Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60(Incoming)_NUCLEUS BT CTA-32 Date: 23-03-2025
Time: 02:00PM to 05:00PM JEE-ADV_(2021-P2) Max. Marks: 180

KEY SHEET
PHYSICS
1 A 2 ACD 3 ABD 4 CD 5 AB 6 AB

7 2 8 3 9 7 10 2 11 2 12 2

13 A 14 A 15 B 16 B 17 3 18 2

19 2

CHEMISTRY
20 BC 21 CD 22 BCD 23 ABD 24 ABCD 25 BCD
23.3 20.62 149.6 0.05
6.6 to
26 27 to 28 to 29 24.4 30 to 31 to
6.7
23.4 20.63 149.7 0.06
32 C 33 C 34 B 35 C 36 24 37 2

38 7

MATHEMATICS
39 BCD 40 ABD 41 BC 42 BC 43 BD 44 BD

45 1 46 2 47 2 48 4 49 60 50 40

51 C 52 B 53 B 54 A 55 5 56 16

57 32
 Sri Chaitanya IIT Academy 23-03-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-32_Key & Sol’s

SOLUTIONS
PHYSICS
2a  d sin 
1  B   0
1  cos  4 r 2
2  i
 i d
  0 1  cos    0
4 2a 4a
0

2 
eE  e viˆ  B 
E
v
 i  B,
E
V
 j B

 i  j  B  0
B is parallel or antiparallel to i – j
1 x 1 y
3 clockwise  Bix     Biy   
2 2 2 2
Bi
  y  x  x  y   
2
4 The observer moving with v rightward sees on EF E upwards
Since no interaction between ring and P. it should move in a cycloidal path with or
without ring
   mg
E  VB Eq  mg  q 
BV
mv 2 v2
mg  BqV  Eq  R
R g
1 mg cos 
5 mg sin   mu 2 , u  observing moving right with V such that
2 Bq
 V
qE  qVB, E  1
VB
mg mu rel
V and R 
Bq Bq
u  v cos  v 2 cos 2   2g sin 
u rel  vsin 

2 m 2 v 2 sin 2  h
R   tan 2 
1 2 4
Bq
6 Br  011R1  022R 2 , Br2  02  2R 2
1
1 2R1L dl  011R1 
  022R 2 
2 2
 
P1  
dl L
 i
7. Magnetic field at the centre due to one side B1  0 sin , where r  a cos 
2r

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 2

 Sri Chaitanya IIT Academy 23-03-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-32_Key & Sol’s
 0i  i
B1  sin   0 tan 
2a cos  2a
Bnet  nB1

0 nir 2 1  ni
8 B   0

2 r2  x 
2 3/2 8 2r

 NAB
9 
i C
 NAB
10 
i C
 ni
11 0
2
0 ni
12
2
mg
13 I0 r 2 B  mgr I 
0 rB
3 2 2g
14 2mgr  mgr  mr   a cm  r 
2 3
 q  5mg
N  mg  m    N 
 3  3
 2Ni0 AB
15 C 
 
1 N 2 A 2 B2
16 I  NABQ  I2 
2 2I
1 2 N 2 A 2 B2  NAB
Cmax   max  Q
2 2I 2Ii0
R
0 j2 2 2 0 j2 3
17  4

R  r dr  
3
R
R
M q
18  along and Q and M and similarly distributed
L 2m
Bi
19 T
2
CHEMISTRY
20 (a)
 B 3k1 3  103 3
  
C 2k 2 4  103 4
(b) n A  1  x  y; n B  3x; n C  2y
At t  ;  x  y   1
n total  3x  2y  x  2  lies between 2  3

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 3

 Sri Chaitanya IIT Academy 23-03-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-32_Key & Sol’s
ln 2
(c) t1/2 (A)  sec
3  103
693
No of half – lives in 693 sec =  3  103
0.693
 A 0
 A t 
23
21
2A  B
x
1 x  y
2
3A  2C
2
1 x  y y
3
d  A  dx dy dB  3 d C  0.07 A
    2   
dt dt dt dt 2 dt
 B  3 x  0.02  % B  % C  50%
   
C 4 y 0.02
ln 2
t1/2  A    10 min
0.07
22 conceptual
23 A4  4A
t=0 aM 0
t= 30min (a-x)M 4x M
a
As a  x  4x  x 
5
Percentage reaction at t = 30min
x
  100  20%
a
t a
Now 30  1/2 log  t1/2  90 min
log 2 ax
24 Conceptual
25 x  179pm; y  163pm
  126
26 & 27
Sol Between two successive dose the former dose spent two half lives
At the time when sixth dose is given
First dose has spent 30 hrs = 10 half – lives
Second dose has spent 24 hrs = 8 half – lives
Third dose has spent 18 hrs = 6 half = lives
Fourth dose has spent to 12 hrs = 4 half – lives
Fifth dose has spent 6 hrs = 2 half – lives
Sixth dose is just given = present completely  mass of drug remaining

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 4

 Sri Chaitanya IIT Academy 23-03-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-32_Key & Sol’s
  1 2  1 4  1 6  1 8  1 10 
 5 1                
  2   2   2   2   2  
1
The above is a geometric progression series with common ratio =
4
6
1
n 1  
1 r  4   1.33
 sum  
1 r 1
1
4
 Mass of the drug remaining = 5  1.33  6.65mg
28 and 29
In the given reaction, the product ether is also chiral but it would be produced as
racemic mixture (by SN1 mechanism) and would not contribute to optical rotation of
solution. Also, at infinite time 5° optical rotation indicates rotation due to some
optically active impurities present in the system
40 1 8
 10k  1n or k  ln ...........(i)
25 10 5
40 8
20k  ln  2ln [From Eq (i)]
 5
   15.625
Total optical rotation after 20 min = 15.625 + 5 (impurity) =20.625°
15.625
Also; fraction of reactant reacted after 20 min  1   0.61
40
Millimoles of reactant reacted = 10 x 0.61 = 6.1
 mmolof alkene formed = 6.1  0.6  3.66 milli mole of Br2 required
3.66
 volume of Br2 required =  24.4mL
0.15
30 and 31
500  3.4
Initial mass of H 2O 2 =  17g
100
17
 initial mol of H 2O2   0.50mol
34
n ln 2 0.50
 Kt  ln 0 or  4  ln  n  0.38
n 10.8 n
 mol of H 2O 2 decomposed = 0.50 -0.38 = 0.12
 moles of O 2 produced = 0.06
 pV  work   Pext V  n g RT
 0.06  8.314  300  149.65J
32 Conceptual
33 Conceptual
34 Conceptual
35 Conceptual
36 Conceptual

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 5

 Sri Chaitanya IIT Academy 23-03-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-32_Key & Sol’s
37 V2O5 and Cr2O3 are amphoteric
2N 2O5  4NO 2  O 2
P0  
38 P0  x 2x x
P0
0 2P0
2
P
2P0  0  Pinert  1550  P0  Pin ert  650
2
x ln 2  600 
Now,  200  x  100   4  ln  
2 t1/2  400 
 t1/2  7 min

MATHEMATICS
2 2
39. 7x  2y  12xy  2x  14y  22  0
2
2 2  2x  y  1
 x  1   y  2  3
 5 
PS
 3 1
PM

 b2  4 2
40. Normal at  ae,
  , passes through (0, b) , then e  e  1
 a 

5 1 2
e2 
2
;b  2 3  5  

LLR 

4 3 5   62 5
2

Area between director and auxiliary circles is b 2  2 3  5  

2
41. H : 3  x  1  y 2  3
2

 x  1

y2
 1
3 3

auxiliary circle is  x  12  y2  3

x 2  y 2  2x  2  0

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 6

 Sri Chaitanya IIT Academy 23-03-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-32_Key & Sol’s

3 3 3
e  1 
3 3

1  2a 2  2
Area of LOL    be  a e
2  b 
42.

 
9  16 e2H  1  e H 
5
4
F1, F2   5,0  ,

 
16  9 ec2  1  ec 
5
3
F3 , F4   0,  5 

1
Area of F1F3F2F4  10 10  50
2
43. Other asymptote is the image of x = 2y in the line x = y i.e, y = 2x
 Hyperbola is (x – 2y) (2x – y) = K
 It passes through (3, 4)  K = 10

 angle between asymptotes  2sec1 e

3 10
 tam 1    2 sec1 e  e 
4 3
44. We know that, in a triangle, joining mid points of two sides is half and parallel to
1
third side M1M 2  QQ1
2

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 7

 Sri Chaitanya IIT Academy 23-03-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-32_Key & Sol’s
B

Maximum values QQ1  BB1 (Major axis)

1 1 1
M1M 2  BB  16  8
2 2
x .cos  y sin 
45. Equation of tangent is  1
4 2
2
Equation of parabola is  y  2   2  x  4   vertex = (4, 2)
 sin   cos   1

cos   4  sin   2   1
   1  sin     
4 2  4 2

32  cos 2  sin 2  
46. 
5  16

4 
2
 2 5
 2
  1  cos   4 1  cos    cos  
2
1
2

47. ( AeH , 0)  ( a, 0)

 eH , eE  1

angle between the asymptotes

B 2 B
2 tan 1  ,  3
A 3 A
b 1
  3  eE2 
aeE 4

48. ( AeH , 0)  ( a, 0) , and b = B

 eH , eE  1

x2 2a 2eE2
On solving curves, 2  2 ,
y b 1  eE2 
9x2
 4
2 y2

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 8

 Sri Chaitanya IIT Academy 23-03-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-32_Key & Sol’s
2 2
49. Equation of director circle is  x  1   y  3  r 2

 Here r 2  a 2  b 2  60
1
50. Area of the quadrilateral BSBS   2ae  2b,  2ae. b  2.2 5 .2 5.2 5  40
2
1
51. m 0 A   m o B  2
2
1
 2
3
tan   2
11 4

3 3
or sin   ,   sin 1  
5 5  
52. Equation of hyperbola 2x 2  2y2  5xy    0
Passing through (1, 1)    9
Equation of hyperbola is 2x 2  2y2  5xy  9
 7
The equation of the tangent at  1,  is S1  0
2 
 7  52   7  
2x  1  2y     x      1 y   9
2 2  2 
 3x  2y  4

53. SS 1  2ae,

Let S   x1 , y1  S 1   x2 , y2 

then x1 x2  y1 y2  1

x1  x2  2h, y1  y2  2k where  h, k  center now SS 1  2ae,  h 2  k 2  5

1 1
54. (h, k) be a focus, then  ,  is the other focus then
h k

1  h2 1  k2
x y , where (x, y) centre, and x 2  y 2  5 as orgin lies on director
2h 2k
circle
1
2x  h  .......... 1
h
1
2y  k  .......... 2 
k

12   2 2

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 9

 Sri Chaitanya IIT Academy 23-03-2025_Sr.Super60(Incoming)_NUCLEUS BT_Jee-Adv(2021-P2)_CTA-32_Key & Sol’s

 
4 x 2  y2  h 2  k 2 
1
h2

1
k2
4

1 1
4  5  4  h2  k2  2

h k
1 1
Locus is x 2  y2  2
  16
x y2

55.  x  32   y  12 2  81
 x  3  2   y  8  2  9
Let the point of intersection be p  ,  
   32 2
    12   81  1
   32 2
    8   9   2 
Add (1) and (2) , then  2  6  4  13  0
Subtract (2) from (1) 2  20  59  0
d    3 2     2  2  d 
Sum of the distance of all intersection points  2  y1  y 2   2  1  2   2  20  40
56. Equation of director circles of ellipse and hyperbola are respectively.
x 2  y 2  a 2  b 2 and x 2  y 2  a 2  c 2 which gives

a 2  b2
9
   9  2  e2  18  9e2  9e2  e2  16
1  1  ee2

1   e2h  1
e h h e
a 2  c2
57. Equation of tangent is

hx  ky  h 2  k 2
Also tangent at P is
x
 yt  2c
t
 (1) and (2) are identical

h2  k2
 
2ck 2
  2 2
 x 2  y2  4c2 xy
2ch h k

Sec: ^Sr.Super60(Incoming)_NUCLEUS BT Page 10