(1
1001CJA10
010212300
051)
@bohring_bot
*1
1001CJ
JA101
102123
30051*
* Te
est Pattern
n
Bo
oard Patter
rn
SCORE-II
S
(Acade
emic Session : 2023 - 20
024) 13-02-2024
4
JEE (M
MAIN + ADVAN
NCED) : ENTHUS
E SIAST C
COURSE
CHEMIS
C TRY SO
OLUTION
N
SECTIION-A / [k.M&v
[
1. (D) 2. (D
D) 3.
3 (C) 4. (C) 5. (C) 6. (B)
7. (C) 8. (A
A) 9.
9 (B) 10. (D) 11. (B) 12. (B)
13
3. (B) 14. (D
D) 15.
1 (C) 16. (D)
SECTIION-B / [k.M&c
[
CN
C
CHO CH=N–OH
C CH
HO CH
HCN
N OH
N
NH3OH
17
7. (i) (C
CHOH)4 (C
CHOH)4 OR (CH
HOH)4 (CHOH
H)4
C
CH2OH CH
C 2OH CH
H2OH CH2OH
H
C
CHO
(ii) HI,
H
(C
CHOH)4 CH3–CH
– 2–CH2––CH2–CH2–C
CH3
C
CH2OH
18
8. Mg2+(aq) || Ag
Mg(s) | M A +(aq) | Ag(s))
0.059
Ecell = E ocell log[Mg 2 ] / [Ag ]2 j
2
19
9. (i) fu V (II) / VsVªklkbuksfud
VsVVªªklkbukbMksfudys dysV (II)
Teetracyanido
onickelate (III) / Tetracyyanonickelaate (II)
2
dssp
(ii) gsDDlk,Dokvk;jju (II)
H
Hexaaquairon(II)
spp3d2
0.0599 [Zn 2 ]
20
0. Ecell = E ocell log vFkok dksbZ vU; lgh uUULVZ lehdj.k dk xf.krh;; izn'kZuA
2 [Cu2 ]
(i) Eccell c<+sxkA
(ii) Eccell ?kVsxkA
0.0599 [Zn 2 ]
Ecell = E o
cell log or any otheer correct mathematica
m al expressionn of Nernst equation.
2 [Cu2 ]
(i) Eccell will incrrease
(ii) Eccell will decrrease
ALLEN CAREER
C INST
TITUTE Pvt. Ltd.
L
Registered & Corporate e Office : ‘SA
ANKALP’, CP--6, Indra Viha
ar, Kota (Rajas
sthan) INDIA--324005 1/8
Ph. : +91-744-3556677, +91-744-2757 7575|E-mail : [email protected]|Website : www.allen .ac.in
ALLEN
OH
@bohring_bot OH
Target : JEE (Main + Advanced) 2024/13-02-2024
O2N NO2
21. (a) conc. HNO3
NO2
(b) CH3CHO
1. CH 3 MgBr
2.H 2 O
(CH3)2CHOH
SECTION-C / [k.M&l
22. (i) (CH3)3CCH(OH)CH2COCH3
(ii) (CH3)3CCH(OH)CN
(iii) (CH3)3CCOONa + (CH3)3CCH2OH
23. (i) ,ekbyst] LVkpZ dk ty esa ?kqyu'khy vo;o gS tcfd ,ekbyksisfDVu ty esa v?kqyu'khy gSA [1]
(ii) xksykdkj izksVhu vkdf̀r esa xksykdkj gksrs gS tcfd js'ksnkj js[kh; gksrs gSA [1]
(iii) U;wfDy;kslkbM ,d 'kdZjk rFkk ,d {kkj j[krs gSA
tc U;wfDy;kslkbM QkWLQsV lewg ls lyafxr gksrs gS ;g U;wfDy;ksVkbM cukrs gSA [1]
(i) Amylose is water soluble component of starch while amylopectin is insoluble in water. [1]
(ii) Globular proteins are spherical in shape while fibrous are linear. [1]
(iii) Nucleoside consists of a sugar and a base.
When nucleoside is linked to phosphate group, it forms a nucleotide. [1]
24. (a) Due to decrease in concentration of reactants with time.
(b) Due to more surface area.
(c) dksfV : ;g 'kwU;@fHkUukRed@_.kkRed Hkh gks ldrh gSA
vkf.odrk : ;g ges'kk /kukRed iw.kkZad gksrh gSA
Order : It may also be zero/fraction/negative.
Molecularity : it is always positive whole number.
25. Gº = –nF Eocell
= –2 × 96500 × {0.80 – (–0.25)}
= –202650 J/mol
Maximum work = 202650 J/mol.
0.059
E ocell log K C
2
2 1.15
log KC =
0.059
= 35.6
2/8 1001CJA101021230051
ALLEN
O
@bohring_bot Enthusiast Course/13-02-2024
26. (i)
OCOCH3
COOH
(ii)
H3C OH
(iii)
OR
CH3
step I
(a) (CH3)3CBr + Br1
H3C CH3
CH3
1 step II
+ OH (CH3)3COH
H3C CH3
CH3 CH3
– +
(b) CH3–C–O Na + CH3–Br CH3–O–C–CH3
CH3 CH3
2.303 [A]0 [A]
27. k= log
t
2.303 100
= log
80 60
2.303
= (1 0.7782)
80
= 0.0064 min–1
2.303 [A]0
t= log
k [A]
2.303 100
= log
0.0064 10
= 360 min
1001CJA101021230051 3/8
ALLEN
CHO
@bohring_bot Target : JEE (Main + Advanced) 2024/13-02-2024
28. (a) (i) / m-ukbVªkscsfUtfYMgkbM
NO2
(ii) / lkbDyksgsDlsu
(iii) CH3–C=N–OH / bFksusy vkWfDle
vFkok
(b) (i) D;ksafd izksisuy dk vkDlhdj.k esa C—H ca/k dk fonyu lekfgr gksrk gS tks fd izksisukWy ds
C—C ca/k dh rqyuk esa nqcZy gksrk gSA
(ii) NaOH rFkk I2 dks lkFk xeZ djus ij] ,lhVksQhukWy vk;ksMksQkeZ dks ihr vo{ksi nsrk gS] tcfd
csUtksQhukWy ugh nsrkA
NO2
(iii) CH3–C–NNH NO2
CH3
CHO
(a) (i) / m-Nitrobenzaldehyde
NO2
(ii) / Cyclohexane
(iii) CH3–C=N–OH / Ethanal oxime
H
OR
(b) (i) Because of oxidation of propanal involves cleavage of C—H bond which is weaker
than C—C bond of propanone.
(ii) On heating with NaOH and I2, acetophenone gives yellow precipitate of iodoform
whereas benzophenone does not.
NO2
(iii) CH3–C–NNH NO2
CH3
SECTION-D / [k.M&n
29. (i) [Ni(H2O)6]Cl2 : sec-valency= 6
(ii) isUVk,ehuDyksjhMksdksckYV(III)lYQsV
(iii) (1) [Ni(CO)4] : prq"Qydh;] izfrpqEcdh;
(2) [Fe(CN)6]3– : v"VQydh;] vuqpqEcdh;
4/8 1001CJA101021230051
ALLEN @bohring_bot vFkok
Enthusiast Course/13-02-2024
(iii) (1) D;ksafd bysDVªkWu ;qXe ds fy, t i;kZIr ugh gksrh gSA fØLVy {ks=k foikVu ÅtkZ (CFSE) bysDVªkWu
;qXe ds fy;s i;kZIr ugh gksrh gSA
(2) NH3 izcy {ks=k fyxs.M ds dkj.k bysDVªkWu ;qfXer dj d2sp3 cuk ldrk gS ysfdu Ni2+ esa nks fjDr
d-d{kdksa dh vumiyC/krk ds dkj.k ;qfXer ugh dj ldrk gSA
(i) [Ni(H2O)6]Cl2 : sec-valency= 6
(ii) Pentaaminechloridocobalt(III)sulphate
(iii) (1) [Ni(CO)4] : Tetrahedral, diamagnetic
(2) [Fe(CN)6]3– : Octahedral, Paramagnetic
OR
(iii) (1) Because t is not sufficient for the pairing of electrons / crystal field splitting
energy (CFSE) is not sufficient for pairing of electrons.
(2) NH3 being a strong field ligand can pair up the electrons to form d2sp3 but cannot pair
up in Ni2+ as two vacant d-orbitals are not available sp3d2 is formed.
30. (i) C6H5MgBr / Qsfuy eSXuhf'k;e czksekbM+ curk gSA
C6H5MgBr / Phenyl magnesium bromide is formed.
(ii) (1) CH2 = CH – CH2 – Cl
(2) (CH3)3C – Cl
(iii) (1) CH3CH2CH2CH2–Cl NaI
acetone
CH3CH2CH2CH2–I
(2) CH3CH2CH = CH2 HBr
Peroxide
CH3CH2CH2CH2 – Br NaI
acetone
CH3CH2CH2CH2–I
OR
(iii) (1) CH3–CH=CH2
Cl
(2)
O CH3
SECTION-E / [k.M&;
31. (a) (i) v;qfXer bysDVªkWuksa dh vuqifLFkfr ds dkj.k Cu+1(3d10) ;kSfxd 'osr gksrk gS tcfd Cu2+(3d9)
;kSfxd] v;qfXer bysDVªkWu ds d-d laØe.k ds dkj.k] jaxhu gksrs gSA [1]
(ii) vEyh; ek/;e esa ØksesV (CrO42–) MkbØksesV (Cr2O72–) vk;u esa ifjofrZr gks tkrk gSA [1]
(iii) d-d{kd dk mudh LFkk;h voLFkk rFkk vkWDlhdj.k voLFkk esa iw.kZ Hkfjr gksus ds dkj.k [1]
(b) Co = [Ar] 4s23d7 , Co+2 = [Ar]3d7 [½+½=1]
= n(n 2) [½]
= 3(3 2) 15 3.92 B.M. [½]
vFkok
1001CJA101021230051 5/8
ALLEN
(a)
@bohring_bot Target : JEE (Main + Advanced) 2024/13-02-2024
[1 × 3 = 3]
ySUFksukWbM ,fDVukWbM
(1) buesa ls lHkh jsfM;kslfØ; ugh gksrs gSA lHkh jsfM;kslfØ; gksrs gSA
(2) ;g vkWDlhdj.k voLFkk dh nh?kZ ijkl ;g vkWDlhdj.k voLFkk dh nh?kZ ijkl n'kkZrs gSA
ugh n'kkZrs gSA
(3) buds lHkh vk;u jaxghu gksrs gSA buds lHkh vk;u jaxhu gksrs gSA
(or any other correct differences)
+3
(b) (i) Sc , v;qfXer bysDVªkWu dh vuqifLFkfr ds dkj.kA [1]
(ii) Cr, Cu dh rqyuk esa izcy vUrjk/kkfRod ca/k dh mifLFkfr ds dkj.kA [1]
+1 10
(a) (i) Cu (3d ) compounds are white because of absence of unpaired electrons
while Cu2+(3d9) compounds are coloured due to unpaired electrons shows d-d
transition. [1]
2– 2–
(ii) Chromate (CrO4 ) changes to dichromate (Cr2O7 ) ion in acidic medium. [1]
(iii) Due to completely filled d-orbitals in their ground state as well as in oxidized
state. [1]
2 7 +2 7
(b) Co = [Ar] 4s 3d , Co = [Ar]3d [½+½=1]
= n(n 2) [½]
= 3(3 2) 15 3.92 B.M. [½]
OR
(a) [1 × 3 = 3]
Lanthanoids Actinoids
(1) most of them are not radioactive All are radioactive
(2) don’t show a wide range of oxidation Show a wide range of oxidation
state states
(3) Most of their ions are colourless Most of their ions are coloured
(or any other correct differences)
+3
(b) (i) Sc , because of absence of unpaired electron. [1]
(ii) Cr, because of presence of strong intermetallic bonding than Cu. [1]
32. A = C6H5CONH2 D = C6H5NC
B = C6 H 5 N 2 Cl E = C6H6
C = C6H5CN
OR
(a) (i) nksuksa ;kSfxdksa esa CHCl3 rFkk ,sYdksgkWyh; KOH feykus ij ,suhfyu nqxZU/k;qDr vkblkslkbukbM+
nsrk gS tcfd N-esfFky ,fuyhu ugh nsrk gSA
Add CHCl3 and KOH (alc.) to both the comounds.
Aniline gives foul smelling isocynides while N-methyl aniline does not.
6/8 1001CJA101021230051
ALLEN
(ii)
@bohring_bot Enthusiast Course/13-02-2024
nksuksa ;kSfxdksa esa B.Mk NaNO2 + HCl feykdj QhukWy ;k -us¶FkkWy feykus ij ,uhfyu yky
ukjaxh jatd cukrk gS tcfd ,fFky ,ehu ugh cukrk gSA
Add Ice cold (NaNO2 + HCl) followed by phenol or -Napthol to both the compound.
Aniline form orange-red dye white ethylamine doesn't.
NH2
Br Br
(b) (i) A = C6H5NH2 B=
Br
(ii) A = CH3OH B = CH3Cl
(iii) A = C2H5NC B = C2H5 NHCH3
33. (a) = iCRT
5.85 1
4.75 = i 0.082 300
58.5 1
i = 1.93
i 1 1.93 1
= 0.93 or 93%
n 1 2 1
(b) Partial pressure of gas in liquid is directly proportional to its solubility or mole fraction.
To prevent 'Bends'
OR
(a) Tf = i Kf m
19.5 1000
l = i × 1.86 ×
78 500
i = 1.075
i 1 1.075 1
= 0.075 or 7.5%
n 1 2 1
(b) (i) KCl ds fo;kstu/ 0.1 M KCl esa d.kksa dh la[;k vf/kd gksus ds dkj.kA
(ii) ijklj.k ds dkj.k cSDVhfj;k dk nzo u"V gks tkrk gS rFkk er̀ gks tkrk gS tks fd laj{k.k djrk gSA
(a) = iCRT
5.85 1
4.75 = i 0.082 300
58.5 1
i = 1.93
i 1 1.93 1
= 0.93 or 93%
n 1 2 1
1001CJA101021230051 7/8
ALLEN @bohring_bot Target : JEE (Main + Advanced) 2024/13-02-2024
(b) Partial pressure of gas in liquid is directly proportional to its solubility or mole fraction.
To prevent 'Bends'
OR
(a) Tf = i Kf m
19.5 1000
l = i × 1.86 ×
78 500
i = 1.075
i 1 1.075 1
= 0.075 or 7.5%
n 1 2 1
(b) (i) Due to dissociation of KCl / number of particles in 0.1 M KCl is more.
(ii) Due to osmosis bacteria loses its water and dies which causes preservation.
8/8 1001CJA101021230051
