7.

½byH$mog H$s dbr` g§aMZm _| EoZmo_ar H$m~©Z h¡ :

(a) C-2 (b) C-3
(c) C-4 (d) C-1
8. {dQ>m{_Z B H$s H$_r go hmo OmVr h¡ :
(a) [aHo$Q²>g
(b) _m§gno{e`m| H$s H$_µOmoar
(c) ñH$du $
(d) ~oar-~oar
9. boS> g§Mm`H$ ~¡Q>ar H$mo Amdo{eV H$aZo Ho$ Xm¡amZ H¡$WmoS> A{^{H«$`m Ûmam hmoVm h¡ :
(a) PbSO4 H$m {Z_m©U
2+ 4+
(b) Pb H$m Pb _| AnM`Z
(c) PbO2 Am¡a Pb H$m ~ZZm
(d) EoZmoS> na Pb H$m {ZjonU
10. {ZåZ{b{IV _| go H$m¡Z-go `wJb AmXe© {db`Z ~ZmE±Jo ?
(a) ~|µOrZ Am¡a Q>mbyB©Z
(b) ZmB{Q´>H$ Aåb Am¡a Ob
(c)
(d)

11. O~ àmapå^H$ gmÝÐVm H$mo XþJwZm {H$`m OmVm h¡, Vmo A{^{H«$`m H$s AY© -Am`w XþJwZr hmo OmVr
h¡ & A{^{H«$`m H$s H$mo{Q> h¡ :
(a) 1 (b) 2
(c) 4 (d) 0

12. {ZåZ{b{IV Am`Zm| _| go {H$g_| A`wp½_V d- ?

3+
(a) Fe3+ (b) V
(c) Ti3+ (d) Sc3+
[na_mUw H«$_m§H$ : Fe = 26, V = 23, Ti = 22, Sc = 21]
56/3/3 6
7. In the ring structure of glucose, the anomeric carbon is :
(a) C-2 (b) C-3
(c) C-4 (d) C-1

8. Deficiency of Vitamin B causes :

(a) rickets
(b) muscular weakness
(c) scurvy
(d) beri-beri

9. The cathode reaction during the charging of a lead storage battery leads
to the :
(a) formation of PbSO4
2+ 4+
(b) reduction of Pb to Pb
(c) formation of PbO2 and Pb
(d) deposition of Pb at the anode

10. Which one of the following pairs will not form an ideal solution ?
(a) Benzene and Toluene
(b) Nitric acid and Water
(c) Hexane and Heptane
(d) Ethyl chloride and Ethyl bromide

11. The half-life of a reaction is doubled when the initial concentration is

doubled. The order of the reaction is :
(a) 1 (b) 2
(c) 4 (d) 0

12. Which of the following ions has the maximum number of unpaired
d-electrons ?
3+
(a) Fe3+ (b) V
(c) Ti3+ (d) Sc3+
[Atomic number : Fe = 26, V = 23, Ti = 22, Sc = 21]
56/3/3 7 P.T.O.
13. {ZåZ{b{IV _| go H$m¡Z-gm ~hþX§Vr {bJÝS> h¡ ?
(a) NH3
(b) H2N CH2 CH2 NH2
(c) EDTA4
2
(d) C2O4

14. {ZåZ{b{IV Cnghg§`moOZ `m¡{JH$m| _| go H$m¡Z-gm ~§YZr g_md`dVm Xem©Vm h¡ ?

(a) [Co(NH3)3Cl3]
(b) [Co(NH3)5(CO3)]Cl
(c) [Co(NH3)5NO2](NO3)2

(d) [Co(en)3]Cl3

15 18 (A)
(R)
(a), (b), (c) (d)

(a) A{^H$WZ (A) Am¡a H$maU (R) XmoZm| ghr h¢ Am¡a H$maU (R), A{^H$WZ (A) H$s
ghr ì¶m»¶m H$aVm h¡ &
(b) A{^H$WZ (A) Am¡a H$maU (R) XmoZm| ghr h¢, naÝVw H$maU (R), A{^H$WZ (A) H$s
ghr ì¶m»¶m H$aVm h¡ &
(c) A{^H$WZ (A) ghr h¡, naÝVw H$maU (R) µJbV h¡ &
(d) A{^H$WZ (A) µJbV h¡, naÝVw H$maU (R) ghr h¡ &

15. (A) :
hmoVm h¡ &
(R) : C I Am~§Y H$s VwbZm _| C Cl Am~§Y H$s Am~§Y D$Om© H$_ hmoVr h¡ &

16. (A) : A{^{H«$`m Ho$ {bE H$mo{Q> Am¡a AmpÊdH$Vm gX¡d g_mZ hmoVo h¢ &
(R) : O{Q>b A{^{H«$`mE± AZoH$ àmW{_H$ A{^{H«$`mAm| Ho$ nXm| Ho$ H«$_ _| gånÞ
hmoVr h¢ Am¡a g~go _§X nX doJ {ZYm©aH$ hmoVm h¡ &
56/3/3 8
13. Which of the following is a polydentate ligand ?
(a) NH3
(b) H2N CH2 CH2 NH2
(c) EDTA4
2
(d) C2O4

14. Which of the following coordination compounds exhibits linkage

isomerism ?
(a) [Co(NH3)3Cl3]
(b) [Co(NH3)5(CO3)]Cl
(c) [Co(NH3)5NO2](NO3)2
(d) [Co(en)3]Cl3

For Questions number 15 to 18, two statements are given one labelled as
Assertion (A) and the other labelled as Reason (R). Select the correct
answer to these questions from the codes (a), (b), (c) and (d) as given below.
(a) Both Assertion (A) and Reason (R) are true and Reason (R) is the
correct explanation of the Assertion (A).
(b) Both Assertion (A) and Reason (R) are true, but Reason (R) is not
the correct explanation of the Assertion (A).
(c) Assertion (A) is true, but Reason (R) is false.
(d) Assertion (A) is false, but Reason (R) is true.

15. Assertion (A) : Nucleophilic substitution of iodoethane is easier than

chloroethane.
Reason (R): Bond energy of C Cl bond is less than C I bond.

16. Assertion (A) : Order and molecularity of a reaction are always same.

Reason (R) : Complex reactions involve a sequence of elementary

reactions and the slowest step is rate determining.

56/3/3 9 P.T.O.
17. (A) : qµOH$ H$mo g§H«$_U VÎd Zht _mZm OmVm h¡ &
(R) : m XmoZm| _| hr BgHo$ 3d
H$jH$ nyU© ^[aV hmoVo h¢ &

18. (A) : Fe2+ AnMm`H$ H$s ^m±{V H$m`© H$aVm h¡ &

(R) : 3d5 {dÝ`mg Ho$ H$maU Fe3+ AdñWm ñWm`r hmoVr h¡ &

IÊS> I
19. {ZåZ{b{IV A{^{H«$`mAm| go Ano{jV CËnmXm| H$s g§aMZmE± Am¡a AmB©.`y.nr.E.gr. Zm_
Xr{OE : 2 1=2

(H$) MgBr H$s ¡ Ho$ gmW A{^{H«$`m Am¡a CgHo$ níMmV² Ob-AnKQ>Z &
_oWoZb
(I) µ\$sZm°b H$s Br2 (aq) Ho$ gmW A{^{H«$`m &

20. {H$gr àW_ H$mo{Q> A{^{H«$`m H$s AY©-Am`w 60 {_ZQ> h¡ & 90% A{^H$_©H$ Ho$ g_mßV hmoZo
_| {H$VZm g_` bJoJm ? 2
[{X`m J`m h¡ : log 2 = 0·3010, log 3 = 0·4771, log 10 = 1]

21. {ZåZ{b{IV A{^{H«$`mAm| go g§~§Õ amgm`{ZH$ g_rH$aU {b{IE : 2

(H$) H$m{~©bEo_rZ A{^{H«$`m
(I) J¡{~«Eb W¡{b_mBS> g§íbofU
22. EWoZm°b Am¡a EogrQ>moZ H$m {_lU amCëQ> {Z`_ go {H$g àH$ma H$m {dMbZ Xem©Vm h¡ ? H$maU
Xr{OE & 2

23. (H$) (i) àmUr eara _| H$m~m}hmBS´>oQ> {H$g ê$n _| g§J«{hV ahVo h¢ ? {H$gr EH$ A§J H$m
CëboI H$s{OE Ohm± `h CnpñWV hmoVo h¢ &
(ii) ? 2
AWdm
(I) {ZåZ{b{IV Ho$ _Ü` AÝVa ñnï> H$s{OE : 2
(i) noßQ>mBS> ~§Y Am¡a ½bmBH$mo{g{S>H$ ~§Y
(ii)

56/3/3 10
17. Assertion (A): Zinc is not regarded as a transition element.
Reason (R): In zinc, 3d orbitals are completely filled in its ground
state as well as in its oxidised state.

18. Assertion (A) : Fe2+ acts as a reducing agent.

Reason (R) : Fe3+ state is stable due to 3d5 configuration.

SECTION B

19. Give the structures and IUPAC name of the products expected from the
following reactions : 2 1=2

(a) Reaction of methanal with MgBr followed by hydrolysis.

(b) Reaction of phenol with Br2 (aq).

20. The half-life of a first order reaction is 60 minutes. How long will it take
to consume 90% of the reactant ? 2
[Given : log 2 = 0 3010, log 3 = 0 4771, log 10 = 1]

21. Write the chemical equation involved in the following reactions : 2

(a) Carbylamine reaction
(b) Gabriel phthalimide synthesis

22.
ethanol and acetone ? Give reason. 2

23. (a) (i) How are carbohydrates stored in animal body ? Mention any
one organ where they are present.
(ii) What is the basic structural difference between starch and
cellulose ? 2
OR
(b) Differentiate between : 2
(i) Peptide linkage and Glycosidic linkage
(ii) Nucleoside and Nucleotide

56/3/3 11 P.T.O.
24. (H$) BªYZ gob H$mo n[a^m{fV H$s{OE Am¡a BgHo$ Xmo bm^ {b{IE & 2
AWdm
(I) ZrMo {XE JE E _mZm| H$m Cn`moJ H$aVo hþE, àmJw{º$ H$s{OE {H$ g§jmaU amoH$Zo Ho$
{bE bmoho H$s gVh na bonZ Ho$ {bE H$m¡Z- ? 2
{X`m J`m h¡ : E X 2 / X = 2 36 V
E 2 = 0 14 V
Y /Y
E 2 = 0 44 V
Fe / Fe

25. H$maU Xr{OE : 2 1=2

(H$) Eogr{Q>H$ Aåb H$s VwbZm _| \$m°{_©H$ Aåb à~bVa Aåb h¡ &
(I) EopëS>hmBS>m| Am¡a H$sQ>moZm| Ho$ Eoë\$m ( )-hmBS´>moOZ Aåbr` hmoVo h¢ &
IÊS> J
26. A{^{H«$`m doJ XþJwZm hmo OmVm h¡ O~ Vmn _| n[adV©Z 27 C go 37 C VH$ hmoVm h¡ &
A{^{H«$`m Ho$ {bE g{H«$`U D$Om© n[aH${bV H$s{OE & ( R = 8·314 J K 1 mol 1) 3
({X`m J`m h¡ : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021)
27. CËnmX H$s g§aMZm {b{IE O~ D-½byH$mog {ZåZ{b{IV Ho$ gmW A{^{H«$`m H$aVm h¡ :
(H$moB© ) 3×1=3
(H$) HI
(I) gm§Ð HNO3
(J) Br2 Ob
(K) HCN
1
28. (H$) {ZåZ{b{IV A{^{H«$`mAm| _| A, B Am¡a C H$s g§aMZmE± {b{IE : 2×1 =3
2
NH 3 Br2 NaOH
(i) CO COOH A B

NaNO2 HCl
C
0C
KCN LiAlH 4 HNO 2
(ii) CH3CH2Br A B C
0C
AWdm
56/3/3 12
24. (a) Define fuel cell and write its two advantages. 2
OR
(b) Using E values of X and Y given below, predict which is better for
coating the surface of Iron to prevent corrosion and why ? 2
Given : E 2 = 2 36 V
X /X
E 2 = 0 14 V
Y /Y
E = 0 44 V
Fe 2 / Fe

25. Give reasons : 2 1=2

(a) Formic acid is a stronger acid than acetic acid.
(b) Alpha ( )-Hydrogens of aldehydes and ketones are acidic.
SECTION C

26. The rate of a reaction doubles when temperature changes from 27 C to

37 C. Calculate energy of activation for the reaction.
(R = 8 314 J K 1 mol 1) 3
(Given : log 2 = 0 3010, log 3 = 0 4771, log 4 = 0 6021)

27. Write the structure of product when D-Glucose reacts with the following :
(any three) 3 1=3
(a) HI
(b) Conc. HNO3
(c) Br2 water
(d) HCN

1
28. (a) Write the structures of A, B and C in the following reactions : 2 1 =3
2
NH 3 Br2 NaOH
(i) CO COOH A B

NaNO2 HCl
C
0C
KCN LiAlH 4 HNO 2
(ii) CH3CH2Br A B C
0C
OR

56/3/3 13 P.T.O.
 (I) Amn {ZåZ{b{IV ê$nmÝVaU H¡$go H$a|Jo : 3×1=3

(i) Eo{ZbrZ go p-~«mo_moEo{ZbrZ

(ii) EWoZm°BH$ Aåb go _oW¡Z¡_rZ
(iii) ã`yQ>oZZmBQ´>mBb go 1-Eo_rZmoã`yQ>oZ

29. 0·3 g Eogr{Q>H$ Aåb (M = 60 g mol 1) 30 g ~|µOrZ _| KmobZo na {h_m§H$ _| 0·45 C H$m
AdZ_Z hmoVm h¡ & `{X `h {db`Z _| {ÛV` ~ZmVm h¡, Vmo n[aH${bV H$s{OE {H$ Aåb H$m
1
g§JwUZ {H$VZo à{VeV hmoJm & ({X`m J`m h¡ : ~|µOrZ Ho$ {bE Kf = 5·12 K kg mol ) 3

30. (H$) {ZåZ{b{IV A{^{H«$`m H$s {H«$`m{d{Y {b{IE :

H
CH3 CH2 OH CH2 = CH2 + H2O
443 K

(I) \$sZm°b Ho$ {daMZ H$s A{^{H«$`m Ho$ {bE g_rH$aU {b{IE & 3

IÊS> K

31. EopëH$b h¡bmBS>m| Ho$ C X Am~§Y H$s Y«wdVm BZHo$ Zm{^H$ñZohr à{VñWmnZ,
{dbmonZ VWm YmVw na_mUwAm| go A{^{H«$`m Ûmam H$m~©YmpËdH$ `m¡{JH$m| Ho$ {Z_m©U Ho$ {bE
CÎmaXm`r h¡ & EopëH$b h¡bmBS>m| H$mo EoëHo$Zm| Ho$ _wº$ _ybH$ h¡bmoOZZ Ûmam, EoëH$sZm| na
h¡bmoOZ Aåbm| Ho$ `moJO Ûmam, EoëH$mohm°b Ho$ OH g_yh H$mo µ\$m°ñ\$moag h¡bmBS> `m
Ho$ Cn`moJ go ~Zm`m OmVm h¡ & E[ab h¡bmBS>m|

~bJ{VH$s JwUm| Ho$ AmYma na Zm{^H$ñZohr à{VñWmnZ A{^{H«$`mAm| H$mo SN1 d SN2
A{^{H«$`mAm| _| dJuH¥$V {H$`m J`m h¡ & SN 1 d SN2 A{^{H«$`m H$s {H«$`m{d{Y H$mo g_PZo
Ho$ {bE {H$ao{bQ>r H$s _hÎdnyU© ^y{_H$m h¡ &
56/3/3 14
 (b) How will you convert the following : 3 1=3

(i) Aniline to p-bromoaniline

(ii) Ethanoic acid to methanamine

(iii) Butanenitrile to 1-aminobutane

29. 0 3 g of acetic acid (M = 60 g mol 1) dissolved in 30 g of benzene shows a

depression in freezing point equal to 0 45 C. Calculate the percentage
association of acid if it forms a dimer in the solution. 3
1
(Given : Kf for benzene = 5 12 K kg mol )

30. (a) Write the mechanism of the following reaction :

H
CH3 CH2 OH CH2 = CH2 + H2O
443 K
(b) Write the equation of the reaction for the preparation of phenol
from cumene. 3

SECTION D

The following questions are case-based questions. Read the case carefully and
answer the questions that follow.

31. The polarity of C X bond of alkyl halides is responsible for their

nucleophilic substitution, elimination and their reaction with metal atoms
to form organometallic compounds. Alkyl halides are prepared by the free
radical halogenation of alkanes, addition of halogen acids to alkenes,
replacement of OH group of alcohols with halogens using phosphorus
halides, thionyl chloride or halogen acids. Aryl halides are prepared by
electrophilic substitution of arenes. Nucleophilic substitution reactions
are categorised into SN1 and SN2 on the basis of their kinetic properties.
Chirality has a profound role in understanding the SN1 and SN2

mechanism.
56/3/3 15 P.T.O.
 {ZåZ{b{IV àíZm| Ho$ CÎma Xr{OE :
(i) hmoVm h¡ O~ ewîH$ B©Wa H$s CnpñW{V _| ~«mo_mo~|µOrZ H$s Mg Ho$ gmW
A{^{H«$`m H$s OmVr h¡ ? 1

(ii) {ZåZ{b{IV `wJbm| _| go H$m¡Z-gm `m¡{JH$ OH Ho$ gmW SN1 A{^{H«$`m

Vrd«Vm go XoJm ? 1
(1) CH2 = CH CH2 Cl AWdm CH3 CH2 CH2 Cl
(2) (CH3)3C Cl AWdm CH3Cl

(iii) (1) 1- (2) ã`yQ>-1-B©Z go 1-Am`moS>moã`yQ>oZ Ho$ {daMZ Ho$

g_rH$aU {b{IE & 2×1=2

AWdm
(iii) {ZåZ{b{IV àË`oH$ A{^{H«$`m _| _w»` CËnmXm| H$s g§aMZm {b{IE : 2×1=2

(1) CH3 CH CH3 + KOH

EWoZm°b
| Ja_
Br

{ZO©br` AlCl3
(2) + CH3COCl

32. Cnghg§`moOZ `m¡{JH$ I{ZOm|, nmXn Am¡a àmUr OJV _| {dñV¥V ê$n go {dÚ_mZ h¢ Am¡a
d¡íbo{fH$ agm`Z, YmVwH$_©, O¡{dH$ àUm{b`m| Am¡a Am¡fY Ho$ joÌ _| AZoH$ _hÎdnyU© àH$m`©
gånÞ H$aZo Ho$ {bE OmZo OmVo h¢ & Aë\«o$S> dZ©a Ho$ {gÕmÝV Ho$ AZwgma, Cnghg§`moOZ
`m¡{JH$m| _| {dÚ_mZ YmVw na_mUw/Am`Z Xmo àH$ma H$s g§`moOH$VmE± (àmW{_H$ Ed§ {ÛVr`H$)
H$m Cn`moJ H$aVo h¢ & g_md`dVm Ho$ JwU H$m Cn`moJ H$aVo hþE CÝhm|Zo AZoH$ Cnghg§`moOZ
gÎmmAm| H$s Á`m{_Vr` AmH¥${V`m| Ho$ ~mao _| àmJw{º$ H$s & g§`moOH$Vm Am~§Y {gÕm§V (VBT)
Cnghg§`moOZ `m¡{JH$m| Ho$ ~ZmZo, Mwå~H$s` ì`dhma VWm Á`m{_Vr` AmH¥${V`m| H$m `Wmo{MV
ñnîQ>rH$aU XoVm h¡ & {\$a ^r `h {gÕm§V BZ `m¡{JH$m| Ho$ Y«wdU JwUm| Ho$ g§~§Y _| Hw$N> ^r Zht
H$hVm & {H«$ñQ>b joÌ {gÕm§V (CFT) Cnghg§`moOZ `m¡{JH$m| _| {dÚ_mZ H|$Ðr` YmVw
na_mUw/Am`Z Ho$ d-H$jH$m| H$s D$Om©Am| H$s g_mZVm na {d{^Þ {H«$ñQ>b joÌm| Ho$ à^md
({bJÝS>m| H$mo q~Xþ Amdoe _mZVo hþE CZHo$ Ûmam àXÎm à^md) H$s ì`m»`m H$aVm h¡ &

56/3/3 16
 Answer the following questions :
(i) What happens when bromobenzene is treated with Mg in the
presence of dry ether ? 1
(ii) Which compound in each of the following pairs will react
faster in SN1 reaction with OH ? 1
(1) CH2 = CH CH2 Cl or CH3 CH2 CH2 Cl
(2) (CH3)3C Cl or CH3Cl
(iii) Write the equations for the preparation of 1-iodobutane from
(1) 1-chlorobutane
(2) but-1-ene. 2×1=2

OR
(iii) Write the structure of the major products in each of the
following reactions : 2×1=2
Ethanol
(1) CH3 CH CH3 + KOH
| heat
Br

Anhyd. AlCl 3
(2) + CH3COCl

32. Coordination compounds are widely present in the minerals, plant and
animal worlds and are known to play many important functions in the
area of analytical chemistry, metallurgy, biological systems and medicine.

(primary and secondary), by a metal atom/ion in a coordination compound.

He predicted the geometrical shapes of a large number of coordination
entities using the property of isomerism. The Valence Bond Theory (VBT)
explains the formation, magnetic behaviour and geometrical shapes of
coordination compounds. It, however, fails to describe the optical
properties of these compounds. The Crystal Field Theory (CFT) explains
the effect of different crystal fields (provided by the ligands taken as point
charges) on the degeneracy of d-orbital energies of the central metal
atom/ion.

56/3/3 17 P.T.O.
 {ZåZ{b{IV àíZm| Ho$ CÎma Xr{OE :

(i) O~ Cnghg§`moOZ `m¡{JH$ NiCl2 . 6H2O H$mo AgNO3 {db`Z Ho$ gmW
{_bm`m J`m, Vmo à{V _mob `m¡{JH$ Ho$ {bE 2 _mob AgCl Adjo{nV hþE &
g§Hw$b H$m g§aMZmË_H$ gyÌ Ed§ {ZH¡$b Am`Z H$s {ÛVr`H$ g§`moOH$Vm
{b{IE & 1

(ii) [Co(NH3)5(SO4)]Cl Ho$ Am`ZZ g_md`d H$m AmB©.`y.nr.E.gr. Zm_

{b{IE & 1

(iii) g§`moOH$Vm Am~§Y {gÕm§V H$m Cn`moJ H$aVo hþE, {ZåZ{b{IV H$s Á`m{_{V
Am¡a Mwå~H$s` ì`dhma H$s àmJw{º$ H$s{OE :
(1) [Ni(CO)4]
3
(2) [Fe(CN)6]
[na_mUw H«$_m§H$ : Ni = 28, Fe = 26] 2×1=2

AWdm
(iii) H$maU Xr{OE : 2×1=2

(1) {ZåZ àMH«$U MVwî\$bH$s` g§Hw$b Zht ~ZVo h¢ &

3+
(2) [Co(NH3)6] EH$ Am§V[aH$ H$jH$ g§Hw$b h¡ O~{H$
2+
[Ni(NH3)6] EH$ ~mø H$jH$ g§Hw$b h¡ &
[na_mUw H«$_m§H$ : Co = 27, Ni = 28]

IÊS> L>
33. (H$) (i) C5H10O AmpÊdH$ gyÌ dmbm H$moB© H$m~©{ZH$ `m¡{JH$ (X) AnZr g§aMZmAm|
na {Z^©a H$aVo hþE {d{^Þ JwUY_© Xem© gH$Vm h¡ & àË`oH$ H$s g§aMZm
It{ME `{X `h :
(1) YZmË_H$ Am`moS>mo\$m°_© narjU XoVm h¡ &
(2) H¡${ZµOmamo A{^{H«$`m Xem©Vm h¡ &
(3) Q>m°boÝg A{^H$_©H$ H$mo An{MV H$a XoVm h¡ Am¡a Bg_| {H$aob H$m~©Z
h¡ &
56/3/3 18
 Answer the following questions :
(i) When a coordination compound NiCl2 . 6H2O is mixed with
AgNO3 solution, 2 moles of AgCl are precipitated per mole of

the compound. Write the structural formula of the complex

and secondary valency for Nickel ion. 1
(ii) Write the IUPAC name of the ionisation isomer of
[Co(NH3)5(SO4)]Cl. 1

(iii) Using Valence Bond Theory, predict the geometry and

magnetic nature of :

(1) [Ni(CO)4]

(2) [Fe(CN)6]3
[Atomic number : Ni = 28, Fe = 26] 2×1=2
OR
(iii) Give reasons : 2×1=2

(1) Low spin tetrahedral complexes are not formed.

3+
(2) [Co(NH3)6] is an inner orbital complex whereas
2+
[Ni(NH3)6] is an outer orbital complex.
[Atomic number : Co = 27, Ni = 28]

SECTION E

33. (a) (i) An organic compound (X) having molecular formula C5H10O
can show various properties depending on its structures.
Draw each of the structures if it
(1) gives positive iodoform test.

(2)
(3) has a chiral carbon.

56/3/3 19 P.T.O.
 (ii) {ZåZ{b{IV go gå~Õ A{^{H«$`m {b{IE :

(1) dmoë\$-{H$eZa AnM`Z

(2) hob-\$mobmS>©-µOoqbñH$s A{^{H«$`m 3+2=5

AWdm

(I) (i) Amn {ZåZ{b{IV àË`oH$ `m¡{JH$ H$mo ~|µOmoBH$ Aåb _| H¡$go ê$nmÝV[aV H$a
gH$Vo h¢ ?
(1) EogrQ>mo\$sZm°Z
(2) E{Wb~|µOrZ
(3) ~«mo_mo~O
|µ rZ

(ii)
ì`dpñWV H$s{OE :

(1) O2N CH2 COOH, F CH2 COOH, CN CH2COOH

(Aåbr` ì`dhma)
(2) EWoZ¡b, àmonoZ¡b, ã`yQ>oZmoZ, àmonoZmoZ
(Zm{^H$ñZohr `moJO A{^{H«$`mAm| _| A{^{H«$`merbVm) 3+2=5

34. (H$) 25 C na {ZåZ{b{IV gob H$m {dÚwV²-dmhH$ ~b (emf) n[aH${bV H$s{OE :

+
Zn (s) Zn2+ (0·1 M) H (0·01 M) H2 (g) (1 bar), Pt (s)

[{X`m J`m h¡ : E = 0·76 V, E = 0·00 V, log 10 = 1]

Z n 2 / Zn H / H2

(I) H$mobamD$e H$m Am`Zm| Ho$ ñdV§Ì A{^J_Z H$m {Z`_ ~VmBE & VZwH$aU Ho$ gmW
? 3+2=5

56/3/3 20
 (ii) Write the reaction involved in the following :

(1) Wolff-Kishner reduction

(2) Hell-Volhard-Zelinsky reaction 3+2=5

OR

(b) (i) How can you convert each of the following compounds to
Benzoic acid ?

(1) Acetophenone

(2) Ethylbenzene

(3) Bromobenzene

(ii) Arrange the following compounds in increasing order of their

property as indicated :

(1) O2N CH2 COOH, F CH2 COOH, CN CH2COOH

(Acidic character)

(2) Ethanal, Propanal, Butanone, Propanone

(Reactivity in nucleophilic addition reactions) 3+2=5

34. (a) Calculate the emf of the following cell at 25 C :

+
Zn (s) Zn2+ (0·1 M) H (0·01 M) H2 (g) (1 bar), Pt (s)

[Given : E = 0·76 V, E = 0·00 V, log 10 = 1]

Zn 2 / Zn H / H2

(b) State Kohlrausch law of independent migration of ions. Why does

the conductivity of a solution decrease with dilution ? 3+2=5

56/3/3 21 P.T.O.
35. (H$) (i) {ZåZ{b{IV Ho$ H$maU Xr{OE :

(1) g§H«$_U YmVwE± g§Hw$b `m¡{JH$ ~ZmVr h¢ &

(2) _¢JZrµO Ho$ {bE E _mZ A{YH$ G$UmË_H$ h¡ O~{H$
Mn 2 / Mn
E Ho$ {bE YZmË_H$ h¡ &
Mn 3 / Mn 2

(3) Obr` {db`Z _| Cu+ Am`Z AñWm`r h¡ &

(ii) nm`amobwgmBQ> A`ñH$ (MnO2) go KMnO4 Ho$ {daMZ go gå~Õ g_rH$aU
{b{IE & 3+2=5

AWdm
(I) (i) {ZåZ{b{IV H$s nhMmZ H$s{OE :

(1) 3d
Xem©Vr h¡ &
(2) 3dloUr H$s g§H«$_U YmVw Omo Obr` {db`Z _| +2
AdñWm _| à~b AnMm`H$ h¡ &
(ii) {ZåZ{b{IV g_rH$aUm| H$mo nyU© Am¡a g§Vw{bV H$s{OE :
2 +
(1) Cr2O7 + 14H + 6Fe2+

(2) KMnO4
Ja_ H$aZo na

(iii) ? BgH$m EH$ Cn`moJ {b{IE & 2+2+1=5

56/3/3 22
35. (a) (i) Account for the following :

(1) Transition metals form complex compounds.

(2) The E value for manganese is highly negative
Mn 2 / Mn
whereas E is highly positive.
Mn 3 / Mn 2

(3) Cu+ ion is unstable in aqueous solution.

(ii) Write the equations involved in the preparation of KMnO4

from Pyrolusite ore (MnO2). 3+2=5

OR

(b) (i) Identify the following :

(1) Transition metal of 3d series that exhibits only one

oxidation state.

(2) Transition metal of 3d series that acts as a strong

reducing agent in +2 oxidation state in aqueous solution.

(ii) Complete and balance the following equations :

2 +
(1) Cr2O7 + 14H + 6Fe2+

heat
(2) KMnO4

(iii) What is Misch metal ? Write its one use. 2+2+1=5

56/3/3 23 P.T.O.