JEE Main Practice Test - 27
JEE Main Practice Test - 27
Question 1:
ML 2
Which of the following units denotes the dimensions of where Q denotes the
Q2
electric charge.
a. Wb/m²
b. Henry (H)
c. H/m²
d. Weber
Question 2:
A stone dropped from a ballon which is at a height h reaches the ground after t
seconds. From the same balloon if two stones are thrown, one upwards and other
downwards with same velocity u and they reach the ground after t1 and t2 seconds
respectively, then
a. t = t 1 − t 2
t1 + t2
b. t = 2
c. t =
√t1t2
2 2
d. t = t 1t 2
Question 3:
Two bodies a and b have masses M and m respectively, where M > m, and they are
at a distance d apart. Equal force is applied to them do that they approach each
other. The position where they hit each other is
a. Nearer to B
b. Nearer to A
d. Cannot be decided
Question 4:
A spring of force constant 800 N/m has an extension of 5 cm. The work done in
extending it from 5 cm to 15 cm is
a. 16 J
b. 8 J
c. 32 J
d. 24 J
Question 5:
a. Friction of tyres
b. Brakes
c. Driver
d. Steering wheel
Question 6:
If the acceleration due to gravity at the surface of the earth is 9.8 ms-2 and the mass
of earth is 80 times that of moon and radius of earth is 4 times that of moon, the
value of G at moon’s surface is:
a. 9.8 ms-2
b. 1.96
c. 4.9
d. None of these
Question 7:
The stress for elastic limit of a material is 3.5 x 108 Nm2. The minimum diameter of
a rod made of this material which can support 500 N load without exceeding elastic
limit will be:
a. 1.35 cm
b. 1.35 mm
c. 1.35 x 10-6m
d. 2 mm
Question 8:
Heat is flowing through two cylindrical rods A and B of same material having same
temperature difference between their ends. The diameter of the rods A and B are in
ratio 1 : 2 and their length in the ratio 2 : 1. The ratio of heat flow in rod A to that in B
is:
a. 1 : 2
b. 2 : 3
c. 4 : 1
d. 1 : 8
Question 9:
If masses of all molecules of a gas are halved and their speeds doubled, the ratio of
initial and final pressure is:
a. 1 : 2
b. 2 : 1
c. 4 : 1
d. 1 : 4
Question 10:
The net external force acting on the disc when its centre of mass is at a
displacement x with respect to its equilibrium position is:
a. –kx
b. -2kx
2kx
c. − 3
4kx
d. − 3
Question 11:
a. Increases
b. Decreases
c. Remains same
d. Not definite
Question 12:
Force acting upon a charged particle kept between plates of a charged condenser is
F. If one of plates of condenser is removed, force acting on the same particle will
become:
a. Zero
F
b. 2
c. F
d. 2F
Question 13:
a. 1.25
b. 8
c. 10
d. 20
Question 14:
a. 36Ω
b. 40Ω
c. 44Ω
d. 48Ω
Question 15:
d. None of these
Question 16:
b. N2
c. N3
d. N
Question 17:
A Short circuited coil is placed in a time varying magnetic field. Electrical power is
dissipated due to the current induced in the coil. If the number of turns were
quadrupled and the wire radius halved, the electrical power dissipated would be:
a. Halved
b. The same
c. Doubled
d. Quadrupled
Question 18:
Usually, microwave signals are not used for ionospheric propagation. The reason is:
Question 19:
A person is suffering from far sightedness. When an object is placed closet to the
eye which of the following lens is used?
Question 20:
d. disappear completely
Question 21:
b. Interference of light
c. Diffraction of light
d. Polarization of light
Question 22:
The wavelength of yellow line of sodium is 5896 A°. Its wave number will be
a. 50883 x 1010
b. 16961 per cm
c. 17581 per cm
d. 50883 per cm
Question 23:
One mg of substance has 2.68 x 1018 nuclei. Its half life is 1620 years. After 3240
years how many nuclei would have integrated?
a. 1.82 x 1018
b. 1.34 x 1018
c. 0.67 x 1018
d. 2.01 x 1018
Question 24:
Question 25:
Question 26:
Consider a neutral conducting sphere. A positive point charge is placed outside the
sphere. The net charge on the sphere is then:
b. Negative and appears only at the point on the sphere closet to the point
charge
c. Negative and distributed non uniformly over the entire surface of the sphere
d. Zero
Question 27:
A hydrogen atom and Li2+ ion are both in the second excited state. if lH and lLi are
their respective electronic angular momenta and EH and ELi their respective
energies, then:
Question 28:
A monoatomic ideal gas, initially at temperature T1 is emclosed in a cylinder fifted
with a frictionless piston. The gas is allowed to expand adiabatically to a
temperature T2 by releasing the piston suddenly. If L1 and L2 are the lengths of the
gas column before and after expansion respectively, then T1/T2 is given by:
()
2
L1 3
a. L2
L1
b. L
2
L2
c. L
1
()
2
L2 3
d. L1
Question 29:
A hollow double concave lens is made of very thin transparent material. It can be
filled with air or either of two liquids L1 and L2 having refractive indices n1 and n2
respectively (n2 > n1 > 1). The lens will diverge parallel beam of light if it is filled with:
c. L1 and immersed in L2
d. L2 and immersed in L1
Question 30:
One quarter section is cut from a uniform circular disc of radius R. This section has
a mass perpendicular to its plane and passing through the centre of the original disc.
Its moment of inertia about axis of rotation is:
1
a. 2 M 2
1
b. 4 MR 2
1
c. 8 MR 2
d. √2MR 2
Chemistry
Question 1:
(
a. NH 4
3)⋅ PO 4 ⋅ 12MoO 3
(
b. NH 4
3)⋅ PO 4 ⋅ 6MoO 3
(
c. NH 4
3)⋅ PO 4 ⋅ 12MoO 2
( )
d. NH 4 PO 4 ⋅ 6MoO 2
3
Question 2:
a. Melamine polymer
b. Bakelite
c. Teflon
d. All of above
Question 3:
Question 4:
Question 5:
Which of the following statements on the atomic wave function Ψ is not correct?
Question 6:
− 1 and
(
Given that K b H O
) = 0.512Kkgmol K f ( H O ) = 1.86 K kg mol − 1.
2 2
a. 0.0585 0C
b. 0.2246 0C
c. 1.864 0C
d. 0.0265 ∘ C
Question 7:
In paper chromatography:
Question 8:
An antigen is:
b. A steroidal hormone
Question 9:
Question 10:
When two solutions (having the same temperature) are mixed, the temperature
during mixing decreases.
Question 11:
a. 32.475pm
b. 173.2pm
c. 37.5pm
d. 212.1pm
Question 12:
When HCl gas is passed through a saturated solution of common salt, pure NaCl is
precipitated because:
[
d. The ionic product of Na + ][Cl ]exceeds the solubility product of NaCl
−
Question 13:
Which of the following will have lower pKa than benzoic acid?
a. p - nitrobenzoic acid
b. p - hydroxybenzoic acid
c. p - aminobenzoic acid
d. All of these
Question 14:
Question 15:
Question 16:
Question 17:
During dehydration of alcohols to alkenes by heating with conc. H 2SO 4, the initiation
step is:
a. Elimination of water
b. Formation of an ester
c. Formation of carbocation
Question 18:
a. 1.78
b. 1.52
c. 1.96
d. 1.20
Question 19:
The pH of a buffer solution prepared by mixing 50ml of 0.2MCH 3COOH and 25ml
of CH 3COON is 4.8. What is the concentration of CH 3COONa ? [pKa of
CH 3COOH = 4.8 ]
a. 0.2M
b. 0.4M
c. 0.5M
d. 0.8M
Question 20:
When three parts of conc. HCl and one part of conc. HNO 3 is mixed, a compound ' X
' is formed. The correct option related to ' X ' is:
Question 21:
d. All of these
Question 22:
a. XeF 4O
b. XeF 2O 2
c. XeO 3
−
d. XeO 3
Question 23:
What is the half-life of a radioactive substance if 87.5% of any given amount of the
substance disintegrate in 40 minutes?
a. 160 min
b. 10 min
c. 20 min
d. 13 min
Question 24:
a. Two
b. Six
c. Three
d. One
Question 25:
Question 26:
a. nitrogen oxide
b. nitrous oxide
c. nitrogen dioxide
Question 27:
a. Cobaltocene
b. Ruthenocene
c. Grignard's reagent
d. Ferrocene
Question 28:
What will happen when diethyl ether is treated with hot and concentrated HI?
a. Ethyl alcohol
b. Ethyl iodide
c. Methyl iodide
d. Methanol
Question 29:
a. F −
b. Cl −
c. Br −
d. I −
Question 30:
a. is negative of E a
d. is always double of E a
Mathematics
Question 1:
Question 2:
a. Reflexive
b. Symmetric
c. Transitive
d. Anti symmetric
Question 3:
a. ƒ(x2) = [ƒ(x)]2
b. ƒ(|x|) = |ƒ(x)|
d. None of these
Question 4:
1 + √3i
The amplitude of is:
√3 + 1
π
a. 3
π
b. − 3
π
c. 6
d. None of these
Question 5:
If sin α, sin2α, 1 are in A.P. where – π < α < π, then lies in the interval:
−π π
a. ( 2 , 2 )
−π π
b. ( 3 , 3 )
−π π
c. ( 6 , 6 )
d. None of these
Question 6:
x 2 − 2x + 4
If y = where x can take real values, then:
x 2 + 2x + 4
1
a. 3 ≤ y ≤ 3
b. 3 < y ≤ 5
c. 5 < y ≤ 7
d. 7 < y ≤ 9
Question 7:
How many 10 digits numbers can be written by using the digits 1 and 2:
a. 10C1
b. 210
c. 10C2
d. 10!
Question 8:
a. 196
b. 197
c. 198
d. 199
Question 9:
1 1 1 1 1 1
The sum of the series 1 + 3 ⋅ 4 + 5 ⋅ 2 + 7 ⋅ 3 …∞ is:
4 4
a. log e1
b. log e2
c. log e3
d. log e4
Question 10:
a. ±3
b. ±4
c. ±2
d. ±1
Question 11:
| | | |
a b c a 2 − bc b 2 − ca c 2 − ab
If Δ = c a b , then the value of c 2 − ab a 2 − bc b 2 − ca is:
b c a b 2 − ca c 2 − ab a 2 − bc
a. Δ 2
b. 2Δ 2
c. Δ 3
d. None of these
Question 12:
The image of the point (−8, 12) with respect to the line mirror 4x+ 7y + 13 = 0:
a. (−16,−2)
b. (−8,−1)
c. (16, 8)
d. None of these
Question 13:
The locus of a point which moves such that the tangents from it to the two circles x2
+ y2 -5x - 3 = 0 and 3x2 + 3y2 + 2x + 4y - 6 = 0 are equal, is given by:
a. 4x + 3y + 7 = 0
b. 17x + 4y + 3 = 0
c. 7x + 9y + 11 = 0
d. 13x + 4y + 15 = 0
Question 14:
5
a. ( 2 , − 1)
5
b. ( − 1, 2 )
3
c. ( 2 , − 1)
d. None of these
Question 15:
The ellipse x2/a2 + y2/b2 = 1 and the straight line y = mx + c intersect in real points
only if
a. a2m2 < c2 - b2
b. a2m2 > c2 - b2
c. a2m2 ≥ c2 - b2
d. c ≥ b
Question 16:
( √1 + x 2 − 1
) ( )
√
2x 1 − x 2
The derivative of tan − 1 x
w.r.t. tan − 1 at x = 0 is:
1 − 2x 2
1
a. 8
1
b. 4
1
c. 2
d. 1
Question 17:
22
a. 7
6
b. 7
c. -6
d. None of these
Question 18:
a. (1, ∞)
b. (−1, ∞)
c. (−∞, ∞)
d. (0, ∞)
Question 19:
a. e
b. ee
c. 1
s
d. √e
Question 20:
cos 4 x
a. − 4
+C
sin x
b. +C
x2
sin 3 x
c. − 3
+C
d. None of these
Question 21:
x
If f(x) = ∫ − 1 | t | dt, then for any x ≥ 0, f(x) equals:
( )
1
a. 2 1 − x 2
1
b. 2 x 2
( )
1
c. 2 1 + x 2
d. None of these
Question 22:
In the interval
[ ] π
0, 2 area lying between the curve y = tanx, y = cotx and x-axis is:
a. log2
1
b. 2 log2
c. 2log
()
1
√2
d. None of these
Question 23:
→
The projection of the vector a = 4 î − 3 ĵ + 2k̂ on the vector making equal angles
(acute) with coordinate axes having magnitude √3 is:
a. 3
b. √3
c. 2√3
d. None of these
Question 24:
The equation of the plane through the point (2, 2, 1) and (9, 3, 6) and perpendicular to
2x + 6y + 6z - 1 = 0 is:
a. 3x + 4y + 5z = 9
b. 3x + 4y - 5z = 9
c. 3x + 4y - 5z + 9 = 0
d. None of these
Question 25:
Dialing a telephone number an old man forgets the last two digits remembering only
that these are different dialed at random. The probability that the number is dialed
correctly is:
1
a. 10
1
b. 45
1
c. 90
d. None of these
Question 26:
π π π
The maximum value of sin(x + ) + cos(x + ) in the interval (0, ) is attained at:
6 6 2
π
a. 12
π
b. 6
π
c. 4
π
d. 3
Question 27:
a. No solution
b. Unique solution
d. None of these
Question 28:
π
a. 6
π
b. 4
π
c. 3
3π
d. 4
Question 29:
a. 0
b. (0, ∞)
c. (−∞, 0)
d. (−∞, 2)
Question 30:
a. 20
b. 25
c. 27
d. 30
Answers Physics
Explanations
Question 1 :
Weber = ML 2 T − 2I − 1
= ML 2 T − 2Q − 1 T = ML 2 T − 1Q − 1 (I = QT ) −1
H = ML 2 T − 2I − 2 also I = QT − 1
so H = ML 2 T − 2Q − 2 T 2 = ML 2Q − 2
Question 2 :
Two other balls are thrown in upward and downward directions simultaneously.
1
For first case of dropping the stone, h = gt 2
2
1 2 1
For second case of downward throwing h = ut 1 + 2 g 1 = 2 g 2
Or we can write
⇒ ut 1
1
( )
2
= 2 g t 2 − t 1 ……. (i)
1 2 1
For third case of throwing upwards h = − ut 2 + 2 gt 2 = 2 gt 2
Or we can write
( )
1 2
⟹ ut 2 = 2 g t 2 − t 2 …(ii)
On solving (i) and (ii) we get,
2
t1 t2 − t1
t2
=
t 22 − t 2
Or,
t=
√t1t2
Question 3 :
Here forces are applied in opposite directions. So net external force is zero. Their centre of mass will remain at
rest and finally they will meet at centre of mass. And centre of mass lies closer to M.
Question 4 :
It is given by
( )
1
W = 2 × k x 2 − x 21
x 1 = 5 cm
x 2 = 15 cm
N 800 N N
k = 800 m = 100 cm = 8 cm
( )
1 1
W = 2 × 8 15 2 − 5 2 = 2 × 8(225 − 25)
1 N
= 2 × 8 × 200 = 800 cm
N N
W = 800 cm = 8 m = 8 J
Question 5 :
The force of friction between the tyres and the road provides the necessary centripetal force to the car to take a
turn on a level road.
Question 6 :
GM e
Here, the acceleration at the earth's surface is g = g e = 2 and the
Re
GM m
acceleration at the moon's surface is g m = 2
Rm
Here, M e = 80M m or M e / M m = 80 and R e = 4R m or R e / R m = 4
gm 1
So,
ge (
= Mm / Me )(Re / Rm ) 2 = ( 80 )(4)2 = 0.2
or g m = 0.2g = 0.2(9.8) = 1.96 m / s 2
Question 7 :
F
A
= stress
400 × 4
= 379 × 10 6
πd 2
1600
d2 = = 1.34 × 10 − 6
π × 379 × 10 6
d= √1.34 × 10 − 3 = 1.15 × 10 − 3 m
Question 8 :
Hence, AL ratio is 1 : 8
Question 9 :
A molecule bounces elastically of the wall and to the other side and back.
21
Time it takes to come back is t = v
Δp 2mv mv 2
Force because of change in momentum when it hits the wall t = t
= l
Pressure is force per area, but we see that the pressure is directly proportional to mass and directly proportional
to square of velocity.
1
Hence if mass is halved and velocity doubled the pressure changes by 2 × 2 × 2 = 2times,
Question 10 :
2kx − f = ma
MR 2
Since we know that Γ = Iα For disk, I = 2
Also, a = Rα
4kx
Hence, ma = 3
Question 11 :
1v
v = 2L
V∝ √T
⇒ v ∝ √T
Hence the frequency of sound produced in organ pipe increases with the increase in temperature.
Question 12 :
The Electric field between oppositely charged plates of a capacitor is twice that due to one plate .Hence ,when
F
one plate is removed,the electric field becomes half and hence ,the force reduces by half ,i.e becomes 2 .
Question 13 :
Given:
I1 = 5 A
R ′ = 2Ω
I2 = 4 A
∴ I R = I (R + R )
1 2
′
∴ 5R = 4(R + 2)
R = 8ohm
voltrmeter reading, V = 20 V.
Series resistance,
R = 3.96 KΩ
R = 3960Ω
So, we have
V = (R + G)Ig
[ ∵ It is connected in sEries
so, 20 = (3960 + G) × 0.005
20 × 10
3960 + G = 0.005 = 4000
G = 4000 − 3960
G = 40Ω
Question 15 :
Gauss's law is based on the inverse square dependence on distance contained in the Coulomb's law. Any
violation of Gauss's law will indicate departure from the inverse square law.
Question 16 :
Self Inductance is directly proportional to the square of the Number of Turns in the coil.
l → length of solenoid
Question 17 :
e2
P= R
dϕ
where, ε = inducedemf = − dt
ϕ = NBA
dB
ε = NA dt
also, R ∝ 1
r2
P ∝ N 2r 2
12
P1
P2
=1
P1 = P2
This means if the number of turns were quadrupled and the wire radius halved, the electrical power dissipated
would remain same.
Question 18 :
Beyond 40 MHz, frequency doesn’t get reflected back by the ionosphere, it can pass through the ionosphere, due
to this microwave frequencies are not suitable for ionospheric propagation. Microwave frequencies are used in
Satellite communication.
Question 19 :
A person suffering from myopia (near-sightedness) can see only nearby objects clearly and it is corrected by
using a concave lens. Whereas a person suffering from hypermetropia (long-sightedness) can see only distant
objects clearly and it is corrected by using a convex lens.
Thus if a person suffers from both, then he must be using a concave lens to see distant objects and a convex
lens to see nearby objects (especially for reading). Hence his spectacles would be made of a concave lens as
the upper lens and convex lens as the lower lens.
Question 20 :
The wavelength as well as the speed of light is maximum in vacuum, as compared to that in any other medium.
Dλ
The fringe width in a double slit setup is given by β = d
Hence, the fringe width, and thus the interference fringes are farther apart in vacuum as compared to that in air.
Question 21 :
Resolving power or limit of resolution is the ability to distinguish two close objects as distinct. It is calculated by
the formula 0.61 λ/ numerical aperture, where λ is the wavelength of light and numerical aperture is the light
collecting ability of lens. Actually after calculations the value comes out to be 0.5 λ or one half the wavelength
of illuminating light. The average wavelength of light used in microscopes is 500 - 600 nm. It gives a maximum
resolution of 250 - 300 nm or 0.25 micrometer to 0.3 micrometer.
Question 22 :
1 1
Wave number v
ˉ= λ =
5896 × 10 − 8
= 16961 per m
Question 23 :
3240
Number of half lives in 3240 years = 1620 = 2
Question 24 :
Energy of electron in Bohr orbit is equal to sum of kinetic and potential energy
ΔE = KE + PE
Question 25 :
V CE = 8
R = 800
V C = 0.8
α = 0.96
Ib = ?
B=
( )
1−α
α 0.96
= 1 − 0.96 = 24
V
IC = R =
( )
0.8
800
5
= 8 × 10 − 3
5
= 8 × 10 − 3
I b = 26μA
or 2.6 × 10 − 5
Question 26 :
As the sphere is isolated, so the total charge on it will remain same, which is zero.
Presence or absence of any external charge nearby cannot change its total charge. But, Presence of external
charge will induce charges on the sphere as shown in the figure, this induction happens due to redistribution of
charges within the sphere only. As positive charge(+q ) will attract negative charges of the sphere. So, the
negative charge will move towards right and positive charges will move towards left.
Question 27 :
Given Z H = 1, Z Li = 3 and n H = n Li = 3
Question 28 :
γ−1
In an adiabatic process T 1 V 1 = T 2 V γ2 − 1
2 2
γ=1+ f =1+ 3
( ) ( ) ()
2 2
T1 V2 γ−1 V2 3 L2 3
T2
= V1
= V1
= L1
since volume is proportional to length due to area being constant.
Question 29 :
For diverging beam of light i.e., bending away from the normal, the ray has to be passes from denser medium μ 2
to lighter medium μ 1, Hence it has to be filled with L 2 and immersed in L 1.
Question 30 :
For complete disc with mass ' 4M ′, M.I. about given axis = (4M)
()
R2
2
= 2MR 2
MR 2 1
M.I. = 2
4
= 2 MR 2
Answers Chemistry
Explanations
Question 1 :
fusion
2P + 3Na 2O 2 + O 2 ⟶ 2Na 3PO 4
air
( 3 ) 3 ( )
Na 3PO 4 + 12 NH 4 MoO 4 + 21HNO 3 ⟶ NH 4 PO 4 ⋅ 12MoO 3 + 21NH 4NO 3 +
12H 2O
The organic compound is fused with sodium peroxide. The fused mass is then extracted with water. The
aqueous solution so obtained is boiled with concentrated nitric acid, and ammonium molybdate solution is
added to it.
A yellow solution or precipitate indicates the presence of phosphorus in the organic compound. The yellow
precipitate is of ammonium phosphomolybdate.
Question 2 :
Bakelite is used for making combs, electrical switches, handles of utensils and computer discs.
Teflon is used in making oil seals and gaskets and also used for non – stick surface coated utensils.
Question 3 :
A pan containing a liquid (b.pt.127°c) is placed over a strong flame capable of heating upto 600°C. The
temperature of boiling liquid can rise above 127°C during boiling, average K.E. of liquid molecules will increase
during boiling, temperature of boiling liquid will remain 127°C is correct about the liquid.
Question 4 :
The standard heat enthalpy of a compound is equal to its standard heat of formation.
When a compound is formed from its constituent elements in their standard states 25 ∘ C and 1 atm pressure),
the heat of the reaction is the standard heat enthalpy or the standard heat of the formation.
Question 5 :
The correct statement is: Ψ 2 is proportional to the probability of finding an electron. Ψ represents the wave
function or the amplitude function.
Question 6 :
ΔT f = iK fm…(1)
ΔT b = iK bm……(2)
ΔT b Kb
ΔT f
= K
f
ΔT b 0.512
0.816
= 1.86
ΔT b = 0.2246 0C
Question 7 :
The principle of paper chromatography is partition chromatography, wherein the substances are distributed or
partitioned between the liquid phase and the stationary phase. hence, here the mobile phase is liquid and
stationary phase is solid.
Question 8 :
An antigen is a foreign molecule that while entering an organism induces certain responses.
An antigen is any substance that causes your immune system to produce antibodies against it. This means your
immune system does not recognize the substance, and is trying to fight it off. An antigen may be a substance
from the environment, such as chemicals, bacteria, viruses, or pollen.
Question 9 :
Vat dye a colourless compound in the reduced state and coloured in the oxidized state.
Vat dye, any of a large class of water-insoluble dyes, such as indigo and the anthraquinone derivatives, that are
used particularly on cellulosic fibres. The dye is applied in a soluble, reduced form to impregnate the fibre and
then oxidized in the fibre back to its original insoluble form.
Question 10 :
When 2 solutions having same temperature are mixed then the temperature during mixture decreases. This can
happen only when the reaction absorbs energy from surroundings and thus lowers the surrounding i.e, mixture
temperature.
Question 11 :
For body centered cubic lattice, the relationship between the edge length a and the radius r is as given below:
4r
a=
√3
4 × 75
a= = 173.2pm
√3
Question 12 :
[ ] [ ]
HCl disassociates as H + + Cl − and common salt (NaCl) disassociates as
[Na ] + [Cl ]
+ −
[ ]
As HCl is passed through NaCl, Cl − increases since it is formed as a product of disassociation of HCl as well
as NaCl
Therefore, the disassociation of either NaCl or HCl ceases and one of these start to precipitate.
The precipitation starts when the ionic product of NaCl exceeds the solubility product.
Question 13 :
pK a value of 4-nitrobenzoic acid (3.41) is lower than that of benzoic acid (4.19).
Lower is the pK a value, greater is the acid strength. The electron withdrawing nitro ( − NO2 ) group increases
the acidity of benzoic acid.
Question 14 :
( )
First we add nitro group NO 2 to the benzene ring to form nitrobenzene through nitration of benzene as
nitration of benzene will give nitro benzene as a product. Then, we will treat nitro benzene with ferric chloride in
the presence of chlorine gas which will give 3- chloro nitro benzene. In the last step, the reduction of nitro group
in 3-chloro nitro benzene by lithium aluminium hydride which will give us 3-chloro aniline.
Since the nitro group is a meta director, we can then add Cl through chlorination. After that, we can reduce the
NO 2 Group to NH 2 Group.
Question 15 :
The number of milligrams of protective colloid which is just sufficient to prevent the coagulation of 10 ml
standard gold solution when 1 ml of 10% solution of sodium chloride is added to it, is called gold number.
The Gold Number is the minimum weight (in milligrams) of a protective colloid required to prevent the
coagulation of 10 ml of a standard hydro gold sol when 1 ml of a 10% sodium chloride solution is added to it. It
was first used by Richard Adolf Zsigmondy in 1901.
Question 16 :
Alkaline earth metals are less electropositive because of the smaller size and higher ionisation enthalpies of
alkaline earth metals as compared to alkali metals.
Question 17 :
Question 18 :
PV = nRT
⇒1×V= m
44
× 0.0821 × 300
⇒d= m
V
⇒d= 44
0.0821 × 300
Question 19 :
( [ CH3COONa ]
)
V×
pH = pK a + log
V × [ CH 3COOH ]
[CH3COONa ] = 0.4M
Question 20 :
Aqua regia is a mixture of nitric acid and hydrochloric acid in the molar ratio of 1:3. Aqua regia is a yellow-
orange fuming liquid. Aqua regia is used for the decomposition of weak acids.
Question 21 :
The CO molecule binds to hemoglobin at a much higher preferential rate compared to oxygen (≈240:1). Tying up
the oxygen carrier in the blood, hemoglobin results in COHb not easily releasing the carbon monoxide.
Therefore, hemoglobin will not be available to transport oxygen from the lungs to the rest of the body.
Question 22 :
XeF6 is one of the three binary fluorides formed by the xenon. The complete hydrolysis of XeF6 produces XeO3
which is xenon trioxide. This xenon trioxide is highly explosive and acts as a powerful oxidising agent in
solution.
Question 23 :
[ R ]0
Kt = 2.303log [ R ]
t
[ R ]0
K × 40 = 2.303log 12.5 [ R ] × 100
0
K = 0.052 min − 1
0.693
t 50% = K
0.693
t 50% = 0.052
Question 24 :
EDTA is a hexadentate ligand. It has 6 donor atoms. These six donor atoms form octahedral environment
around central metal atom.
Hence, one molecule of EDTA is required to form an octahedral complex with Ca 2 + ion.
Question 25 :
A. Concentrated sulphuric acid reacts with aluminium to produce sulphur dioxide and aluminium sulphate.
B. Aluminum react with nitric acid to produce aluminum nitrate, nitrogen dioxide and water.
C. Aluminium metal react with dilute HCl to give a salt and hydrogen gas.
Question 26 :
NO 2 exists as dimer N 2O 4.
The lewis structure of nitrogen dioxide requires that the central atom nitrogen be bonded to one oxygen through
a double covalent bond and to another oxygen through a three electron bond. So one electron remains unpaired.
If two nitrogen dioxide units dimerize through N − N bonds formation the odd electron on N couples with that of
another molecule. So it is dimagnetic in nature.
Question 27 :
Question 28 :
HI → H + + I −
The iodide ion produced will attack one of the Carbon-oxygen bonds, gets attached to carbon, the hydrogen ion
produced in the first step will get attached to a negatively charged oxygen atom:
The ethanol produced in the above step still has a carbon-oxygen bond and we are provided with an excess of
HI (concentrated), so the iodide ion will now attack the carbon-oxygen bond of ethanol similarly, and the
hydrogen ion will get attached to hydroxide ion produced:
CH 3CH 2 − OH + HI → CH 3CH 2 − I + H 2O
Thus, the overall reaction between diethyl ether and hot and concentrated HI will be:
Question 29 :
Fluoride ions are difficult to oxidize into fluorine because the size of fluoride ions is so small that the electrons
present in the orbitals experience strong repulsive forces from each other. Due to these repulsions, the effect of
the electrons outweighs their closeness with the nucleus and it becomes very easy to remove an electron.
Hence, it takes very less energy to remove an electron from a fluoride ion.
Hence, the fluoride ion is the strongest oxidizing agent and a weak reducing agent i.e., fluoride ion itself gets
reduced by gaining electrons and oxidizing other molecules. Therefore, the halide which is not oxidized by
Question 30 :
As we know,
ΔH = E a − E a ; if ΔH = − ve, E a > Ea
(f) (b) (b) (f)
if ΔH = + ve, E a < Ea
(b) (f)
Answers Mathematics
Explanations
Question 1 :
x2 + 1 = 0
⇒x = −1
2
⇒x= ±i
i.e., x is an imaginary number.
}
Hence {x : x is a real number and x 2 + 1 = 0 is an empty set.
Question 2 :
Obviously, the relation is not reflexive and transitive but it is symmetric, because
x2 + y2 = 1 ⇒y 2 + x 2 = 1.
Question 3 :
f(x) = [x − 1]
( )
f x 2 = (f(x)) 2
|x 2 −1 |≠x 2 + 1 − 2x
||x | − 1 | = | x − 1 |
x= −5≠6
Question 4 :
1 i
√3 + 1
+
√3
√3 + 1
√3
√3 + 1
tan − 1( 1 )
√3 + 1
= tan − 1(√3)
π
= 3
Question 5 :
We have,
Then,
Commondifference=Secondterm-firstterm
Where
T 1 = First term
T 2 = Second term
T 3 = Third term
⇒ 2sin α − sinα − 1 = 0
2
⇒ 2sin α − (2 − 1)sinα − 1 = 0
2
⇒ 2sinα(sinα − 1) + 1(sinα − 1) = 0
⇒ (sinα − 1)(2sinα + 1) = 0
⇒ sinα − 1 = 0, 2sinα + 1 = 0
⇒ sinα = 1, sinα = −1
2
⇒ sinα = sin π
2
, sinα = − sin 6
π
⇒α= π
2
, sinα = sin π + 6
( ) π
∵ sin(π + θ) = − sinθ
⇒α= π
2
, α= 6
7π
π
α= − 2
Hence, α =
( π π
− 2, 2
)
Question 6 :
x 2 − 2x + 4
y=
x 2 + 2x + 4
x 2y + 2xy + 4y = x 2 − 2x + 4
x 2(y − 1) + 2x(y + 1) + 4y − 4 = 0
Since x is real, D ≥ 0
− 12y 2 + 40y − 12 ≥ 0
3y 2 − 10y + 3 ≤ 0
(3y − 1)(y − 3) ≤ 0
1
Hence, 3 ≤ y ≤ 3
Question 7 :
Each place of a ten digit number can be fixed by any of the two digits. So, the number of ways to form a ten digit
number is 2 10.
Question 8 :
(√2 + 1) 6 = A
(√2 − 1) 6 < 1
⇒ 198 = [A] + f + f 1
0 < f1 < 1
0 < f + f1 < 2
Question 9 :
log 2
() ()
3
− log 2
1
( 1
2
1
2
1
= 2 2 + 3 ⋅ 3 + 5 ⋅ 5 + …∞
1 1
)
()
3
⇒ log e
2
1
1 1
=1+ 3 ⋅ 4 + 5 ⋅ 2 +…
4
1 1
⇒ log 3 = 1 +
e
1 1
⋅ + 5 ⋅ 2 + …∞
3 4 4
1 1
Question 10 :
Orthogonal matrix is a square matrix with real entities whose columns and rows are orthogonal unit vectors
⇒ AA T
=I
⇒ |A| = 1 2
⇒ |A| = ± 1
Question 11 :
| |
a b c
Δ= c a b
b c a
( ) (
= a a 2 − bc − b − b 2 + ac + c c 2 − ab ) ( )
= a 3 − abc − abc + b 3 + c 3 − abc
= a 3 + b 3 + c 3 − 3abc
Now,
| |
a 2 − bc b 2 − ac c 2 − ab
c 2 − ab a 2 − bc b 2 − ac
b 2 − ac c 2 − ab a 2 − bc
| | | |
a2 b2 c2 bc ca ab
= c2 a2 b2 − ab bc ac
b2 c2 a2 ac ab bc
( ) (
= a 2 a 4 − b 2c 2 − b 2 − b 4 + a 2c 2 + c 2 c 4 − b 2a 2 ) ( )
{ ( ) (
− bc b 2c 2 − a 2bc − ac acb 2 − a 2c 2 + ab b 2a 2 − abc 2 ) ( )}
(
= a 3 + b 3 + c 3 − 3abc ) 2
= Δ2
Question 12 :
( )
Here x 1, y 1 is ( − 8, 12)
a = 4, b = 7 and c = 13
α+8 β − 12 − 2 { 4 ( − 8 ) + 12 ( 7 ) + 13 }
4
= 7
=
( − 8 )2 + ( 7 )2
α+8 β − 12 − 2 ( 65 )
4
= 7
= 65
⇒ = − 2, = − 2
α+8
4
β − 12
7
⇒ α = − 8 − 8, β = − 14 + 12
⇒ α = − 16, β = − 2
So, the image of the point is ( − 16, − 2).
Question 13 :
Given, 3x 2 + 3y 2 + 2x + 4y − 6 = 0
⇒x 2
+ y2 +
() ()
2
3
x+
4
3
y − 2 = 0 (1)
and x 2 + y 2 − 5x − 3 = 0 (2)
solving (1) and (2) we locus, i.e., x 2 + y 2 − 5x − 3 = x 2 + y 2 +
() ()
2
3
x+
4
3
y−2
⇒ 17x + 4y + 3 = 0
Question 14 :
Let (h, k) be the mid-point of the chord 2x + y − 4 = 0 of the parabola y 2 = 4x. Then, its equation is
ky − 2(x + h) = k 2 − 4h
[using T = S ′ ]
⇒ 2x − ky + k 2 − 2h = 0 (i)
∴ − k = 1 and k 2
−2h= −4
⇒ k = − 1, h = 5
2
Question 15 :
x2 ( mx + c ) 2
+ =1
a2 b2
⇒ x2
a2
+
m 2x 2
b2
+
c2
b2
+
2cmn
b2
=1
⇒b x 2 2
(
+ a 2 m 2x 2 + 2cmn + c 2 = a 2b 2 )
⇒ x (b 2 2
) ( )
+ a 2m 2 + x 2cma 2 + a 2c 2 − a 2b 2 = 0
for x to be real,
(2cma ) 2 2
(
≥ 4 b 2 + a 2m 2 )(a c2 2
− a 2b 2 )
⇒ 4c m a ≥ 4a b c − a b + a m c − a b m
2 2 4 2 2 2 2 4 4 2 2 4 2 2
⇒a c m ≥b c −b +a m c −a b m
2 2 2 2 2 4 2 2 2 2 2 2
⇒0≥c −b −a m ⇒a m ≥c −b
2 2 2 2 2 2 2 2
Question 16 :
Let y = tan −1
( √1 + x 2 − 1
x ) Put x = tanθ
∴ y = tan −1
( √1 + tan2 θ − 1
tan θ )
= tan − 1
( ) sec θ − 1
sin θ
cos θ
= tan − 1
( 1 − cos θ
sin θ )
( )
θ
2sin 2 2
= tan − 1 θ θ
2sin 2 cos 2
( )
= tan − 1 tan 2
θ θ 1
= 2 = 2 tan − 1x
∴ dy
dx
=
2 ( 1 + x )2
1
( ) √
2x 1 − x 2
Let z = tan − 1 Put x = sinϕ
1 − 2x 2
∴ z = tan −1
( 2sin ϕcos ϕ
1 − 2sin 2 ϕ )
( )
= tan − 1 cos 2ϕ
sin 2ϕ
= 2ϕ
∴ z = 2sin −1
x ∴ dz
dx
=
2
√1 − x 2
1
(
2 1 + x2 ) √1 − x 2
∴ dy
dz
= 2 =
√1 − x 2 (
4 1 + x2 )
dy √1 − 0 1
At x = 0, dz = 4 ( 1 + 0 ) = 4
Question 17 :
t 2 + 3t − 10 = 0 ⟹ t = 2 or t = − 5
From (i)
2t 2 − 2t − 4 = 0 ⟹ t 2 − t − 2 = 0 ⟹ t = 2 or t = − 1
dx
dt
= 2t + 3……. . (ii)
dy
dt
= 4t − 2…… (iii)
dy
dy dt
Now, dx = dx
dt
4t − 2
= 2t + 3 …. From (iii) and (iv)
∴ dy
dx
4t − 2
= 2t + 3 is the slope of tangent to the given curve
∴ | | dy
dx
(2, −1)
=
| | 4t − 2
2t + 3
t=2
8−2 6
= 4 + 3 = 7 is the slope of tangent to the given curve at (2,−1).
Question 18 :
f(x) = cot − 1x + x
d d
f ′(x) = dx cot − 1x + dx (x)
−1
= +1
1 + x2
− 1 + 1 + x2
=
1 + x2
=
x2
1 + x2
≥ 0, ∀x ∈ R
So f(x) is increasing on ( − ∞, ∞).
Question 19 :
Let
y=
()
1
x
2x 2
Or
lny = − 2x 2lnx
Now
y ′ = − y[4xlnx + 2x]
() 1 2x 2
= − x
(4xlnx + 2x)
Now
()1
x
2x 2
cannot be equal to zero.
Hence 4xln(x) + 2x = 0
Or
2x(2ln(x) + 1) = 0
Or
⇒x=
−1 1
x = 0 or lnx = 2 e−2
Hence
1
y = ee
Question 20 :
I = ∫ cos 3xsinxdx
t4 cos 4 x
I = − ∫ t 3dt = − 4 + C = − 4
+C
Question 21 :
{
x
∫ − 1 − tdt −1 ≤ x ≤ 0
0 x
∫ − 1 − tdt + ∫ 0tdt x≥0
f(x) =
(1 − x ),
1
2 −1 ≤ x ≤ 0
2
{ (1 + x ),
1
2 x≥0
= 2
Question 22 :
C 1 → y = tanx, x ∈ [− π π
,
3 3 ]
C2 → y = x ∈[ π π
,
6 6 ]
π π
The region is symmetric about lines x = 4 and its first portion is bounded between the lines x = 0 and x = 4
π
Required Area = 2∫ 04 tanxdy
π π
= 2[log(sec)] 0y = 2[log(sec ) − log(sec0)]
Question 23 :
→
a = 4 î − 3 ĵ + 2k̂
→ 1̂
Let b = x 1 + y ĵ + zk̂
⇒ x
= cosθ x = cosθ y =
y
= cosθ z =
z
√x 2 + y 2 + z 2 √x 2 + y 2 + z 2 √x 2 + y 2 + z 2
⇒x=y=z
∴ b = x( î + ĵ + k̂)
¯
|b| = √3
⇒ √x + x + x = √ 3
2 2 2
⇒ 3x = 3 2
⇒k= ±1
∴ b = î + ĵ + k̂ or b = − ( î + ĵ + k̂)
→ →
Projection of a or b
→ →
⇒ a⋅b
| bˉ |
⇒ x(4−3+2)
√3
⇒± (3)
√3
= ± √3
Question 24 :
∴ 7a + b + 5c = 0 and 2a + 6b + 6c = 0
On solving above equations by cross-multiplication, we get
⇒ a
6 − 30
−b
= 42 − 10 = 42 − 2
c
⇒ a
− 24
= − 32 = 40
b c
⇒ a
−3
= −4 = 5
b c
Question 25 :
⇒P= 1
90
Question 26 :
Differentiating once w.r.t to x and equating it to zero to get the extremum points we get,
⇒ f (x) = cos (x +
′
π
6 ) ( )
− sin x + 6
π
⇒ cos (x + π
6 ) ( )
− sin x + 6
π
=0
⇒ cos (x + π
6 ) ( )
= sin x + 6
π
⇒x+ π
6
= 4
π
⇒x= π
12
Again differentiating to perform double derivative test and check whether the extremum gives a maximum or
minimum
⇒ f (x) = − sin (x +
′′
π
6 ) ( )
− cos x + 6
π
⇒f (′′
π
12 ) (
= − sin 12 + 6
π π
) ( π
− cos 12 + 6
π
)
⇒f (′′
π
12 ) π
= − sin 4 − cos 4
π
⇒f ( ′′
π
12 ) = − √2
⇒f ( ′′
π
12 ) <0
π
Hence the point x = 12 is a point of maxima.
Question 27 :
Given sin −1
x − cos −1
x = cos −1
( )
√3
2
⇒ sin − 1x
π
− cos − 1x = 6 …… (i)
π
But sin − 1x + cos − 1x = …… (ii)
2
π
On solving Eqs. (i) and (ii), we get sin − 1x = 3
∴x= √
π 3
and cos − 1x = is the unique solution.
6 2
Question 28 :
LHS is an infinite G.P. with common ratio sinθ and first term 1
⇒ 1
1 − sin θ
= 2√3 + 4 = 2(√3 + 2)
⇒ 1 − sinθ = 1
2 ( 2 + √3 )
2 − √3
⇒ 2(1 − sinθ) = 1
2 + √3
⋅
2 − √3
2 − √3
⇒ 2 − 2sinθ = 4−3
= 2 − √3
√3
⇒ sinθ = 2
⇒θ= π
3
Question 29 :
We have 5x − 3 < 3x + 1
⇒ 5x − 3 + 3 < 3x + 1 + 3
⇒ 5x < 3x + 4
⇒ 5x − 3x < 3x + 4 − 3x
⇒ 2x < 4 ⇒ x < 2
(i) When x is an integer the solutions of the given inequality are {. . , − 4, − 3, − 2, − 1, 0, 1}
(ii) When x is a real number the solutions of the inequality are given by x < 2 i.e. all real number x which are less
than 2 Therefore the solution set of the inequality is x ( − ∞, 2) ∈
Question 30 :
We may have:
= (20 + 5) = 25