CHEMISTRY (SET-A)
PATTERN: JEE-MAIN
PHASE: VII PHASE TEST PAP-I-JEE-M DATE: 16.09.2024
SINGLE CORRECT TYPE (20)
51. Flocculation power depends upon.
(A) the shape of flocculating ion
(B) the amount of flocculating ion
(C) nature of the charge on the flocculating ion
(D) both, the nature and magnitude of the charge of the flocculating ion
51. D
52. Glucose does not react with
(A) C6H5NHNH2 (B) NH2 -OH (C) HCN (D) NaHSO3
52. D
53. 3 g of activated charcoal was added to 50 mL of acetic acid solution (0.06 N) in a flask. After an hour it was filtered and
the strength of the filtrate was fond to be 0.042 N. The amount of acetic acid absorbed (per gram of charcoal) is:
(A) 54 mg (B) 18 mg (C) 46 mg (D) 42 mg
53. B
54. Which of the following statement is false?
(A) The repeat unit in natural rubber is isoprene
(B) Both starch and cellulose are polymers of glucose
(C) Artificial silk is derived from cellulose
(D) Nylon-6,6 is an example of elastomer
54. D
55. Which one of the following statements is false?
(a)Raoult’s law states that the vapour pressure of a components over a solution is proportional to its mole fraction
(b)Two sucrose solutions of same molality prepared in different solvents will have the same
freezing point depression
(c)The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is
BaCl2 > KCl > CH3COOH > sucrose
(d)The osmotic pressure () = MRT, where M is the molarity of the solution
55. B
56. Two liquids X and Y form an ideal solution. At 300K, vapour pressure of the solution containing 1
mol of X and 3 mol of Y is 550 mm Hg. At the same temperature, if 1 mol of Y is further added to
this solution, vapour pressure of the solution increases by 10 mm Hg. Vapour pressure (in mmHg)
of X and Y in their pure states will be, respectively :
(a) 200 and 300 (b) 300 and 400
(c) 400 and 600 (d) 500 and 600
56. C
57. Consider the following solution
(I) 1M Sucrose (II) 1M KCl (III) 1M Benzoic acid (IV) 1M (NH 4)3 PO4
Which of the following is/are true ?
(A) All solutions are isotonic (B) III is hypertonic of II, I, IV
(C) I, II and III are hypertonic of IV (D) IV is hypertonic of I, II and III
57. D
58. In which of the following the chemical formula and the name are incorrectly matched
(A) K Pt NH3 Cl5 -Potassium amminepentachloropalatinate (IV)
(B) Ag CN2 – Dicyanoargentate (I) ion
(C) K 3 Cr C2 O4 3 – Potassium trioxalato chromate (III)
(D) Na2 Ni EDTA – sodium ethylene diammine tetra–aceto nickel (II)
58. D
59. Which of the following statements are incorrect about brown ring complex
(A) It is paramagnetic complex (B) Oxidation state of Fe is + 1
(C) Charge on NO is + 1 (D) Coordination number of Fe is 5.
59. D
60. –
Nickel (Z = 28) combines with a uninegative monodentate ligand X to form a paramagnetic
2−
complex [NiX4 ] . The number of unpaired electron(s) in the nickel and geometry of this complex
ion are, respectively
(a) one, tetrahedral (b) two, tetrahedral
(c) one, square planar (d) two, square planar
60. b
61. Which of the following compounds give paramagnetic gas on decomposition?
(I) Pb(NO3)2 (II) LiNO3 (III) NaNO3 (IV) NH4NO2
(A) I, II, III (B) II, III (C) I, II (D) III, IV
61. A
62. Column I (Ion) Column II (Observation in flame test)
2+
(A) Cu (P) Apple green flame
2+
(B) Ba (Q) Green flame with blue tip
2+
(C) Ca (R) Crimson red flame
+
(D) Li (S) Brick red flame
(a) (A)-(R), (B)-(Q), (C)-(S), (D)-(P) (b) (A)-(Q), (B)-(P), (C)-(S), (D)-(R)
(c) (A)-(R), (B)-(S), (C)-(Q), (D)-(P) (d) (A)-(P), (B)-(Q), (C)-(R), (D)-(S)
62. B
63. The Prussian blue colour obtained during the test or nitrogen by Lassaigne’s test is due to the formation of :
(A) Fe[Fe(CN)6]3 (B) Na3[Fe(CN)6] (C) Fe(CN)3 (D) Na4[Fe(CN)5NOS]
63. D
64. Lassaigne’s test for the detection of nitrogen fails in
(A) NH2 CONHNH 2 .HCl (B) NH2 NH2 .HCl
(C) NH2 CONH 2 (D) C6 H5NHNH2 .HCl
64. B
3
65. 0.2g of an organic compound on Kjeldahl’s analysis gave ammonia enough, to just neutralise 20 cm of 0.1 N
H2 SO 4 . The percentage of nitrogen in the compound is
(A) 14 (B) 20 (C) 70 (D) 24
65. A
66. The sodium extract prepared from sulphuric acid, contains SCN . It gives blood red colouration with
(A) FeCl 3 (B) Na2 CO 3
(C) FeSO 4 (D) a mixture of Na2 S and CS 2
66. A
67. Which of the following hydrocarbon gives a white ppt. with AgNO 3 NH 4 OH ?
CH2
(A) CH2 CH CH3 (B) H2C CH2 (C) CH 4 (D) HC CCH3
67. D
68. Choose the incorrect statement(s)
(A) 2 valency of Cr en2 Cl2 Cl is 6
(B) M-C bond order is more in V C O as compared to Mn CO
6 6
3
(C) hybridisation of Fe in Fe(CO)5 is sp d
(D) for a given ligand & geometry 0 increases in the order : 3d < 4d < 5d
68. C
69. Which of the following gives an optically inactive compound when reacted with sodium borohydride, NaBH 4
CHO CHO CHO CHO
H OH H OH HO H H OH
OH H HO H HO H H OH
HO H H OH H OH HO H
H OH HO H H OH H OH
CH2OH CH2OH CH2OH CH2OH
(A) (B) (C) (D)
69. A
70. Observe the following reaction and mark the correct statement(s) given below:
O
H OMe MeO H
C C
H OH
H OH H OH
HO H MeOH HO H HO H
+
H OH
dry HCl H OH H OH
H OH
H O H O
OH CH2OH CH2OH
D-glucose -D-Methyl glucoside -D-Methyl glucoside
(A) Methyl glucosides do not react with Fehling’s or Tollens reagent
(B) The reaction passes through a carbo cation
(C) The two forms of glucosides are enantiomers.
(D) The non-reducing character of glucoside indicates the absence of free –CHO group in it.
70. C
NUMERICAL_5
71.
Aqueous solution of cation (A) (i) dil. HCl
Black ppt(B)
(ii) H2S
Excess Dark Blue coloured
NH3 solution solution(C)
K4[Fe(CN)6]
Chocolate Brown colored
solution ppt(D)
Find the total number of moles of ions produced when one mole of complex (D) is fully ionized.
71. 3
72. K 4 Fe CN 6 can detect how many of the following ions. Fe2 ,Fe3 ,Zn2 ,Cu2 ,Cd2 ,Ca2
72. 6
–1
73. The molal freezing point depression constant for benzene (C6H6) is 4.90 K kg mol . Selenium exists as a polymer of the
type Sex. When 3.26g of selenium is dissolved in 226g benzene, the observed freezing point is 0.112C lower than that
–1
of pure benzene. Deduce the value of x. (Atomic mass of Se = 78.8 g mol ).
73. 8
74. Gold number of gelatin is 0.01. Calculate the amount of gelatin to be added to 1000 ml of collidial sol of gold to prevent
its coagulation before adding 1 ml of 10% NaCl
74. 1
75. Number of optical isomers possible for a ketohexose is
75. 8
