0203 Enthusiast Score-II Answerkey Solution P
0203 Enthusiast Score-II Answerkey Solution P
PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I (i)
A. A,B A,C A,B,D B,D B,C A,C
Q. 7 8 9 10
SECTION-I (ii)
A. C D C A
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 0.06 5.00 5.00 3.00 6.00 3.00 6.00 7.00
PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I (i)
A. B,C,D B,D B,D B A,B,D B,C,D
Q. 7 8 9 10
SECTION-I (ii)
A. A B A A
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 4.00 2688.00 17.00 2.00 5.00 47.50 2.00 2.00
HINT – SHEET
dQ dQ dt Q
I= ⇒ = ⇒ = 1 − e−t/ε0ρ
dt q0 − Q ∈0 ρ q 0
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3. Ans ( B,C,D ) 5. Ans ( A,C )
h
⇒ WAB = – 60 kJ = ⇒ |WAB| = 60 kJ a
= 2 ∫ ρ 2x4 . dx
Work done in process B → C (Isothermal process) 0
a
V V 4ρx5 4ρa5
WBC = nRT ℓn C = PB VB ℓn C =[ ] =
VB VB 5 5
0
5 0.8
⇒ WBC = 3 × 10 × 0.4ℓn
0.4 Now,
⇒ WBC = 84 kJ
WCA = P Δ V = 0 ( ∵ ΔV = 0)
So total work done in the process A → B → C Moment of inertia of the plate about x-axis
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6. Ans ( C,D ) 10. Ans ( C )
f = −Kv 2SW = P(dhW)g
dv
m⋅ = −Kv
dt
v t
dv k
∫ =− ∫ dt
v m
v0 0
v K
ln( ) = − ⋅t
v0 m 2S
v = v0 e− m ⋅t
K
h=
ρgd
mv mv0 − mK ⋅t 4S 2
R= = e WST = (2SW )h =
qB qB ρgd
F rom f− = Kv h 2S 2
dv Wg = (ρdhW g) =
m. v − = Kv 2 ρgd
dx
v 0 WST − Wg = ΔH
K
∫ dv = − ⋅ ∫ dx
m Force of attraction
v0 x
K K mv0 2S h
v = v0 − ⋅ x = v0 − ⋅ P0 hW − (P0 − + ρg )hW = F
m m 2K d 2
v
v= 0 2S 2 W
2 F=
mv mv0 ρgd 2
R= =
qB 2qB
PART-1 : PHYSICS
PART-1 : PHYSICS
SECTION-II
SECTION-I (ii)
3. Ans ( 6.25 )
9. Ans ( C )
ω2 x2
The equation of rotating surface is given by y =
2g
also the radius of curvature at any point is v = 325 m/s
dy 2 3/2
ρ = [1 + ( dx ) ] V 325
v= ∴ ν10 =
4L 4 × 0.52
d2y
dx2 325
ν20 =
ω2 x2 dy ω2 x 4 × 0.50
y= ; =
2g dx g 325 1 325 0.004
d2y ω2 ν10 – ν20 =
4
(1 −
0.264
) =
4
(
0.260 × 0.0264
)
=
dx2 g 0.325
3/2 = = 6.25Hz
ω2 x2
[ 1+ ] 0.260 × 0264
g2
∴ ρ=
ω2 /g
3/2
4. Ans ( 1.25 )
ω4 r20
[ 1+ ] Δ X = 2 µt
r 4g 2
ρ( 0 ) = For destructive interference
2 ω2 /g
r20
r0 ω2 2µt = λ /2
4
h( ) = λ
2 2g μ= = 1.25
4t
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5. Ans ( 12.75 ) 7. Ans ( 3.00 )
For first refraction from lens V1 = 3 sin ωt;
1 1 1 1 1 1
− = ⇒ = −
v 30 20 v 20 30 V2 = 5 sin(ωt + ϕ1 );
v = +60 cm (image on principal axes)
V3 = 5 sin(ωt − ϕ2 )
2nd refraction from lens
1 1 1
− =
v +60 20
1 1 1 1 3+1
= + ⇒ =
v 20 60 v 60
V = + 15 cm
Now for second lens principal axis is 3mm below 2
5 √3 2
Vmax = ⎷( ) + (1.5) = √21
the original principal axis 2
hi v h +15 Vmax √ 21 21 × 3
Hence = ⇒ i = Imax = = =√ = 3A
ho u +3 +60 R 7 7
√
3 3
hi =
4
mm
8. Ans ( 0.80 )
3 9
∴ y coordinate = – (3 − ) = − mm λLα = 124 pm
4 4
Coordinates = (15, −9 )
4
6. Ans ( 4.00 )
Ceq = 3 μF
30
P.D. across R1 in steady state = 100 + 50
× 100 = 20 V
1
∴ U= (1 + 2) × 10−6 × 400 = 6 × 10−4 J
2
hc
E1 = = 10 keV
After switch is opened, heat is generated is R1 and λL α
E3 = E1 + E2
R2 only.
E3 = 10 + 5.5 = 15.5 keV
Heat developed,
Energy required to ionise eΘ from ‘L’ shell is 15.5
H1 ∫ I 2R 1 dt
R
= = 1
H2 I 2 R2 dt
∫ R2 keV i.e. the minimum wavelength of characteristics
UR2 200
H2 = = 6 × 10−4 × = 4 × 104 J x-ray we can produce
R1 + R2 300
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PART-2 : CHEMISTRY PART-2 : CHEMISTRY
SECTION-I (i) SECTION-I (ii)
(conc)
interchanged. ⇒n=2
(B) Void is surrounded by 6 face centre atoms. (D) Hydrolysis of ester in alkaline medium obey
(C) No. of octahedral voids = 4 per unit cell
second order kinetics.
No. of tetrahedral voids = 8 per unit cell
No. of THV 2
10. Ans ( A )
(D) Ratio of =
No. of OHV 1
Phenol gives white precipitate of
4. Ans ( B,D )
B2H6 burns spontaneously in air to form oxide BN with bromine water & violet complex with FeCl3.
is bad conductor of electricity.
5. Ans ( B,C ) Aniline gives white ppt of with
NaNO2 +HCl
−−−−−−−−→ bromine water and Lassagne’s test for
When leaving group is present at equatorial Lassagne’s test for both sulphur and nitrogen and
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PART-2 : CHEMISTRY 5. Ans ( 6.00 )
SECTION-II
1. Ans ( 0.06 )
Let after 200 min,
x mole of A remained.
P = XA . PAo + XB . PBo
x 20
6. Ans ( 3.00 )
400 = × 300 × 500
21 + x 21 + x
∴ x = 16
noA
Now, K = 1 . ln
t nA
1 20 All aldehyde isomers of ‘A’ and PhCOCH2CH3
= × ln
200/60 16 and PhCH2COCH3 does not give iodoform
= 0.06 hr –1
7. Ans ( 6.00 )
3. Ans ( 5.00 ) (i), (ii), (iii), (v), (vii) & (viii) gives aldehydes.
Cane sugar + H2O(ℓ) → Glucose + Fructose
t = 0 0.05 mole 0 0 PART-3 : MATHEMATICS
t 0.05–0.05α 0.05α 0.05α SECTION-I (i)
Total moles = 0.05 – 0.05α + 0.05α + 0.05α = 0.05 (1 + α) 1. Ans ( B,C,D )
ΔTf = iKmf r2 1 r r
Tr = = ( + )
0.05 (2r − 1)(2r + 1) 4 2r − 1 2r + 1
0.279 = (1 + α) 1.86 × ( )
500/1000 500
r r
0.279 × 5 4S = ∑ ( + )
(1 + α) = = 1.5 2r − 1 2r + 1
1.86 × 0.5 r=1
2πrn1 nλ
= 1 1 ....(i) 2. Ans ( B,D )
2πrn2 n 2 λ2 →
Let w = λ1 →u + λ2→v + λ3 (→u × →v)
Also we know that
0.529n2 Taking dot product with →u × →v, we get λ3 = 5 .
rn = 3
z
Putting the value in equation (i) → . →u = λ1 ; w
w → . →v = λ2
n1 λ ⇒ 3 λ1 + 2λ2 = 0
⇒ = 1
n2 λ2
2λ1 2λ1
Also n1 = 1 and if we provide energy equal to x3 + 1 dx
12.09 eV, then electron will jump to n2 = 3 Given : ∫ dx = 2 ∫
x2 + 1 x2 + 1
−2λ1 0
λ1 1
⇒ = 1 3
λ2 3 ⇒ λ1 = , λ2 = −
⇒ λ2 = 3λ1 2 4
19
So, wavelength increases 3 times. → . w
w → =
8
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3. Ans ( B,D ) 5. Ans ( A,B,D )
1 ∞
A + BT = adjB ; B + AT = adjA −( z 2 + 1
) −( z 2 + 1
)
A=∫ e z2 dz + ∫ e z2 dz
⇒ AT + B = (adj B)T 0 1
1
⇒ adj A = (adj B)T Let z =
t
2 2
⇒ |B| = |A| ∞ ∞
1 − ( t2 +
1
) −( z 2 +
1
)
A=∫ e t2 dt + ∫ e z2 dz
|B| = ±|A| t2
1 1
∞
(a) |A| = |B| 1 − ( x2 + 1
) 1
A=∫ ( 1+ )e x2 dx let x − =u
x 2 x
(B−1 )T = A−1 1
∞
T u2 +2) B
⇒ A=B = ∫ e− (
du =
e2
0
adj B = 2BT
6. Ans ( B,C,D )
2
⇒ |B| = 8|B|
Let x = tan θ
⇒ |B| = |A| = 8
π
x⩽0 ( θ ∈ (− , 0])
2
(b) |A| = −|B|
sin θ + cos θ
similarly ⇒ A = −BT f(x) = cos−1 ( )
√ 2
= 29 .9 (λ2 )
λ2 = 9 8
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PART-3 : MATHEMATICS (ii) f(−1) > 0 and f(1) > 0
2(−1)2 − 10p(−1) + 7p − 1 > 0 and
SECTION-I (ii)
2(1)2 − 10p(1) + 7p − 1 > 0
7. Ans ( A ) 17p + 1 > 0 and −3p + 1 > 0
(I) A, B, C are the 3 critical points of y = f(x) −1 1
⇒ p ∈ ( , )
f ′′ (x) = 0 for x = 2 and fails to exists at x = 0 17 3
−1 1
From (i), (ii) and (iii) p ∈
, ) (
17 3
(II) Exactly one roots of f(x) = 0 lies in (−1, 1)
f(−1) ⋅ f(1) < 0
(17p + 1) (−3p + 1) < 0
(II) x = 1/4 and 2. Make a quadratic in log2x and (17p + 1) (3p − 1) > 0
interpret the result. −1 1
⇒ p ∈ ( −∞, ) ∪ ( , ∞)
17 3
dy 3 1 −1
(III) = −1 + 2x31 = − ⇒ x1 = Also when f(−1) = 0 ⇒ p=
dx 4 2 17
1 1 10 24
⇒ = + y1 or f(x) = 2x2 + x−
32 2 17 17
15 57 f(x) = 34x2 + 10x − 24
y1 = − ⇒ c=−
32 32
Here, f(1) = 34(1)2 + 10(1) − 24 > 0
⇒ Other root is lies in (−1, 1)
−1
∴ p= is also possible.
17
1
Again f(1) = 0 ⇒ −3p + 1 = 0 ⇒ p=
(IV) f ′ (x) = 2x3 − 3x + 1 this is always positive in 3
10 4
(1, 2) f(x) = 2x2 − x+ = 6x2 − 10x + 4
3 3
∴ increasing [1, 2] f(−1) = 6(−1)2 − 10(−1) + 4 > 0
∴ f(2) will be greatest value. ⇒ Other root lies in (−1, 1)
2
= 4(25 p − 14p + 2 ) −b 5p 2
(ii) 2a
> 1 ⇒
2
> 1 ⇒ p = ( , ∞)
5
∵For the equation 25p2 − 14p + 2 = 0 1
(iii) f(1) > 0 ⇒ −3p + 1 > 0 ⇒ p <
⇒ a − 25 > 0 and 3
1
D = (−14)2 − 4 ⋅ 25 = 2 − 4 < 0 ⇒ p ∈ ( −∞,
3
)
⇒ 4(25p2 − 14p + 2) > 0 for all p ∈ R From (i), (ii) and (iii) p ∈ ϕ
⇒ D > 0 (IV) One root of f(x) = 0 is greater than 1 and other
Now, root of f(x) = 0 is less then –1.
(I) Both roots of f(x) = 0 are confined in (−1, 1) f(1) < 0 and f(−1) < 0
⇒ (i) D 0 (for all p ∈ R)
⩾ ⇒ f(1) < 0 and f(−1) < 0
−b ⇒ 17p + 1 < 0 and − 3p + 1 < 0
(ii) −1 < < 1
−1 1
2a ⇒ p < and p >
−10p −2 2
⇒ −1 < − ( ) < 1 ⇒ p ∈ ( , ) 17 3
4 5 5 ⇒ p ∈ ϕ
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9. Ans ( A ) 10. Ans ( A )
x2 y2
(I) We have f(x) = 5
√ x + sin−1 x (I) + =1
9 16
Clearly domain of f(x) = [−1, 1]. Mid point (0, 3)
Ans. P, S y=3
x2 9
(1 − |x|) + =1
(II) f(x) = sgn 9 16
(1 + |x|) 3
x = ± √7
Df = R 4
3√
Length of chord = 7
2
Rf = {−1, 0, 1} even function
(II) Equation of chord of parabola is
Ans. Q, R, T y(t1 + t2 ) = 2x + 2at1 t2
y(t + 1) = 2x + 2t
2x = (t + 1)y
[−x]
=1 .....(1)
2 |x| −x −x
−2t
(III) f(x) = −2 =2 −2 =0∀x⩽0
2{x} y 2 = 4x(1)
Ans. T y 2 = 4x (
2x − (t + 1)y
)
−2t
(IV) For domain of f(x) we must have −2 + y 2 = 8x2 − 4(t + 1)xy
⇒ (x + 4) (x − 2) ⩽ 0 8 + 2t = 0
⇒ x ∈ [−4, 2] t = −4
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PART-3 : MATHEMATICS 5. Ans ( 5.00 )
y = 2 + (1 − x) − √ x2 − 2x + 1, x < 1
SECTION-II
1. Ans ( 4.00 ) = 2 + (1 − x) − (1 − x)
e(1 + (1/x)) y = 2
l = Lim x ln ( ) ( ∞ × 0 form)
x→∞
(1 + (1/x))x
A, y = 2 x2 + 4 = 13
= Lim
x→∞
x (1 + ln(1 + 1 ) − x ln(1 + 1 ))
x x
1 x2 = 9
put x = ; as x → ∞ , t → 0
t
ln(1 + t) x = 3, −3, x < 1
1
Hence l = Lim
t→0 t
(1 + ln(1 + t) − )
t x1 = −3
1/t t − ln(1 + t)
= Lim
t→0
[ln (1 + t) + ]
t2 A(−3, 2, 0)
ey − 1 − y
= 1 + Lim( ) where ln(1 + t) = y; 1 + t
y→0 y2 x22 + y22 < 13
= ey, hence t = ey – 1 x22 < 9
1 3 m
=1+ = = −3 < x2 < 3, x2 < 1
2 2 n
2. Ans ( 2688.00 ) Max(x2) = 0
Equation of line
So, total number of ways to distribute chocolates x+3 y−2 z−3
= =
among his grand children 3 4 5
8! 8!
=( + ) 3!
1! 2! 5! 1! 3! 4!
= 2688
3. Ans ( 17.00 )
P(G G G G)
↓↓ 3(3λ) + 4(4λ) + 5(5λ + 3) = 0
4 3 3
= × =
8 7 14 50λ = −15
4. Ans ( 2.00 ) λ =
−3
If |z| = |z – 2| 10
2 2 2
z. ¯z = zz¯ − 2z − 2z¯ + 4 9 12 15
PQ = √
( ) + ( ) + ( )
10 10 10
z. ¯z = 2 1
= √81 + 144 + 225
∴ |z + ¯z | = 2 10
√450 3 × 5 √2 3
If |z| = |z + 2| = = =
10 10 2
z. ¯z = zz¯ + 2z + 2z¯ + 4 √
z + ¯z = −2
A = 3, b = 2
∴ |z + ¯z | = 2 a +b = 5
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6. Ans ( 47.50 ) 7. Ans ( 2.00 )
Let the equation of curve is Y = F(x)
1 xb−1 2x
I(a, b) = ∫ dx
2 (1 + x2 )a
A =
1
, B =
1−b F ′ (x) (x + y) = y − x
b + 1 − 2a b + 1 − 2a y−x
F ′ (x) =
y+x
Let y = tx
b = 97, a = 50 dt t−1
t+x =
dx t+1
dt t − 1 − t − t2
x =
−1 dx t+1
A= , B = 48 (t + 1) dt
2 −dx
=
2
t +1 x
1 2t 1 dx
( + ) dt = −
A + B = 47.5 2 t2 + 1 t2 + 1 x
1
ln(t2 + 1) + tan−1 t = − ln x + C
2
1 x2 + y 2 −1 y
ln( ) + tan = − ln x + C
2 x2 x
1 y
ln(x2 + y 2 ) + tan−1 = C
2 x
f(1) = 0 ⇒ 1 ln(1) + tan−1 (0) = C ⇒ C = 0
2
1 y
ln(x + y ) = −tan−1 ( )
2 2
2 x
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8. Ans ( 2.00 )
1
z
k
f(k) = lim z ∫ tt+k−1 dt
z→∞
0
1
Put z =
x
x
∫ tt+k−1 dt
0
= lim
x→0 xk
xx ⋅ xk−1
= lim
x→0 K xk−1
1
= lim xx
K x→0
1
= lim ex ln x
K →0
x
1 ln x
= lim e 1/x
K x→0
1
f (k) =
K
1
f(4) =
4
xy = 4, x2 + y 2 = 8
16
x2 + =8
x2
x4 − 8x2 + 16 = 0
x2 = 4 ⇒ x = ±2
y = ±2
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