxides. Hydrolysis: None known.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizers, water-reactive materials.
POSSIBILITY OF HAZARDOUS REACTION OR POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Exposure to or contact with extreme temperatures and incompatible chemicals.
11. TOXICOLOGICAL INFORMATION
SYMPTOMS OF EXPOSURE BY ROUTE OF EXPOSURE: The most
significant routes of occupational exposure are inhalation and contact with skin HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
and eyes. The symptoms of exposure to this material, via route of entry, are as
described below.
Inhalation: This product does not normally present a significant inhalation hazard under HEALTH HAZARD (BLUE) 1
anticipated circumstances of use. Inhalation of vapors, mists, or sprays of this
material, may mildly irritate the nose, throat, and other tissues of the respiratory
system.
Contact with Skin or Eyes: Due to the pigment, skin contact may discolor contaminated (RED) 0
FLAMMABILITY HAZARD
areas. Skin contact may cause mild irritation in sensitive individuals. Repeated or
prolonged skin exposure may cause dermatitis (dry, red skin). Eye contact with this
material can moderately irritate the eyes, causing discomfort, tearing, and redness.
Because the eye tissue may be stained, vision may be temporarily blurred.
Skin Absorption: No component is known to be absorbed via intact skin. PHYSICAL HAZARD (YELLOW) 0
Ingestion: Though not anticipated to be a significant route of occupational exposure,
ingestion of large quantities of this material may cause nausea, vomiting, diarrhea,
and discoloration of the mouth, teeth, and tissues of the throat. PROTECTIVE EQUIPMENT
Injection: Accidental injection of this liquid (as may occur by a puncture with a
contaminated object) will cause local pain, irritation, and redness.
EYES HANDS BODY
HEALTH EFFECTS OR RISKS FROM EXPOSURE: In the event of exposure, RESPIRATORY
the following symptoms may be observed:
Acute: The ink may stain hair, skin, and other contaminated tissue. Eye contact will SEE SECTION 8 SEE SECTION 8
cause moderate irritation. Ingestion of large amounts may cause nausea, vomiting,
diarrhea.
For Routine Industrial Use and Handling Applications
Chronic: Repeated or prolonged skin exposure may cause dermatitis (dry, red skin).
TARGET ORGANS: Acute: Skin, central nervous system, eyes. Chronic: Skin. Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate
3 = Serious 4 = Severe * = Chronic hazard
TATTOO PAINT NO. BLK SDS
Page 5 of 11
11. TOXICOLOGICAL INFORMATION (Continued)
TOXICITY DATA: Specific toxicology data currently available for components of this product in greater than 1%
concentration are as follows.
CARBON BLACK: CARBON BLACK (continued):
LD50 (Oral-Rat) > 15 400 mg/kg: Behavioral: somnolence (general depressed activity) TDLo (Intratracheal-Rat) 10 mg/kg: Lungs, Thorax, or Respiration: sputum; Biochemical:
LD50 (Skin-Rabbit) > 3 gm/kg Metabolism (Intermediary): other proteins; Biochemical: Metabolism (Intermediary):
TCLo (Inhalation-Rat) 7 mg/m3: Lungs, Thorax, or Respiration: other changes; effect on inflammation or mediation of inflammation
Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of TDLo (Intratracheal-Mouse) 20 mg/kg/4 days-intermittent: Lungs, Thorax, or Respiration:
inflammation sputum; Immunological Including Allergic: increase in cellular immune response;
TCLo (Inhalation-Rat) 1.66 mg/m3/7 hours: Lungs, Thorax, or Respiration: sputum; Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of
Blood: changes in leukocyte (WBC) count; Biochemical: Metabolism (Intermediary): inflammation
effect on inflammation or mediation of inflammation TDLo (Intratracheal-Mouse) 4000 µg/kg/4 weeks-intermittent: Lungs, Thorax, or
TCLo (Inhalation-Rat) 50 mg/m3: Sense Organs and Special Senses (Olfaction): effect, Respiration: other changes; Immunological Including Allergic: increase in cellular
not otherwise specified; Biochemical: Metabolism (Intermediary): effect on immune response; Biochemical: Metabolism (Intermediary): effect on inflammation or
inflammation or mediation of inflammation mediation of inflammation
TCLo (Inhalation-Rat) 229 mg/m3/6 hours: Lungs, Thorax, or Respiration: other changes; TDLo (Intratracheal-Mouse) 1000 µg/kg: Lungs, Thorax, or Respiration: other changes;
Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of Biochemical: Metabolism (Intermediary): effect on inflammation or mediation of
inflammation inflammation
TCLo (Inhalation-Rat) 50 mg/m3/6 hours/90 days-intermittent: Lungs, Thorax, or TDLo (Parenteral-Mouse) 36 µg/kg/3 days-intermittent: Immunological Including Allergic:
Respiration: other changes increase in humoral immune response
TCLo (Inhalation-Rat) 1 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: Mutation in Microorganisms (Bacteria-Salmonella typhimurium) 1 mg/plate
other changes; Biochemical: Metabolism (Intermediary): effect on inflammation or DNA Adduct (Inhalation-Mouse) 6200 µg/m3/16 hours/12 weeks-intermittent
mediation of inflammation DNA Damage (Human Lymphocyte) 16 µg/L/48 hours
TCLo (Inhalation-Rat) 1 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: DNA Damage (Inhalation-Rat) 50 ug/L/13 weeks-intermittent
other changes, changes in lung weight; Biochemical: Metabolism (Intermediary): effect DNA Damage (Inhalation-Rat) 50 gm/L/13 weeks
on inflammation or mediation of inflammation ISOPROPYL ALCOHOL:
TCLo (Inhalation-Rat) 50 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: LDLo (oral, man) = 5272 mg/kg; Behavioral: coma; Vascular: BP lowering not
other changes; Biochemical: Metabolism (Intermediary): other characterized in autonomic section; Lungs, Thorax, or Respiration: chronic pulmonary
TCLo (Inhalation-Rat) 50 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: edema
other changes; Biochemical: Metabolism (Intermediary): other, Metabolism LDLo (oral, human) = 3570 mg/kg; Behavioral: coma; Lungs, Thorax, or Respiration:
(Intermediary): effect on inflammation or mediation of inflammation respiratory depression; Gastrointestinal: nausea or vomiting
TCLo (Inhalation-Rat) 7 mg/m3/6 hours/13 weeks-intermittent: Sense Organs and TDLo (oral, man) = 14,432 mg/kg; Behavioral: coma; Vascular: BP lowering not
Special Senses (Olfaction): effect, not otherwise specified; Biochemical: Metabolism characterized in autonomic section; Lungs, Thorax, or Respiration: dyspnea
(Intermediary): effect on inflammation or mediation of inflammation TDLo (oral, human) = 223 mg/kg; Behavioral: hallucinations, distorted perceptions;
TCLo (Inhalation-Rat) 11,600 µg/m3/18 hours/2 years-intermittent: Tumorigenic: Cardiac: pulse rate; Vascular: BP lowering not characterized in autonomic section
carcinogenic by RTECS criteria; Lungs, Thorax, or Respiration: tumors TDLo (oral, infant) = 13 gm/kg; Behavioral: somnolence (general depressed activity),
TCLo (Inhalation-Mouse) 50 mg/m3/6 hours: Sense Organs and Special Senses irritability; Gastrointestinal: nausea or vomiting
(Olfaction): effect, not otherwise specified LDLo (unreported, man) = 2770 mg/kg
TCLo (Inhalation-Mouse) 1 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: Skin Irritancy (rabbit) = 500 mg; mild
other changes; Biochemical: Metabolism (Intermediary): effect on inflammation or Eye Irritancy (rabbit) = 100 mg; severe
mediation of inflammation Eye Irritancy (rabbit) = 16 mg
TCLo (Inhalation-Mouse) 1 mg/m3/13 weeks-intermittent: Lungs, Thorax, or Respiration: Eye Irritancy (rabbit) = 10 mg; moderate
other changes, changes in lung weight; Biochemical: Metabolism (Intermediary): effect LD50 (oral, rat) = 5045 mg/kg
on inflammation or mediation of inflammation LD50 (oral, mouse) = 3600 mg/kg
TCLo (Inhalation-Mouse) 7 mg/m3/6 hours/13 weeks-intermittent: Sense Organs and LD50 (oral, rabbit) = 6410 mg/kg
Special Senses (Olfaction): effect, not otherwise specified; Biochemical: Metabolism LD50 (skin, rabbit) = 12,800 mg/kg
(Intermediary): effect on inflammation or mediation of inflammation LD50 (intravenous, rat) = 1099 mg/kg
TCLo (Inhalation-Hamster) 7 mg/m3/13 weeks-intermittent: Lungs, Thorax, or LD50 (intravenous, mouse) = 1509 mg/kg
Respiration: other changes; Biochemical: Metabolism (Intermediary): effect on LD50 (intravenous, rabbit) = 1184 mg/kg
inflammation or mediation of inflammation LD50 (intraperitoneal, rat) = 2735 mg/kg
TCLo (Inhalation-Hamster) 50 mg/m3/6 hours/13 weeks-intermittent: Sense Organs and LD50 (intraperitoneal, mouse) = 4477 mg/kg
Special Senses (Olfaction): effect, not otherwise specified LD50 (intraperitoneal, rabbit) = 667 mg/kg
TDLo (Oral-Mouse) 20,000 µg/kg/4 weeks-intermittent: Brain and Coverings: other LD50 (intraperitoneal, guinea pig) = 2560 mg/kg
degenerative changes; Biochemical: Metabolism (Intermediary): effect on LD50 (intraperitoneal, hamster) = 3444 mg/kg
inflammation or mediation of inflammation LDLo (oral, dog) = 1537 mg/kg; Gastrointestinal: nausea or vomiting
TDLo (Skin-Rat) 11 gm/kg/4 weeks-intermittent: Blood: pigmented or nucleated red LDLo (oral, cat) = 6 mL/kg
blood cells; Liver: changes in liver weight; Nutritional and Gross Metabolic: weight loss LCLo (inhalation, rat) = 16,000 ppm/4 hours
or decreased weight gain LCLo (inhalation, mouse) = 12,800 ppm/3 hours
TDLo (Intravenous-Rat) 10 mg/kg/2 minutes: Liver: changes in liver weight; Blood: LDLo (intravenous, cat) = 1963 mg/kg
changes in spleen LDLo (parenteral, frog) = 20 g/kg; Peripheral Nerve and Sensation: spastic paralysis with
TDLo (Intravenous-Rat) 10 mg/kg/2 minutes: Biochemical: Enzyme inhibition, induction, or without sensory change; Behavioral: somnolence (general depressed activity)
or change in blood or tissue levels: hepatic microsomal mixed oxidase (dealkylation, LDLo (subcutaneous, mouse) = 6000 mg/kg
hydroxylation, etc.) TDLo (Intratracheal-Rat) 16 mg/kg: Lungs, Thorax, or Respiration: LDLo (intravenous, dog) = 5120 mg/kg
other changes; Biochemical: Metabolism (Intermediary): effect on inflammation or TDLo (oral, rat) = 6480 mg/kg/male 26 weeks pre; Reproductive effects
mediation of inflammation TCLo (inhalation, rat) = 10,000 ppm/7 hours/female 1–19 days post; Teratogenic
TDLo (Intratracheal-Rat) 15 mg/kg: Lungs, Thorax, or Respiration: other changes; effects
Biochemical: Enzyme inhibition, induction, or change in blood or tissue levels: Cytogenetic Analysis (Saccharomyces cerevisiae) = 200 mmol/tube
cytochrome oxidases (including oxidative phosphorylation) Cytogenetic Analysis (inhalation, rat) = 1030 µg/m3/16 weeks/intermittent
CARCINOGENIC POTENTIAL OF COMPONENTS: Components of this product are listed by agencies tracking the
carcinogenic potential of chemical compounds, as follows;
CARBON BLACK: ACGIH TLV-A3 (Confirmed Animal Carcinogen), IARC-2B (Possibly Carcinogenic to Humans); MAK-3B (Substances for Which in vitro tests or Animal
Studies Have Yielded Evidence Of Carcinogenic Effects That is Not Sufficient for Classification of the Substance In One of the Other Categories. Further studies are required
before a final classification can be made. A MAK or BAT value can be established, provided no genotoxic effects have been detected.); NIOSH-Ca (Potential Occupational
Carcinogen with No Further Categorization * In presence of PAHs)
ISOPROPYL ALCOHOL: ACGIH TLV-A4 (Not Classifiable as a Human Carcinogen); IARC-3 (Not Classifiable as to Carcinogenicity to Humans)
The remaining components of this product are not found on the following lists: U.S. EPA, U.S. NTP, U.S. OSHA, U.S.
NIOSH, GERMAN MAK, IARC, and ACGIH, and therefore are neither considered to be nor suspected to be cancer-
causing agents by these agencies.
IRRITANCY OF PRODUCT: Acute exposure to this product via eye contact may irritate contaminated eyes. Acute exposure
to this product via skin contact and inhalation may mildly irritate contaminated tissue, especially if exposure is prolonged.
SENSITIZATION TO THE PRODUCT: The components of this product are not known to be human skin or respiratory
sensitizers.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of components of this
product on the human reproductive system.
Mutagenicity: No data are available on possible mutagenic effects from this product or its components.
TATTOO PAINT NO. BLK SDS
Page 6 of 11
11. TOXICOLOGICAL INFORMATION (Continued)
REPRODUCTIVE TOXICITY INFORMATION (continued):
Embryotoxicity: The components of this product are not reported to produce embryotoxic effects in humans. The Isopropyl Alcohol
component has produced fetotoxicity (reduced fetal weight) in rats exposed by inhalation, in the absence of maternal toxicity.
Reduced survival in the early postnatal period has been observed in the offspring of rats exposed to high oral doses, in the
presence of minimal maternal toxicity. Rats were exposed by inhalation to 0, 3500, 7000 or 10000 ppm during days 1-19 of
pregnancy. Maternal toxicity was observed at the 2 high doses, but not at 3500 ppm. Fetal weights were significantly reduced in a
concentration related manner at all treatment levels. At 7000 and 10000 ppm, teratogenicity and/or embryotoxicity were observed.
Teratogenicity: No data are available on possible teratogenic effects from this product and its components.
Reproductive Toxicity: The components of this product are not reported to cause reproductive effects in humans. In a two-generation
study of Isopropyl Alcohol, rats were orally dosed with 0, 100, 500 or 1000 mg/kg/day for 10 weeks prior to mating. Females were
dosed during mating, gestation and lactation and males were dosed during mating through delivery of the last litter sired. In the first
generation, a significant reduction was observed in the live birth index and the survival index on days 1 and 4 for the offspring of
animals exposed to 1000 mg/kg/day, as well as the survival rate of off-spring. Only minimal maternal toxicity (increased liver
weight) was observed at 500 mg/kg/day. At 1000 mg/kg/day, 2/30 females in the first generation (P1) and 2/26 females died in the
second generation.
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
MOBILITY: This product has not been tested for mobility in soil. It is expected to be somewhat mobile in soil. The following
information is available for the Isopropyl Alcohol component.
ISOPROPYL ALCOHOL: The Koc of Isopropyl Alcohol is estimated as 25, using a measured log Kow of 0.05 and a regression-derived equation. According to a classification scheme,
this estimated Koc value suggests that Isopropyl Alcohol is expected to have very high mobility in soil.
PERSISTENCE AND BIODEGRADABILITY: This product has e not been tested for persistence or biodegradability. It is
expected that some biodegradation will occur to this product; however, no specific information is known. The following
information is available for the Isopropyl Alcohol component.
ISOPROPYL ALCOHOL: Based on a classification scheme, an estimated Koc value of 25, determined from a log Kow of 0.05 and a regression-derived equation, indicates that
Isopropyl Alcohol is expected to have very high mobility in soil. Volatilization of Isopropyl Alcohol from moist soil surfaces is expected to be an important fate process given a Henry's
Law constant of 8.10X10-6 atm-cu m/mole. The potential for volatilization of Isopropyl Alcohol from dry soil surfaces may exist based upon a vapor pressure of 45.4 mmHg. Isopropyl
Alcohol is readily degraded in aerobic systems; the range of half-lives for aerobic degradation using a sewage sludge inoculum are < 1 day to 48 days. Isopropyl Alcohol has also
been shown to be readily degraded under anaerobic conditions. Volatilization from water surfaces is expected based upon a Henry's Law constant of 8.10X10-6 atm-cu m/mole.
Using this Henry's Law constant and an estimation method, volatilization half-lives for a model river and model lake are 57 hours and 29 days, respectively. Isopropyl Alcohol is
readily degraded in aerobic systems; the range of half-lives for aerobic degradation using a sewage sludge inoculum are < 1 day to 48 days. Isopropyl Alcohol has also been shown to
be readily degraded under anaerobic conditions. According to a model of gas/particle partitioning of semi-volatile organic compounds in the atmosphere, Isopropyl Alcohol, which has
a vapor pressure of 45.4 mm Hg at 25°C, is expected to exist solely as a vapor in the ambient atmosphere. Vapor-phase Isopropyl Alcohol is degraded in the atmosphere by reaction
with photochemically-produced hydroxyl radicals; the half-life for this reaction in air is estimated to be 3.2 days, calculated from its rate constant of 5.07X10-12 cu cm/molecule-sec at
25°C.
BIO-ACCUMULATION POTENTIAL: This product has not been tested for bio-accumulation potential. The following
information is available for the Isopropyl Alcohol component.
ISOPROPYL ALCOHOL: An estimated BCF of 3 was calculated for Isopropyl Alcohol, using a log Kow of 0.05 and a regression-derived equation. According to a classification scheme,
this BCF suggests the potential for bioconcentration in aquatic organisms is low.
ECOTOXICITY: This product has not been tested for the effects of this product on terrestrial or aquatic organisms if
released to the environment. Plants may be discolored and damaged (depending on the severity of the contamination). The
following aquatic toxicity data are available for the Isopropyl Alcohol component (not all available data are given in the SDS.
Contact Dynamic Color for information on other available data) .
ISOPROPYL ALCOHOL: ISOPROPYL ALCOHOL (continued):
EC50 (Daphnia magna) 3,010 mg/L LC50 (Brachionus calyciflorus) 24 hours = 28,600 mg/L
LC50 (Artemia salina) 24 hours = 16,700 mg/L LC50 (Crangon crangon brown shrimp) 98 hours = 1,150 mg/L
LC50 (Streptocephalus proboscideus) 24 hours = 11,600 mg/L LC50 (goldfish) 24 hours = > 500 mg/L
LC50 (Daphnia magna) 24 hours = 9,500 mg/L LC50 (fathead minnow) 96 hours = 11,130 mg/L
RESULTS OF PBT AND vPvB ASSESSMENT: No data available. PBT and vPvB assessments are part of the chemical
safety report required for some substances in European Union Regulation (EC) 1907/2006, Article 14.
OTHER ADVERSE EFFECTS: This product does not contain any constituents with known ozone depletion potential.
ENVIRONMENTAL EXPOSURE CONTROLS: Controls should be engineered to prevent release to the environment,
including procedures to prevent spills, atmospheric release and release to waterways.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS: It is the responsibility of the generator to determine at the time of disposal whether the product
meets the criteria of a hazardous waste per regulations of the area in which the waste is generated and/or disposed of.
Waste disposal must be in accordance with appropriate Federal, State, and local regulations. This product, if unaltered by
use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.
Shipment of wastes must be done with appropriately permitted and registered transporters.
DISPOSAL CONTAINERS: Waste materials must be placed in and shipped in appropriate 5-gallon or 55-gallon poly or
metal waste pails or drums. Permeable cardboard containers are not appropriate and should not be used. Ensure that any
required marking or labeling of the containers be done to all applicable regulations.
PRECAUTIONS TO BE FOLLOWED DURING WASTE HANDLING: Wear proper protective equipment when handling
waste materials.
U.S. EPA WASTE NUMBER: Not applicable to wastes consisting only of this product.
EUROPEAN WASTE CODES: Wastes from MFSU and Removal of Printing Inks: 08 03 99: Wastes Not Otherwise
Specified
TATTOO PAINT NO. BLK SDS
Page 7 of 11
14. TRANSPORTATION INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION: This product is not classified as dangerous goods, per U.S. DOT regulations,
under 49 CFR 172.101.
TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is NOT classified
as dangerous goods, per regulations of Transport Canada.
INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA): This product is NOT classified as
dangerous goods.
INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO): This product is NOT classified as
dangerous goods.
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
(ADR): This product is NOT classified by the United Nations Economic Commission for Europe to be dangerous goods.
AUSTRALIAN FEDERAL OFFICE OF ROAD SAFETY CODE FOR THE TRANSPORTATION OF DANGEROUS GOODS
BY ROAD OR RAIL: This product is NOT classified as dangerous goods, per regulations of the Australian Federal Office of
Road Safety.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE: Not applicable.
ENVIRONMENTAL HAZARDS: This product is neither environmentally hazardous according to the criteria of the UN
Model Regulations (as reflected in the IMDG Code, ADR, RID, and ADN); no component meets the criteria of
environmentally hazardous.
15. REGULATORY INFORMATION
UNITED STATES REGULATIONS:
U.S. SARA Reporting Requirements: The components of this product are subject to the reporting requirements of Sections 302, 304,
and 313 of Title III of the Superfund Amendments and Reauthorization Act and are listed as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Isopropyl Alcohol (mfg-strong acid process) No No Yes
U.S. SARA Threshold Planning Quantity (TPQ): There are no specific Threshold Planning Quantities for this material. The default
Federal SDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply, per 40 CFR 370.20.
U.S. CERCLA Reportable Quantity (RQ): Not applicable.
U.S. TSCA Inventory Status: The components of this product are listed on the TSCA Inventory.
U.S. Hazardous Air Pollutant (HAPs): The components of this product are not listed by the EPA under section 112(b) of the Clean Air
Act as a ‘HAP’.
Other U.S. Federal Regulations: Not applicable.
California Safe Drinking Water And Toxic Enforcement Act (Proposition 65): The Carbon Black component, (airborne, unbound particles
of respirable size) is on the California Proposition 65 Lists. If airborne particles of this product are generated, the following warning
must be on packaging and labeling of this product: WARNING! This product contains a component known to the State of California
to cause cancer. As a liquid, this warning is not expected to be required.
CANADIAN REGULATIONS:
Canadian DSL/NDSL Inventory Status: Components listed by CAS# in Section 3 (Composition and Information on Ingredients) are
listed on the DSL Inventory.
Canadian Environmental Protection Act (CEPA) Priority Substances Lists: The Isopropyl Alcohol component is listed as a Substance
With Greatest Potential For Human Exposure Substance on Environment Canada/Health Canada Pilot Project List (CEPA 1999,
Section 73). Meets categorization criteria: *may present, to individuals in Canada, the greatest potential for exposure; or *are
persistent or bioaccumulative in accordance with the regulations, and inherently toxic to human beings or to non-human organisms,
as determined by laboratory or other studies.
Canadian WHMIS HPR 2015 Classification and Symbols: See the following section for classification and symbols under WHMIS.
EUROPEAN UNION REGULATIONS:
Safety, Health, and Environmental Regulations/Legislation Specific for the Product: Currently, there is no specific legislation pertaining to
this product.
CHEMICAL SAFETY ASSESSMENT: No data available. The chemical safety assessment is required for some substances according
to European Union Regulation (EC) 1907/2006, Article 14.
AUSTRALIAN REGULATIONS:
Australian Inventory Of Chemical Substances (AICS) Status: Components listed by CAS# in Section 3 (Composition and Information
on Ingredients) are listed on the AICS.
Hazardous Substances Information System (HSIS): Components listed by CAS# in Section 3 (Composition and Information on
Ingredients) are not listed in the HSIS.
Standard for the Uniform Scheduling of Drugs and Poisons: Not applicable.
CHINESE REGULATIONS:
Chinese Inventory of Existing Chemical Substances Status: Components listed by CAS# in Section 3 (Composition and Information on
Ingredients) are on the Chinese Inventory of Existing Chemical Substances (IECSC).
JAPANESE REGULATIONS:
Japanese ENCS Inventory: Components listed by CAS# in Section 3 (Composition and Information on Ingredients) are on the ENCS
Inventory or are excepted.
Japanese Ministry of Economy, Trade, and Industry (METI) Status: Components listed by CAS# in Section 3 (Composition and
Information on Ingredients) are not listed as Class I Specified Chemical Substances, Class II Specified Chemical Substances, or
Designated Chemical Substances by the Japanese METI.
TATTOO PAINT NO. BLK SDS
Page 8 of 11
15. REGULATORY INFORMATION (Continued)
JAPANESE REGULATIONS (continued):
Poisonous and Deleterious Substances Control Law: Components listed by CAS# in Section 3 (Composition and Information on
Ingredients) are not listed as a Specified Poisonous Substance under the Poisonous and Deleterious Substances Control Law.
KOREAN REGULATIONS:
Korean Existing Chemical Substances Inventory Status: Components are listed on the Korean Existing Chemicals List, as indicated in
composition tables in Section 3 (Composition and Information on Ingredients).
NEW ZEALAND REGULATIONS:
New Zealand Inventory of Chemicals (NZIoC): Components listed by CAS# in Section 3 (Composition and Information on Ingredients)
are on the NZIoC.
MEXICAN REGULATIONS:
Mexican Workplace Regulations (NOM-018-STPS-2000): This product is not classified as hazardous.
TAIWANESE REGULATIONS:
Taiwan Existing Chemical Substances Inventory Status: Components listed by CAS# in Section 3 (Composition and Information on
Ingredients) are listed on the Taiwan Existing Chemicals List.
16. OTHER INFORMATION
ANSI LABELING (Z129.1): CAUTION! MAY CAUSE SERIOUS EYE IRRITATION. MAY CAUSE SKIN AND
RESPIRATORY TRACT IRRITATION. MAY DISCOLOR CONTAMINATED SKIN, EYES, HAIR, AND CLOTHES. Use with
adequate ventilation. Avoid contact of liquid with skin, eyes, and clothing. Avoid exposure to vapors, mists, or sprays.
Wash thoroughly after handling. Wear appropriate hand and eye protection. FIRST-AID: In case of contact, immediately
flush skin with plenty of water. Remove contaminated clothing and shoes. If inhaled, remove to fresh air. If swallowed, do
not induce vomiting. Get medical attention if irritation develops or persists or if any other adverse effect occurs. IN CASE
OF FIRE: Use water fog, dry chemical, or CO2, or alcohol foam. IN CASE OF SPILL: Absorb spill with inert materials (e.g.,
polypads, dry sand). Rinse area with soapy water. Consult Safety Data Sheet for additional information.
GLOBAL HARMONIZATION LABELING AND CLASSIFICATION: Classified in accordance with Global Harmonization
Standard under U.S. OSHA Hazard Communication Standard, Canadian WHMIS HPR-GHS 2-15, EU CLP Regulation
(EC) 1272/2008, Japanese JIS Z7253: 2012 and Singapore Standards. For information on Korean ISHA and New
Zealand HSNO classification, see below.
Classification: Eye Irritation, Category 2A
Hazard Statements: H319: Causes serious eye irritation.
Precautionary Statements:
Prevention: P264: Wash thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response: P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. P337 + P313: If eye irritation persists: get medical advice/attention.
Storage: None
Disposal: None
Signal Word: Warning
Hazard Symbols/Pictograms: GHS07
KOREAN ISHA (Notice 2009-68) LABELING AND CLASSIFICATION: Classified in accordance with ISHA Notice 2009-68.
Under ISHA, the following differences in classification are applicable. Refer to information given under the Global
Harmonization Standard Classification.
Classification: Eye Irritation, Category 2
Hazard Statement Codes: H319: Causes serious eye irritation.
Precautionary Statements:
Prevention: P264: Wash thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response: P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. P337 + P313: If eye irritation persists: get medical advice/attention.
Storage: None
Disposal: None
Signal Word: Warning
Hazard Symbols/Pictograms: GHS07
NEW ZEALAND HAZARDOUS SUBSTANCES and NEW ORGANISMS ACT (HNSO) CHEMICAL CLASSIFICATION:
The product is classified as follows under the regulation:
Classification:
6.4A: Irritation to the eye.
CLASSIFICATION INFORMATION FOR COMPONENTS:
CLP Regulation (EC) 1272/2008
Carbon Black:
Classification: Carcinogenic Category 2
Hazard Statements: H350i: May cause cancer by inhalation.
Isopropyl Alcohol:
Classification: Flammable Liquid Category 2, Eye Irritant Category 2A, Specific Target Organ Toxicity (Inhalation-Central Nervous System) Single
Exposure Category 3
Hazard Statements: H225: Highly flammable liquid and vapour. H319: Causes serious eye irritation. H336: May cause drowsiness or dizziness.
All Remaining Components:
Classification: An official classification for this substance has not been published under CLP 1272/2008 and a self-classification is not applicable.
TATTOO PAINT NO. BLK SDS
Page 9 of 11
16. OTHER INFORMATION
CLASSIFICATION INFORMATION FOR COMPONENTS (continued):
NEW ZEALAND HAZARDOUS SUBSTANCES and NEW ORGANISMS ACT (HNSO) CHEMICAL CLASSIFICATION:
Carbon Black:
Classification: 6.3B: Mildly irritating to the skin. 6.4A: Irritating to the eye. 6.7B: Suspected human carcinogen.
Isopropyl Alcohol:
Classification: 3.1B: Flammable liquids: high hazard. 6.1E (oral): Substances that are acutely toxic. 6.3C: Mildly irritating to the skin. 6.4A: Irritating
to the eye.
REVISION DETAILS: May 2017: Conversion of old MSDS to GHS compliant SDS.
REFERENCES AND DATA SOURCES: Contact the supplier for information.
METHODS OF EVALUATING INFORMATION FOR THE PURPOSE OF CLASSIFICATION: Bridging principles were used to classify this product.
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc., PO Box 1961, Hilo, HI 96721, 800/441-3365
DATE OF PRINTING: August 17, 2018
The data in this Safety Data Sheet is true and accurate to the best of Dynamic Color Company’s knowledge. However, since data, safety standards, and government regulations are subject to change
conditions of handling, use, or misuse are beyond the control of Dynamic Color, Dynamic Color Company MAKES NO WARRANTY, EITHER EXPRESSED OR IMPLIED, WITH RESPECT TO THE
COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN AND DISCLAIMS ALL LIABILITY FOR RELIANCE THEREON. The user is required to comply with all
laws and regulations relating to the purchase, use, storage, and disposal of the product. User must be familiar with and follow generally accepted safe handling procedures of chemicals, and is solely
responsible for any effects caused by its misuse or mixing of this chemical with any other substance.
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a SDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies each constituent. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD
EXPOSURE LIMITS IN AIR: RATINGS (continued):
CEILING LEVEL: The concentration that shall not be exceeded during any part of the working HEALTH HAZARD (continued): 3 (Serious Hazard) [continued]: Eye Irritation: Corrosive,
exposure. irreversible destruction of ocular tissue; corneal involvement or irritation persisting for more than 21
DFG MAK Germ Cell Mutagen Categories: 1: Germ cell mutagens which have been shown to days. Draize > 80 with effects irreversible in 21 days. Oral Toxicity LD50 Rat: > 1-50 mg/kg. Dermal
increase the mutant frequency in the progeny of exposed humans. 2: Germ cell mutagens which Toxicity LD50Rat or Rabbit: > 20-200 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.05-0.5 mg/L.); 4
have been shown to increase the mutant frequency in the progeny of exposed mammals. 3A: (Severe Hazard: Life-threatening; major or permanent damage may result from single or repeated
Substances which have been shown to induce genetic damage in germ cells of human of animals, or exposure. Skin Irritation: Not appropriate. Do not rate as a “4”, based on skin irritation alone. Eye
which produce mutagenic effects in somatic cells of mammals in vivo and have been shown to reach Irritation: Not appropriate. Do not rate as a “4”, based on eye irritation alone. Oral Toxicity LD50 Rat:
the germ cells in an active form. 3B: Substances which are suspected of being germ cell mutagens < 1 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05
because of their genotoxic effects in mammalian somatic cell in vivo; in exceptional cases, substances mg/L).
for which there are no in vivo data, but which are clearly mutagenic in vitro and structurally related to FLAMMABILITY HAZARD: 0 (Minimal Hazard-Materials that will not burn in air when exposure to a
known in vivo mutagens. 4: Not applicable (Category 4 carcinogenic substances are those with non- temperature of 815.5°C [1500°F] for a period of 5 minutes.); 1 (Slight Hazard-Materials that must be
genotoxic mechanisms of action. By definition, germ cell mutagens are genotoxic. Therefore, a pre-heated before ignition can occur. Material require considerable pre-heating, under all ambient
Category 4 for germ cell mutagens cannot apply. At some time in the future, it is conceivable that a temperature conditions before ignition and combustion can occur, Including: Materials that will burn in
Category 4 could be established for genotoxic substances with primary targets other than DNA [e.g. air when exposed to a temperature of 815.5°C (1500°F) for a period of 5 minutes or less; Liquids,
purely aneugenic substances] if research results make this seem sensible.) 5: Germ cell mutagens,
solids and semisolids having a flash point at or above 93.3°C [200°F] (e.g. OSHA Class IIIB, or; Most
the potency of which is considered to be so low that, provided the MAK value is observed, their
ordinary combustible materials [e.g. wood, paper, etc.]; 2 (Moderate Hazard-Materials that must be
contribution to genetic risk for humans is expected not to be significant.
moderately heated or exposed to relatively high ambient temperatures before ignition can occur.
DFG MAK Pregnancy Risk Group Classification: Group A: A risk of damage to the developing
Materials in this degree would not, under normal conditions, form hazardous atmospheres in air, but
embryo or fetus has been unequivocally demonstrated. Exposure of pregnant women can cause
under high ambient temperatures or moderate heating may release vapor in sufficient quantities to
damage of the developing organism, even when MAK and BAT (Biological Tolerance Value for
produce hazardous atmospheres in air, Including: Liquids having a flash-point at or above 37.8°C
Working Materials) values are observed. Group B: Currently available information indicates a risk of
damage to the developing embryo or fetus must be considered to be probable. Damage to the [100°F]; Solid materials in the form of course dusts that may burn rapidly but that generally do not form
developing organism cannot be excluded when pregnant women are exposed, even when MAK and explosive atmospheres; Solid materials in a fibrous or shredded form that may burn rapidly and create
BAT values are observed. Group C: There is no reason to fear a risk of damage to the developing flash fire hazards (e.g. cotton, sisal, hemp; Solids and semisolids that readily give off flammable
embryo or fetus when MAK and BAT values are observed. Group D: Classification in one of the vapors.); 3 (Serious Hazard- Liquids and solids that can be ignited under almost all ambient
groups A-C is not yet possible because, although the data available may indicate a trend, they are not temperature conditions. Materials in this degree produce hazardous atmospheres with air under
sufficient for final evaluation. almost all ambient temperatures, or, unaffected by ambient temperature, are readily ignited under
IDLH-Immediately Dangerous to Life and Health: This level represents a concentration from which almost all conditions, including: Liquids having a flash point below 22.8°C [73°F] and having a boiling
one can escape within 30-minutes without suffering escape-preventing or permanent injury. point at or above 38°C [100°F] and below 37.8°C [100°F] [e.g. OSHA Class IB and IC]; Materials that
LOQ: Limit of Quantitation. on account of their physical form or environmental conditions can form explosive mixtures with air and
MAK: Federal Republic of Germany Maximum Concentration Values in the workplace. are readily dispersed in air [e.g., dusts of combustible solids, mists or droplets of flammable liquids];
NE: Not Established. When no exposure guidelines are established, an entry of NE is made for Materials that burn extremely rapidly, usually by reason of self-contained oxygen [e.g. dry
reference. nitrocellulose and many organic peroxides]); 4 (Severe Hazard-Materials that will rapidly or completely
NIC: Notice of Intended Change. vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air,
NIOSH CEILING: The exposure that shall not be exceeded during any part of the workday. If and which will burn readily, including: Flammable gases; Flammable cryogenic materials; Any liquid or
instantaneous monitoring is not feasible, the ceiling shall be assumed as a 15-minute TWA exposure gaseous material that is liquid while under pressure and has a flash point below 22.8°C [73°F] and a
(unless otherwise specified) that shall not be exceeded at any time during a workday. boiling point below 37.8°C [100°F] [e.g. OSHA Class IA; Material that ignite spontaneously when
NIOSH RELs: NIOSH’s Recommended Exposure Limits. exposed to air at a temperature of 54.4°C [130°F] or below [e.g. pyrophoric]).
PEL-Permissible Exposure Limit: OSHA’s Permissible Exposure Limits. This exposure value PHYSICAL HAZARD: 0 (Water Reactivity: Materials that do not react with water. Organic Peroxides:
means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Materials that are normally stable, even under fire conditions and will not react with water. Explosives:
Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Substances that are Non-Explosive. Unstable Compressed Gases: No Rating. Pyrophorics: No
Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are Rating. Oxidizers: No “0” rating allowed. Unstable Reactives: Substances that will not polymerize,
indicated. The phrase, “Vacated 1989 PEL,” is placed next to the PEL that was vacated by Court decompose, condense or self-react.); 1 (Water Reactivity: Materials that change or decompose upon
Order. exposure to moisture. Organic Peroxides: Materials that are normally stable, but can become
SKIN: Used when a there is a danger of cutaneous absorption. unstable at high temperatures and pressures. These materials may react with water, but will not
STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a 15-minute time-weighted release energy. Explosives: Division 1.5 & 1.6 substances that are very insensitive explosives or that
average (TWA) exposure that should not be exceeded at any time during a workday, even if the 8-hr do not have a mass explosion hazard. Compressed Gases: Pressure below OSHA definition.
TWA is within the TLV-TWA, PEL-TWA or REL-TWA. Pyrophorics: No Rating. Oxidizers: Packaging Group III; Solids: any material that in either
TLV-Threshold Limit Value: An airborne concentration of a substance that represents conditions concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a
under which it is generally believed that nearly all workers may be repeatedly exposed without adverse 3:7 potassium bromate/cellulose mixture and the criteria for Packing Group I and II are not met.
effect. The duration must be considered, including the 8-hour. Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise
TWA-Time Weighted Average: Time Weighted Average exposure concentration for a conventional time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing Group I and II are not met.
8-hr (TLV, PEL) or up to a 10-hr (REL) workday and a 40-hr workweek. Unstable Reactives: Substances that may decompose, condense or self-react, but only under
conditions of high temperature and/or pressure and have little or no potential to cause significant heat
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD generation or explosive hazard. Substances that readily undergo hazardous polymerization in the
RATINGS: This rating system was developed by the National Paint and Coating Association and absence of inhibitors.); 2 (Water Reactivity: Materials that may react violently with water. Organic
has been adopted by industry to identify the degree of chemical hazards. Peroxides: Materials that, in themselves, are normally unstable and will readily undergo violent
HEALTH HAZARDS: 0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not chemical change, but will not detonate. These materials may also react violently with water.
anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = “0”. Eye Irritation: Essentially Explosives: Division 1.4 – Explosive substances where the explosive effect are largely confined to the
non-irritating, or minimal effects which clear in < 24 hours [e.g. mechanical irritation]. Draize = “0”. package and no projection of fragments of appreciable size or range are expected. An external fire
Oral Toxicity LD50 Rat: < 5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 2000 mg/kg. Inhalation must not cause virtually instantaneous explosion of almost the entire contents of the package.
Toxicity 4-hrs LC50 Rat: < 20 mg/L.); 1 (Slight Hazard): Minor reversible Injury may occur; slightly or Compressed Gases: Pressurized and meet OSHA definition but < 514.7 psi absolute at 21.1°C (70°F)
mildly irritating. Skin Irritation: Slightly or mildly irritating. Eye Irritation: Slightly or mildly irritating. Oral [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group II Solids: any material that, either in
Toxicity LD50 Rat: > 500-5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 1000-2000 mg/kg. concentration tested, exhibits a mean burning time of less than or equal to the mean burning time of a
Inhalation Toxicity LC50 4-hrs Rat: > 2-20 mg/L); 2 (Moderate Hazard): Temporary or transitory injury 2:3 potassium bromate/cellulose mixture and the criteria for Packing Group I are not met. Liquids:
may occur. Skin Irritation: Moderately irritating; primary irritant; sensitizer. PII or Draize > 0, < 5. Eye any material that exhibits a mean pressure rise time less than or equal to the pressure rise of a 1:1
Irritation: Moderately to severely irritating and/or corrosive; reversible corneal opacity; corneal aqueous sodium chlorate solution (40%)/cellulose mixture and the criteria for Packing Group I are not
involvement or irritation clearing in 8-21 days. Draize > 0, < 25. Oral Toxicity LD50 Rat: > 50-500 met. Unstable Reactives: Substances that may polymerize, decompose, condense, or self-react at
mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 200-1000 mg/kg. 3 (Serious Hazard): Major injury likely ambient temperature and/or pressure, but have a low potential for significant heat generation or
unless prompt action is taken and medical treatment is given; high level of toxicity; corrosive. Skin explosion. Substances that readily form peroxides upon exposure to air or oxygen at room
Irritation: Severely irritating and/or corrosive; may destroy dermal tissue, cause skin burns, dermal temperature);
necrosis. PII or Draize > 5-8 with destruction of tissue.
TATTOO PAINT NO. BLK SDS
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DEFINITIONS OF TERMS (Continued)
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS
RATINGS (continued): (continued):
PHYSICAL HAZARD (continued): 3 (Water Reactivity: Materials that may form explosive reactions FLAMMABILITY HAZARD (continued): 3 (continued): Liquids having a flash point below 22.8°C
with water. Organic Peroxides: Materials that are capable of detonation or explosive reaction, but (73°F) and having a boiling point at or above 37.8°C (100°F) and those liquids having a flash point
require a strong initiating source, or must be heated under confinement before initiation; or materials at or above 22.8°C (73°F) and below 37.8°C (100°F) and below 37.8°C (100°F) (i.e. Class IB and
that react explosively with water. Explosives: Division 1.2 – Explosive substances that have a fire IC liquids). Materials that, on account of their physical form or environmental conditions, can form
hazard and either a minor blast hazard or a minor projection hazard or both, but do not have a mass explosive mixtures with air and are readily dispersed in air. Flammable or combustible dusts with a
explosion hazard. Compressed Gases: Pressure > 514.7 psi absolute at 21.1°C (70°F) [500 psig]. representative diameter less than 420 microns (40 mesh). Materials that burn with extreme
Pyrophorics: No Rating. Oxidizers: Packing Group I Solids: any material that, in either concentration rapidity, usually by reason of self-contained oxygen (e.g. dry nitrocellulose and many organic
tested, exhibits a mean burning time less than the mean burning time of a 3.:2 potassium peroxides). Solids containing greater than 0.5 percent by weight of a flammable or combustible
bromate/cellulose mixture. Liquids: Any material that spontaneously ignites when mixed with cellulose solvent are rated by the closed cup flash point of the solvent. 4 Materials that will rapidly or
in a 1:1 ratio, or which exhibits a mean pressure rise time less than the pressure rise time of a 1:1 completely vaporize at atmospheric pressure and normal ambient temperature or that are readily
perchloric acid (50%)/cellulose mixture. Unstable Reactives: Substances that may polymerize, dispersed in air and will burn readily: Flammable gases. Flammable cryogenic materials. Any
decompose, condense or self-react at ambient temperature and/or pressure and have a moderate liquid or gaseous materials that is liquid while under pressure and has a flash point below 22.8°C
potential to cause significant heat generation or explosion.); 4 (Water Reactivity: Materials that react (73°F) and a boiling point below 37.8°C (100°F) (i.e. Class IA liquids). Materials that ignite when
explosively with water without requiring heat or confinement. Organic Peroxides: Materials that are exposed to air, Solids containing greater than 0.5 percent by weight of a flammable or combustible
readily capable of detonation or explosive decomposition at normal temperature and pressures. solvent are rated by the closed cup flash point of the solvent.
Explosives: Division 1.1 & 1.2-explosive substances that have a mass explosion hazard or have a INSTABILITY HAZARD: 0 Materials that in themselves are normally stable, even under fire
projection hazard. A mass explosion is one that affects almost the entire load instantaneously. conditions: Materials that have an estimated instantaneous power density (product of heat of reaction
Compressed Gases: No Rating. Pyrophorics: Add to the definition of Flammability “4”. Oxidizers: and reaction rate) at 250°C (482°F) below 0.01 W/mL. Materials that do not exhibit an exotherm at
No “4” rating. Unstable Reactives: Substances that may polymerize, decompose, condense or self- temperatures less than or equal to 500°C (932°F) when tested by differential scanning calorimetry. 1
react at ambient temperature and/or pressure and have a high potential to cause significant heat Materials that in themselves are normally stable, but that can become unstable at elevated
generation or explosion.). temperatures and pressures: Materials that have an estimated instantaneous power density (product
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS: of heat of reaction and reaction rate) at 250°C (482°F) at or above 0.01 W/mL and below 10 W/mL. 2
HEALTH HAZARD: 0 (materials that, under emergency conditions, would offer no hazard beyond that Materials that readily undergo violent chemical change at elevated temperatures and pressures:
of ordinary combustible materials): Gases and vapors whose LC50 for acute inhalation toxicity is Materials that have an estimated instantaneous power density (product of heat of reaction and reaction
greater than 10,000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity is greater than rate) at 250°C (482°F) at or above 10 W/mL and below 100W/mL. 3 Materials that in themselves
200 mg/L. Materials whose LD50 for acute dermal toxicity is greater than 2000 mg/kg. Materials are capable of detonation or explosive decomposition or explosive reaction, but that require a
whose LD50 for acute oral toxicity is greater than 2000 mg/kg. Materials that are essentially non- strong initiating source or that must be heated under confinement before initiation: Materials that
irritating to the respiratory tract, eyes and skin. 1 (materials that, under emergency conditions, can have an estimated instantaneous power density (product of heat of reaction and reaction rate) at
cause significant irritation): Gases and vapors whose LC50 for acute inhalation toxicity is greater 250°C (482°F) at or above 100 W/mL and below 1000 W/mL. Materials that are sensitive to thermal or
than 5,000 ppm but less than or equal to 10,000 ppm. Dusts and mists whose LC50 for acute mechanical shock at elevated temperatures and pressures. 4 Materials that in themselves are
inhalation toxicity is greater than 10 mg/L but less than or equal to 200 mg/L. Materials whose readily capable of detonation or explosive decomposition or explosive reaction at normal
LD50 for acute dermal toxicity is greater than 1000 mg/kg but less than or equal to 2000 mg/kg. temperatures and pressures: Materials that have an estimated instantaneous power density (product
Materials whose LD50 for acute oral toxicity is greater than 500 mg/kg but less than or equal to of heat of reaction and reaction rate) at 250°C (482°F) of 1000 W/mL or greater. Materials that are
2000 mg/kg. Materials that cause slight to moderate irritation to the respiratory tract, eyes and sensitive to localized thermal or mechanical shock at normal temperatures and pressures.
skin. 2 (materials that, under emergency conditions, can cause temporary incapacitation or residual FLAMMABILITY LIMITS IN AIR:
injury): Gases and vapors whose LC50 for acute inhalation toxicity is greater than 3,000 ppm but Much of the information related to fire and explosion is derived from the National Fire Protection
less than or equal to 5,000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity is Association (NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors
greater than 2 mg/L but less than or equal to 10 mg/L. Materials whose LD50 for acute dermal to form an ignitable mixture with air. Autoignition Temperature: The minimum temperature required to
toxicity is greater than 200 mg/kg but less than or equal to 1000 mg/kg. Materials whose LD50 for initiate combustion in air with no other source of ignition. LEL - the lowest percent of vapor in air, by
acute oral toxicity is greater than 50 mg/kg but less than or equal to 500 mg/kg. Any liquid whose volume, that will explode or ignite in the presence of an ignition source. UEL - the highest percent of
saturated vapor concentration at 20°C (68°F) is equal to or greater than one-fifth its LC50 for acute vapor in air, by volume, that will explode or ignite in the presence of an ignition source.
inhalation toxicity, if its LC50 is less than or equal to 5000 ppm and that does not meet the criteria
for either degree of hazard 3 or degree of hazard 4. Compressed liquefied gases with boiling TOXICOLOGICAL INFORMATION:
points between -30°C (-22°F) and -55°C (-66.5°F) that cause severe tissue damage, depending on Human and Animal Toxicology: Possible health hazards as derived from human data, animal
duration of exposure. Materials that are respiratory irritants. Materials that cause severe, but studies, or from the results of studies with similar compounds are presented. Definitions of some terms
reversible irritation to the eyes or are lachrymators. Materials that are primary skin irritants or used in this section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed animals;
sensitizers. 3 (materials that, under emergency conditions, can cause serious or permanent injury): LC50 - Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration
3
Gases and vapors whose LC50 for acute inhalation toxicity is greater than 1,000 ppm but less than expressed in parts of material per million parts of air or water; mg/m concentration expressed in
or equal to 3,000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity is greater than 0.5 weight of substance per volume of air; mg/kg quantity of material, by weight, administered to a test
mg/L but less than or equal to 2 mg/L. Materials whose LD50 for acute dermal toxicity is greater subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to
than 40 mg/kg but less than or equal to 200 mg/kg. Materials whose LD50 for acute oral toxicity is cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or
greater than 5 mg/kg but less than or equal to 50 mg/kg. Any liquid whose saturated vapor TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects.
concentration at 20°C (68°F) is equal to or greater than one-fifth its LC50 for acute inhalation Cancer Information: The sources are: IARC - the International Agency for Research on Cancer;
toxicity, if its LC50 is less than or equal to 3000 ppm and that does not meet the criteria for degree NTP - the National Toxicology Program, RTECS - the Registry of Toxic Effects of Chemical
of hazard 4. Compressed liquefied gases with boiling points between -30°C (-22°F) and -55°C (- Substances, OSHA and CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing
66.5°F) that cause frostbite and irreversible tissue damage. Materials that are respiratory irritants. potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used.
Cryogenic gases that cause frostbite and irreversible tissue damage. Materials that are corrosive Other Information: BEI - ACGIH Biological Exposure Indices, represent the levels of determinants
to the respiratory tract. Materials that are corrosive to the eyes or cause irreversible corneal which are most likely to be observed in specimens collected from a healthy worker who has been
opacity. Materials that are corrosive to the skin. 4 (materials that, under emergency conditions, can exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV.
be lethal): Gases and vapors whose LC50 for acute inhalation toxicity less than or equal to 1,000 REPRODUCTIVE TOXICITY INFORMATION:
ppm. Dusts and mists whose LC50 for acute inhalation toxicity is less than or equal to 0.5 mg/L. A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the
Materials whose LD50 for acute dermal toxicity is less than or equal to 40 mg/kg. Materials whose changes will propagate through generational lines. An embryotoxin is a chemical that causes damage
LD50 for acute oral toxicity is less than or equal to 5 mg/kg. Any liquid whose saturated vapor to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage
concentration at 20°C (68°F) is equal to or greater than one-fifth its LC50 for acute inhalation does not propagate across generational lines. A teratogen is a chemical that causes damage to a
toxicity, if its LC50 is less than or equal to 1000 ppm. developing fetus, but the damage does not propagate across generational lines. A reproductive toxin
FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire conditions, including is any substance that interferes in any way with the reproductive process.
intrinsically noncombustible materials such as concrete, stone, and sand: Materials that will not ECOLOGICAL INFORMATION:
burn in air when exposed to a temperature of 816°C (1500°F) for a period of 5 minutes in EC is the effect concentration in water. BCF = Bioconcentration Factor, which is used to determine if a
according with Annex D. 1 Materials that must be preheated before ignition can occur. Materials substance will concentrate in lifeforms which consume contaminated plant or animal matter. TLm =
in this degree require considerable preheating, under all ambient temperature conditions, before median threshold limit; Coefficient of Oil/Water Distribution is represented by log Kow or log Koc and
ignition and combustion can occur: Materials that will burn in air when exposed to a temperature is used to assess a substance’s behavior in the environment.
of 816°C (1500°F) for a period of 5 minutes in accordance with Annex D. Liquids, solids and
semisolids having a flash point at or above 93.4°C (200°F) (i.e. Class IIIB liquids). Liquids with a
REGULATORY INFORMATION:
U.S. and CANADA:
flash point greater than 35°C (95°F) that do not sustain combustion when tested using the Method
of Testing for Sustained Combustibility, per 49 CFR 173, Appendix H or the UN Recommendation ACGIH: American Conference of Governmental Industrial Hygienists, a professional association which
on the Transport of Dangerous Goods, Model Regulations (current edition) and the related Manual establishes exposure limits.
of Tests and Criteria (current edition). Liquids with a flash point greater than 35°C (95°F) in a This section explains the impact of various laws and regulations on the material. EPA is the U.S.
water-miscible solution or dispersion with a water non-combustible liquid/solid content of more than Environmental Protection Agency. NIOSH is the National Institute of Occupational Safety and Health,
85 percent by weight. Liquids that have no fire point when tested by ASTM D 92 Standard Test which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA).
Method for Flash and Fire Points by Cleveland Open Cup, up to a boiling point of the liquid or up to WHMIS is the Canadian Workplace Hazardous Materials Information System. DOT and TC are the
a temperature at which the sample being tested shows an obvious physical change. Combustible U.S. Department of Transportation and the Transport Canada, respectively. Superfund Amendments
pellets with a representative diameter of greater than 2 mm (10 mesh). Solids containing greater and Reauthorization Act (SARA); the Canadian Domestic/Non-Domestic Substances List
than 0.5 percent by weight of a flammable or combustible solvent are rated by the closed up flash (DSL/NDSL); the U.S. Toxic Substance Control Act (TSCA); Marine Pollutant status according to the
point of the solvent. Most ordinary combustible materials. 2 Materials that must be moderately DOT; the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA or
heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in Superfund); and various state regulations. This section also includes information on the
this degree would not under normal conditions form hazardous atmospheres with air, but under precautionary warnings which appear on the material’s package label. OSHA - U.S. Occupational
high ambient temperatures or under moderate heating could release vapor in sufficient quantities Safety and Health Administration.
to produce hazardous atmospheres with air: Liquids having a flash point at or above 37.8°C EUROPEAN and INTERNATIONAL:
(100°F) and below 93.4°C (200°F) (i.e. Class II and Class IIIA liquids.) Solid materials in the form The DFG: This is the Federal Republic of Germany’s Occupation Health Agency, similar to the U.S.
of powders or coarse dusts of representative diameter between 420 microns (40 mesh) and 2 mm OSHA. EU is the European Union (formerly known as the EEC, European Economic Community).
(10 mesh) that burn rapidly but that generally do not form explosive mixtures in air. Solid materials EINECS: This is the European Inventory of Now-Existing Chemical Substances. The ARD is the
in fibrous or shredded form that burn rapidly and create flash fire hazards, such as cotton, sisal European Agreement Concerning the International Carriage of Dangerous Goods by Road and the
and hemp. Solids and semisolids that readily give off flammable vapors. Solids containing greater RID are the International Regulations Concerning the Carriage of Dangerous Goods by Rail. AICS is
than 0.5 percent by weight of a flammable or combustible solvent are rated by the closed cup flash the Australian Inventory of Chemical Substances. METI is the Japanese Ministry of Economy, Trade,
point of the solvent. 3 Liquids and solids that can be ignited under almost all ambient temperature and Industry.
conditions. Materials in this degree produce hazardous atmospheres with air under almost all
ambient temperatures or, though unaffected by ambient temperatures, are readily ignited under
almost all conditions:
TATTOO PAINT NO. BLK SDS
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