Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_NUCLEUS & STERLING BT WTA-22/WTA-17 Date: 08-10-2023
Time: 09:00AM to 12:00PM JEE-ADV_(2021-P2) Max. Marks: 180

KEY SHEET
PHYSICS
1 ABC 2 ABD 3 AC 4 C 5 ABC 6 BC

7 10 8 1 9 0.11 10 12.45 11 54 12 2

13 D 14 C 15 C 16 B 17 4 18 4

19 2

CHEMISTRY
20 ABC 21 ABC 22 ABCD 23 ABD 24 AC 25 CD

26 60 27 30 28 6 29 1 30 3 31 3

32 C 33 C 34 D 35 C 36 8 37 8

38 2

MATHEMATICS
39 BD 40 ABCD 41 AC 42 BCD 43 ABD 44 BC

45 12 46 45 47 4 48 120 49 5 50 0

51 D 52 A 53 C 54 C 55 1 56 2

57 8
 Sri Chaitanya IIT Academy 08-10-2023_Jr.Su60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-22/WTA-17_Key & Sol’s

SOLUTIONS
PHYSICS
1. From first law of thermodynamics,
Q  W  U
For an isothermal process, Q = W, slope of W – Q graph is 1, hence straight line 3
represents an isothermal process.
For an isobaric process,
W  R T
 f 2
Q  C p T    RT
 2 
Where f is the number of degrees of freedom. Slope of W versus Q line is
W 2

Q f 2
For monatomic gas f  3 and for diatomic gas f  5 . Thus slope of the straight line
representing the W versus Q is 2/5 for a monatomic gas and 2/7 for a diatomic gas.
Straight line 1 corresponds to a monatomic gas and straight line 2 corresponds to a
diatomic gas.
In an isochoric process work done is zero, the corresponding straight line coincide with
the horizontal axis.
In an adiabatic process heat is not absorbed, the corresponding straight line coincide
with the vertical axis.
2. Conceptual
3. Conceptual
4. Conceptual
5. Conceptual
6. Conceptual
7. Since, no heat exchange takes place, so the gas expands adiabatically.
P1 T   cons tan t
1
P  
 T2  T1  1 
 P2 
5
where, T1  T0 , P1  P0  l gH , P2  P0  l g  H  y  and  
3
5
1
3
 P0  l gH  5
 T2  T0   3
 P0  l g  H  y  

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8. Buoyant Force FB  V g
l
nRT nRT2
Since, V  
P  P0  l g  H  y  
Substituting the value of T2 , V , we get
l nRgT0
FB 
2 3

 P0  l gH  5 P0  l g  H  y  5 
9. At B: PB  2.5  105 N / m 2
VB  2V  2  20  103  0.04 m3
TB  600 K
Now TB  600 K
1
 TB   1
VC  VB    0.04  2 2  0.113 m3
 TC 
10.  
Work done WAB  PV  2.5  105   40  20   103  5000 J
nR
WBC 
 1
TB  TC 
2  8.3
 600  300  7450 J
5 
  1
3 
Total work done W  WAB  WBC  12450 J
11. Given P  V ….(i)
V V
The work done in the process W   PdV   VdV
V V
V 2 2

2

 1 
R
The change in internal energy U  nCV T  1 T f  Ti 
 1  
 Pf V f  PV
i i
 
  1 
 2V 2  V 2   2 
2  1
   V  
   1     1 

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The heat exchange in the process Q  U  W
V 2 V 2  2 

 
  1
2

 1 
2


 1


V 2 2    1

2

 1  
  1

PV
By PV  nRT  T   n  1
R
 V  V  V 2  2V 2
Ti   and T f 
R R R
Q R    1
By the definition of hear capacity C   
T f  Ti 2    1 
12. Given P  V ….(i)
V V
The work done in the process W   PdV   VdV
V V
V 2 2

2

 1 
R
The change in internal energy U  nCV T  1 T f  Ti 
 1  
 Pf V f  PV
i i
 
  1 
 2V 2  V 2   2 
2  1
   V  
   1     1 
The heat exchange in the process Q  U  W
V 2 V 2  2 

   1
2

 1  
2 
 1


V 2 2

2

 1    11
PV
By PV  nRT  T   n  1
R
V  V V 2  2V 2
Ti   and T f 
R R R

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Q R    1
By the definition of hear capacity C   
T f  Ti 2    1 
13. When pressure changes from 1 atm to 3 atm, the change in pressure P  2 atm
 2  1 105 N / m2
The force exerted on the piston F  PA  2  105  4 104
F 80
The compression of the spring x    0.008m
k 104
The change in volume of the air due to displacement of piston by x
V  Ax  4  104  0.008  3.2  106 m3
 Final volume V2  V1  V  20 106  3.2  106  23.2  106 m3

PV PV P V T  3
By equation state 1 1  2 2  T2  2 2 1    
 23.2  10 6
   273  20 
T1 T2 PV
1 1  1   20  106 
 1020K
The change in internal energy of air

 
U  mCV T  2.38  105  718  1020  293  12.42J

1 2 104 2
Work done in compressing the spring by x W  kx    0.008  0.32 J
2 2
From first law of thermodynamics Q  U  W  12.42  0.32  12.74 J
14. When pressure changes from 1 atm to 3 atm, the change in pressure P  2 atm
 2  1 105 N / m2
The force exerted on the piston F  PA  2  105  4 104
F 80
The compression of the spring x    0.008m
k 104
The change in volume of the air due to displacement of piston by x
V  Ax  4  104  0.008  3.2  106 m3
 Final volume V2  V1  V  20 106  3.2  106  23.2  106 m3

PV P V P V T  3 
By equation state 1 1  2 2  T2  2 2 1    
23.2 106 
  273  20 

T1 T2 PV
1 1  1  20  10 6
 
 1020K
The change in internal energy of air

 
U  mCV T  2.38  105  718  1020  293  12.42J
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1 2 104 2
Work done in compressing the spring by x W  kx    0.008  0.32 J
2 2
From first law of thermodynamics Q  U  W  12.42  0.32  12.74 J
15. As the system is made of insulating material so process between the chambers will be
adiabatic.
When pressure in the right chamber becomes 32 times initial, let its volume becomes
VR . Then
P0V0   32 P0 VR
1
 1 
or VR     V0
 32 
For monoatomic gas
5

3
3
 1 5 V
 VR    V0  0
 32  8
If TR is the corresponding temperature of the right chamber, then
P0V0  32 P0 V0 8 

T0 TR
or TR  4 T0
The work done on the gas in right chamber

W
 PV 
i i  Pf V f 
  1
 V 
  P0V0  32P0  0 
8 
 
5 
  1
3 
9P V 9 RT0
 0 0
2 2
16. Total volume of the two chambers  2V0 .
V
Finally when volume of right chamber becomes 0 , the volume of left chamber will be
8
V 15V0
 2V0  0 
8 8
The pressure of the left chamber is also PL  32 P0 .
If TL is the final temperature of the left chamber, then
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15V0 
P0V0
 32 P0   
  8   T  60 T0
T0 TL
17. Percentage efficiency
Wcycle
   100
Heat sup plied
9
P0V0
 2  100
nCv  TA  TD   nCv TB  TA   WAB
9
PV
 2 0 0  100
3
R TB  TD   area under AB
2
9
P0V0
 2  100
3  25 
 P V  P V   6 P0V0
2 4 0 0 0 0
12
  100  12
37
18. All the diatomic gases  H 2 , O2 , N 2 , etc. exhibit 5 degrees of freedom between
100 – 1000 K, 3 of translation and 2 of rotation. Hence, internal energy of n moles of
N 2 at T = 300 K would be
5
U  nRT
2
Translational kinetic energy of each molecule is
1 2 3
ma vrms  kT
2 2
where ma is the mass of the molecule.
If rms speed increases  times, v'rms   vrms , then temperature has to be raised to
T ' such that
1 3
ma v '2rms  kT '
2 2
or T' 2T
The internal energy therefore increases to
5
U '  nRT '
2
Change in internal energy,

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5
U  U '  U  nR T '  T
2
 
5
 nRT  2  1
2
 
5 m

2M
RT  2  1 
m
where the number of moles n  , m is the mass of gas and M is its molecular weight.
M
On substituting numerical values, m  15 g , T  300 K ,   2 and M  28 g mol for N 2 , we
get
5 15
U    8.31 300   4  1 J
2 28
 104 J
19. Figure shows the pressure versus volume graph corresponding to n moles of an ideal
monatomic gas for a cyclic process ABCDA. Find the efficiency of the cycle.
Network done by the gas during the cyclic process is given by area enclosed by cyclic
process
W   2 P0  P0  2V0  V0 
 P0V0
For the isochoric process A to b the heat supplied is given by,
Q  U  W
 nCv T  0
 3R  V0  2 P0  P0 
 n 
 2  nR
3V
 P0V0
2
Temperature in respective states A, B, C, D is given by
PV 2P V 4P V 2P V
TA  0 0 , TB  0 0 , TC  0 0 ,TD  0 0
nR nR nR nR
For the isobaric process B to C the heat absorbed will be given by
Q2  nC p T
 5 R  2 P0  2V0  V0 
 n 
 2  nR
For the processes C to D and D to A, the heat is rejected from the system.
Net work doen per cycle
Efficiency   of the cycle 
Total heat given per cycle

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P0V0 2
 
3P0V0 13
 5 P0V0
2
CHEMISTRY
20.
Br
Br Br
has no chiral centre
Br Br
Br Br (2 Ena + 1 Meso)
(2 Ena + 1 Meso)
(2 Ena + 1 Meso) Br
21.

meso enantiomer
No chiral
(meso)
centre
22. All the given factors influence extent of optical rotation
23. Option-3 is identical to given structure.
24. Since they have same physical properties like Mp, Bp, density etc. they can not be
separated by any physical method of seperation
25. 3 and 4 are meso.
 mix 20
26. Enantiomeric excess =  100  100  40% of d
  pure 50
 R.M  60%
27. EE  40% of d
30%  d 
RM  60%
30%   
 %  30%
28. Structure 4 & 6 are enantiomers
C C

29. is the only Meso-compound in the given list.

30. Single enantiomer of amine can be used.
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31. b, e and f are single enantiomeric compounds.
F

32. F is meso (optically inactive)

33. The diasteriomer of given enantiomer is meso
34.

has plane of symmetry

35. A and B are identical
36. Geometrical isomerism is not possible at bridge head centres
37. Enantiomers = 24  16
Racemic mixtures = 8

38. two stereo isomers are possible

MATHEMATICS

39. LHL  f 0    xlim
1
0
3 1  tan x 

tan x 
, 1 form 
tan x 
lim
tan x
x 0
 3.e  3e
 
Now, RHL  f 0  lim f  x 
x  0
2
 sin x  tan x
 lim 3 1 
x 0   3 
  
, 1 form 
sin x 2 2
lim
 2 tan x
 3e x 0  3e 3
So, for the function f  x  to be continuous at x  0 we must have
2
At x  0, we must have 3e  3e 3 

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2
2
so.  ,   3e 3
3
40. Discontinuous when a  sin  x  1
If a  1 then sin  x  0 for x  1, 2,3, 4,5
If a  3 then sin  x  2 not possible
1 1
If a  the sin  x  for six values of x
2 2
1 5 9
If a  0 then sin  x  1 for x  , ,
2 2 2
Hence (A), (B), (C) and (D) are correct
sin 3 x  A sin 5 x  B sin  x
41. f 1  lim 5
put x  1  h
x 1  x  1
 sin 3 x  A sin 5 h  B sin  h
 lim
h 0 h5
 3 5  5 h  5 h 3 5  h 5 3 5
3 h       h   h  
 3 h  
3 h   
 
  A    ...  B  h   ...
 3! 5!    1 3! 5!   3! 5!
     
 lim 
h 0 h5
   3 h3 
 h  3  5 A  B 
  3!

27  53 A  B   
 
 5 h5 5 5
 lim 5!

3 5 A B 
h 0 h5
For limit to exist 3  5 A  B  0 & 27  125 A  B  0
1
We get A  , B  2
5
5  5
Required limit =  
5!
5

243  5 A  B 
5!

 243  625  2 
5 16 5
  384  
120 5
Hence (A) and (c) are correct
x
 ax  1 
42. f  x   lim 1  1
x   bx  2 

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x
x   a b  x 1
lim 
1   a  b  x  1  x   bx  2 

 lim   e
x   bx  2 
x 1 1
lim 
When a  b, f  x   e x  bx  2 e b or ea
When a  b, f  x   e   , does not exist

When a  b, f  x   e   0
 x4 
43.  x 4   x4     1
  x4
If x 4 is integer f  x   1 otherwise f  x   0

44. x 2  ax  1  ax 2  2 x  b
At x  1 and x  2
1
 b  0, a 
2
1
2
 x  f  x x  x2  f  x 
45. lim 1  2
 exists only when it is in 1 form i.e. lim 2
0
x 0  x  x 0 x
 
So the term of least degree in f  x  is of degree 2.

i.e. f  x   a2 x 2  a3 x3  ...
1
 x2  f  x  2
x
now, lim  1    e
x 0 
 x2 

1 x2  f  x 
x 2 lim
 f  x  x x3
lim   e 2  e x  0 e2
x 0  x2 
e  

x2  f  x 
 lim 3
2
x 0 x
x 2  a2 x 2  a3 x3  ...
 lim 2
x 0 x3
 a2  1, a3  2 and a4 , a5 ... are any arbitrary constants. Since, we want a
polynominal of the least degree, we choose f  x    x 2  2 x3

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1
2
 x  f  x x  x2  f  x 
46. lim 1  2
 exists only when it is in 1 form i.e. lim 2
0
x 0  x  x 0 x
 
So the term of least degree in f  x  is of degree 2.

i.e. f  x   a2 x 2  a3 x3  ...
1
2
 x  f  x x
2
now, lim  1    e
x 0 
 x2 

1 x2  f  x 
 x2  f  x   x 2 lim
lim   e  e x  0 x3 e2
x 0  x2 
e  

x2  f  x 
 lim 2
x 0 x3
x 2  a2 x 2  a3 x3  ...
 lim 2
x 0 x3
 a2  1, a3  2 and a4 , a5 ... are any arbitrary constants. Since, we want a
polynominal of the least degree, we choose f  x    x 2  2 x3

47. For n  1,2,3 we have 2 n  n

1
 x  x
n  n 
Limit  lim 2    1  2 n
x   2n  

For n  4 , we have 2 n  n .
1
 n  x  x
2
Hence Limit  lim n     1  n
x    n  
 
48. For n  1,2,3 we have 2 n  n
1
 x  x
n  n 
Limit  lim 2    1  2 n
x   2n  

For n  4 , we have 2 n  n .

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1
 n  x  x
2
Hence Limit  lim n     1  n
x    n  
 
 n  2n  1
49. f  x 

1  sin 2  x


1 if x 
2
n 

11  sin 2  x 0 if x   2 n  1

 2
 f is discontinuous at
1 3 5 7 9
x , , , ,
2 2 2 2 2
f  x   g  x  is possible where
2 x 1
2x 1
e 2 1  0
2
1
 x
2
1
but at x  f  x  0
2
 no solution
 n  2n  1
50. f  x 

1  sin 2  x


1 if x 
2
n

11  sin 2  x 0 if x   2 n  1

 2
 f is discontinuous at
1 3 5 7 9
x , , , ,
2 2 2 2 2
f  x   g  x  is possible where
2 x 1
2x 1
e 2 1  0
2
1
 x
2
1
but at x  f  x  0
2
 no solution
1
51.   Here, f  x  
1 x
 x 1

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1
f  f  x  
1 f  x
1 x 1
 
1 x
1
1 x
 x  0,1
1
f  x 1 1 x 1

and f f  f  x   
f  x


1
 x , where x  0,1
x 1
Here, point of discontinuity are x  0,1
 3 
52. From graph, a    ,1 , as  ,     0,1
 2 

X  X2
x  2y  3  0

 3
 0, 
 2
 0,1
 a, a 2 
O X
X' 
3 1 1
2


53. f  x   f  x
 f is odd function
 0, 4 

 0,7 

5 3 3 5

 0, 7 
 0, 4

54. f  x   f  x
 f is odd function
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 Sri Chaitanya IIT Academy 08-10-2023_Jr.Su60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-22/WTA-17_Key & Sol’s

 0, 4 

 0,7 

5 3 3 5

 0, 7 
 0, 4

55. Here,
2
g 1  lim  ln e  ln x  ln x
x l
2
 lim 1  ln x ln x
x l
2
lim ln x ln x
 e x l
g 1  e 2
 x m f 1  h  x   1 
Now, lim g  x   lim lim  
m
x 1 x 1 m  2 x  3 x  3 
h 1  1  m 
 sin ce x  1  lim x  0
33  m 
h 1  1
 lim g  x         2
x 1 6
 x m f 1  h  x   1 
and, lim g  x   lim lim  
m
x 1 x 1 m   2 x  3 x  3 
f 1  h  x  x m  1 x m f 1
 lim lim 
x 1 m 2  3 x m 1  3 x m 2
f 1
 lim g  x          3
x 1 2
As g  x  is continuous at x = 1, from (1), (2) and (3)
h 1  1 f 1
e2  
2 2
 h 1  6e2  1 and f 1  2e 2
 2 g 1  2 f 1  h 1  2e2  4e2  6e 2  1  1

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 Sri Chaitanya IIT Academy 08-10-2023_Jr.Su60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-22/WTA-17_Key & Sol’s
 2 g 1  2 f 1  h 1  1
56. using sin 3  3sin   4sin 3 
x 1 x 
T1  sin 3  3sin  sin x 
3 4 3 
x 3 x x
T2  3sin 3  3sin  sin 
32 4  32 2
and so on -----------
1 x 
 T1   3sin  sin x 
4 3 
1 x x
T2   32 sin  3sin 
4 32 3
1 x x 
Tn  3n sin  3n 1 sin 
4 3n 3n 1 
1 n x 
 f  x   lim  3 sin  sin x 
n 4  3n 
 x 
x sin
1 
3n  sin x 
  lim
4  n  x 
n
 3 
1
  x  sin x 
4
g  x   x  4 f  x   sin x
lim  cot x  sin x 
cot x
Now lim 1  sin x   e x 0 e
x 0

57.  x 2  is not continuits at x  2, 3

 
 x3  is not continuous at
 
x.3 2,3 3,3 4
3 5,3 6,3 7

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