Operations Manual Electrochemistry Meters

Orion Lab Star PH111 pH/mV

Bench Meter User Manual

68X002222 | Revision 01 | June 2022

Table of Contents
Chapter 1 ................................................................ 6
Introduction .................................................... 6
1.1 Intended Use........................................ 6
1.1.1 Intended Use ............................................. 6
1.1.2 Non-Intended Use ..................................... 6
1.1.3 Safety ........................................................ 6
1.1.4 Power Connection ..................................... 6
1.2 Cleaning Instructions (Meter Only) ......... 6
Chapter 2 ................................................................ 7
Getting Started ............................................... 7
2.1 Electrode Holder Installation ................. 7
2.2 Universal Power Supply Assembly ........ 8
2.3 Keypad Functions ................................ 9
2.3.1 Setup Menu Scrolling ................................. 9
2.3.2 Setup Menu Value Changes ....................... 9
2.3.3 Mode Shortcut Key .................................... 9
2.3.4 Date and Time View Shortcut Key .............. 9
2.4 Display Overview ................................ 10
2.5 Meter Connections ............................. 11
2.6 Electrode Information ......................... 11
2.7 Meter Startup Sequence..................... 11
Chapter 3 .............................................................. 12
Setup Menu .................................................. 12
3.1 Setup Menu Overview ........................ 12
3.2 Setup Menu Items .............................. 13
3.2.1 View Logs ................................................ 13
3.2.1a Viewing the Data Log ........................... 13
3.2.1b Viewing the Calibration Log.................. 14
3.2.2 Log Export Type ...................................... 15
3.2.3 Export All Logs ........................................ 15
3.2.4 Temperature Calibration or Manual
Temperature Input ............................................ 16
 3.2.4a Temperature Calibration ....................... 16
3.2.4b Manual Temperature Input ................... 16
3.2.5 Measure Mode ........................................ 17
3.2.6 pH Resolution .......................................... 17
3.2.7 Calibration Buffer Set ............................... 18
3.2.8 Read Type ............................................... 18
3.2.9 Timed Interval .......................................... 19
3.2.10 Calibration Due Alarm ............................ 19
3.2.11 Temperature Units ................................. 20
3.2.12 Set Date Format .................................... 20
3.2.13 Set Date Value ....................................... 21
3.2.14 Set Time Value....................................... 22
3.2.15 Audio Mode ........................................... 22
3.2.16 Sleep Mode ........................................... 23
3.2.17 Clear Data ............................................. 23
3.2.18 Factory Reset ........................................ 24
Chapter 4 .............................................................. 25
Calibration .................................................... 25
4.1 pH Calibration .................................... 25
4.1.1 pH Calibration Overview........................... 25
4.1.2 pH Calibration Procedure ......................... 25
4.1.3 pH Calibration Example............................ 26
4.1.4 pH Value vs. Temperature ........................ 27
4.2 Millivolt (mV) Offset Adjustment ........... 28
4.3 Temperature Calibration ..................... 28
Chapter 5 .............................................................. 29
Measurements .............................................. 29
5.1 Read Types ........................................ 29
5.1.1 Continuous .............................................. 29
5.1.2 Auto-Read ............................................... 29
5.1.3 Timed ...................................................... 29
5.2 pH and ORP Measurements ............... 29
5.3 pH Electrode Icon .............................. 29
5.4 Data Viewing ...................................... 30
5.5 Data Exporting ................................... 30
5.5.1 USB Computer Cable Interfacing ............. 30
 5.5.2 Remote Commands................................. 31
5.6 Software Update Procedure ............... 32
Chapter 6 .............................................................. 33
Troubleshooting ............................................ 33
6.1 Meter Troubleshooting........................ 33
6.2 Measurement Troubleshooting ........... 33
6.3 Technical Support .............................. 33
Chapter 7 .............................................................. 34
Meter Info ..................................................... 34
7.1 Meter Specifications ........................... 34
7.2 Meter Dimensions .............................. 35
7.3 Warranty ............................................ 35
7.3.1 Return of Items ........................................ 35
Chapter 8 .............................................................. 36
Regulatory Compliance ................................. 36
8.1 European Union ................................. 36
8.2 Product Safety ................................... 36
8.3 Electromagnetic Compatibility ............. 36
8.3.1 FCC Statement (USA) .............................. 36
8.4 Canadian ISED IC Notice .................... 36
8.5 Environmental Compliance ................. 36
8.5.1 REACH - Europe ................................... 36
8.5.2 RoHS - Europe ...................................... 36
8.6 WEEE Compliance ............................. 37
Chapter 9 .............................................................. 38
Ordering Info................................................. 38
9.1 Meter Ordering Information ................. 38
9.2 Electrode and Solution Ordering Info ... 38
Chapter 1
Note: This symbol, in the context of a
Note, indicates to follow the manufacturer
specified instructions, notes and
requirements set out in the manuals.

Introduction CAUTION: Before using or maintaining

this product, please be sure to read the
manual carefully. Failure to follow these
instructions may cause the product to
Thank you for purchasing the Thermo Scientific™ Orion™ malfunction.
Lab Star PH111 pH/mV bench meter. The Orion Lab Star
CAUTION: Use this product only in the
meters are designed to provide the important functions
way described in the product literature
needed for routine measurements with simplified, and in this manual. Before using it, verify
convenient, easy-to-use functionality. that this product is suitable for its
intended use. If the product is used in a
The Orion Lab Star PH111 pH meters are capable of manner not specified by the manufacturer,
measuring pH or ORP simultaneously with mV and the protection provided by the product
temperature. These meters offer a large, backlit display for may be impaired.
clear viewing with small footprint to conserve laboratory CAUTION: Do not modify system
bench space. components. Use OEM exact
replacement equipment or parts. Before
Ensure important data is preserved with a 500-point data
use, confirm that the product has not
log with date/time stamp that can also be exported to a been altered in any way.
printer or computer using the meter communication port.
Note: Unauthorized repair of your meter
All Orion Lab Star PH111 pH meters include a meter- will invalidate the warranty. For additional
attached electrode holder, computer cable and universal information, contact Technical Support at
1-800-225-1480, +1-978-232-6000 or
100-240V 50/60 Hz power adapter with wall plugs for
[email protected].
US/Japan, Euro, UK/Singapore, Australia/New Zealand
and China. Additional meter accessories can be viewed at
www.thermofisher.com/electrochemistry. 1.1.4 Power Connection
See the Universal Power Supply Assembly section for
complete instructions on assembling and installing the
1.1 Intended Use included meter power supply.

Note: Position the meter so the user can

1.1.1 Intended Use access power connection and unplug
power adapter in the event of a fault, so
This device is a bench laboratory meter intended for use in hazard of electrocution can be removed.
a typical, indoor, controlled, laboratory environment. This
device should only be used for analytical testing in

1.2 Cleaning Instructions

accordance with these instructions.

1.1.2 Non-Intended Use (Meter Only)

This device is not a Medical Device. It is not intended to be Wipe the exterior surfaces (except the display panel) using
used to diagnose, treat, cure, or prevent disease. a lint-free cloth dampened with clean water.

Wipe the display panel with a clean microfiber cloth, taking

1.1.3 Safety care to wipe lightly to avoid scratching the meter display.

The meter keypad can also be cleaned using a clean

CAUTION: This symbol, in the context of
a CAUTION, indicates a potentially microfiber cloth dampened with IPA (isopropyl alcohol) for
hazardous situation which if not avoided disinfection purposes.
could result in minor to moderate injury or
damage to the equipment.

6 Chapter 1 | Introduction
Chapter 2
Getting Started
2.1 Electrode Holder
Installation
The meter-attached electrode holder (Catalog Number
LSTAR-ARM) can be installed on either side of the meter.

Unpack the base plate and stand with electrode

holder from the meter box.

Turn the meter over, with the meter display facing

down, on a clean dry surface.

Identify the side of the meter that the holder will be

installed on and remove the screw between the
circles on that side of the meter.
Place the electrodes into the electrode holder. The
Align the base plate of the holder with the circles on
recommended electrode diameter for each slot is
the meter.
shown on the holder.

The recommended location for the ATC temperature probe

is in the middle slot, which allows the ATC probe to be
near the sensing electrode.

Replace the screw from step 3 to attach the base

plate to the meter.

Turn the meter over, with meter display facing up.

Insert the stand with electrode holder into the metal

post on the base plate.

Orion Lab Star PH111 pH/mV Bench Meter 7

2.2 Universal Power b. Align the two tabs on the power adapter
Supply Assembly connector with the two slots on the meter
power input.
A universal power adapter (Catalog Number LSTAR-PWR)
with US/Japan, Euro, UK/Singapore, Australia/New
Zealand and China wall plug plates is included with the
meter. This universal power adapter is specifically for use
with this meter. Use of other power adapters can damage
the meter and will void the warranty.

Note: The power adapter plug has two prongs that allow
the power adapter to be locked onto the meter. These two
prongs must be properly aligned when connecting it to
ensure it is fully connected and locked onto the meter.
Unpack the power supply provided with the meter.

Select the appropriate wall plug plate for the power

c. Insert the power adapter connector into the
outlet that will be used.
meter power input and twist clockwise to lock
Slide the appropriate wall plug plate into the groove the connection.
on the back of the power adapter.

Connect the assembled power adapter to a power

outlet.

You are now ready to turn on the meter.

Connect the assembled power adapter to the meter
input.
CAUTION: Use of a surge protector or
a. Locate the two slots on the meter power input. uninterrupted power supply (UPS) is
recommended, as an unintended power
surge of electricity to the meter may
damage the meter and void the warranty.

8 Chapter 2 | Getting Started

2.3 Keypad Functions 2.3.1 Setup Menu Scrolling
To scroll through the Setup Menu list:

• Press the “Menu” key to enter the Setup Menu.

• The first Setup Menu item will always be show.

• Press the  key to scroll to the second item or

press the  key to scroll to the last item.

• The item list is cyclical and will scroll from the last
item to the first item as the  key is pressed.

2.3.2 Setup Menu Value Changes

Key Function For all numeric value changes, press the  or  key to
edit a value:
In Auto-Read measure mode, press to start a
new reading. • Press the  key once to increase the value by one
Press to escape the Setup Menu and least significant digit/unit.
Calibration mode without saving changes.
• Press the  key once to decrease the value by one
In Continuous measure mode, press to save least significant digit/unit.
the reading to the data log and export to an
external device if one is connected. • Press and hold the  key to quickly increase the
numeric value.
Press to enter the Setup Menu.
• Press and hold the  key to quickly decrease the
Press to exit the Setup Menu.
numeric value.
Press to enter the Calibration mode.
Press while in the Calibration mode to save and
end the calibration when performing a one to
2.3.3 Mode Shortcut Key
four point pH calibration. In the main measure mode, press and hold (long press) the
 or  key for approximately three seconds to change the
Press to scroll through menu items in the main measure mode to pH or relative mV (RmV).
Setup Menu; the list is cyclical.
In the Measure mode, press and hold (long
press) for three seconds as a shortcut key to 2.3.4 Date and Time View
change the measure type from pH to RmV.
Shortcut Key
Press to change a setting in the Setup Menu. In the main measure mode, press and hold (long press) the
Press to scroll through a list or change a
 or  key for approximately three seconds to view the
numeric value.
current date and time settings.
In the Calibration mode, press to manually
change the calibration value.
In the Measure mode, press and hold (long
press) for three seconds as a shortcut key to
view current date and time setting.

Press to save a setting in the Setup Menu.

Press to accept a calibration point in the
Calibration mode.

Press to power on the meter. When the meter

is on, press to turn the backlight off or on.
When the meter is on, press and hold for three
seconds to power off the meter.

Orion Lab Star PH111 pH/mV Bench Meter 9

2.4 Display Overview Icon Description

Calibration Icon: Indicates meter is in

the calibration mode; also shown with
the Setup Menu Icon and Memory Icon
when viewing the calibration log.
Setup Menu Icon: Indicates meter is in
the Setup Menu mode.
Measure Icon: Indicates meter is in the
Measure mode.
Memory Icon: Indicates meter is in the
Setup Menu and viewing the data log
or calibration log.
Log Saved Icon: Indicates meter is
Icon Description actively saving data to the data log or
calibration log.
Main Measurement Field:
Displays pH or RmV Continuous Icon: Indicates the current
readings in Measure mode. meter read type is Continuous and
measurement values are continuously
2nd Measurement Field: updated on the display.
Displays raw mV readings in
Measure mode. ORP Icon: Indicates the Orion ORP
standard value was automatically
3rd Measurement Field: recognized in the RmV calibration.
Displays temperature value
as °C or °F in Measure Stopwatch Icon: Indicates stability
mode. criteria for current measurement is
stabilizing/not ready and meter is
4th Measurement Field: actively reading.
Displays calibration slope
value in Measure mode. Checkmark Icon: Indicates stability
criteria for current measurement is
Press  to scroll Icon: stable/ready and meter has determined
On-screen text prompt the measurement is complete.
shown when keys can be
used to scroll through a list; Timed Icon: Indicates the current
for example, scroll through meter read type is Timed,
list of Setup Menu options. measurement values are continuously
updated on the display and
Press   to change Icon: logged/exported according to the
On-screen text prompt selected time intervals.
shown when keys can be
used to change a value; for Auto-Read Icon: Indicates the current
example, to change the meter read type is Auto-Read,
temperature value in the measurement value is updated on the
Setup Menu. display until stable and then
measurement is logged/exported and
Press CAL to save & end locked on display until the “Measure”
Icon: On-screen text prompt key is pressed again.
shown when in calibration
mode and calibration can be MAN Icon: Indicates no temperature
saved and ended, when one probe is connected to the meter, user
to four points are complete. must use the Setup Menu to enter the
sample temperature.
Press Enter to accept Icon:
On-screen text prompt ATC Icon: Indicates a temperature
shown when changes must probe is connected to the meter and
be saved by pressing the actively sending temperature readings.
“Enter” key on the keypad.

10 Chapter 2 | Getting Started

Icon Description
2.6 Electrode Information
Electrode Good Icon: Indicates the pH
electrode condition is good, based on The Orion Lab Star PH111 pH/mV meter is compatible
the last saved calibration data and with pH electrodes and ORP (redox) electrodes with a BNC
resulting slope value. connector. The Orion Lab Star PH111 pH/mV meter can
Electrode Warning Icon: Indicates the be purchased in a meter only configuration (purchase
pH electrode condition is fair or bad, electrode separately) or kitted with different electrodes.
based on the last saved calibration
Refer to the electrode instructions for specific care and
data and resulting slope value.
maintenance procedures. The following are general
Computer Export Icon: Indicates recommendations for electrode preparation.
meter is actively exporting
measurement data or calibration data Remove the protective cap/bottle from the electrode
to a computer. and save for storage.
Printer Export Icon: Indicates meter is Rinse any salt deposits off the electrode using
actively exporting measurement data or
distilled or deionized water.
calibration data to a printer.
If the electrode is refillable, uncover the fill hole and
add filling solution to the electrode up to the fill hole.
The fill hole should remain open when the electrode
is in use.

2.5 Meter Connections Soak the electrode in storage solution when first
preparing the electrode and when the electrode is
not in use.

Connect the electrode to the meter.

2.7 Meter Startup

Input Function Sequence
Power Universal power supply
When the meter is powered on, it displays a set of startup
GND Ground screens, starting with all segments lit screen, followed by
the meter info screen and then the meter self-test screen.
Export Connection to printer or computer
The meter info screen shows the meter model number and
ATC Connection to ATC temperature probe current software revision.

BNC Connection to pH or ORP (redox) electrode After the meter info screen, the meter performs a series of
internal self-tests to verify that the meter is operating
correctly and then the self-test results are shown.

Finally, the meter proceeds to the main measure mode.

Orion Lab Star PH111 pH/mV Bench Meter 11

Chapter 3
# Setup Menu Item Description
View up to 500 data log points
1 View Logs and active pH, RmV and

Setup Menu
temperature calibrations
Set the export type as computer
2 Log Export Type
or printer or turn export off
Send all saved data logs and

3.1 Setup Menu Overview 3 Export All Logs calibration logs to the selected
export device

Use the meter Setup Menu to customize meter settings. When an ATC probe is
Temperature connected, use the Temp.
In the Measure Mode, press the “Menu” key to Calibration Calibration menu to perform a
access the meter Setup Menu. or temperature offset calibration
4
The first Setup Menu item (View Logs, Data Log) will Manual When no ATC probe is
Temperature connected, use the Manual
be shown. To scroll through the Setup Menu list,
Input Temp. Input menu to enter the
press the  or  key.
sample temperature value
a. Press the  key to scroll to the second item.
Set the main measure mode to
5 Measure Mode
b. Press the  key to scroll to the last item. pH or relative mV (RmV)

c. The list is cyclical, so continue to press the  Set the displayed pH resolution
6 pH Resolution
as 0.1, 0.01 or 0.001 pH units
key to scroll from the last item to the first item.
Set the pH buffers to be used for
To change a setting within a Setup Menu item, Calibration Buffer
7 automatic buffer recognition
press the  or  key. Set
during pH calibrations
a. For numeric value changes: Set the read type to define how
measurements are performed
i. Press the  key once to increase the value 8 Read Type
and when measurements are
by one least significant digit/unit. saved and exported
ii. Press the  key once to decrease the When Timed is set as the Read
value by one least significant digit/unit. Type, set the time interval to be
9 Timed Interval
used to automatically save and
iii. Press and hold the  key to quickly export measurements
increase the value.
Set the calibration due alarm
iv. Press and hold the  key to quickly Calibration Due interval; an alarm is triggered if a
10
decrease the value. Alarm calibration is not performed
within the specified time interval
Once a setting is changed, press the “Enter” key to
save the change. 11 Temp. Units Set the temp. units as °C or °F
Set the date format as month-
When viewing data logs or calibration logs, press
12 Set Date Format day-year (MM.DD.YYYY) or day-
the “Menu” key to go back to the main Setup Menu month-year (DD.MM.YYYY)
list.
13 Set Date Value Set the day, month and year
Press the “Measure” key at any time to exit the
Set the time in AM/PM or 24
Setup Menu and return to the measure mode. 14 Set Time Value
hour formats
15 Audio Mode Set the audible beep on or off
16 Sleep Mode Set the sleep mode on or off
Setup Menu Item
17 Clear Data Erase all data or calibration logs
Setting Options for
Erase all data logs, calibration
Setup Menu Item
18 Factory Reset logs and settings and return the
meter to its factory default state

12 Chapter 3 | Setup Menu

 3.2.1a Viewing the Data Log
3.2 Setup Menu Items
Press the “Enter” key to view the display log.

3.2.1 View Logs

View up to 500 data log points and active pH, RmV and
temperature calibrations. When the “Menu” key is pressed,
the View Logs setup menu item is always shown first.

Press the  or  key to scroll through the data and

calibration log options.
For the data log, press the  or  key to scroll
through the data log points. Scroll through data log
points when viewing the date/time screens or the
measurement data screens.

Press  key

Press  key

Press  key

For the data log, press the  or  key to change

the view from the date/time screen to the
measurement data screen.

Press  key

Press  or  key

Press  key

If desired, press the “Log/Export” key to export the

individual data log point being viewed.

Press the “Enter” key to view the display log. Press the “Menu” key to return to the main Setup
Menu list.

Orion Lab Star PH111 pH/mV Bench Meter 13

3.2.1b Viewing the Calibration Log
Press the “Enter” key to view the display log.

Press  key

For the calibration log, press the  or  key to

change the view from the date/time screen to the
calibration data screen.

Press  key

Press  or  key

Press  key

For the calibration log, press the  or  key to

scroll through the calibration log data.

If desired, press the “Log/Export” key to export the

individual calibration log being viewed.

Press the “Menu” key to return to the main Setup

Menu list.

Press  key

Press  key

14 Chapter 3 | Setup Menu

3.2.2 Log Export Type 3.2.3 Export All Logs
Set the log export type as computer or printer or turn off Send all saved data logs and calibration logs to the
the export function. If computer is selected, the logs are selected export device. Note that this menu will not be
exported in CSV format. If printer is selected, the logs are shown if the Log Export Type menu is set to off.
exported in list format. If off is selected, no logs will be
Press the  or  key to scroll through the Setup
exported, and the Export All Logs menu will not be shown.
Menu list until the Export All Logs item is shown.
Press the  or  key to scroll through the Setup
Menu list until the Log Export Type item is shown.

Press the “Enter” key to export all saved logs to the

selected export device.
Press the  or  key to change the setting to
a. The display will show the data log numbers as
computer, printer or off.
they are exported in the 4th measurement field.

b. The computer or printer icon will blink as the

logs are exported.

Note: If a large amount of data is exported, the meter may

take a few minutes to complete exporting all saved data
logs and calibration logs to the selected device.

Press the “Enter” key to save the change.

Orion Lab Star PH111 pH/mV Bench Meter 15

3.2.4 Temperature Calibration or 3.2.4b Manual Temperature Input
Manual Temperature Input When no ATC probe is connected, use the Manual
Temperature Input menu to enter the sample temperature
3.2.4a Temperature Calibration value, from -5.0 °C to 105.0 °C.

When an ATC probe is connected, use the Temperature Press the  or  key to scroll through the Setup
Calibration menu to perform a one-point temperature offset Menu list until the Manual Temperature Input item is
calibration, up to ±5.0 °C. shown.

Press the  or  key to scroll through the Setup

Menu list until the Temp. Calibration item is shown.

Press the  or  key to adjust the temperature

value.

The temperature value will blink, indicating the a. Press the  key to increase the value by 0.1°.
reading from the ATC probe is being measured. Press and hold the  key to quickly increase.

Once the reading is stable, the value will stop b. Press the  key to decrease the value by 0.1°.
blinking and the checkmark icon will be shown. Press and hold the  key to quickly decrease.

Press the  or  key to adjust the temperature

value in the 3rd field. The temperature offset value
will be shown in the 2nd field.

a. Press the  key to increase the value by 0.1°.

Press and hold the  key to quickly increase.

b. Press the  key to decrease the value by 0.1°.

Press the “Enter” key to save the change.
Press and hold the  key to quickly decrease.

Press the “Enter” key to save the change.

16 Chapter 3 | Setup Menu

3.2.5 Measure Mode 3.2.6 pH Resolution
Set the main measure mode to pH or relative mV (RmV). Set displayed pH resolution as 0.1, 0.01 or 0.001 pH units.

Press the  or  key to scroll through the Setup Press the  or  key to scroll through the Setup
Menu list until the Measure Mode item is shown. Menu list until the pH Resolution item is shown.

Press the  or  key to set the measure mode. Press the  or  key to set the pH resolution.

Press the “Enter” key to save the change.

Press the “Enter” key to save the change.

Orion Lab Star PH111 pH/mV Bench Meter 17

3.2.7 Calibration Buffer Set 3.2.8 Read Type
Set the pH buffer set as USA or DIN for automatic buffer Set the Read Type as Continuous, Auto-Read or Timed to
recognition during pH calibrations. define how measurements are performed and when
measurements are saved and exported.
USA: 1.68, 4.01, 7.00, 10.01, 12.46

DIN: 1.68, 4.01, 6.86, 9.18, 12.46

Continuous:
In the Continuous measure mode, measurements are
Note: During a pH calibration, pH buffer values can also be
continuously updated on the display and the stopwatch
manually entered for each calibration point.
(stabilizing) or checkmark (stable) icon indicates the
Press the  or  key to scroll through the Setup
measurement stability status. Press the “Log/Export” key
Menu list until the Calibration Buffer Set item is
to save a measurement to the data log and export.
shown.
Auto-Read:
In the Auto-Read measure mode, press the “Measure” key
to start a measurement. When the measurement is stable,
the checkmark (stable) icon is shown and the
measurement is locked on the display until the “Measure”
key is pressed again. The stable measurement is
automatically saved to the data log and exported.
Press the  or  key to set the pH buffer set.
Timed:
In the Timed measure mode, the measurement values are
continuously updated on the display. Measurements are
automatically saved to the data log and exported at the
selected time intervals, from 5 seconds to 60 minutes, the
entire time the meter is in the measurement mode.

Press the  or  key to scroll through the Setup

Press the “Enter” key to save the change. Menu list until the Read Type item is shown.

Press the  or  key to set the read type.

Press the “Enter” key to save the change.

18 Chapter 3 | Setup Menu

3.2.9 Timed Interval 3.2.10 Calibration Due Alarm
When Timed is set as the Read Type, set the time interval Set the calibration due alarm interval from 0 hours (off) to
from 5 seconds to 60 minutes. This time interval is used to 168 hours. An alarm is triggered if a calibration is not
automatically save and export measurements. performed within the specified time interval.

Press the  or  key to scroll through the Setup Press the  or  key to scroll through the Setup
Menu list until the Timed Interval item is shown. Menu list until the Calibration Due Alarm item is
shown.

Press the  or  key to adjust the time value.

Press the  or  key to adjust the alarm value.
a. Press the  key to increase the time value by
one second. Press and hold the  key to a. Press the  key to increase the alarm value by
quickly increase. one hour. Press and hold the  key to quickly
increase.
b. Press the  key to decrease the time value by
one second. Press and hold the  key to b. Press the  key to decrease the alarm value
quickly decrease. by one hour. Press and hold the  key to
quickly decrease.

Press the “Enter” key to save the change.

Press the “Enter” key to save the change.

Orion Lab Star PH111 pH/mV Bench Meter 19

3.2.11 Temperature Units 3.2.12 Set Date Format
Set the temperature units as °C (Celsius) or °F (Fahrenheit). Set the date format as month-day-year (MM.DD.YYYY) or
day-month-year (DD.MM.YYYY).
Press the  or  key to scroll through the Setup
Menu list until the Temperature Units item is shown. Press the  or  key to scroll through the Setup
Menu list until the Set Date Format item is shown.

Press the  or  key to set the temperature units.

Press the  or  key to set the date format.

Press the “Enter” key to save the change.

Press the “Enter” key to save the change.

20 Chapter 3 | Setup Menu

3.2.13 Set Date Value b. Press the  key to decrease by one year.
Press and hold the  key to quickly decrease.
Set the month, day and year values.
Press the “Enter” key to save the change.
The date format used for this Setup Menu item will match
the setting in the Set Date Format item. For this example,
the month-day-year (MM.DD.YYYY) format is shown.

Press the  or  key to scroll through the Setup

Menu list until the Set Date Value item is shown.

The month value will flash. Press the  or  key to

adjust the month.

a. Press the  key to increase by one month.

Press and hold the  key to quickly increase.

b. Press the  key to decrease by one month.

Press and hold the  key to quickly decrease.

Press the “Enter” key to save the change.

The day value will flash. Press the  or  key to

adjust the day.

a. Press the  key to increase by one day. Press

and hold the  key to quickly increase.

b. Press the  key to decrease by one day.

Press and hold the  key to quickly decrease.

Press the “Enter” key to save the change.

The year value will flash. Press the  or  key to

adjust the year.

a. Press the  key to increase by one year. Press

and hold the  key to quickly increase.

Orion Lab Star PH111 pH/mV Bench Meter 21

3.2.14 Set Time Value 3.2.15 Audio Mode
Set the time in AM/PM or 24 hour formats. Set the audible beep on or off. The audible beep is used
when an alarm is triggered.
Press the  or  key to scroll through the Setup
Menu list until the Set Time Value item is shown. Press the  or  key to scroll through the Setup
Menu list until the Audio Mode item is shown.

The AM/PM setting will flash. Press the  or  key

to set the time as AM, PM or 24 hour format. Press the  or  key to set the audio mode.

Press the “Enter” key to save the change.

The hour value will flash. Press the  or  key to

adjust the hours.

a. Press the  key to increase by one hour.

Press and hold the  key to quickly increase.

b. Press the  key to decrease by one hour.

Press the “Enter” key to save the change.
Press and hold the  key to quickly decrease.

Press the “Enter” key to save the change.

The minutes value will flash. Press the  or  key

to adjust the minutes.

a. Press the  key to increase by one minute.

Press and hold the  key to quickly increase.

b. Press the  key to decrease by one minute.

Press and hold the  key to quickly decrease.

Press the “Enter” key to save the change.

22 Chapter 3 | Setup Menu

3.2.16 Sleep Mode 3.2.17 Clear Data
Set the sleep mode on or off. When the meter sleep mode Erase all data logs or erase all calibration logs
is on, the meter will enter sleep mode when no keys are
Press the  or  key to scroll through the Setup
pressed for 20 minutes. Once the meter is in sleep mode,
Menu list until the Clear Data item is shown.
press the “Power” key to resume using the meter. Make
sure sleep mode is off when taking timed measurements.

Press the  or  key to scroll through the Setup

Menu list until the Sleep Mode item is shown.

Press the  or  key to select the data log (dAtA)

or calibration log (CAL) to be cleared.

Press the  or  key to set the sleep mode.

Press the “Enter” key to confirm the selection.

Press the “Enter” key to save the change.

Press the “Enter” key again to ensure the selected

log is not accidentally erased.

The meter will confirm when the selected log is fully

erased.

The meter will return to the measurement screen.

Orion Lab Star PH111 pH/mV Bench Meter 23

3.2.18 Factory Reset
Erase all data logs, calibration logs and settings and return
the meter to its factory default state.

Press the  or  key to scroll through the Setup

Menu list until the Factory Reset item is shown.

Press the “Enter” key to confirm the selection.

Press the “Enter” key again to ensure all meter data

is not accidentally erased.

The meter will confirm when the factory reset is fully

complete.

The meter will restart and then return to the

measurement screen.

24 Chapter 3 | Setup Menu

Chapter 4
points without having to program the number of points
before starting the calibration.

Calibration 4.1.2 pH Calibration Procedure

Ensure the active measure mode is pH.

Press the “Cal” key to start the calibration.

4.1 pH Calibration Rinse the pH electrode and ATC probe and place
into the pH buffer.

Wait for the pH value to stabilize.

4.1.1 pH Calibration Overview
a. While the reading is stabilizing, the stopwatch
For best results, periodic calibration with known, accurate icon is shown and the reading flashes.
and fresh pH buffers is recommended. Calibrate with pH
buffers that bracket the expected measuring range and b. When the reading is stable, the checkmark icon
include a neutral buffer. For example, if samples will be pH is shown, and the reading is solid.
6.2 to 9.5, calibrate with pH 4.01, 7.00, and 10.01 buffers. Once the reading is stable, accept or edit the
Perform one to five point pH buffers. The non-volatile meter displayed pH buffer value:
memory retains the most recent, active calibration data
a. To accept the pH buffer value, press the
when powered off.
“Enter” key.
During the pH calibration, the meter will automatically
or
recognize each pH buffer value using the pH buffer set
selected in the setup menu and the mV signal measured b. To edit the pH buffer value, press the  or 
by the pH electrode. Once the reading is stable, the meter key to change the value and then press the
will automatically display the buffer value at its measured “Enter” key to save the value.
temperature from the selected buffer set.
i. Press the  key to increase by one
The following pH buffers are automatically recognized: digit. Press and hold the  key to
quickly increase.
• USA: 1.68, 4.01, 7.00, 10.01, 12.46
ii. Press the  key to decrease by one
• DIN: 1.68, 4.01, 6.86, 9.18, 12.46
digit. Press and hold the  key to
Refer to the Calibration Buffer Set section to change the quickly decrease.
pH buffer group.
Proceed to the next calibration point or save and
If the mV value does not correspond to within ± 60mV of a end the calibration:
pH buffer in the selected buffer set, once the pH reading is
a. To proceed to the next calibration point, repeat
stable, the meter will display the theoretical pH value of the
steps 3-5.
buffer according to the last pH calibration that was
performed or, if no calibration has been performed, the or
meter will display the theoretical pH value of the buffer b. To save and end the calibration, press the
according to the Nernst equation. “Cal” key.
The pH buffer values can be manually entered for each i. When performing a one point pH
calibration point. If the pH buffer value needs to be calibration, press the  or  key to
manually adjusted, use the  or  key to edit the value of edit the slope value and then press the
the pH buffer at its measured temperature. “Enter” key to accept.
To eliminate temperature errors associated with pH, use an The meter will display the calculated slope value and
automatic temperature compensation (ATC) probe with pH then proceed to the main measure mode.
electrode for best accuracy.
Note: Press the “Measure” key at any time to abort the
Press the “Cal” key to start and end the calibration. This calibration and return to the main measure mode.
allows pH calibrations to be performed using one to five

Orion Lab Star PH111 pH/mV Bench Meter 25

4.1.3 pH Calibration Example
The following is an example of a three point pH calibration
using auto-recognized pH 4.01, 7.00 and 10.01 pH
buffers. The pH buffers can be read in any order. For this
example, pH buffers are read lowest to highest.

Press the “Cal” key to start the pH calibration. The

Rinse the pH electrode and ATC probe and place
active Calibration Buffer Set is shown.
into the pH 7.00 buffer.

Wait for the pH value to stabilize.

a. When the reading is unstable, the stopwatch

icon is shown and the reading flashes.

Rinse the pH electrode and ATC probe and place

into the pH 4.01 buffer.

Wait for the pH value to stabilize.

a. When the reading is unstable, the stopwatch

b. When the reading is stable, the checkmark icon
icon is shown and the reading flashes.
is shown and the reading is solid.

b. When the reading is stable, the checkmark icon

Once the reading is stable, press the “Enter” key.
is shown and the reading is solid.
The meter will save the second calibration point and
proceed to the next calibration point.

Once the reading is stable, press the “Enter” key.

The meter will save the first calibration point and
proceed to the next calibration point.

Rinse the pH electrode and ATC probe and place

into the pH 10.01 buffer.

Wait for the pH value to stabilize.

a. When the reading is unstable, the stopwatch

icon is shown and the reading flashes.

26 Chapter 4 | Calibration
 4.1.4 pH Value vs. Temperature
The following table lists theoretical values for the Orion pH
buffers at various temperatures. Actual values displayed on
the meter may vary slightly due to rounding deviations from
the actual pH and temperature measurements.

USA Buffer Set

b. When the reading is stable, the checkmark icon
is shown and the reading is solid. pH pH pH pH pH
Temp.
1.68 4.01 7.00 10.01 12.46
(°C)
Buffer Buffer Buffer Buffer Buffer
0 1.667 4.000 7.111 10.320 13.474
5 1.668 3.999 7.082 10.249 13.245
10 1.669 3.999 7.056 10.182 13.030
15 1.672 4.001 7.033 10.121 12.828
20 1.675 4.005 7.013 10.064 12.638
Once the reading is stable, press the “Enter” key. 25 1.678 4.010 6.997 10.013 12.460
The meter will save the third calibration point. 30 1.683 4.016 6.984 9.967 12.293
35 1.688 4.024 6.974 9.925 12.137
40 1.693 4.033 6.967 9.889 11.991
45 1.700 4.044 6.964 9.858 11.855
50 1.707 4.057 6.963 9.832 11.728
55 1.715 4.071 6.966 9.811 11.609
60 1.724 4.086 6.973 9.794 11.499
65 1.733 4.103 6.982 9.783 11.396
Press the “Cal” key to end the calibration.
70 1.744 4.122 6.995 9.777 11.301
The “Cal” key can be pressed when either the
75 1.755 4.142 7.011 9.776 11.213
Saved or 4th Point screens is shown.
80 1.766 4.163 7.030 9.780 11.130

DIN Buffer Set

pH pH pH pH pH
Temp.
1.68 4.01 6.86 9.18 12.46
(°C)
Buffer Buffer Buffer Buffer Buffer
0 1.667 4.000 6.984 9.455 13.474
The average slope value is shown and then the 5 1.668 3.999 6.952 9.391 13.245
Calibration Done screen is shown. 10 1.669 3.999 6.924 9.332 13.030
15 1.672 4.001 6.900 9.278 12.828
20 1.675 4.005 6.881 9.229 12.638
25 1.678 4.010 6.865 9.184 12.460
30 1.683 4.016 6.853 9.143 12.293
35 1.688 4.024 6.844 9.106 12.137
40 1.693 4.033 6.838 9.072 11.991
45 1.700 4.044 6.834 9.041 11.855
50 1.707 4.057 6.833 9.013 11.728
55 1.715 4.071 6.837 8.964 11.609
60 1.724 4.086 6.841 8.942 11.499
65 1.733 4.103 6.847 8.922 11.396
70 1.744 4.122 6.854 8.903 11.301
75 1.755 4.142 6.861 8.885 11.213
The meter will proceed to the main measure mode. 80 1.766 4.163 6.984 9.455 11.130

Orion Lab Star PH111 pH/mV Bench Meter 27

4.2 Millivolt (mV) Offset 4.3 Temperature
Adjustment Calibration
Oxidization Reduction Potential (ORP) or Redox is useful as The thermistor sensor used for automatic temperature
a relative indicator of the oxidizing or reducing nature of a compensation and measurement is both accurate and
sample solution. The offset adjustment in the relative mV stable, so frequent calibration is not required.
(RmV) mode allows readings to be comparable to
When an ATC probe is connected to the meter, use the
reference. An offset of up to ±250 mV from the measured
Temperature Calibration item within the Setup Menu to
raw mV value can be entered.
perform a one-point offset calibration, up to ±5.0 °C.
During the calibration, the meter will automatically
Use the Temperature Units item in the meter Setup Menu
recognize when the Orion ORP standard (catalog number
to select the displayed temperature units as degrees
967901 or 967961) is used. Once the reading is stable, the
Celsius or Fahrenheit.
meter will automatically display the value of the standard at
its measured temperature. Place the ATC probe into a solution with a stable
temperature and NIST traceable thermometer.
Alternative ORP standards can also be used to perform the
calibration. Once the reading is stable, manually enter the Press the “Menu” key to enter the Setup Menu.
value of the standard at its measured temperature. Press the  or  key to scroll through the Setup
Ensure the active measure mode is RmV. Menu list until the Temp. Calibration item is shown.

Press the “Cal” key to start the calibration. The temperature value will blink, indicating the
reading from the ATC probe is being measured.
Rinse the ORP electrode and ATC probe and place
into the ORP standard. Once the reading is stable, the value will stop
blinking and the checkmark icon will be shown.
Wait for the RmV value to stabilize.
Press the  or  key to adjust the temperature
a. While the reading is stabilizing, the stopwatch
value. The temperature offset value will be shown in
icon is shown and the reading flashes.
the 2nd field.
b. When the reading is stable, the checkmark icon
c. Press the  key to increase the value by 0.1°.
is shown, and the reading is solid.
Press and hold the  key to quickly increase.
Once the reading is stable, accept or edit the
d. Press the  key to decrease the value by 0.1°.
displayed ORP standard value:
Press and hold the  key to quickly decrease.
a. To accept the ORP standard value, press the
Press the “Enter” key to save the change.
“Enter” key.
Note: Press the “Measure” key at any time to abort the
or
calibration and return to the main measure mode.
b. To edit the ORP standard value, press the 
or  key to change the value and then press
the “Enter” key to save the value.

iii. Press the  key to increase by one

digit. Press and hold the  key to
quickly increase.

iv. Press the  key to decrease by one

digit. Press and hold the  key to
quickly decrease.

The meter will display the calculated offset value and

then proceed to the main measure mode.

Note: Press the “Measure” key at any time to abort the

calibration and return to the main measure mode.

28 Chapter 4 | Calibration
Chapter 5 5.2 pH and ORP
Measurements
Measurements Rinse the electrode with distilled water or
appropriate solution and blot gently with a lint-free
tissue to remove excess water.

5.1 Read Types Place the electrode into the sample, submerging the
measurement sensor and reference junction.
The Read Type selected in the meter Setup Menu will Allow time for the reading to stabilize.
determine how measurements are performed and when
The meter displays the stopwatch icon while
measurements are saved to the data log and exported to
the reading is stabilizing.
an external device. Set the Read Type as Continuous,
Auto-Read or Timed to define. The meter displays the checkmark icon when
the reading is stable.

5.1.1 Continuous Note the displayed measurements as required.

In the Continuous measure mode, measurements are Remove the electrode from the sample.
continuously updated on the display and the stopwatch Repeat steps 1-5 for all samples.
(stabilizing) or checkmark (stable) icon indicates the
When all samples have been measured, store the
measurement stability status.
electrode per instructions in the electrode manual.
Press the “Log/Export” key to save a measurement to the
data log and export.

5.3 pH Electrode Icon

5.1.2 Auto-Read The pH Electrode Icon indicates the condition of the pH
In the Auto-Read measure mode, press the “Measure” key electrode based on the last saved calibration data and
to start a measurement. resulting slope value.
When the measurement is stable, the checkmark (stable)
icon is shown and the measurement is locked on the
display until the “Measure” key is pressed again.

The stable measurement is automatically saved to the data

log and exported.

5.1.3 Timed Electrode Good: pH calibration slope is 92.0% to 102.0%

In the Timed measure mode, the measurement values are Electrode Warning: pH calibration slope is 82.0% to 91.9%
continuously updated on the display. or 102.1% to 114.0%, recommended actions include:

Measurements are automatically saved to the data log and • Check that all pH buffers are fresh, uncontaminated,
exported at the selected time intervals, from 5 seconds to and not expired
60 minutes, the entire time the meter is in the • Clean and condition the pH electrode
measurement mode.
Electrode Error: pH calibration slope is less than 82.0% or
higher than 114.0%, recommended actions include:

• Replace all pH buffers

• Replace pH electrode

Refer to the Troubleshooting section for more

recommended actions.

Orion Lab Star PH111 pH/mV Bench Meter 29

5.4 Data Viewing 5.5 Data Exporting
Store up to 500 data points in the meter memory. Use the Export data from the meter to a computer or printer. Use
View Logs item in the meter Setup Menu to view the data the Log Export Type item in the meter Setup Menu to set
log points, active pH calibration log, active RmV calibration the export type as computer or printer.
log and active temperature calibration log.
If computer is selected, logs are exported in CSV format.
The data log shows the most recent data log point first.
If printer is selected, logs are exported in list format.
The meter will save up to 500 data log points and then
automatically overwrite the oldest data log point with the Meter Serial Communication Protocol
newest data log point when the limit is reached. Each data
Computer Setting Printer Setting
log point is saved with its associated date and time stamp.
To view the time stamp with seconds included, the data Baud Rate : 9600 bps Baud Rate : 9600 bps
log must be exported to a computer or printer. Data bits: 8 Data bits: 8
Parity: None Parity: None
The pH calibration log shows each calibration point and
the calculated slope value. Three, four and five point pH Stop bits: 1 Stop bits: 1
calibrations will display the average slope value and then Flow Control: None Flow Control: None
the appropriate number of segmented slope values. The
RmV calibration log shows the RmV value with raw mV
value and temperature. The temperature calibration log
shows the temperature and offset value. Each calibration 5.5.1 USB Computer Cable
log is saved with its associated date and time stamp. To Interfacing
view the time stamp with seconds included, the calibration
Orion Lab Star meters include a computer cable that
log must be exported to a computer or printer.
allows the meter to be interfaced with a computer using a
Note: If desired, when in the View Logs item in the meter standard USB-A computer port.
Setup Menu, press the “Log/Export” key to export the
Power on the meter.
individual data log point or calibration log being viewed.
First, connect the computer cable to the EXPORT
port on the back of the meter.

Second, connect the computer cable to a standard

USB-A port on the computer.

After the computer cable is connected to the

computer, the computer should automatically
identify the cable and install the required driver.

a. If the driver is not automatically installed, go to

www.thermofisher.com/orionsoftware and
download the USB computer cable driver for
Orion Lab Star series meters.

Once the driver is installed, data can be transferred

from the meter to a computer using computer
programs such as LIMs, Putty, LabView,
HyperTerminal or similar programs.

a. To record the COM port location of the

computer cable, use the computer’s Device
Manager tool.

30 Chapter 5 | Measurements
5.5.2 Remote Commands Remote
Command
Action
Example
Command
Remote commands allow the meter to be interfaced with Prints the system
computer software like LIMs and HyperTerminal. information including
SYSTEM
meter model, serial
The remote engine receives input from the serial port and <CR>
number, software
processes it. Commands sent to the remote interface will version, date and time
be in the form of “OPCODE <OPERAND> CR”.
Sets the output format
SETCSV
• Only one command can be executed at a time. A to Comma Separated
<CR>
Values (CSV)
new command cannot be issued until the previous
command is done and prompt is given, shown as Locks or unlocks the
SETKEYLOCK meter keypad
the greater than symbol (“>”) followed by a space. SETKEYLOCK
NUMBER
1
• Empty commands (i.e. just a <CR>) will be ignored <CR> NUMBER = 1 (lock) or 0
and a new prompt will be issued. (unlock)
SETRTC
• <CR> (Carriage Return, ASCII 13) is used to Sets the date and time
YYYY-MM-
for the meter SETRTC
terminate a command. Whenever this character is DD-HH-MM-
2021-08-19-
received, the internal buffer will be processed. SS-
TIME MODE = 1 (PM), 2 01-32-00-1
TIMEMODE
• Remote commands are not case sensitive. (AM) or 3 (24 Hour)
<CR>
Remote Commands List Sets the meter
SETMODE
measurement mode. SETMODE PH
MODE <CR>
Remote Example MODE = PH or RMV
Action
Command Command
GETMODE Prints the active
Prints the current <CR> measurement mode
GETMEAS
measurement
<CR>
immediately
Prints the current
measurement for a set
GETMEAS
number of times
Data Count GETMEAS 2
<CR>
Data Count = 1, 2, 3,
etc.
Prints all current
calibration data
GETCAL
<CR> If no calibration is saved,
returns “>” to receive
next command
Prints the calibration
GETCAL data for specific mode
GETCAL PH
MODE <CR>
MODE = PH or RMV
Prints all logged
measurement data

Output format is based

GETLOG on the Log Export Type
<CR> setting

If no data is logged,
returns “>” to receive
next command

Orion Lab Star PH111 pH/mV Bench Meter 31

 a. Select “Serial” as the connection method.
5.6 Software Update b. Enter the COM port location of the USB
Procedure computer cable (viewable in Device Manager
under Ports).
A computer with Microsoft Windows 10, 64bit (x64 based
c. Enter the meter baud rate as 9600.
processor) operating system is required to perform the
software update procedure. Click the Upgrade Firmware button. Wait while the
update is installed on the meter.
Computer screen savers and power management settings
must be disabled so the computer does not enter sleep or The update will take approximately six minutes.
standby mode while performing the software update. Once the update is complete, the dialog box will
show “Done!”.
Laptop computers may enter sleep or standby mode when
the lid is closed, so the lid must remain open throughout Close the software update and detach the USB
the software update procedure. Laptop computers should computer cable from the meter and computer.
also be connected to a power supply when performing the
software update procedure.

Note: Back up all meter data before performing the

software update procedure.

Note: Uninstall any previous versions of the Orion Lab Star

meter software program using the computer’s Programs
and Features tool.

Make sure the meter is interfaced with the computer

using the USB computer cable and the driver has
been installed according to the instructions in the
USB Computer Cable Interfacing section.

Power on the meter.

Download the latest Orion Lab Star meter software

at www.thermofisher.com/orionsoftware.

Unzip/extract the Orion Lab Star meter software files

to the computer’s desktop.

Open the folder containing the unzipped/extracted

software files and double click the setup.exe file to
install the setup program onto the computer.

Follow all prompts to install the setup program onto

the computer. If any security warning messages
appear, select the run software option.

After successful installation of the setup program, a

new icon will appear on the computer’s desktop
and start menu. Double click the icon from desktop
or start menu to launch the program.

Follow all prompts, including reviewing and

accepting the licensing agreement, to start the
software update. If any security warning messages
appear, select the run software option.

Set the interface parameters for running the

software update program.

32 Chapter 5 | Measurements
Chapter 6 6.2 Measurement
Troubleshooting
Troubleshooting Reading is unstable, slow to stabilize

• Clean electrode to remove build-up or

contaminants, 0.1M HCl is recommended and

6.1 Meter Troubleshooting adding pepsin is helpful if protein build-up occurs

• If electrode was stored dry, soak electrode in

Meter display not powering on: storage solution for at least 30 minutes
• Verify that power cord is fully plugged into meter • If electrode is refillable, add electrode fill solution and
and wall outlet ensure the fill hole is uncovered during use
• The power adapter plug has two prongs used to • Check electrode for damage, cracks or breaks
lock it onto the meter; ensure the prongs are
• Check cables for damage or breaks
properly aligned when connecting it with the meter
• Remove any interfering devices from area
• Check that the wall outlet is functional
• Replace old electrode with new electrode
• Press the “Power” key on the meter
• If sample temperature is changing, allow
Meter not responding to any key presses:
temperature to stabilize
• Check that the key being pressed is active in the
Reading freezes on display
current meter mode
• Check meter Read Type setting
• Unplug and reconnect the meter power supply
o If meter Read Type is set to Auto-Read, press
• Contact Technical Support
the “Measure” key to start a new measurement
Meter error shown:
• Check electrode for damage, cracks or breaks
• pH Out of Range, RmV Out of Range, Temperature
• Check cables for damage or breaks
Out of Range:
• Replace old electrode with new electrode
o Ensure electrode is connected to meter

o Check that electrode does not have any

damage or cracks

o Ensure the electrode is properly immersed in

6.3 Technical Support
the sample solution, with the electrode sensing Contact our Orion Technical Support team at
bulb and reference junction submerged below 1-800-225-1480, +1-978-232-6000 or
the top of the sample solution [email protected]

o Verify cables do not have any damage

o Perform a factor reset on the meter

• pH Electrode Icon:

o Troubleshoot pH buffers and pH electrode

o Replace pH buffers

o Clean and condition pH electrode

o Replace pH electrode as needed

Orion Lab Star PH111 pH/mV Bench Meter 33

Chapter 7
Active pH, ORP, temperature with
Calibration log
time and date
Calibration alarm Yes, 1 to 168 hours or off

Meter Info Sleep mode

Self-test
Yes, optional
Automatic with startup
Memory Non-volatile

7.1 Meter Specifications Input BNC, ATC

Data output Computer or printer
pH Data output format CSV or print
Range -2.000 to 18.000 pH Warranty 3 years
Resolution 0.1, 0.01, 0.001 pH Certifications CE, TUV 3-1, FCC Class A
Relative accuracy ±0.005 pH ± 1 LSD Enclosure IP-54
Calibration points 1 to 5 points 100-240 VAC, 50-60Hz, 9 DC
Power
Automatic buffer recognition with adapter, 1.3A
Calibration method
manual buffer entry option Dimensions 198.3 mm x 155.2 mm x 61.7 mm,
Calibration pH USA: 1.68, 4.01, 7.00, 10.01, 12.46 (L x W x H) 7.81” x 6.11” x 2.43”
buffer sets DIN: 1.68, 4.01, 6.86, 9.18, 12.46 Weight 700 grams, 1.54 lbs.
Slope display Yes Environmental Conditions
mV / RmV / ORP Environmental
Indoors
Range ±2000 mV conditions

Resolution 0.1 mV Altitude Up to 2,000 Meters

±0.2 mV or ±0.05 % of the Operating

Relative accuracy 5°C to 45°C
reading, whichever is greater temperature

Calibration points 1 point Operating relative

5 to 85%, non-condensing
humidity
Offset adjustment Up to ±250 mV
Storage
Temperature -20°C to 60°C
temperature
Range -5.0 to 105.0 ºC, 23.0 to 221.0 ºF Storage relative
5 to 85%, non-condensing
humidity
Resolution 0.1 ºC, 0.1 ºF
Mains fluctuation ±10% of range (100-240VAC)
Relative accuracy ±0.3 ºC, ±0.5 ºF
Installation category II
Calibration points 1 point
Pollution degree 2
Offset adjustment Up to ±5 ºC
Protection class III
Features
Display 5” backlit LCD
Time and date Yes
Time format 12 hour AM/PM or 24 hour
Selectable, DD-MM-YYYY or MM-
Date format
DD-YYYY
Read types Continuous, Auto-Read, Timed
Timed interval 5 seconds to 60 minutes
Data log 500 sets with time and date

34 Chapter 7 | Meter Info

7.2 Meter Dimensions 7.3 Warranty
This meter is supplied with a warranty against significant
deviations in material and workmanship for a period of
three (3) years from date of purchase. Electrode warranties
are separate from the meter and differ based on the
selected electrode.

If meter repair or adjustment is necessary within the

designated warranty period and has not been the result of
abuse or misuse, please contact the Technical Support
Team for return authorization and a correction will be made
without charge. The manufacturer will determine if the
meter problem is due to deviations or customer misuse.

Out of warranty products will be repaired on a charged

basis.

The warranty on your meter shall not apply to defects

resulting from:

• Improper or inadequate maintenance by customer

• Unauthorized modification or misuse

• Operation outside of the environment specifications

of the products

7.3.1 Return of Items

Authorization must be obtained from our Technical
Support Team or authorized distributor before returning
items for any reason. Please include data regarding the
reason the items are to be returned. For your protection,
items must be carefully packed to prevent damage in
shipment and insured against possible damage or loss.
The manufacturer will not be responsible for damage
resulting from careless or insufficient packing. A restocking
charge will be made on all unauthorized returns.

Note: The manufacturer reserves the right to make

improvements in design, construction, and appearance of
products without notice.

Orion Lab Star PH111 pH/mV Bench Meter 35

Chapter 8
Note: This equipment has been tested and found to
comply with the limits for a Class A digital device, pursuant
to part 15 of the FCC Rules. These limits are designed to
provide reasonable protection against harmful interference

Regulatory when the equipment is operated in a commercial

environment. This equipment generates, uses, and can

Compliance
radiate radio frequency energy and, if not installed and
used in accordance with the instruction manual, may
cause harmful interference to radio communications.
Operation of this equipment in a residential area is likely to
cause harmful interference in which case the user will be
8.1 European Union required to correct the interference at his own expense.

8.4 Canadian ISED IC

The European voltage models of this product meet all the
Notice
applicable requirements of the European Directives and This ISM digital apparatus complies with Canadian ICES-
therefore display the CE Marking. These Directives include 001.
those captured in the EU Declaration of Conformity. The Cet appareil ISM est conforme á la norme NMB-001 du
most current EU Declaration of Conformity may be Canada.
obtained from the manufacturer.

8.2 Product Safety 8.5 Environmental

Compliance
8.5.1 REACH - Europe
We are committed to meeting all compliance obligations to
evaluate, communicate, and register any Substances of
This product family has been tested to applicable product Very High Concern (SVHC), substances of authorization
standards by TUV SUD a Nationally Recognized Test and finding alternates where appropriate.
Laboratory (NRTL).
8.5.2 RoHS - Europe
We are determined to reduce the impact we have on the
8.3 Electromagnetic environment, and so can declare that this product fully

Compatibility complies with the European Parliament’s RoHS2 and

RoHS2 amendment (Restriction of Hazardous Substances)
Directive 2011/65/EU and 2015/863/EU, with respect to all
the following substances:
8.3.1 FCC Statement (USA)
• Lead (0,1 %)

• Mercury (0,1 %)

• Cadmium (0,01 %)

• Hexavalent chromium (0,1 %)

Any changes or modifications not expressly approved by
the party responsible for compliance could void the user’s • Polybrominated biphenyls (PBB) (0,1 %)
authority to operate the equipment. • Polybrominated diphenyl ethers (PBDE) (0,1 %)

36 Chapter 8 | Regulatory Compliance

 • Bis(2-ethylhexyl) phthalate (DEHP) (0,1%) www.thermofisher.com/

• Butyl benzyl phthalate (BBP) (0,1%)

• Dibutyl phthalate (DBP) (0,1%)

• Diisobutyl phthalate (DIBP) (0,1%)

Our compliance relies on declarations from our suppliers,

testing and evaluations per the assessment requirements Conformità WEEE. Questo prodotto deve rispondere alla
defined in standard EN 63000:2018. This confirms that any direttiva dell’ Unione Europea 2012/19/EU in merito ai
potential trace contamination levels of the substances Rifiuti degli Apparecchi Elettrici ed Elettronici (WEEE).
listed above are below the maximum level set by the latest marcato col seguente simbolo.Thermo Fischer Scientific ha
regulations or are exempt due to their application. stipulato contratti con una o diverse società di
riciclaggio/smaltimento in ognuno degli Stati Membri
Europei. Questo prodotto verrà smaltito o riciclato tramite
8.6 WEEE Compliance queste medesime. Ulteriori informazioni sulla conformità di
Thermo Fisher Scientific con queste Direttive, l’elenco delle
ditte di riciclaggio nel Vostro paese e informazioni sui
prodotti Thermo Scientific che possono essere utili alla
rilevazione di sostanze soggette alla Direttiva RoHS sono
disponibili sul sito http://www.thermofisher.com/

WEEE Compliance. This product is required to comply with

the European Union’s Waste Electrical & Electronic
Equipment (WEEE) Directive 2012/19/EU. It is marked with
the following symbol. Thermo Fisher Scientific has
contracted with one or more recycling/disposal companies
Conformité WEEE. Ce produit doit être conforme à la
in each EU Member State, and this product should be
directive euro-péenne (2012/19/EU) des Déchets
disposed of or recycled through them. Further information
d’Equipements Electriques et Electroniques (DEEE). Il est
on our compliance with these Directives, the recyclers in
marqué par le symbole suivant. Thermo Fisher Scientific
your country, and information on Thermo Scientific
s’est associé avec une ou plusieurs compagnies de
products which may assist the detection of substances
recyclage dans chaque état membre de l’union
subject to the RoHS Directive are available at
européenne et ce produit devraitêtre collecté ou recyclé
www.thermofisher.com/
par celles-ci. Davantage d’informations sur laconformité de
Thermo Fisher Scientific à ces directives, les recycleurs
dans votre pays et les informations sur les produits Thermo
Fisher Scientific qui peuvent aider le détection des
substances sujettes à la directive RoHS sont disponibles
sur http://www.thermofisher.com/

WEEE Konformittät. Dieses Produkt muss die EU Waste

Electrical & ElectronicEquipment (WEEE) Richtlinie
2012/19/EU erfüllen. Das Produkt ist durch folgendes
Symbol gekennzeichnet. Thermo Fisher Scientific hat
Vereinbarungen getroffen mit Verwertungs-
/Entsorgungsanlagen in allen EU-Mitgliederstaaten und
dieses Produkt muss durch diese Firmen widerverwetet
oder entsorgt werden. Mehr Informationen über die
Einhaltung dieser Anweisungen durch Thermo Scientific,
dieVerwerter und Hinweise die Ihnen nützlich sein können,
die Thermo Fisher Scientific Produkte zu identizfizieren, die
unter diese RoHS. Anweisungfallen, finden Sie unter

Orion Lab Star PH111 pH/mV Bench Meter 37

Chapter 9
Ordering Info
9.1 Meter Ordering Information
Description Catalog Number

Orion Lab Star PH111 pH/mV meter with stand, PC cable and universal power adapter LSTAR1110
Orion Lab Star PH111 pH/mV meter standard kit, includes meter with stand, PC cable, universal
power adapter, 9157BNMD refillable epoxy-body pH/ATC electrode, 916099 pH buffer and LSTAR1115
solution kit
Orion Lab Star PH111 pH/mV bench meter easy-to-clean bio kit, includes meter with stand, PC
cable, universal power adapter, GD9156BNWP double junction refillable epoxy-body pH electrode, LSTAR1116
927007MD stainless steel ATC temperature probe, 916099 pH buffer and solution kit
Orion Lab Star PH111 pH/mV bench meter low-maintenance bio kit, includes meter with stand,
PC cable, universal power adapter, GD9106BNWP double junction gel-filled epoxy-body pH LSTAR1117
electrode, 927007MD stainless steel ATC temperature probe, 916099 pH buffer and solution kit
Orion Lab Star PH111 pH/mV bench meter difficult sample kit, includes meter with stand, PC
cable, universal power adapter, 9165BNWP Sure-Flow refillable epoxy-body pH electrode, LSTAR1118
927007MD stainless steel ATC temperature probe, 916099 pH buffer and solution kit
Orion electrode arm with meter-attached bracket for Orion Lab Star meters LSTAR-ARM
Orion twist-and-lock universal 100-240V, 50/60Hz power adapter for Orion Lab Star meters LSTAR-PWR
Orion USB computer cable for Orion Lab Star meters LSTAR-USB
Orion dust cover for Orion Lab Star meters LSTAR-CVR
Orion compact ink-ribbon printer for Orion Lab Star meters; 100-240V, 50/60Hz STARA-106
Orion replacement ink ribbon for compact printer, 6 pack STARA-108
Orion replacement paper for compact printer, 5 pack STARA-109

9.2 Electrode and Solution Ordering Info

Description Catalog Number

General purpose refillable pH electrode with chemically-resistant glass-body, BNC, 1m cable 9102BNWP
General purpose gel-filled pH electrode with durable epoxy-body, BNC, 1m cable 9106BNWP
General purpose refillable pH electrode with durable epoxy-body, BNC, 1m cable 9156BNWP
Double junction refillable pH electrode with chemically-resistant glass-body, BNC, 1m cable 9102DJWP
Double junction gel-filled pH electrode with durable epoxy-body, BNC, 1m cable GD9106BNWP
Double junction refillable pH electrode with durable epoxy-body, BNC, 1m cable GD9156BNWP
Triode gel-filled pH/ATC temperature electrode with epoxy-body, BNC and MiniDIN, 1m cable 9107BNMD
Triode polymer-filled pH/ATC temperature electrode with epoxy-body, BNC and MiniDIN, 1m cable 9107APMD
Triode refillable pH/ATC temperature electrode with epoxy-body, BNC and MiniDIN, 1m cable 9157BNMD

38 Chapter 9 | Ordering Info

Description Catalog Number

Sure-Flow refillable pH electrode with chemically-resistant glass-body, BNC, 1m cable 9172BNWP

Sure-Flow refillable pH electrode with durable epoxy-body, BNC, 1m cable 9165BNWP
ATC temperature probe, epoxy body, MiniDIN, 1m cable 927005MD
ATC temperature probe, stainless steel body, MiniDIN, 1m cable 927007MD
Triode refillable ORP/ATC temperature electrode with epoxy-body, BNC and MiniDIN, 1m cable 9180BNMD
Sure-Flow refillable ORP electrode with durable epoxy-body, BNC, 1m cable 9678BNWP
Standard All-in-One pH Buffer Kit: 475 mL each of pH 4.01, 7.00 and 10.01 buffers; 475 mL of pH
910199
electrode storage solution and electrode storage bottle
All-in-One 60 mL pH Buffer Kit: 60 mL each of pH 4.01, 7.00 and 10.01 buffers; 60 mL of pH
916099
electrode storage solution and 60 mL of pH electrode cleaning solution
pH Electrode Cleaning Kit – 30 mL each protein and general cleaning solutions, 60 mL each
900020
bacteria and oil cleaning solutions, beaker and pipet
pH 1.68 buffer, 5 x 60 mL 9116860
pH 1.68 buffer, 475 mL 910168
pH 4.01 buffer, 5 x 60 mL 910460
pH 4.01 buffer, 475 mL 910104
pH 4.01 buffer, 19 L cubitainer 9104CB
pH 6.86 buffer, 5 x 60 mL 916860
pH 6.86 buffer, 475 mL 910686
pH 7.00 buffer, 5 x 60 mL 910760
pH 7.00 buffer, 475 mL 910107
pH 7.00 buffer, 19 L cubitainer 9107CB
pH 9.18 buffer, 5 x 60 mL 9191860
pH 9.18 buffer, 475 mL 910918
pH 10.01 buffer, 5 x 60 mL 911060
pH 10.01 buffer, 475 mL 910110
pH 10.01 buffer, 19 L cubitainer 9110CB
pH 12.46 buffer, 5 x 60 mL 911260-WA
pH 12.46 buffer, 475 mL 910112
Electrode storage solution, 5 x 60 mL 910060
Electrode storage solution, 475 mL 910001
Electrode storage solution, 19 L cubitainer 9100CB
ORP Standard, +420 mV standard hydrogen electrode EH, 5 x 60 mL 967961
ORP Standard, +420 mV standard hydrogen electrode EH, 475 mL 967901
Single junction silver-chloride pH and ORP electrode filling solution, 5 x 60 mL 900011
Double junction silver-chloride pH electrode filling solution, 5 x 60 mL 910008-WA
Electrode storage sleeve (12 mm diameter electrodes) with stand 810017

Orion Lab Star PH111 pH/mV Bench Meter 39

Orion Lab Star PH111 pH/mV Meter

Scientists have trusted Thermo Scientific Orion Lab Products for over 60 years to provide them with accurate and reliable
analytical testing instruments in the lab and in the field. Since 1962, Thermo Scientific Orion products have set the
standard for quality in electrochemistry. We offer instruments for analytical and optical measurement that allow scientists
to solve some of the most challenging issues facing society today. Whether online in the plant, in the field or in the lab,
scientists trust Orion products deliver precise and accurate readings, which help you keep our communities healthier,
cleaner, and safer.

Find out more at thermofisher.com/electrochemistry

Contact us today at [email protected]

This product is intended for General Laboratory Use. It is the customer’s responsibility to ensure
that the performance of the product is suitable for customers’ specific use or application. © 2022
Thermo Fisher Scientific Inc. All rights reserved. All trademarks are the property of Thermo Fisher
Scientific and its subsidiaries unless otherwise specified. 68X002222 Rev 01 0622

40 Chapter 9 | Ordering Info