C6 – Thermodynamics 15

Advanced Assignment – C6 – Thermodynamics

INSTRUCTIONS

Answer each of the following questions.

OBJECTIVE QUESTIONS
1. If work done by a gas is 144.5 𝐽 when heat given to the gas in isobaric process is 506 𝐽. Then the gas is
A) 𝑆𝑂2 B) 𝑁𝐻3 C) 𝐻𝑒 D) 𝑂2

2. A process is carried out at constant pressure. Given that ∆𝐻 is negative and ∆𝐸 is less than ∆𝐻,
A) The system loses heat and gets compressed during the process
B) The system loses heat and expands during the process
C) The system absorbs heat and expands during the process
D) The system absorbs heat and gets compressed during the process

3. 𝑃 − 𝑉 plot two gases (assuming ideal behaviour and same number of moles) during adiabatic process are given in
the Plot 𝑋 and plot 𝑌 should correspond respectively to:

A) 𝐻𝑒 and 𝐻2 B) 𝐻2 and 𝐻𝑒
C) 𝐶𝑙2 and 𝐻2 D) 𝐻2 and 𝐶𝑙2

4. Consider the reaction

3𝐶 (𝑠) + 2𝐹𝑒2 𝑂3 (𝑠) → 4𝐹𝑒 (𝑠) + 3𝐶𝑂2 (𝑔)
∆𝐻° = −93657 kcal at 25°𝐶
𝐶 (𝑠) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔)
∆𝐻° = −94050 kcal at 25°𝐶
The value of ∆𝐻°𝑓 (𝐹𝑒2 𝑂3 ) is
A) −19.650 kcal B) −196.5 kcal
C) 93.657 kcal D) −286.4 kcal

5. The heat of formation of 𝐶𝑂2 is −409 𝑘𝐽/𝑚𝑜𝑙. The energy required for the process
3𝐶𝑂2 (𝑔) → 3𝐶 (𝑔) + 203 (𝑔) is
A) Is equal to 1227 𝑘𝐽 B) Less than 1227 𝑘𝐽
C) More than 1227 𝑘𝐽 D) Cannot be predicted

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6. Calculate 𝑄 and work done by the gas for the isothermal reversible expansion of one mole of an ideal gas form an
initial pressure of 1.0 bar to a final pressure of 0.1 bar at a constant temperature of 300 𝐾.
A) 5.75 𝑘𝐽, −5.75 𝑘𝐽 B) −30 𝑘𝐽, 30 𝑘𝐽
C) 30 𝑘𝐽, −30𝑘𝐽 D) −5.75𝑘𝐽, 5.75 𝑘𝐽

7. For which reaction change of entropy will be negative?

A) 𝐻2(𝑔) + 𝐼2(𝑔) ⇌ 2𝐻𝐼𝑔 B) 𝑀𝑔𝑂(𝑠) + 𝐻2(𝑔) ⇌ 𝑀𝑔(𝑔) + 𝐻2 𝑂(1)
C) 𝑁𝐻4 𝑁𝑂3(𝑠) ⇌ 𝑁2 𝑂(𝑔) + 2𝐻2 𝑂(𝑔) D) 𝐻𝐶𝑙(𝑔) + 𝑁𝐻3(𝑔) ⇌ 𝑁𝐻4 𝐶𝑙(𝑠)

8. 𝐴 particular reaction given below can be spontaneous if

2𝑃𝑂𝐶𝑙3 (𝑔) → 2𝑃𝐶𝐿3 (𝑔) + 𝑂2 (𝑔)
∆𝐻° = 572 𝑘𝐽; ∆𝑆° = 179 𝐽/𝐾
A) 𝑇 > 1200 𝐾 B) 𝑇 > 1600 𝐾 C) 𝑇 > 2400 𝐾 D) 𝑇 > 3200 𝐾

9. Which of the following statement is false?

A) Work is a state function
B) Temperature is a state function
C) Change of state is completely defined when initial and final states are specified.
D) Work appears at the boundary of the system.

10. One mole of a non-ideal gas undergoes a change of state (2.0 𝑎𝑡𝑚, 3.0 𝐿, 95 𝐾) → (4.0 𝑎𝑡𝑚, 5.0𝐿, 245𝐾) with a
change in internal energy, ∆𝑈 = 30.0 𝐿 𝑎𝑡𝑚. The change in enthalpy (∆𝐻) of the process in 𝐿 atm is
A) 40.0
B) 42.3
C) 44.0
D) Not defined, because pressure is not constant

11. Which of the following reaction defines ∆𝐻°𝑓 ?

1 1
A) 𝐶 (diamond) +𝑂2 (𝑔) → 𝐶𝑂2 (𝑔) B) 𝐻2 (𝑔) + 𝐹2 (𝑔) → 𝐻𝐹(𝑔)
2 2
1
C) 𝑁2 (𝑔) + 3𝐻2 (𝑔) → 2𝑁𝐻3 (𝑔) D) 𝐶𝑂(𝑔) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔)
2

12. Two moles of an ideal gas is expanded isothermally and reversibly form 1 𝑙𝑖𝑡𝑟𝑒 of 10 𝑙𝑖𝑡𝑟𝑒 at 300 𝐾. The enthalpy
change (in 𝑘𝐽) for process is for the process is
A) 11.4 𝑘𝐽 B) −11. 𝑘𝐽 C) 0 𝑘𝐽 D) 4.8 𝑘𝐽.

13. The enthalpy of vapourization of a liquid is 30 𝑘𝐽 𝑚𝑜𝑙 −1 and entropy of vapourization is 75 𝑚𝑜𝑙 −1 𝐾. The boiling
point of the liquid at 1 𝑎𝑡𝑚 is
A) 250 𝐾 B) 400 𝐾 C) 540 𝐾 D) 600 𝐾

14. One mole of monatomic ideal gas at 𝑇(𝐾) is expanded from 1 𝐿 to 2 𝐿 adiabatically under a constant external
pressure of 1 𝑎𝑡𝑚 the final temperature of the gas in Kelvin is
A) 𝑇 B) 𝑇/25/3−1
2 3
C) 𝑇 − D) 𝑇 +
3×0.0821 2×0.0821

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15. For the reaction, 2𝐶𝑂 + 𝑂2 → 2𝐶𝑂2 , ∆𝐻 = −560𝑘𝐽. Two moles of 𝐶𝑂 and one mole of 𝑂2 are taken in a container
of volume 1 𝐿. They completely form two moles of 𝐶𝑂2 , the gases deviate appreciably from ideal behavior. If the
pressure in the vessel changes from 70 to 40 𝑎𝑡𝑚, find the magnitude (absolute value) of ∆𝑈 at 500 𝐾.
(1 𝐿 𝑎𝑡𝑚 = 0.1 𝑘𝐽)
A) 557 𝐾𝐽 B) 55.7 𝐾𝐽 C) 278 𝐾𝐽 D) 27.8 𝐾𝐽

16. The direct conversion of 𝐴 to 𝐵 is difficult, hence it is carried out by the following shown path:
𝐶 → 𝐷
↑ ↓
𝐴 𝐵
Given
∆𝑆(𝐴 → 𝐶) = 50 𝑒. 𝑢
∆𝑆(𝐶 → 𝐷) = 30 𝑒. 𝑢.
∆𝑆(𝐵 → 𝐷) = 20 𝑒. 𝑢
Where 𝑒. 𝑢. is entropy unit then ∆𝑆 (𝐴 → 𝐵) is
A) +100 𝑒. 𝑢. B) +60 𝑒. 𝑢. C) +100 𝑒. 𝑢. D) −60 𝑒. 𝑢.

17. For the process

𝐻2 𝑂 (𝑙)(1 bar, , 373 𝐾) → 𝐻2 𝑂(𝑔)(1 bar, 373 𝐾), the correct set of thermodynamic parameters is
A) ∆𝐺 = 0, ∆𝑆 = +𝑣𝑒 B) ∆𝐺 = 0, ∆𝑆 = −𝑣𝑒
C) ∆𝐺 = +𝑣𝑒, ∆𝑆 = 0 D) ∆𝐺 = −𝑣𝑒, ∆𝑆 = +𝑣𝑒

18. The species which by definition has ZERO standard molar enthalpy of formation at 298 𝐾 is
A) 𝐵𝑟2 (𝑔) B) 𝐶𝑙2 (𝑔) C) 𝐻2 𝑂 (𝑔) D) 𝐶𝐻4 (𝑔)

19. The reversible expansion of an ideal gas under adiabatic and isothermal conditions is shown in the figure. Which
of the following statement (𝑠) is (are) correct?

A) 𝑇3 > 𝑇1 B) 𝑇1 = 𝑇2
C) ∆𝑈𝑖𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 > ∆𝑈𝑎𝑑𝑖𝑎𝑏𝑎𝑡𝑖𝑐 D) 𝑊𝑖𝑠𝑜𝑡ℎ𝑒𝑚𝑎𝑙 > 𝑊𝑎𝑑𝑖𝑎𝑏𝑎𝑡𝑖𝑐

20. Using the data provide, calculate the multiple bond energy (𝑘𝐽 𝑚𝑜𝑙 −1 ) of a 𝐶 = 𝐶 bond in 𝐶2 𝐻2 . That energy is (take
the bond energy of a 𝐶 − 𝐻 bond as 350 𝑘𝐽 𝑚𝑜𝑙 −1 )
2𝐶(𝑠) + 𝐻2 (𝑔) → 𝐶2 𝐻2 (𝑔)∆𝐻 = 225 𝑘𝐽 𝑚𝑜𝑙 −1
2𝐶 (𝑠) → 2𝐶(𝑔) ∆𝐻 = 1414𝑘𝐽 𝑚𝑜𝑙 −1
𝐻2 (𝑔) → 2𝐻(𝑔) ∆𝐻 = 330 𝑘𝐽 𝑚𝑜𝑙 −1
A) 837 B) 1165 C) 815 D) 865

𝑘𝐽
21. The standard enthalpies of formation of 𝐶𝑂2 (𝑔), 𝐻2 𝑂(𝑙) and glucose(𝑠) at 25° 𝐶 are −400 , −300 𝑘𝐽/𝑚𝑜𝑙 and
𝑚𝑜𝑙
𝑘𝐽
−1300 , respectively. The standard enthalpy of combustion per gram of glucose at 25° 𝐶 is
𝑚𝑜𝑙

A) +2900 𝑘𝐽 B) −2900 𝑘𝐽 C) −16.11 𝑘𝐽 D) +16.11 𝑘𝐽

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SINGLE INTEGER
22. The standard molar enthalpies of formation of cyclohexane (𝑙) and benzene (𝑙) are −155 𝑘𝐽 𝑚𝑜𝑙 −1 and
+49 𝑘𝐽 𝑚𝑜𝑙 −1 respectively. The standard enthalpy of hydrogenation of cyclohexane (𝑙) at 25° 𝐶 − 120 𝑘𝐽 𝑚𝑜𝑙 −1 .
Resonance energy per gram of benzene is approximately __________ 𝑘𝐽.

23. The enthalpy change involved in oxidation of glucose is −2880 𝑘𝐽 𝑚𝑜𝑙 −1 , 25% of this energy is available for
muscular work. If 100 𝑘𝐽 of muscular work is needed to walk one km. the maximum distance (𝑘𝑚) that a person
will be able to walk after taking 150 𝑔 of glucose is __________.
24. The freezing point of isobutene is −160°𝐶. ∆𝐻(𝑠𝑜𝑖𝑙𝑑→𝑙𝑖𝑞𝑢𝑖𝑑). is +4520 𝐽 𝑚𝑜𝑙 −1 . For this fusion process, entropy
change in 𝐽 𝑚𝑜𝑙 −1 is 10 𝑦. The value of 𝑦 is __________

𝑘𝐶𝑎𝑙
25. The latent heat of vaporization of a liquid at 500 𝐾 and 1 𝑎𝑡𝑚 pressure is 10.0 . The change in internal energy
𝑚𝑜𝑙𝑒
of one mole of the liquid at the same temperature and pressure is __________ kcal.

26. 2 moles of an ideal gas at 27° 𝐶 is expanded reversibly from 1.5 𝐿 to 15 𝐿 The entropy change (𝑅 =
1.987 𝑐𝑎𝑙 𝑚𝑜𝑙 −1 𝐾 −1 ) is __________ (approximately)

27. The bond energy of an 𝑂 − 𝐻 bond is 109 𝑘𝑎𝑐𝑙 𝑚𝑜𝑙 −1 When 5 × 10−3 𝑚𝑜𝑙𝑒 of water is formed, the energy released
in kcals is approximately __________.

1
28. For the reaction, 𝐴𝑔2 𝑂(𝑠) ⇌ 2𝐴𝑔(𝑠) + 𝑂2 (𝑔) ∆𝐻, ∆𝑆 and 𝑇 are 40.657 𝑘𝐽 𝑚𝑜𝑙 −1 , 109 𝐽𝐾 −1 𝑚𝑜𝑙 −1 and 373 𝐾
2
respectively. Find the free energy change (∆𝐺) of the reaction.

29. 4.48 𝐿 of an ideal at 𝑆𝑇𝑃 requires 12 𝑐𝑎𝑙 to raise the temperature by 15°𝐶 at constant volume. The 𝐶𝑝 of the gas is
__________ cal.

30. The heat of solution of anhydrous 𝐶𝑢𝑆𝑂4 in a large volume of water is −15.9 𝑘. 𝑐𝑎𝑙 per mole at 20°𝐶 while that of
𝐶𝑢𝑆𝑂4 . 5𝐻2 0 is 2.75 𝑘𝐶𝑎𝑙 𝑚𝑜𝑙 −1 . The heat of hydration of 𝐶𝑢𝑆𝑂4 is about −𝑥 × 10𝑛 𝑘. 𝑐𝑎𝑙 where 𝑛 is __________

31. 15 𝑚𝐿 of gaseous hydrocarbon requires 45 𝑚𝐿 of oxygen for complete combustion which produces 30 𝑚𝐿 of 𝐶𝑂2
𝑦
gas, measured under identical conditions. The formula of the hydrocarbon is 𝐶𝑥 𝐻𝑦 . The ratio is __________
𝑥

32. The enthalpies of combustion of 𝐶(𝑔𝑟𝑎𝑝ℎ𝑖𝑡𝑒) and 𝐶𝑑𝑖𝑎𝑚𝑜𝑛𝑑) are −393.5 and −393.5 𝑘𝐽/𝑚𝑜𝑙 respectively. Then
𝐶(𝑔𝑟𝑎𝑝ℎ𝑖𝑡𝑒) to 𝐶(𝑑𝑖𝑎𝑚𝑜𝑛𝑑) in 𝑘𝐽/𝑚𝑜𝑙 is

MATRIX MATCH
33. Match the following: (‘1’ refers to initial state, ‘2’ the final state)
List I List II
𝑅𝑃2 𝑇1
A) Reversible isothermal expansion P) 𝑤 = −𝑅𝑇2 +
𝑃1
𝑅
B) Irreversible isothermal expansion Q) 𝑤 = [𝑇2 − 𝑇1 ]
𝛾−1

C) Irreversible adiabatic expansion R) 𝑤 = −𝑃𝑒𝑥𝑡 ∆𝑉

S) 𝑤 = −2.303 𝑅𝑇 log10 𝑉2 /𝑉1

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34. Match the following:

List I List II
P) ∆𝐻 = −𝑣𝑒, ∆𝑆 = +𝑣𝑒
A) 2𝑂3 (𝑔) → 3𝑂2 (𝑔) Q) ∆𝐺 = +𝑣𝑒
B) 3𝑂2 (𝑔) → 2𝑂3 (𝑔) R) ∆𝐻 = +𝑣𝑒, ∆𝑆 = −𝑣𝑒
S) ∆𝐺 = −𝑣𝑒

PASSAGE
Refer to the passage below for Q35 – Q36
𝐴 fixed mass ′𝑚′ of a gas is subjected to transformation of states from 𝐾 to 𝐿 to 𝑀 to 𝑁 and back to 𝐾 as shown in the
figure

35. The succeeding operation that enable this transformation of states are
A) Heating, cooling, heating, cooling B) Cooling, heating, cooling, heating
C) Heating, cooling, cooling, heating D) Cooling, heating, heating, cooling

36. The pair of isochoric processes among the transformation of sates is

A) 𝐾 to 𝐿 and 𝐿 to 𝑀 B) 𝐿 to 𝑀 and 𝑁 to 𝐾
C) 𝐿 to 𝑀 and 𝑀 to 𝑁 D) 𝑀 to 𝑁 and 𝑁 to 𝐾

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