SRI CHAITANYA IIT ACADEMY, INDIA 01‐10‐22_SR.

S60_NUCLEUS & STERLING‐BT_ Jee‐Main_PTM‐04_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.S60_NUCLEUS & STERLING‐BT JEE-MAIN Date: 01-10-2022
Time: 09.00Am to 12.00Pm PTM-04 Max. Marks: 300
KEY SHEET
PHYSICS
1) 2 2) 4 3) 1 4) 1 5) 1
6) 3 7) 2 8) 4 9) 2 10) 3
11) 3 12) 3 13) 2 14) 1 15) 3
16) 1 17) 3 18) 2 19) 3 20) 4
21) 8 22) 7 23) 18 24) 49 25) 130
26) 40 27) 22 28) 8 29) 2 30) 125

CHEMISTRY
31) 4 32) 2 33) 1 34) 1 35) 4
36) 3 37) 3 38) 1 39) 1 40) 2
41) 2 42) 4 43) 2 44) 4 45) 4
46) 3 47) 1 48) 4 49) 3 50) 1
51) 9 52) 6 53) 6 54) 4 55) 3
56) 2 57) 8 58) 4 59) 4 60) 4

MATHEMATICS
61) 4 62) 2 63) 3 64) 1 65) 2
66) 3 67) 3 68) 1 69) 2 70) 3
71) 1 72) 4 73) 2 74) 1 75) 1
76) 4 77) 4 78) 3 79) 2 80) 2
81) 9 82) 8 83) 3 84) 4 85) 11
86) 2 87) 13 88) 2 89) 2 90) 2

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SOLUTIONS
PHYSICS
1. Since a
dv
 v
dv
a  vdv  adx
dt dx
v
v2
  vdv   adx
0

2
 area under a  x graph

 v  2  area under a  x graph

1 1 1
Area A  2  2   6  2   2  4  2    2  4
2 2 2
 A  2  12  6  4  24  v  2  24  4 3ms 1
2.

3.

4. Conceptual

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5.

1 2 a a æ πr 2 ÷ö 2π 2
sin θc = = r = tan θc = \ A = 4 ´çç = a
μ 3 2 5 çè 2 ÷÷ø 5
6.

7.

8.

9. Acceleration of the rod is parallel to incline. If the wedge and rod maintain contact,
they must have equal components of acceleration along the normal drawn to the wedge.
2ao
 a cos15o  a0 cos 450  a 
3 1
10. R1  R2  f1  30cm  As   1.5
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Similarly, The focal length of the liquid lens (in air)

1  1 1   1 1  1
    1     1.3  1   
f3  R2 R3   30 70  70
1 1 1 1 1 1 1 1
Further, equivalent length of the combination.       
F f1 f 2 f3 30 70 70 30
1 1 1 1 1 1
Using the lens formula   , we have     45 cm
 u F  90 30
Thus, image will be formed at a distance of 45cm from the combination.
11. ⎛δ ⎞ ⎛δ ⎞ 2π 2π
I = 4 I 0 cos 2 ⎜⎜ ⎟⎟ ⇒ I 0 = 4 I 0 cos 2 ⎜⎜ ⎟⎟ ⇒ δ =  δ= × Δx
⎝2 ⎠ ⎝2⎠ 3 λ
2π 2π ⎛ d ⎞ λD ⎛ λD λD ⎞ λD
⇒ = ⎜⎜ y ⎟⎟ ⇒ y = ∴ (Δy ) min = 2 × ⎜⎜ − ⎟⎟ =
3 λ ⎝ D⎠ 3d ⎝ 2d 3d ⎠ 3d
12. If thermal resistance of each rod is considered R then, the given
combination can be redrawn as follows

(120 − 20) (120 − θ )

(Heat current)AC = (Heat current)AB =  θ = 70 °C
R R
13.

14. 1
T2 T
 1 3
T1 T2

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15. Mg – T = Ma0 ……….. (i)
T – R = 2 ma0 ……….. (ii)
R = ma0 ……….. (iii)
mg =  ma0 ……….. (iv)
2
a  g , T = 2 mg M = 6 m.
0
3
16. for block, this experiences pseudo force with respect to wedge

Hence 15m -5m =ma , a=10 m/s 2

1 1
S=1m= at 2  t  sec.
2 5
17.

18. Conceptual
19. Process A  B Occurs at constant pressure Hence the work done in this process is pdv
= 10J. W.D done along BC is zero. Total W.D = 5J.
5 = 10 +0 + W CA WCA =- 5J
20. Work done by gas in going isothermally from state A to B is
PA
W AB  nRT ln = nRT l n2………..(1)
PB
Work done by gas in going isothermally from state B to C is
P P
WBC  nRT l n B  nRT 0 ………..(2)
PC 2PC
P P
l n 0  l n  2
2
It is given that WBC  2WAB  PC  0
2 PC 8
21.

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22.

23. Let i and j be the unit vectors along the horizontal and vertical directions respectively.

Let velocity of rain be vr  a i  b j

Then speed of rain will be v r  a 2  b2
   
In the first case v m =velocity of man= 3i  v rm  v r  v m   a  3  i  bj
It seems to be in vertical direction. Hence, the horizontal component must be zero.
a  3  0 a  3
 
In the second case v m  6i  v m   a  6  i  bj  3i  bj

vy b
This seems to be at 45 0 with the vertical 
 tan 450   vx

3
b 3


Therefore, from equation (2) speed of rain is vr   3   3  3 2 kmh1
2 2

24. P  P0 4P  P 3P0 3P0

 0 0
V  2V0 V0  2V0
P  P0 
V0
V  2V0  P  P0 
V0
V  6 P0

3P0 1  3P0 2 
P V  7 P0 T  V  7 PV
0 
V0 R  V0 
dT 7V0 49PV
For maximum temperature 0 V Tmax  0 0

dv 6 12R
25. Power incident, P = I.(A1)

P ⎛⎜ IA1 ⎞⎟ ⎛ 20 ⎞2
Intensity on screen = = ⎜ ⎟ = I .⎜⎜ ⎟⎟ = 130 kW / m 2
A2 ⎝ A2 ⎠ ⎝2⎠
26. Interference will be obtained between direct rays from S and reflected rays S’ (image of
S on mirror)

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Since, the reflected rays will lie between region P and Q on the screen. So, interference
is obtained in this region only. From geometry will can show that,
OP  1.9cm and OQ  3.9cm
ANS.
 PQ  2cm.

Fringe width,  
D

 5000  10   200  cm  0.05cm
8

d  2  10 
1

PQ 2
Total number of fringes in the region PQ, N    40.
 0.05
27. T 1  T 
  T correction    30  86400
T 2  T 
28.

29. Conceptual
30. 1 2  2  1  2  2 / 1  1
 
f R2 R1
Here R1  25cm, R2  25cm, 1  1 and 2  3 / 2
Image coincide with object, hence, u  v   x  say 

Substituting in mirror formula, we have

1 1 2  3 / 2  2  3 / 2  1
  
x x 25 25
2 3 1 4
or   
x 25 25 25
x  12.5cm.
Hence, the object should be placed at a distance 12.5cm in front of the silvered lens.
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CHEMISTRY
31. Williamson reaction is SN . A double bond in  position increases rate. Crowding
2

on  carbon decreases rate. S > Q > R > P

32. Aldehydes are oxidized to acids through formation of gem diols which occurs in
aqueous medium
33. Dibromo methyl gets lowest number then tribromo methyl
34. + M effect exerted by F makes p- fluoro phenol less stable and strong
base. So para- fluro phenol is a weak acid among the four.
35. Optically active compound ‘D’ is stabilized by intramolecular hydrogen bond
36. 4 – Methyl hex – 2 – ene gives two Geometrical isomers which rotate the plane
polarized light in same direction
37.

38.

39. OH
I – gives |
CH 3  C H  CH 3
OH
II – gives |
CH 3  C H  CH 3
OH
III – gives |
CH 3  C H  CH 3
IV – gives CH 3  CH 2  OH
40. It is syn addition
41. Elimination followed by hydroboration.
42. Williamson ether synthesis : Substitution dominated by elimination.
43. Retention followed by inversion.
44. It is free radical halogenation
45. Overall reaction antihydroxylation
46. A:alkylbromide, B;Grignard reagent, B to C is SN2 raection.
47. A to B reduction followed diazotization gives C. D to F Riemann-Tiemerr reaction.
B to E gives carbyl amine reaction
48. RLi addition with ketone followed by acidification.
49. NaI/acetone is dehalogenating agent
50. NCERT.

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51.

52.

53. Carbocations are stabilized generally by rearrangement or ring expansion

54.

Primary Amines will be positive carbyl amine test

55. Free radical monochlorination at 1st carbon gives one, 3rd carbon gives one,
and fourth gives one optically active compounds
56. 1 mole for cleavase of ether and 2nd mole for Markoniff addition.
57. It is allylic or Benzylic bromination
58. Pkb Compound
9.38 Benzenamine
8.92 N, N-Dimethyl aniline
3 N – ethylethanamine
3.38 Methanamine
4.70 Phenylmethanamine
59. Gabriel synthesis is used for preparation of primary amines, Halo benzene, Vinyl
halides, 30 halides do not participate Gabriel synthesis
60. Geometrical isomers = 2, optical isomers = 2
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MATHEMATICS
61. a 2
a 1 1 1 1
b2 b 1 2 2 2  2  2  4  16
c2 c 1 2 2 2
62.

 a, a  lies
2
a  a 2  2  0 a  1, 2 a  a 2  2  0
of y  x 2 a  1,  2
63. Three non parallel lines are concurrent if   0
k 2 2
2 k 3  0  k  2,3, 5 But for k= 2, first two lines are parallel.
3 3 k
64. Clearly circumcentre of triangle ABQ will lie on perpendicular bisector of line AB,
which is 6 x  8 y  7  0
65. a  c b d 
Use the S.D. between two skew lines     6  d  d  6.
bd
66.  x  p  x      y  q  y     0  or 
x 2  y 2   p    x   q    y  p  q   0  1
put y  0, we get x 2   p    x  p  q   0   2 
  Locus of B  ,   is  p  x 2   4qy

 x  p
2
 4qy
67. Let A   2t  1,3t  2,4t  3 and B   s  2,2s  1,3s  2   t  1& s  1
AB  2 6 .
68. Let Q   t  1, t  2,2t  3 be the required point as AQ is parallel to the
plane ‘P’ whose normal D.r’s are 1,1,1 .  AQ  1,1,1  0  t  1  AQ  14 .
69. x 1 y  2
Centre of the circles are given by  5
cos  sin 
3 4 3 4 3
where tan   , cos  , sin   or cos  , sin  
4 5 5 5 5
 Centres are(5, 5) and (-3, -1) and the circles are

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x  y  10 x  10 y  25  0 and x 2  y 2  6 x  2 y  15  0
2 2

Ist circle lies in the first quadrant as it touches both the axes and centre is also in this
Quadrant
70. Equation of a family of circles through (0, a) and (0, -a) is x 2  y 2  2 ax  a 2  0
If two members are for   1 and   2 then since they intersect
orthogonally 212 a 2  2a 2   12  1
2
  am  c 
Since the two circles touch the line y  mx  c    2a 2  a 2
2 
 1 m 
 a   2mca  c  a (1  m )  0s
2 2 2 2 2

 a 2 (1  m2 )  c 2  a 2  c 2  (2  m2 )a 2
71. Since the circle x 2  y 2  2 gx  2 fy  c  0 cuts the three given circles at the
extremities of a diameter, the common chords will pass through the centre of the
respective circles, so that 2 gx  2 fy  c  4  0 passes through (0, 0)
 c  4 (i)
Next 2 gx  2 fy  c  6 x  8 y  10  0 passes through (3, 4)
 (2 g  6)3  (2 f  8)4  14  0
 3g  4 f  18  0 (ii)
And 2 gx  2 fy  c  2 x  4 y  2  0 passes through (-1, 2)
 (2 g  2)(1)  (2 f  4)2  2  0
 g 2f 40 (iii)
From (ii) and (iii) we get g  2 and f  3  g  f  c  1  5
g 2  f 2  c  4  9  4  17.gf  6
72. 1 x x 1 1 x 1 1 0 1
f  x   x  x  1 2
2
x  1 x  1  x  x  1 2
2 2
x  1 1  x  x  1 2 1 1
2 2

3 x  2 x 1 3 x2 1 3 2 1
 x 2  x 2  1 1  1( 1)   0
73.  4 
Let b  xi  y j Since a is perpendicular to b so 4 x  3 y  0. Thus b  x  i  j  . Let
 3 
c  id  vj be the required vector. According to the given condition
c.a c.b ux   4 / 3 vx
1  4u  3v  5. Also 2    2  3u  4v  10
|a| |b| x 1  16 / 9  
2

Solving these equations we have u  2 and v  1 or u  2 / 5, v  11 / 5.

    1 
74.
  
 .c  b  a.b c  b  b and c are linearly independent
a
2
 1  
 a.c  and a.b  0
2
 
 
 
(All given vectors are unit vectors)  a, c   60o , a, b  90o      30o

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75. Let n1 = (3, - 2,1), n 2 = (4, - 3, 4), n 3 = (2, - 1, m )
Then n1 ´n 2 is parallel to the line and ^ to normal n3 to the given plane
 (n1 ´ n 2 ).n 3 = 0 or [n1 n2 n 3 ] = 0  m = -2
76. Let equation of AB; 7 x  y  4  0  m1  7
Equation of AC is x  y  1  0  m2  1
Slope of BC is m
A

 
B (1,2) C

m1  m m m 1
tan    2  m  3,
1  mm1 1  m2 m 3
77.  3 1 
Solving x  5 y  1  0,5 x  y  7  0 we get A   , 
 2 2
a1a2  b1b2  10  0
Equation of longer diagonal is acute angle bisector of given lines
x  y 1 0
78. r1 : r2  1: 3 triangle is equilateral
79.   
2

2     …(1)   0    4  0    4  

2 2
 4
 2 


  
2

 16 
   
2

 12 



2 3
   
80. D =distance between parallel lines
Area of the parallelogram =2 times area of the triangle ABB1
81.  a1 b1 c1   a1 b1 c1  0  1
Let M   a2 b2 c2   a2 b2 c2  1    2  b1  1, b2  2, b3  3
 a3 b3 c3  ,  a3 b3 c3  0  3  ,
 a1 b1 c1   1   1 
 a b c   1   1 
 2 2 2      a1  b1  1, a2  b2  1, a3  b3  1 , a1  0, a2  3, a3  2
 a3 b3 c3   0   1 ,
 a1 b1 c1  1  1 
 a b c  1   0  a1  b1  c1  1, a2  b2  c2  0, a3  b3  c3  12
 2 2 2    ,
 a3 b3 c3  1 12  ,
c1  2, c2  5, c3  7

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 SRI CHAITANYA IIT ACADEMY, INDIA 01‐10‐22_SR.S60_NUCLEUS & STERLING‐BT_ Jee‐Main_PTM‐04_KEY &SOL’S

0 1 2 
M=  3 2 5
2 3 7 
82.
A
2 2
D 8
1 1

C1 C2
p
Ap 2   r  1  9
2

Ap 2  r 2  8
 r  1
2
 9  r2  8
r 2  2r  8  r 2  8
2 r  16, r  8
 2   
83.
P.V. of F  a  b  c
3
 
84. 4 x 2a - p x a p x y z a b c
det( B ) = 4 y 2b -q = (4)(2)(-1) y b q = -8 a b c = -8 p q r
4 z 2c -r z c r p q r x y z
= -8´ 2 = -16
85. y
A
M

2 B

C (2, 3)
2

Let mid point of AB is M(h, k)

AB subtends 90 at (2, 3) AM = MB  (h  2) 2  (k  3)2
Also, CM2 + MB2 = CB2  (h – 2)2 + (k – 2)2 + (h – 2)2 + (k – 3)2 = 4
 x2 + y2 – 2x – 5y + 17 = 0.
2
86. The edges of unit cube along co-ordinate axes are OA  i , OB  j , OC  k
Let P = (1,1,1), then OP  i  j  k
Let M is foot of perpendicular from C to OP, OM = projection of OC on OP =
1 2
CM2=OC2 - OM2 =
3 3

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 SRI CHAITANYA IIT ACADEMY, INDIA 01‐10‐22_SR.S60_NUCLEUS & STERLING‐BT_ Jee‐Main_PTM‐04_KEY &SOL’S
87.
D A(, )

(a, a)
Q

C
P B

Equation of circle is x 2  y 2  2ax  2ay  a 2  0

Satisfying by A(, ) 2 + 2 – 2a – 2a + a2 = 0 …(1)
Also equation of PQ = x + y – a = 0
  a
 13   ( +  – a)2 = 26.
2
If we subtract (1), then 2 = 26  = 13 = area of the rectangle.
88. Let log 2x  y  y 2  y  y 2  1  2 y 2  y  1  0
1
y   ,1 Since log 2x  0, log 2x  1  x  2
2
A(1, 2)
89.

y = –2x y=x
(0, 0)
I

B D C
A2 A1

Image of A about y  x , y  2 x are A1 and A2 which lies on BC.

 11 2 
A1  (2,1) , A2    , 
 5 5
equation of BC is x  7 y  5  0
5 5 1
r  ID   
1  49 5 2 2
90. 4r  1  4r  4r  1  4r , Also 4r 4  1   2r 2  2r  1 2r 2  2r  1
4 4 2 2

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