Cement, Concrete
Cement, Concrete
Introduction
In this modern age of technology, building material plays an important role. Without building material, any construction
activities cannot be act. Many naturally occurring substances, such as clay, sand, wood and rocks even thatch and leaves
have been used to construct building. Apart from naturally occurring materials, many industrial products are in used like
brick, concrete, glass, reinforcement, paints etc. For example:
a) Rock: Rocks are usually available. There are many types of rock e.g. igneous rock, sedimentary rock and
metamorphic rock.
b) Wood: Natural and locally available material for building construction. It can be moulded in desired shape and size
which makes it more usable. The main problems with wood structure are fire risk and durability.
c) Thatch: Thatch is one of the oldest of building materials known; grass is a good insulator and easily harvested. It was
easily available material.
d) Mud and clay: The amount of each material used leads to different styles of buildings. The deciding factor is usually
connected with the quality of the soil being used. Larger amount of clay usually mean using the cob/adobe (sun dried
brick) style. Soil and especially clay is good thermal mass; it is very good at keeping temperature at a constant level.
Homes built with earth tend to be naturally cool in the summer heat and warm in cold weather.
e) Lime: Lime is a general term for calcium-containing inorganic materials, in which carbonates, oxides and hydroxides
predominate. In general lime is calcium oxide or calcium hydroxide, obtain from lime stone. These materials are still
used in large quantities as building and engineering materials (including limestone products, concrete and mortar)
f) Sand: Used with cement and sometimes lime, to make mortar for masonry work and plaster. Sand is used as a part of
the concrete mix. Sometimes it also used as damp proof materials.
g) Cement: Cement is a artificial building material, manufactured by mixing the calcareous and argillaceous material
then burning and then grinding.
h) Concrete: Concrete is a composite building material made from the combination of aggregate and a binder such as
cement.
i) Glass: It is a generally made from mixtures of sand and silicates, mixed in a kiln with high temperature. It is very
brittle and hard in nature.
j) Metal; Metal is used as structural frame work for larger buildings such as sky scrapers. Steel is a metal alloy whose
major component is iron. There are many types of metals used for building.
k) Plastic: Plastic is an organic material prepared from resins, natural or synthetic with or without fillers.
l) Paints: Paints are artificial building material. They are used to protect wood from decaying, corrosion of metal and
harmful effects of atmospheric agencies.
Cement is a back bone of all types of other building materials like stone, brick, sand, gravel, and even reinforcing bars.
These materials are useless without cement. The work in which cement is used is called “civil works”.
Cement is a very important building material in the construction industry. It may be natural or artificial. Natural cement is
manufactured by burning and then crushing the natural cement stones. Natural cement stones are such types of stone
which contain 20%--40% of argillaceous matter i.e., clay and other remaining content mainly Calcareous matter which is
either calcium carbonate (CaCO3) alone or mixture of Calcium Carbonate or Magnesium Carbonate (MgCO3). Natural
cement is very closely eminent Hydraulic lime.
Artificial cement
Artificial cement is manufactured by burning appropriately proportioned mixture of calcareous or argillaceous material at
a very high temperature and then grinding to a fine powder. The burnt mixture of Calcareous and Argillaceous mater is
known as klinker. In order to delay the setting action of cement, when mixed with water, a little percentage of gypsum is
added in klinker. It should be done for natural and artificial stone. When water mixed with cement, chemical reaction is
takes place, as a result which the cement paste first sets and then hardens into a like stone.
When cement is mixed with fine sand and water, the mixture is called cement mortar. When cement is mixed with sand,
crushed stone aggregate and water, the mixture is called cement concrete. Cement is always used in form of mortar and
concrete in construction works and never alone.
Natural Cement
1.Roman Cement: It is the best cement of natural category. It is known as Parkers cement. This clay contains 30% to 40%
of clay and remaining contents as calcium carbonate (Ca CO3) and magnesium carbonate (MgCO3). The clay for roman
cement is burnt in low temperature and then grinded to fine powder. Then cement sets immediately, when mixed with
water. Hence small quantity is mixed water and used immediately due to its fast setting character. It should be carefully
stored so as to avoid direct contact with atmosphere.
2.Pozzolana Cement: It is volcanic clay, which was first obtained at a place named Pozzuoli in Italy. This clay contains
80% clay along with lime, magnesia and iron oxide. Its colour is generally red or purple due to iron oxide. This type of
cement is more resistant to chemical reaction than ordinary Portland cement.
3.Medina Cement: This cement is manufactured by using Sepria clay occurring in England. It is quick setting and light
brown in colour.
1. Normal setting cement: Portland cement starts setting after 30 min. and develops full strength after 24 hours.
2. Rapid hardening cement: The rate of strength development is much rapid than that of ordinary cement. Strength
attained by 3 days whereas by ordinary cement 7 days. This is caused due to higher degree in fineness in grinding,
burning at high temperature and adding line content in the composition.
Uses: Repair of bridge, highway slab which is to be opened to the traffic earlier moment.
3. Quick setting of cement: When concrete has to be laid under water, quick setting cement can be used. The setting
action of this cement starts within 5 minutes and it becomes stone-hard in less than one hour. This property of cement
is developed by adding small percentage of aluminum sulphate and also by grinding much finer than the ordinary
cement.
4. High alumina cement: This is also known as aluminous cement. It is another rapid hardening cement of chocolate
color by melting the mixture of bauxite (Al2O32H2O) and lime and grinding the clinkers into very fine powder. This
cement is very dark in color. The initial setting time is 3 to 6 hrs and final setting is within 2 hours of initial setting. In
this cement, content of alumina is 32%. This cement is very costly. It evolves considerable heat in setting and should
not be used in massive construction as after setting there is no expansion. It is capable of resisting the action of acid
and high temperature. It is used for sealing rocks, concreting internal water flow, heat resistant concreting, etc.
5. Water proof cement: Water-proof cement is prepared by mixing to ordinary cement a small percentage of metal
separate (Al and Ca) to ordinary cement at the time of grinding. Concrete made with such cement is more resistant to
water penetration. Such cement is used for the construction of tanks, reservoirs, retaining walls, swimming pools,
dams, bridges, etc.
6. White and colored cement: It is ordinary cement having pure white color. It is very costly. It is used for terrazzo
flooring, face plasters, traffic curbs and other ornamental works. Colored cements are produced by adding suitable
mineral pigments to ordinary white cement. Pigments are added at the time of grinding process.
Benefits
Benefits − Character Hydration
− Saving in concrete − Improved soundness
− Saving in cement − Resistance against chemical attacks
− Early removal of formwork − Lower heat of hydration
− Early and ultimate strength of concrete − Optimum initial setting times
− Reduces construction time − Low level of impurities
− Slimmer construction resulting reduced − Higher durability of structure
structural load
− Economy in steel reinforcement
The Colors of cement should be grey or greenish grey speaking of good Portland cement. This color is due to oxide of
iron and manganese. The color also varies with the degree of calcinations (burning). The brown color indicates an excess
of clay, which makes cement shrink and disintegrate in setting. A yellowish shade gives the indication of poor burning. To
obtain a white color of cement the product should not have more than 0.8% of Fe2O3’
Crushing Crushing
Grinding Grinding
Storage Storage
Mixing-in-correct-proportion 1
Rotary Kiln 2
Clinker Formation
Gypsum
Clinker Grinding 3
Mixing in dry process: This process of mixing is adopted when raw materials are very hard. All the involved materials
are first of all broken in crushers in size of about 2.5cm separately. The crushed materials are then dried with the help of
drought of dry air being passed over them. All the dried materials are then pulverized separately into fine powders with
the help of ball mills and tube mills and stored separately in hoppers.
Burning: All the pulverized materials are then mixed together thoroughly in appropriate proportion. The prepared dry
mix is kept stored in silos, ready to be fed into the kiln for burning.
Grinding: Cooled clinkers are fed into ball and tube mills for grinding to fine powder. During the process of grinding,
gypsum is added to control the initial setting time of the cement. The ground cement as it comes out from grinding mills,
it forced by compressed air in to the silos. The cement from silos is packed in to bags by packing machine automatically.
Each bag of cement contains 50 kg which volume is taken at 35 liters.
Prepared by R.L.Tamrakar
Figure 1 Page 7
Flow diagram of wet- process for cement manufacture
Crushing Washing
Slurry- Formation
Correcting Basin
Storage-Tanks
Pumping
Coal Dust
Rotary Kiln
Formation Of clinkers
Clinker Coolers
Gypsum
Storage in silos
Wet Process
This process of mixing is usually adopted when raw materials are quite soft. Chalk or limestone is crushed in balls or
roller mills and stored in silos. Clay or argillaceous materials are mixed with water in containers known as wash mills.
This washed clay is stored in basins. Now crushed dry limestone or chalk from silos and wet clay from basins are allowed
to fall in a channel in correct proportion. The channel leads the mix to grinding mills, where both the materials are
intimately mixed. Some water may be added, if resulting mix is quite thick. This mix is known as slurry. The slurry thus
prepared is stored in tanks where it is kept constantly stirred. The chemical composition of slurry is checked here and if it
needs any correction, it is done. The corrected slurry is kept stored in storage tank and kept ready for feeding into the
rotary kiln for burning.
The proportion of bogue compounds vary is various types of cements. Tri-calcium silicate (C3S) and di-calcium silicate
(C2S) are the compounds mostly responsible for the strength characteristics of the cement. After addition of water in
cement, tri-calcium aluminates (C3A) is the first compound which starts hydrating and is responsible for early setting of
the cement. Hydration of C3A does not contribute any strength to the concrete. But it is mainly responsible for setting
action of the cement. After C3A hydration of tri-calcium silicate (C3S) starts. It is C3S, whose hydration process is
responsible for the initial strength of the cement. The strength acquired during first 7 days is mostly due to hydration of
C3S.
di-calcium silicate (C2S) reacts with water at a very slow rate and hence, strength of the concrete, after 7 days, is mainly
due to hydration of C2S. C2S starts contributing strength after 7 days of its placement and continues for about one year,
through rate of getting strength from its compound goes on decreasing with passage of time. Tetra-calcium-alumino
ferrite is more or less inactive compound and does not play any significant role in setting and hardening properties of the
cement. In short it can be said, that the rapidity of initial setting of the cement is controlled by amount of tri-calcium
aluminate, where as high early strength by that of tri-silicate. Strength of cement developing after 7 or 8 days of its
placement is dependent on the amount of Di-calcium silicate.
Laboratory Test for Portland cement
1) Soundness
2) Fineness
3) Tensile strength
4) Compressive strength
5) Test for chemical composition
6) Rough and ready method of examining cement
7) Setting time
1) Soundness: Due to presence of free lime and magnesia, cement undergoes volume change after setting as these
substances go on slaking very slowly. The expansion is called unsoundness. The mortar and concrete prepared by
such cement is liable to crack and disintegrate. Soundness test is done to determine the resulting expansion. The
xpansion of cement under test should not be greater than 10mm.For soundness test “Le-chartelier” apparatus is
used.
3) Tensile strength: this is tested by making briquettes of cement sand mortar (1:3) and subjecting them to tension in
tensile strength testing machine. The tensile strength should not be less than 25 kg/cm2 after 7 days immersion of
briquettes in water.
7) Setting time:
Initial setting time is not less than minutes and final setting time notmore than 10 hours. Setting time is tested by
Vicat’s needle apparatus.
Cement Mortar: Mixture of cement, sand and water in a form of paste. It is stronger than mud mortar or lime
mortar. Hence used in construction works of load bearing walls, pillars, columns and plastering brick and stone masonry.
1) Gauged mortar: This mortar is nothing but lime mortar prepared as before, but in it some cement is also added at
the time of using it. It is also known as lime cement mortar. Addition of small amount of cement in lime mortar
increases the strength, hydraulicity and the rate of setting of the mortar. Such mortar is more plastic and workable.
As hydraulic lime itself has got sufficient strength characteristics, no useful purpose is served by adding cement in
it. Cement is mostly added to lime mortar having fat lime. This type of mortar (gauged mortar) is excellent for
brick or stone masonry in foundation, plinth and super structure. It is very good mortar for rubble stone masonry.
2) Light weight mortar: this mortar is obtained by adding materials such as asbestos fibers, jute fibers, wood powder,
saw dust, etc to ordinary cement or lime mortar. It is very useful in heatproof and soundproof structures. The
mortars having bulk density of less than 1500 kg/m2 are termed as light mortars.
3) Water resisting mortar: When it is required to carry out a work with mortar in presence of running water, the
work can’t be done safely and even with quick setting and rapid hardening cement. In such case. Entry of water
should be stopped or diverted as far as practicable at least for several hours and dry mix of 3 parts of cement and
one part of sand with wood charcoal powder and potash moistened with a solution of sea salt should be used.
4) Sound absorption mortar: Its main purpose is to reduce noise level. The bulk density of such mortar varies from
600-1200 kg/m3. The composition of this mortar consists of cement, sand, lime, gypsum slag, etc. the aggregates
are taken from light weight porous materials such as ciners, pumice, etc.
5) X-ray shielding mortar: These plasters are used to cover walls and ceiling of X-ray cabinets. It is heavy type of
mortar having bulk density over 2700 kg/m3.
6) Fire resistance mortar: This is obtained by mixing powder of fire bricks or fire clays with aluminous cement.
Thus mortar can withstand the effects of very high temperature and as such is used for lining of furnaces, fire
places and ovens, etc.
Concrete is an artificial material, obtained by mixing together cementing material, coarse aggregate (C.A.), fine aggregate
(F.A.) and water. If cement is used as cementing material in the mix, it is known as plain cement concrete. If steel rods are
embedded in the plain cement concrete it is then called reinforced cement concrete (RCC). In lime concrete steel rod can’t
be used because of chemical reaction between lime and steel makes distortion of steel (decay of steel). Lime concrete is
used for foundation blocks or as under coats in case of flat roofs and floors. Cement concrete is the concrete which is
universally used. There is no structural element which can’t be made from cement concrete or RCC.
Classification of Concrete
1. Mud Concrete
2. Lime Concrete
3. Cement Concrete
1) Mud Concrete - Mixture of brick bats in mud mortar. Brick bats may be of kuchha or pukka brick sometimes
crushed stone can be used. It is used for not very important works or on temporary works.
2) Lime Concrete – It is used for foundation works, hard base for floors, over roof slabs. This concrete is cheaper
than cement concrete. Hydraulic lime is always used in this concrete.
3) Cement Concrete – It is prepared by mixing together cement, sand, crushed rock and water. It is used in all types
of construction work universally. This mixture when placed in the skeleton of forms and allowed to cure becomes
hard like a stone. Cement concrete has a major value for building in modern architecture because of the following
reasons:
a. It can be readily molded into durable structural items of various sizes and shapes at practically no
considerable labor expenditure.
b. It is possible to control the properties of cement concrete within a wide range by using appropriate
ingredients and by applying special processing techniques – mechanical, chemical and physical.
c. It possesses adequate plasticity for mechanical working.
Constituents of Concrete
The main ingredients of concrete are:
The proportion and properties of water, cement and aggregates influence the workability of the concrete. In other
words, “workability is that property of concrete which determines the amount of internal work necessary to
produce full compaction”. Elements that affect workability can be listed as follows:
a) Quantity of water in the mix. Increased amount of water increased workability.
b) Proper grading of the aggregate mix. If F.A. as well as C.A. is properly graded, workability is increased.
c) Increased amount of cement will also increased workability as more water will have to be added to maintain w/c
ratio.
d) Proper ratio of F.A. and C.A. can improve workability.
e) If aggregates with rounded grains are used, workability will improved.
f) By adding admixtures workability can be improved.
g) Maximum size of C.A. also affects workability.
h) Methods of compaction of concrete affect workability. Compaction can be done by either vibrator or steel rod
1.2 Segregation
Tendency of separation of C.A. grains from the concrete mass is called segregation. It increases when concrete
mixture is lean and too wet. It also increases when rather larger and rough textured aggregate is used. Segregation
is harmful to concrete properties. Segregation can be avoided as following:
1.3 Bleeding
The tendency of water to rise to the surface of freshly laid concrete is known as bleeding. The water raised to the
surface carries with it, particles of sand and cement, which on hardening form a scum layer.
1.4 Harshness
Harshness is the resistance offered by concrete to its surface finishing. It is due to the presence of lesser fines,
lesser cement mortar and use of poorly graded aggregates in concrete mix and insufficient water cement required
for workability. The surface of harsh concrete remains rough and porous.
Concrete is not truly an elastic material but behaves as an elastic material within the range of usual working stresses.
The value of elasticity varies from 14 t/cm2 30 t/cm2.
Sustained loads applied to concrete cause permanent deformation which is called “creep”.
Like other materials, concrete also expands or shrinks with rise or fall of temperature.
Mixing of concrete
The process of mixing cement, water, F.A. and C.A. in suitable proportion is known as mixing of concrete. This process
should ensure uniform color, consistency and homogeneity of the concrete. Segregation should not take place during
process of mixing. There are two types of mixing of concrete
1. Hand mixing: Hand mixing is used, where quantity of concrete is very small. It can also be used where machines
for mixing are not available or where noise is not desirable. In this process cement and sand are first of all mixed
dry on clean, hard and impermeable platform. Dry mixing is continued until the mix attains uniform color. Now
this mix is spread on the measured stock of course aggregate in required amount and they are mixed dry again to
have uniform color. Shovels are used for this mixing purpose.
Make hollow in the middle of the mixed pile add about 75% of the required quantity of water. Now mixing is done
and the remaining quantity of water is added to acquire the uniform workability. In this method of mixing, about
0% more cement is used to make good the cement lost due to possible water flowing out of the mix and also to
make good strength characteristics due to inferior result of hand mixing.
2. Machine mixing: In large works, machine mixing proves to be economical and convenient. Concrete produced by
machine mixing is more homogenous and can be prepared with comparatively lesser W/C ratio. The concrete
mixtures may be batch type or continuous type. Batch mixtures, mix and discharge each load of materials
separately, where as continuous mixers produce steady stream of concrete so long as it is in operation. Latter type
mixers are not in common use. Batch type mixers are mostly adopted. These may be rotary or non-tilting type or
tilting type
Placing of concrete
The concrete should be placed and compacted before its setting starts. Following precautions should be taken while
placing:
a) Concrete should be laid continuously to avoid irregular and unsightly lines.
b) To avoid sticking of concrete, formwork should be oiled before concreting.
c) While placing concrete, the position of formwork and reinforcement should not be disturbed.
d) To avoid segregation, concrete should not be drooped from height more than 1m.
e) Concrete should not be placed at rains.
f) Thickness of concrete layer should not be more than 30-45 cm, in case of mass concrete and 15-30cm in case of
RCC works.
g) Walking on freshly laid concrete should be avoided.
h) It should be placed as near to its final position as practicable.
Finishing
Finishing means giving desired smoothness or finishing to the surface
of compacted concrete. For achieving good finishing slump of the
concrete should not be more than 5cm. Screeding, traweling are the
usual operations involved in finishing.
Curing of concrete
Curing is the operation by which moist condition s is maintained of finished concrete surface, to improve continued
hydration of cement. If proper curing is not done, complete hydration of cement will not take place, with the result that the
concrete will not acquire its full intended strength. More over shrinkage and cracks will developed in the concrete. Curing
also brings about improvements in durability, impermeability, wear and weather resisting qualities. There are several
methods of curing. Adoption of specific methods depends upon the nature of work and the climatic conditions. Following
are the methods of curing:
1. Shading
2. Sprinkling water
3. Ponding of water
4. Membrane curing: In this method, surface of concrete is covered by a water proof membrane which is kept in
contact with concrete. The membrane prevents evaporation of water from concrete. Wax, emulsion, bitumen
emulsion, bituminized water proof paper, and plastic films are the common membrane materials.
5. Steam curing
Admixtures
Sometimes ingredients other than conventional have to be added in concrete to improve some of its qualities. These
ingredients are known as admixtures. Admixtures improve the concrete width to its strength, hardness, workability; water
resisting power etc. following are the commonly used admixtures:
Alum, aluminum sulphate, barium oxide, bitumen, calcium chloride, coal ash, common salt, lime, iron oxide, mineral oils,
organic oils, potassium fluoride, silicate of soda, tar products, zinc chromate and volcanic ashes.
The use of admixtures is as follows:
1) Quantity of cement is reduced.
2) W/C ratio can be reduced.
3) Durability of concrete gets increased.
4) Permeability of concrete can reduced or increased as desired.
5) Time in saved in repairs and maintenance.
6) Final setting time can be adjusted.
7) Higher early and ultimate strength are achieved
8) Higher slumps and self leveling concretes are obtained.
2. Aggregates: These are the inert or chemically inactive materials which form the bulk of cement concrete. These aggregates
are bound together by means of cement. The aggregates are classified into two categories: Fine and Coarse.
The material which is passed through 4.75mm size B.S test sieve is termed as a fine aggregate. Usually natural
river sand is used as a fine aggregate. But at places, where natural sand is not available economically, finely
crushed stone may be used as fine aggregate.
The material which is retained on 4.75mm size B.S. test sieve is termed as a coarse aggregate. Broken stone is
generally used as a coarse aggregate. The nature of work decides the maximum size of the coarse aggregate. For
thin slabs and walls, the maximum size of coarse aggregate should be limited to one-third the thickness of the
concrete section.
3. Steel: The steel reinforcement is generally in the form of round bars of mild steel. The diameters of bars vary
from 5mm to 40mm. Sometimes, square bars or twisted bars or ribbed tor-steel are used as steel reinforcement.
For road slabs and such other construction reinforcement may also consists of sheets of rolled steel of suitable
thickness. Hybrid which is a steel lath may also be used as steel reinforcement.
4. Water: This is the least expensive but most important ingredient of concrete. Water, which is used for making
concrete, should be clean and free from harmful impurities such as oil, alkali, acid etc. in general, water which is
fit for drinking should be used for making concrete.
It may be noted that sometimes ingredients other than above are added in concrete to give it certain improved
equalities. These ingredients or substances are known as admixtures. The addition of an admixture may improved
the concrete with respect to its strength, hardness, workability, water-resisting power, etc
Corrosion of Steel in Concrete
Corrosion of steel in concrete sometimes occurs to reinforcing bars placed in concrete. The term corrosion is used
to indicate the conversion of metals by natural agencies into various compounds. The terms rusting is used to refer
corrosion of ferrous metals.
Causes of corrosion
1. Coagulated reinforcement in small concrete sections
2. Excessive w/c ratio
3. Improper construction method
4. Inadequate design procedure
5. Incomplete supervising staff of contractor
6. Initially rusted reinforcement before placing concrete
7. Poor workability
8. Presence of moisture in concrete
9. Presence of salts
Prevention of corrosion
1. Avoiding heavily congested reinforcement.
2. Avoiding the steel to come into contact with bricks soil, wood and other porous non-alkaline materials.
3. Cleaning the reinforcement with wire-brush to remove the rust scales before placing of concrete.
4. Maintaining the high degree of workmanship.
5. Proper structural design with due provision of concrete.
6. Providing surface coating of paints, tars, asphalts etc
7. Use of high qualities or impermeable concrete
8. Using stone pebbles in place of badly made concrete blocks
9. Using the correct w/c ratio
Guniting
It is process by which inferior or damaged concrete work can be repaired. It is also used for providing an impervious layer.
Gunite is mixture of cement and sand, usually in proportions of 1:3. A special equipment known as cement gun is used to
deposit this mixture on the concrete surface under a pressure of about 2 to3 kg/cm2.
The surface to be treated is cleaned and washed the nozzle of the gun is generally kept at a distance of about 80cm from
the surface to be treated. Velocity of flow through the nozzle is from 120 to 160 m/sec.
This process gives following advantages:
a) High impermeability is achieved.
b) The repair can be carried out in any situation in a very short time.
c) High compressive strength say 500 to 700 N/mm2 at 28 days can be obtained.