Class 12th JEE

Advanced

PAPER-1
MKJM/12 Milestone Test-8 Phase-1

DURATION ::180
DURATION Minutes
90 Minutes DATE : 20/10/2024 M.MARKS : 180

Topics covered
Moving Charges and Magnetism, Magnetism and Matter, Electromagnetic Induction, Alternating
Physics:
Current, Electromagnetic Waves, Ray Optics and Optical Instruments
Coordination Compounds, Chemical Kinetics, Alcohols, Phenols and Ethers, Aldehydes, Ketones
Chemistry:
and Carboxylic Acids, Amines, The Solid State, Surface Chemistry
Limit Continuity and Differentiability, Method of Differentiation, Application of Derivatives,
Mathematics:
Indefinite Integration, Definite Integration, Application of Integrals, Differential Equation

General Instructions:
1. Immediately fill in the particulars on this page of the test booklet.
2. The test is of 3 hours duration.
3. The test booklet consists of 54 questions. The maximum marks are 180.
SECTION-1 (Maximum Marks: 24)
This section contains EIGHT (08) questions.
• The answer to each question is NUMERICAL VALUE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual
numeric keypad in the place designated to enter the answer. If the numerical value has more than two decimal places,
truncate/round-off the value of TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.

SECTION-2 (Maximum marks: 24)

• This section contains SIX (06) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are)
correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if (all) the correct option(s) is(are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
SECTION-3 (Maximum marks: 12)
• This section contains FOUR (04) Matching List Sets.
• Each set has ONE Multiple Choice Question.
• Each set has TWO lists: List-I and List-II.
• List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
• FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four
options satisfies the condition asked in the Multiple Choice Question.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the option corresponding to the correct combination is chosen;
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
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 PART-I (PHYSICS)
SECTION-1 5. An LCR series circuit with 100Ω resistance is connected
Numerical Value Type Questions (01-08) to an ac source of 200 V and angular frequency 300
1. A current of I = πA flows around a closed path in a rad/s. When only the capacitance is removed, the
circuit which is in the horizontal plane as shown in the current lags behind the voltage by 60°. When only the
figure. The circuit consists of eight alternating arcs of inductance is removed, the current leads the voltage by
radii r1 = 0.08 m and r2 = 0.125 m. Each arc subtends 60°. Calculate the current (in A) in LCR circuit
the same angle at the centre O.
6. An AC current is given by I = (10 + 5 10 sin ωt)A then
its rms value will be (in A)

7. A cube of side length 1 mm is placed on the axis of a

concave mirror at a distance of 45 cm from the pole as
shown in the figure. One edge of the cube is parallel to
The magnetic field produced by this circuit at the
centre O is (in μT). (Use π2 = 10) the axis. The focal length of the mirror is 30 cm. The
approximate volume of the image. (in mm3)
2. An infinite uniform current carrying wire is kept along
z-axis, carrying current I0 in the direction of the positive
z-axis. OABCDEFG represents a circle (where all the
points are equally spaced), whose centre at point O (4m,
0m) and radius 4m as shown in the figure. If
0 I 0
 B.d = k in S.I. unit, then find the value of k 8. A plane electromagnetic wave of frequency 50 MHz
DEF travels in free space along the x-direction. At a
particular point in space E = 7.2 ˆj V/m . At this point,
B is equal to x × 10–8 k̂ T. Find the value of x.

SECTION-2
One Or More Than One Correct Type Question (09-14)
9. A particle of positively charge q is projected with a
3. A triangular wire frame (each side = 2m) is placed in a
momentum P = Piˆ in the given region of uniform
region of time variant magnetic field having
dB / dt = 3 T/s. The magnetic field is perpendicular magnetic field B = Bkˆ . It emerges from the magnetic
to the plane of the triangle. The base of the triangle field after deviating through an angle θ = 30° as
AB has a resistance 1 while the other two sides shown.
have resistance 2 each. The magnitude of potential
difference between the points A and B will be

(A) The value of P is 2qBd

(B) The value of P is qBd

4. Two coils 1 & 2 have a mutual inductance = M and (C) Maximum change in momentum takes place for
resistance R each. A current flows in coil 1, which P
varies with time as; I1 = kt2, where k is a constant and t d
qB
is time. The total charge that flown through coil 2,
xkMT 2 (D) Maximum change in momentum takes place for
between t = 0 and t = T is . The value of x is P
R d
2qB
[3]
10. Two charges particles traverse identical helical paths in (A) The current in the loop at t = 0 due to induced
a completely opposite sense in a uniform magnetic field emf is 0.16 A
B = B kˆ (charge to mass ratio of both particle are
0
(B) At t = 2s, induced emf has magnitude 0.08 V
(C) The magnitude of the force required to move the
 e1  e2
  and respectively conducting rod at constant speed 5 cm/s at
 m1  m2
t = 2s, is equal to 0.08 N
(A) They have equal z-components of momenta (D) The magnitude of the force required to move the
(B) They must have equal charges (e1 = e2) conducting rod at constant speed 5 cm/s at
(C) They must have equal mass (m1 = m2) only t = 2s is required to 0.16 N
(D) The charge to mass ratio satisfy
 e1   e2  13. A thin conducting rod of length is moved such that
 + =0
 m1   m2  its end B moves along the x-axis while end A moves
along the y-axis. A uniform magnetic field B = B kˆ0
11. A disc of radius r and carrying positive charge q and exists in the region. At some instant, velocity of end
uniformly distributed is rotating with an angular speed B is v and the rod makes an angle of  = 60º with the
 in a uniform magnetic field B about a fixed axis as
x-axis as shown in the figure. Then, at this instant
shown in figure, such that angle made by axis of disc
with magnetic field is  .

2v
(A) angular speed of rod AB is  =
3
(A) Torque applied by axis on the disc is clockwise 3v
(B) angular speed of rod AB is  =
2
(B) Torque applied by axis on the disc is
anticlockwise (C) Magnitude e.m.f. induced in rod AB is B v 3
(C) Magnitude of torque applied by axis on the disc
(D) Magnitude e.m.f induced in rod AB is
qr 2 B
is sin  B v/2 3
4
(D) Magnitude of torque applied by axis on the disc
qr 2 B sin  14. A lens is formed by a material having refractive index
is 3
2 & radii of curvature 20 cm & 10 cm. Then choose
2
12. Figure shows a conducting rod AB of negligible the correct option(s)
resistance that can slide on smooth U-shaped rail made (A) If lens is concavo-convex & light is falling on
of wire of resistance 1 Ω/m. Position of the conducting the surface having radius of curvature 20 cm,
rod at t = 0 is shown. A time dependent magnetic field then focal length is 40 cm
B = 2t Tesla is switched on at t = 0. After the magnetic (B) If lens is concavo-convex & light is falling on
field is switched on, the conducting rod is moved to the the surface having radius of curvature 10 cm,
left perpendicular to the rails at constant speed 5 cm/s then focal length is –40 cm
by some external agent. (All parameter are given at (C) If lens is convexo-concave & light is falling on
t = 0) the surface having radius of curvature 20 cm,
then focal length is 40 cm
(D) If lens is convexo-concave & light is falling on
the surface having radius of curvature 10 cm,
then focal length is –40 cm

[4]
 SECTION-3
Matrix Match Type Questions (15-18)
Light emerges
15. Three wires are carrying same constant current i in III R parallel to
different directions. Four loops enclosing the wires in surface QR
different manners are shown. The direction of d is
shown in figure by arrow in different loops while
The light ray
List-II shows the resultant ampere’s law for different
emerges from
option of List-I IV S
face PR
perpendicularly
When light ray
passes through
T the prism it is
parallel to the
base PR
I II III IV
(A) P Q R,T P,T
List-I List-II (B) P Q R P
I Along closed loop –1 P  B.d = 0i (C) Q P R,T P,T
(D) P Q T R
II Along closed loop –2 Q  B.d = −0i
 B.d = 0
17. List-I gives the different Situation and List-II gives
III Along closed loop –3 R
their magnetic moment. Math List-I with List-II.
IV Along closed loop –4 S  B  d = −20i (Note:- all bodies in List-I is uniformly mass
distributed)
T  B  d = 20i List-I List-II
I II III IV a uniformly charged ring having
(A) Q P Q P charge q and radius r rotating qr 2
I P
(B) P Q Q S uniformly about its axis with 5
(C) P Q Q T angular speed 
(D) Q R S T a uniformly charged disk
having charge q and radius r qr 2
II Q
16. Light is incident at surface PQ of prism as shown in rotating uniformly about its axis 4
List-I then match the List-I with List-II (surrounding with angular speed 
medium is air in all cases and refractive index of prism a uniformly charged spherical
shell having charge q and radius
is 2 in all cases) qr 2
III r rotating uniformly with R
List-I List-II angular speed  about its 3
diameter
Total internal a uniformly charged sphere
reflection takes having charge q and radius r
I P qr 2
place at surface IV rotating uniformly about one of S
QR its diameter with angular speed 2

T qr 2
Light emerges I II III IV
II Q normally from (A) S Q R P
the surface QR (B) S R Q T
(C) Q P S S
(D) R Q S S

[5]
 6 List-I List-II
18. When an inductor of inductance H, a capacitor of
 I XL P 200 Ω
50 II XC Q 300 Ω
capacitance F and resistor of resistance R are III Resistance(R) R 500 Ω

connected in series with an AC supply of rms voltage IV Z S 600 Ω
T 1000Ω
220 V and frequency 50 Hz, the rms current through
I II III IV
the circuit is 440 mA. Match the inductive reactance
(A) S T P R
XL, the capacitive reactance, XC, the resistance R and (B) S R P Q
the impedance Z of the circuit given in List-I with the (C) S P Q R
corresponding values given in List-II. (D) P S R T

PART-II (CHEMISTRY)
SECTION-1
Numerical Value Type Questions (19-26) 25.
 Number of 
 
isomeric products
→(B)  
19. Cyclobutylethene ⎯⎯⎯⎯⎯
Dil.H 2SO4 Calculate the molecular mass (in amu) of the final
(A)  including stereo −  Major product (y).
 
 isomers  (Give an atomic mass N = 14u, O = 16u, H = 1u, C =
Calculate (B). 12u)

20. Final major product(A) contains how many chiral

centres. 26.
O O OH
Ba(OH) 2
+ H (A)
HO OH OH The number of sp2 hybridized carbon atoms in B is

SECTION-2
21. One or More Than One Correct Type Questions (27-32)
27. Which of the following acid-base reactions is/are given
below feasible?
Compound (C) is a hydrocarbon. Find total number
(A) PhONa + CH3CH2OH
of π bonds in C.
⎯→ PhOH + CH3CH2ONa
22. The rate constant of a reaction at 500 K and 700 K (B) PhOH + NaOH ⎯→ PhONa + H2O
are 0.02 s–1 and 0.07s–1, respectively. Calculate the (C) PhONa + aq. HCl ⎯→ PhOH + NaCl
value of Ea (in kJ). (nearest integer). (Use; R = 8.3 (D) CH3C  CH + NaNH2 ⎯→ CH3C  C–Na+ + NH3
JK–1mol–1, log7 = 0.84, log 2 = 0.3)
28. Observe the following reaction:
4–
23. The crystal field splitting energy for [CoCl6] is 
18000 cm–1. The t for [CoCl4]2– will be 10x cm–1. CH3 – C– CH 2 – C– CH3 ⎯⎯⎯⎯⎯
HCN(excess)
→ ⎯⎯⎯⎯
3 →
H O /
|| ||
Find x. O O
The correct statement(s) is/are
24. An element crystallises as face-centred cubic lattice
(A) The product is a mixture of two compounds
with density as 5.20 g / cm3 and edge length of the
(B) All stereoisomers obtained are optically active
side of unit cell as 300 pm. Calculate mass of the
(C) The product is a mixture of two chiral and one
element (in gram) which contains 3.01 × 1024 atoms.
(nearest integer) (N0 = 6.02 × 1023) achiral stereoisomer.
(D) The product is a mixture of three stereoisomers.
[6]
29. Reaction involves isocyanate as intermediate 34. A → Product, –d[A]/dt = k[A]n where rate constant = k
product:  2  10 3
K
(A) Hoffmann rearrangement If log10k(min )= 5 − 
–1

(B) Lossen rearrangement  T 
(C) Schmidt rearrangement Match the given property in List-I with its related
(D) Curtius rearrangement value in List-II and select answer from codes given:
List-I List-II
30. On mixing a lyophilic sol with a lyophobic sol I Arrhenius constant (min–1) P 1.0
(A) lyophobic sol is protected II Order of the reaction Q 2.0
(B) lyophilic sol is protected III At 500 K, rate of reaction at R 105
(C) a film of lyophilic sol is formed over a lyophobic [A]0 = 0.2M
sol IV Ea(in kcal mol–1) S 9.2
(D) a film of lyophobic sol is formed over a lyophilic T 5
sol I II III IV
(A) P Q R S
31. Synergic bonding in metal carbonyl complexes: (B) Q P R S
(A) decreases C—O bond strength (C) R P Q S
(B) increases M—C bond length (D) T P Q S
(C) increases bond order for M—C bond
(D) increases paramagnetism of complex 35. Match the following
List – I (Complex) List- II
32. In which case(s) numerical value is 1.5 (E.A.N)
(A) T75/T50 for zeroth order reaction I [Fe(CO)4]2– P 34
(B) T99.9/T99 for first order reaction II [Co(NH3)5Cl]Cl2 Q 35
(C) T75/T50 for third order reaction III K2[Ni(CN)4] R 36
(D) T50/T20 for third order reaction IV [Cu(NH3)4]2+ S 37
T 38
SECTION-3
I II III IV
Matrix Match Type Questions (33-36)
(A) T Q R R
33. Match the following
(B) P T P Q
List - I List- II
(C) R R P Q
I P Rosenmund’s (D) Q P R R
reduction
36. Match the following
List- I List- II
II Q Beckmann
Ionic crystal structure Distance between
rearrangement
nearest spheres (in
III R Claisen terms of a)
rearrangement
I Rock salt P 0.44 a
II Fluorite Q 0.86 a
IV S Clemmensen
reduction III CsCl R 0.5 a
IV Aluminium S 0.7 a
T Reimer– (Crystallising in fcc)
Tiemann’s T a
reaction 1.16
I II III IV I II III IV
(A) P Q R S (A) S P Q R
(B) Q P S R (B) P P S, T R
(C) T R P Q (C) R P Q, T S
(D) T P R S (D) R P T, S Q

[7]
 PART-III (MATHEMATICS)
SECTION-1 SECTION-2
Numerical Value Type Questions (37 to 44) One or more than one correct type question (45 to 50)
− x 2 /2
e − cos x 45. Given a real-values function f such that
37. If L = lim , then the value of 3L is
x→0 x3 sin x  tan 2{x}
 2 for x  0
x 
(
 x − [ x]
2
)
38. f ( x) =  [1,3] is non- f ( x) =  for x = 0 , where [x] is the
1 + (ln x)(ln x).... 1

differentiable at x = k. Then the value of |k2| is  {x}cot{x} for x  0


(e + h)ln( e + h ) − e 25
39. If L = lim , then the value of is integral part and {x} is the fractional part of x then
h →0 h L
(A) lim f ( x) = 1
x→0+
40. At the point P(a, an) on the graph of y = xn (n  N) in (B) lim f ( x) = cot1
the first quadrant, a normal is drawn. The normal x→0−
2
1  
intersects the y-axis at the point (0, b). If lim b = , (C) cot −1  lim f ( x)  = 1
a →0 2  x→0− 
15 −1   
then 2 equals (D) tan  lim f ( x)  =
n  x →0 +  4


( )
x dt −1 2
41. Let f ( x) =  and g(x) be the inverse of f(x),  sin x cos(1 / x), x  0
0
1+ t 3 46. If f ( x) =  then
0, x=0
g ''( x)
then the value of 4 is
(A) f (x) is continuous everywhere in x  (–1, 1)
( g ( x )) 2
(B) f (x) is discontinuous in x [–1, 1]
(C) f (x) is differentiable everywhere in x(–1, 1)
2cos x − sin x +  (D) f (x) is non-differentiable in x  [–1, 1]
42. If  dx =A ln |cos x + sin x –2| + Bx
cos x + sin x − 2
A 47. The angle between the tangents at any point P and the
+ C. Then the value of is line joining P to the origin, where P is a point on the
B
2 2 –1 y
curve ln (x + y ) = c tan , c is a constant, is
x
43. If ‘a’ (a > 0) is the value of parameter for each of
(A) Independent of x
which the area of the figure bounded by the straight
(B) Independent of y
a 2 − ax (C) Independent of x but dependent on y
line, y= and the parabola
1+ a 4
(D) Independent of y but dependent on x
x 2 + 2ax + 3a 2
y= is the greatest, then the value of 48. If f (2 – x) = f (2 + x) and f (4 – x) = f (4 + x) for all x
1+ a 4
2
a 4 and f(x) is a function for which 0 f ( x)dx = 5 , then
is
5 50
0 f ( x)dx is equal to
46
−4 f ( x)dx
44. The perpendicular from the origin to the tangent at (A) 125 (B)
any point on a curve is equal to the abscissa of the
51 52
point contact. Also curve passes through the point (1, 1).
Then the length of intercept of the curve on the x-axis
(C) 1 f ( x)dx (D) 2 f ( x)dx

is

[8]
49. Area bounded by the curve y = lnx, y = 0 and x = 3 is Has infinite
(A) (ln 9 – 2) sq unit IV f(x) = |x| – |2x –3| S points of
(B) (ln 27 – 2) sq unit minima
 27  I II III IV
(C) ln  2  sq unit
e  (A) Q R S P
(D) greater than 3 sq unit
(B) S S R Q
(C) P Q R S
50. Which of the following function(s) is/are
homogeneous? (D) R P Q S
x− y
(A) f ( x, y) = 2
x + y2 53. Match the List-I with List-II containing
1
−
2 corresponding solution angle
x
(B) f ( x, y) = x3 y 3 tan −1 List-I List-II
y

( )
(C) f ( x, y) = x ln x 2 + y 2 − ln y + ye x / y If f(x) is an integrable function
 2 x2 + y 2  x + 2y  
(D) f ( x, y) = x ln − ln( x + y )  + y 2 tan for x   6 , 3  and
 x  3x − y  
 /3
I1 =  sec2  f (2 sin 2)d
SECTION-3 I  /6 P 3
Matrix Match Type Questions (51-54) /3
and I 2 =  cosec2
/6
 5e1/ x + 2
 ,x0 f (2sin2)d, then I1/I2 is equal
51. Let f ( x) =  3 − e 1/ x
 0, x=0
to

List-I List-II
If f(x + 1) = f (3 + x) for  x ,
I y = f(x) is P Continuous at x = 0 a +b
II y = xf(x) is Q Discontinuous at x = 0 II
and the value of a f ( x)dx
Q 1
is independent of a then the
III y = x2 f(x) is R Differentiable at x = 0
value of b can be
y = x–1 f(x)
IV S Non-differentiable at x = 0
is
The value of
I II III IV
III 4 tan −1[ x 2 ]dx R 2
(A) P,S Q,S P,Q P,R 2
1 tan −1[ x 2 ] + tan −1[25 x + x 2 − 10 x]
(B) P,R Q,S P,S Q
(C) Q,S P,S P,R Q,S
2
(D) Q,S P,R Q,S P,R If I = 0 x + x + x + ...
IV
dx (where x > 0), then [I] is S 4
52. Match the List-I and List-II (f : R → R) .
equal to (where [] denotes the
List-I List-II
Has no points greatest integer function)
I f(x) = |2x –1| + | 2x – 3| P
of extrema I II III IV
Has one point (A) Q R,S P P
II f(x) = 2 sin x – x Q
of maxima
(B) R R P Q
Has one point
III f(x) = |x – 1| + |2x –3| R (C) S P Q S
of minima
(D) P Q S R
[9]
54. Match the List-I and List-II Of family of curve
List-I List-II IV Degree 3 S y2 = 2c ( x − c ) ,
Of all parabolas whose where c > 0
I Order 1 P
axis is the x-axis
I II III IV
Of family of curves (A) Q,S P P Q,R,S
II Order 2 Q y = a (x + a)2 where a (B) P Q,R,S P Q,S
is an arbitrary constant (C) Q,R,S P Q,S P
2/3
4d 3 y (D) P Q,S Q,R,S P
 dy 
III Degree 1 R  1 + 3  =
 dx  dx3

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ROUGH WORK