SR OUTGOING(MPC) Date:23-03-25

Time: 3HRS IGTM-1 Max. Marks: 300

PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. The net force experienced by dipole (placed along the axis of ring at distance 2R from centre of
the ring of Radius R ) due to uniformly charged ring as shown in figure is

(A) Towards left (B) Towards right (C) Upward (D) No force
2. Assertion (A) :- The electrostatic force between the plates of a charged isolated capacitor
decreases when dielectric just fill the whole space between the plates.
Reason (R) :- The electric field between the plates of a charged isolated capacitor decreases
when dielectric fills the whole space.
(A) Both A and R are true and R is correct explanation of A
(B) Both A and R are true but R is not correct explanation of A
(C) Assertion A is true but Reason R is false
(D) Assertion A is false but Reason R is true
3. The electron of hydrogen atom is considered to be revolving around the fixed proton in circular
b2 e2 h
orbit of radius 2
with velocity where b  , the electric current associated due to this
me b 2
revolution is
2 2 me5 4 2 me5 2 me5 4 me5
(A) (B) (C) (D)
h3 h3 h3 h3
4. At time t  0 , the LC circuit shown in the figure has equal amount of energy stored in the
1
capacitor C  20 F and in the inductor, each of 200 J . Current amplitude is A . The value
10
of inductor is

(A) 2 mH (B) 4 mH (C) 8 mH (D) 16 mH

ˆ
5. A negatively charged ion (with charge -q and mass m ) moving with velocity v0 i enters a
ˆ
region of uniform magnetic field of Intensity B0 k at time t  0 . Here B0 and v0 are positive
m
constants. The angular momentum of ion at time t  about the point where the ion enters
2B0 q

the region of field is

m 2v02 ˆ m 2v02  ˆ  m 2 v 20  ˆ 
(A) k (B) k  (C) zero (D) k
B0 q B0 q   2 B0 q  

6. The instantaneous voltage drop VR across resistor in circuit is

 V0 V0    V0  
(A) VR  cost (B) VR  V0 cost (C) VR  cos  t   (D) VR  sin  t  
2 2  4 2  4
7. A parallel plate capacitor (with circular plates of radius r and plate separation d ) is being
charged. Magnitude of electric field in between the plates of capacitor at any time t is E .
Magnitude of poynting vector at outer edge of capacitor plate just inside the plate is (where 0
and  0 respectively represent magnetic permeability and electrical permittivity of free space)

1  dE  1  dE  1 0  dE  1 0  dE 
(A) 0 rE   (B) 0 rE   (C) rE   (D) rE  
2  dt  2  dt  2 0  dt  2 0  dt 
8. In the given figure there are two ideal, relaxed springs S1 & S2 of spring constants k1 & k2
respectively. An application of external Variable force F causes block to move very slowly
towards the wall on smooth horizontal floor by a distance x .

Column-I Column-II

Work done by
(I) (P) Zero
S2 on block

Work done by 1 k k  2
(II) (Q)   1 2 x
S 2 on S1 2  k1  k 2 

Work done by F 1  k1k 2  2

(III) (R)  x
on block 2  k1  k 2 

1 k1k 22
(IV) Work done by (S) x2
2  k1  k 2  2

(A) I Q;II  S;III  R;IV  P (B) I  R ; II -S ; III -Q ; IV -P

(C) I S; II  R ; III P; IV  Q (D) I -R ; II -S ; III -P ; IV –Q

9. A light ray AB is incident on solid sphere of glass of refractive index 3 . A mirror is placed at
some distance which is perpendicular to BO . Where O is centre of sphere and B is incident point
of ray, then final emergent ray from glass sphere after reflection from plane mirror is :-

(A) Horizontal and parallel to BO (B) Vertical and perpendicular to BO

(C) Ray will retrace it's path and finally emerge out from point B as BA
(D) Light can not emerge out from sphere as T.I.R takes place from sphere to air boundary
 10. In the following YDSE setup, there is monochromatic light source S of wavelength 5000Å is
placed 1 m behind the plane of slits and in front of one of the slits, then central maxima O is
shifted by distance y from central point O as shown in figure then

(A) y  1 mm and Ist maxima at O (B) y  1 mm and Ist minima at O

(C) y  0.75 mm and Ist minima at O (D) y  0.75 mm and Ist maxima at O
11. If E n represents the kinetic energy of electron in n th orbit of hydrogen like atom then select the
correct relation from the following.
E n 1  E n 1 E n 1  E n 1
(A) E n  (B) E n 
2 2
E n 1  E n 1 E n 1  E n 1
(C) E n  (D) E n 
2 2
 dN 
12. A graph is plotted between rate of disintegration   and number of active nuclei at any
 dt 
instant. What is half life of radio active substance? (If time in seconds)

1 ln2
(A) 3sec (B) sec (C) 3ln2sec (D) sec
3 3
13. The density versus pressure graph of one mole of an ideal monoatomic gas of molar mass M
undergoing a process AB is shown in figure. The amount of heat rejected by gas in the process is
 2P0 M P0 M 1 P0 M P0 M
(A) n2 (B) ln2 (C) ln2 (D) 4 ln2
0 0 2 0 0

14. Statement-I :- Two particles of mass 1 kg and 3 kg move towards each other under their mutual
force of attraction. No other force acts on them. When the relative velocity of approach of two
particle is 2 m / sec , their centre of mass has velocity of 0.5 m / sec . When the relative velocity of
approach increases to 3 m / sec , the velocity of the centre of mass decreases to 0.25 m / sec

1 1
Statement-II :- The total kinetic energy as seen from ground is Vrel2  MVc.2 m and here
2 2
m1m2
 is reduced mass   and M is total mass M   m1  m2  and in absence of
m1  m2
external force, total mechanical energy remains conserved
(A) Statement-I is true, Statement-II is true (B) Statement-I is false, Statement-II is true
(C) Statement-I is false, Statement-II is false (D) Statement-I is true, Statement-II is false
15. A particle of mass m is moving in a horizontal circle of Radius R under a centripetal force given

 2 
by  Fcen  R 2  then. (If potential energy at infinity is zero)
 
1
(A) Kinetic energy is
6R
1
(B) Total energy of particle is
R
2
(C) Kinetic energy of particle is
R
1
(D) Potential energy is
R
16. A particle of mass m strikes a smooth disc of radius R and of same mass m with velocity v .
Initially the disc is at rest. The coefficient of restitution e  0.5 . Find the speed of particle just
after the impact. Assuming the disc is placed on smooth horizontal table as shown by top view of
table
 3v v v v
(A) 19 (B) 19 (C) 19 (D) 19
4 4 2 8
17. The time period of following oscillation system is :(All pulley and spring are ideal)

 m m 16 m m
(A) (B) 2 (C) 2 (D) 4
2 k 32k k k
18. A ball is projected on a smooth horizontal surface towards a smooth circular track of radius R
with speed 5gR . The ball after leaving the semicircular track lands on the smooth ground where
1
coefficient of restitution is . The range between first collision and second collision is
2

3R 2R
(A) R (B) (C) (D) 2 R
2 3
19. A rigid ring A and a rigid thin disk B both made of same material, when gently placed on water,
just manage to float due to surface tension as shown in the figure. Both the ring and the disk have
same radius. What can you conclude about their masses (thickness may be different)?

(A) Both have the same mass.

(B) Mass of the ring is half of that of the disk.
(C) Mass of the ring is double to that of the disk.
(D) More information is needed to decide.
20. Three tubes A, B, C are connected to a horizontal pipe in which liquid is flowing. The radii of the
pipes at the joints of A, B and C are 2 cm,1 cm and 2 cm respectively. The height of the liquid

(A) in A is lesser than C (B) in A and C is equal

(C) is same in all the three (D) in A and B is same
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the decimals , Round
off to the nearest Integer only. Have to Answer all 5 questions and question will be evaluated according to the
following marking scheme:
Marking Scheme: +4 for correct answer, 0 if not attempted and –1 if not correct.
21. For the situation shown in figure liquid of coefficient of viscosity  flown over the surface of
fixed plate in x  z plane. The velocity of liquid as a function of y (perpendicular distance from
 y  y 2 
plate to free surface) is given as v        . If magnitude of shear stress that liquid applies
 h  h  

N
at base plate is then N is
h
22.

A solid sphere is released from a point at a height h  7 m on a parabolic surface as shown in

figure. Left part of the surface ( x  0) is sufficiently rough to avoid slipping and right part of the
surface ( x  0) is perfectly smooth. The maximum height in meter upto which the sphere will
reach on right part, is

23. A uniform rod of mass M , length  and area of cross section A is hanging vertically from ceiling
as shown. If Young's modulus of elasticity is Y , the elastic potential energy stored in upper half

14M 2 g 2 
of the rod, is , then value of n is .
nAY
24. A reversible heat engine has an efficiency of 33.3% , removing heat from a hot reservoir and
rejecting heat to a cold reservoir at 0 C . If the engine now operates in reverse, how long would it
take of freeze 1.0 kg of water at 0 C , if it operates on a power of 186 W?

25. The value of power dissipated across the zener diode  Vz  15 V  connected in the circuit as

shown in the figure is x 101 watt.

The value of x , to the nearest integer, is .

CHEMISTRY MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
26. Which of the following statement is correct regarding the line spectrum of Hydrogen & Hydrogen
like species?
(A) All the lines of Balmer series for H -atom belongs to the visible region.
(B) The first line of Balmer series for H -atom will be red line.
(C) Balmer series for He ion belongs to the visible region.
(D) Second line of Balmer series of H -atom is red line.
27. Which of the following Processes are exothermic?
(1) O  g   O  g 

(2) Be  g   Be  g 

(3) P  g   P3 (g)

(4) H  g   H  g 

(A) 1,2,4 (B) 2,4 (C) 2,3 (D) 1,3

28. Assertion :- Solubility of Pb(OH)2 (weak base) decreases on addition of NaOH .

Reason :- NaOH increases OH concentration forcing the equilibrium to shift in the backward
direction.
(A) Assertion and Reason both are correct and reason is correct explanation of assertion.
(B) Assertion and Reason both are correct and reason is incorrect explanation of assertion.
 (C) Assertion and Reason both are incorrect.
(D) Assertion is correct and Reason is incorrect.
29. Which of the following statement is correct?
(A) As per MOT, double bond in C2 consist of sigma bond and pi bond.

(B) Bond energy : N2  C2  O2  B2  F2

(C) Bond length : N 2  C2  O 2  B2  F2
(D) Diamagnetic Li 2 molecules are known to exist in solid phase.
30. The aqueous solution of which of the following will have highest freezing point?
(A) Glucose ( 0.1 m ) (B) NaCl  0.1 m 

(C) Na 3 PO4  0.05 m  (D) CH3COOH(0.2 m , degree of dissociation  0.1)

31.

The structure of E is :-

(A) (B) CH3CH 2OH

(C) (D) CH3CH 2 NH2

32. Two system PCl5  g   PCl3  g   Cl2  g  and COCl 2  g   CO  g   Cl2  g  are simultaneously

in equilibrium in a vessel at constant volume. If some CO is introduced in the vessel, then at new
equilibrium, the moles of :
(A) PCl5 increase (B) PCl5 remain unchanged
(C) PCl5 decrease (D) Cl2 increase
33. During estimation of nitrogen present in an organic compound by kjeldahl's method, the ammonia
evolved from ' m ' g of the compound in kjeldahl's estimation of nitrogen, was absorbed in 'V'ml
of ' M  molar H2SO4 solution. The excess of acid required ' V1 ' ml of NaOH of molarity ' M '.
The % of ' N ' in the organic sample is :-
 V   V 
28  M  2  V  1  14  M   V  1 
 2  100  2  100
(A)  (B) 
1000 m 1000 m
 V 
28  M  V  1 
14  M  2  2 V  V1  100  2  100
(C)  (D) 
1000 m 1000 m
34. Match the column and choose the correct option :

Column-I Column-II
(multiple) (Prefix)

(A) 109 1 atto

(B) 1021  2 zeta

(C) 1018  3 exa

(D) 1018 (4) giga

(A) A  2; B  1;C  3;D  4 (B) A  4; B  2;C  1;D  3
(C) A  1;B  2;C  3;D  4 (D) A  3; B  2;C  4;D  1
35.
 The galvanometer shows no deflection when R1  100ohm . Find the molar conductivity of 0.05 M

KCl solution, if the cell constant is 1.25 cm 1 .

(A) 200 S cm 2 mol1 (B) 400 S cm 2 mol1
(C) 1000 S cm 2 mol 1 (D) 125 S cm 2 mol1
36.

What is the correct structure of D is :-

(A) (B)

(C) (D

37. Give the correct order of Acidic strength.

(A) 1   2    3   4  (B)  3  1   2    4 

(C) (2)  (1)  (4)  (3) (D)  2   1   3   4 

2
38. Consider the complex :  Ni  NH 3 6 2 n (en) n  The maximum number of sterioisomers is possible

for -
(A) n  0 (B) n  1 (C) n  2 (D) n  3
 3
39. For the complex Co  C2O 4 3  , which information is "Incorrect" ?

(A) C2O42 is monodentate ligand.

(B) Inner orbital complex.
(C) Oxidation state of Co  3 .
(D) Complex has octahedral geometry.
40. Statement-1 : Benzaldehyde gives positive test with both Tollens' reagent and Fehling's reagent.
Statement-2 : Ph  CH 2  CHO gives positive test with Fehling's reagent.
(A) Statement-1 is true, statement-2 is false.
(B) Statement-1 is false, statement-2 is true.
(C) Both Statement-1 and statement-2 are true.
(D) Both Statement-1 and statement-2 are false.
41. A compound ' X ' having molecular formula C4 H11 N give reaction with C6 H5SO2Cl and give
compounds ' Y ' and HCl , But does not give reaction with chloroform in presence of KOH .
Compound ' X ' also undergo acylation with ethanoyl chloride to yield ' Z '.
Choose incorrect statement.
(A) Compound ' Y ' is insoluble in NaOH .
(B) ' Z ' is an Amide.
(C) ' X ' reacts with nitrous acid to give N 2 gas.
(D) Compound ' X ' does not give mustard oil test.
42. What is the common name of the following compound?

(A) Tricarboxylic acid (B) Carballylic acid

(C) Propane tricarboxylic acid (D) Hexane trioic acid
43. What will be the expression of rate constant (k) of reaction in terms of pressure for following
reaction, when the initial pressure is P0 and, at time ' t ', total pressure is PT (considering reaction

is following first order kinetics) : 2 A  g   B  g 

1 P0 1 P0 1 P0 2.303 P
(A) k  ln (B) k  ln (C) k  ln (D) k  log 0
t 2P0  PT 2t P0  PT 2t 2PT  P0 t PT
44. Calculate enthalpy of reaction for following reaction C3H8  g   H2  g   CH 4  g   C2 H 6  g 
Given that -
Enthalpy of combustions :
Δ c Ho (Graphite, s )  393 kJ mol 1
Δ c Ho  CH4 , g   890kJmol1
Δ c Ho  C2 H 6 , g   1560kJmol 1
and enthalpy of formation :
Δ f H o (Propane, g )  104kJmol 1
Δ f H o  H 2O,    285kJmol 1
(A) 50kJmol1 (B) 2061kJmol1 (C) 2061kJmol1 (D) 50kJmol1
45. What is the f-subshell electronic configuration of Am3  Z  95 ?

(A) 5 f 4 (B) 5 f 5 (C) 5f 6 (D) 5f 7

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the decimals , Round
off to the nearest Integer only. Have to Answer all 5 questions and question will be evaluated according to the
following marking scheme:
Marking Scheme: +4 for correct answer, 0 if not attempted and –1 if not correct.
46. According to VSEPR theory, how many single super pairs are present in C2 (CN)4
47. Iron (III) chloride (aq.) is treated with potassium ferrocyanide to give a blue ppt ' A '. Which on
further treatment with excess of potassium ferrocyanide give a colloidal solution 'B'.
Find the sum of number of Iron atoms present in ' A ' and ' B '.
48. Find the molecular mass of Tripeptide formed using Amino acids - Glycine, Alanine, Leucine.
49. How many of the following compound will give turbidity in 5 to 10 minutes with Lucas Reagent?
Methyl Alcohol, n-Propyl alcohol, Isopropyl alcohol, n-Butyl alcohol, sec-Butyl alcohol, Isobutyl
alcohol, tert-Butyl alcohol.
50.

Two flasks '1' & '2' are filled with H 2 gas as shown above connected by a valve of negligible

volume. When the valve is opened, what will be the change in entropy, (in cal K 1 ) due to
mixing.
Given : ln2  0.7R  2calmol1 K 1
MATHS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
5 8 11
51. Sum of series 2     is
7 49 343
35 49 35 7
(A) (B) (C) (D)
12 18 16 12

52. Given a right circular cone has a volume V1 and the largest right circular cylinder that can be
a
inscribed in the cone has a volume V2 . Then V1 : V2 is (where a, b are coprime). Find the value
b
of a 2  b2
(A) 25 (B) 65 (C) 64 (D) 20

53. Assertion (A) : Line 7 x  5 y  1  0 cannot intersect the parabola y  x 2 in a rational point (whose
abscissa & ordinate both are rational)

Reason (R) : For odd integer a,b and cequation ax 2  bx  c  0 cannot have rational roots.
(A) Both A and R are correct and R is the correct explanation of A
(B) Both A and R are correct but R is NOT the correct explanation of A
(C) A is correct but R is not correct
(D) A is not correct but R is correct

f x f  5x 
54. Let f : 1,     0,  be a continuous decreasing function with lim  1 Then lim is
x  f 8 x  x  f 8 x 

equal to
4 4 6
(A) (B) (C) (D) 1
8 6 8

55. Let a ray of light be travelling along the, line : 4x  3y  2k  0 and strike, a parabolic mirror at

1, p  . After reflection it moves, along the : line 3x  4 y  k  0 . If the directrix of the parabola is
the line 3x  4 y  15  0 then the length of latus-rectum of the parabola is :
(A) 4 (B) 6 (C) 8 (D) 13
56. If AB is a chord of the circle x 2  y2  25 . The tangents at A and B intersect at C . If  2, 3 is the

mid point of AB , then the area of the quadrilateral OACB is, where O is the origin.
3 3
(A) sq. unit (B) 50 sq. unit
13 13

(C) 100 sq. unit (D) 100 3 sq. unit

57. A company has 10 employees. The company has decided to form a team including at least three
employees and also excluding at least three employees. Then the number of ways of forming the
team is
(A) 950 (B) 912 (C) 1000 (D) 953

58. A ray of light passing through the point A 1, 2  is reflected at a point B on the x - axis and then

passes through  5,3 . Then the equation of AB is :

(A) 5x  4 y  13 (B) 5x  4y  3 (C) 4 x  5 y  14 (D) 4 x  5 y  6

59.

List-I List-II

2
1  8  log10 x 
If  ,  (   ) are the two roots of the equation 2
 1 the the
log10 x  2  log10 x 
(A) (I) 5

value of
 3
1  is equal to
2 3
 

1  1
(B) Number of solution(s) of equation log 2  x 2  3  log1/3  x   , x  0 is (II) 11
2 x  

4  x2 4
(C) Integers satisfying the equation x   is/are (III) 0
x x
 If log c 2log b125  log10 8log c10
(D) where c  0,c  1, b  0, b  1 , (IV) 1
then b is

(A) A  I, B  III, C  IV, D  II (B) A  II, B  III, C  IV, D  I

(C) A  IV, B  II, C  IV, D  I (D) A  IV, B  III, C  II, D  I

60. The A.M. of n observations is M . If the sum of  n  4  observation is a , then the mean of

remaining 4 observations is  a  nM  :

nM  a nM  a nM  a
(A) (B) (C) (D) nM  a
4 4 2

( x )5 1  xk 
61. If  dx  ln    c then k is equal to :
( x )7  x 6 k  1 xk 

(where c is constant of integration)

1 2 5
(A) (B) (C) 5 (D)
5 5 2

62. Number of roots of the function

1
f x   3 x  sinx is :
( x  1) 3
(A) 0 (B) 1 (C) 2 (D) More than 2

 1 1 1 1 1
63. The value of the expression, 14tan  tan 1  tan 1  tan 1  tan 1  tan 1  is an integer
 3 7 13 21 31 
which is equal to :
(A) 2 (B) 5 (C) 7 (D) 10

64. lim
e 2 x2

 1  2 x 2  cosx  1
:
x 
 sin3x  ln 1  3x   x 4

2 1 1 2
(A) (B) (C)  (D) 
9 9 9 9
65. Let f  x  be a continuous function in  0, 7  and graph of f   x  is given below

S1 : f  x  has three points of extrema S2 : f  x  has 4 points of inflection

(A) Both statement-I and statement-II are correct.

(B) Both statement-I and statement-II are incorrect.
(C) Statement-I is incorrect and statement-II is correct.
(D) Statement-I is correct and statement-II is incorrect.

x2 y2 x2 y2 1
66. If the ellipse   1 and the hyperbola   are orthogonal, then find the value of
16 7 144  25
4e1 . (where e1 is the eccentricity of the hyperbola)

(A) 10 (B) 5 (C) 8 (D) 6

g  2
67. If f  x   2 x  x3  1 and g  x   f 1  x  then value of lies in
g   2 

(A) Set of irrational numbers (B) Set of prime numbers

(C)  10,10 (D) None of these

12t  3t  4t  1
68. lim is equal to
t 0 2cost  7  3
1
(A) loge 12 (B) loge 3  loge 4 (C)  log e 3  loge 4  (D) 6loge 3  loge 4

       
  
69. Let a , b be two non collinear unit vectors and x  a  a  b b and y  a  b . Now consider the

following statements :
 
Statement-I: x  y
  
Statement-II: y  x  x.b

(A) Statement-I is true but Statement-II is false

 (B) Both Statement-I and Statement-II are false
(C) Both Statement-I and Statement-II are true
(D) Statement-I is false but Statement-II is true



2
cotx cos 2 x
70. If I1   dx & I2   dx , then -
0 cotx  tanx 
1  x
1 1 3 2 1 5 2 1 8 1 1 6
(A)   (B)   (C)   (D)  
I1 I 2  I1 I 2  I1 I 2  I1 I 2 

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the decimals , Round
off to the nearest Integer only. Have to Answer all 5 questions and question will be evaluated according to the
following marking scheme:
Marking Scheme: +4 for correct answer, 0 if not attempted and –1 if not correct.
71. The probability of getting either all heads or all tails for exactly the second time in the 3rd trial, if
in each trial three coins are tossed, is p then the value of ( 64 p ) equals to -
1
4 3 4
72. The value of  ( x  1) ( x  2) ( x  3)
3
dx is

73. Number of roots of the equation

cos 2 x 
 3 1 sinx  3
 1  0 which lie in the interval   ,   is
2 4
74. The smallest possible natural number ' p ' for which the equation x 2  px  1258  0 has integral
roots ?

75. If x, y, z be three distinct real numbers, and x  1, y  1, z  1 . If the vectors p  xiˆ  ˆj  kˆ ,
     1 1 1
q  iˆ  yjˆ  kˆ, r  iˆ  ˆj  zkˆ are such that  p  q   r  0 , then   is equal to
1 x 1 y 1 z