PHASE TEST

BATCHES – XI 2426 A LOT (PHASE-3) PHYSICS, CHEMISTRY & MATHEMATICS

PHASE-3 JEE ADVANDED PAPER - 1 23-03-2024
Time Allotted: 3 Hours Maximum Marks: 186

 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three SUBJECTS.
3. SUBJECT-1 is Physics, SUBJECT-2 is Chemistry and SUBJECT-3 is Mathematics.
4. Each SUBJECT is further divided into Two Sections: SECTION-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Sections.

(i) SECTION-A (01-04) – Contains four (04) multiple choice questions which have ONLY ONE CORRECT
answer Each question carries +3 marks for correct answer and -1 marks for wrong answer.
(ii) SECTION-A (05-12) – Contains eight (08) multiple choice questions which have One or More correct
answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened. Negative Marks:  1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result
in 1 marks, as a wrong option is also darkened.

(iii) SECTION-B (01-06) contains six (06) Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer. There is no negative
marking.

Name of the Candidate :_________________________________________________

Batch :________________________ Date of Examination :____________________

PSID:_____________________________ROLL NO. ___________________________

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 2

Useful Data Chemistry:

Gas Constant R = 8.314 J K1 mol1
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
Useful Data Physics:

Acceleration due to gravity g = 10 m / s2

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 3

SUBJECT – 1 (Physics)
SECTION – A
Single Correct Type

1. Two vibrating tuning forks produce progressive waves given by y1  4sin  500 t  and
y2  2sin  506 t  . These tuning forks are held hear the ear of person. The person will hear

(A) 3 beats/s with intensity ratio between maxima and minima equal to 2
(B) 3 beats/s with intensity ratio between maxima and minima equal to 9
(C) 6 beats/s with intensity ratio between maxima and minima equal to 2
(D) 6 beats/s with intensity ratio between maxima and minima equal to 9

2. Two identical rods are made of different materials whose thermal k1 k2

1 2
conductivities are k1 and k2. They are placed end to end between two heat
reservoirs at temperatures 1 and 2. The temperature of the junction of the
rods is
  2 k   k 2 2
(A) 1 (B) 1 1
2 k1  k 2
k12  k 2 1 k11  k 2 2
(C) (D)
k1  k 2 k1  k 2

3. If the work done in blowing a soap bubble of volume V is W, then the work done in blowing a
soap bubble of volume 2V will be
(A) W (B) 2W (C) 2W (D) W ( 4) 1 / 3
5R
4. An ideal gas has a specific heat at constant pressure CP  .The gas is kept in a closed vessel
2
of volume 0.0083 m3, at a temperature of 300K and a pressure of 1.6  10 6 N / m 2 . An amount of
2.49  10 4 joules of heat energy is supplied to the gas. Take the final pressure (in mega pascal) of
5P
the gas to be P. Calculate .
9
(A) 2 (B) 4 (C) 6 (D) 8

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 4

One or More Than One Correct

5. A uniform rope having mass m hangs vertically from a rigid support. A transverse wave pulse is
produced at the lower end. The speed v of wave pulse varies with height h form the lower end as

v v
(A) (B)

h h

v v
(C) (D)

h h

6. A bimetallic strip is formed by two identical strips, one of copper and the other of brass.
The coefficients of linear expansion of the two metals are C and  B . On heating, the
temperature of the strip goes up by T and the strip bends to from an arc of radius of curvature
R. Then R is
(A) proportional to T (B) inversely proportional to T
(C) proportional to  B   C (D) inversely proportional to  B   C

7. Which of the following represents a progressive harmonic wave?

(A) A(ax – bt) (B) A tan (t – kx)
(C) A cos (vt – x) (D) a cos kx sin t

8. A wall of length  supports water to a height H as shown in figure.

Choose the correct statement(s). Take  as the density of water.
1
(A) the force exerted by water on the wall per unit length is gH2 H
2
1
(B) the force exerted by water on the wall is gH2 
2
2
(C) the point of application of the resultant force acts H below the free surface
3
H
(D) the point of application of the resultant force acts below the free surface
3

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 5

9. The figure shows the P-V plot of an ideal gas taken through a cycle P
ABCDA. The part ABC and CDA are parts of two different ellipses A
3
then,
(A) the process during the path A  B is isothermal 2 B
D
(B) heat flows out of the gas during the path B  C  D 1
C
(C) work done during the path A  B  C is zero
(D) positive work is done by the gas in the cycle ABCDA 0
1 2 3 V

10. A metallic circular disc having a circular hole at its centre rotates about an axis passing through
its centre and perpendicular to its plane. When the disc is heated:
(A) its speed will decrease (B) its diameter will decrease
(C) its moment of inertia will increase (D) its speed will increase

11. Two waves travelling in opposite directions produce a standing wave. The individual wave
functions are given by y1 = 4 sin(3x – 2t) and y2 = 4 sin(3x + 2t) cm, where x and y are in cm
3
(a) The maximum displacement of the motion at x  cm is 4 cm.
4

(b) The displacement of the motion at t  sec is 4 2 cm .
6
(c) Nodes are formed at x values given by 0, /3, 2/3, , 4/3, ………..
(d) Antinodes are formed at x values given by /6, /2, 5/6, 7/6, ………….

12. A flat closed tube of rectangular cross-section has inner radius 'a' and outer radius 'b’. It is
filled completely with water and is kept flat on a horizontal surface. Now, entire water in the tube
is rotated with a uniform and steady angular velocity  about the vertical axis of the tube. Viscous
forces between the tube and water is neglected and density of water is  . 1 and 2 are two points
in water in the same horizontal plane as shown in figure. Let P be the pressure and E be total
energy of fluid particle per unit volume. Then

1 1
(A) P1  P2 
2
 
 b2  a2  2 (B) P2  P1 
2

 b2  a2  2 
(C) E1  E2 
(D) E1  E2   b2  a2 2
space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 6

SECTION – B
Integer Type

13. Figure below shows a massless pulley, a spring of constant K =

250 N/m and a mass 1 kg. On displacing the mass slightly, find
its frequency (approximate) of its vertical oscillation K

14. A standing wave exists in a string of length 150 cm and is fixed at both ends. The displacement
amplitude of a point at a distance of 10 cm from one of the ends is 5 3 mm. The distance
between the two nearest points, within the same loop and having displacement amplitude equal
to 5 3 mm, is 10 cm. Find the mode of vibration of the string i.e. the harmonic produced.

15. One mole of a monoatomic ideal gas is mixed with one mole of a diatomic ideal gas. The molar
specific heat (in calories) of the mixture at constant volume is ……………..

16. An amount Q of heat is added to a monatomic ideal gas in a process in which the gas performs a
work Q/4 to its surrounding. The molar heat capacity for the process is kR. Find the value of k?

17. A certain amount of a mono-atomic ideal gas undergoes a process u = C, where  is the
W
density of the gas and u is the internal energy of the gas. It was found that the ratio r = for
Q
the process was r = 2/3. What is the value of ?

18. Two soap bubbles A and B are kept in a closed chamber where the air is maintained at pressure
8 N/m 2. The radii of bubbles A and B are 2 cm and 4 cm, respectively. Surface tension of the
soap water used to make bubbles is 0.04 N/m. If the ratio PA and PB pressure in bubbles A and
x
B, respectively is . Find the value of x. [Neglect the effect of gravity]
3
space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 7

SUBJECT – II (Chemistry)
SECTION – A
Single Correct Type

19. The acid strength order is:

OH
O OH HO OH H3C CH3
C C
O O
O OH III IV
I II
(A) I> IV> II> III (B) III> I> II> IV
(C) II >III> I>IV (D)I >III >II> IV

20. Ordinarily the barrier to rotation about a carbon-carbon double bond is quite high but in compound
P double bond between two rings was observed by NMR to have a rotational energy barrier of only
about 20 cal.\mol., showing that it has lot of single bond character.
nC 3H7

nC 3H7
(P)
The reason for this is
(A) Double bond having partial triple bond character because of resonance
(B) Double bond undergo flipping
(C) Double bond having very high single bond character because of aromaticity gained in both
three and five membered rings.
(D) +I effect of nC3H7 groups makes double bond having partial single bond character.

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 8

21. The end product 'W' in the following sequence of reactions is :

CH2CH3
alc.KOH
Y
NBS Hg  OAc  2
 X NaBH 4 W
aq.KOH
Z
(A) CH3

Ph  CH 2  CH 2  O  CH  Ph
(B) CH3 CH3

Ph  CH  O  CH  Ph
(C) Ph  CH2  O  CH2  CH2  Ph
(D) CH CH2

Ph CH CH3

22. The most stable conformation of the product of following reaction :-

HBr /R2 O2
CH 
1 equivalent    
HBr
C

(A) (B)

(C) (D)

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 9

One or More Than One Correct

23. Which of the following electrophilic substitution reaction represent correct product.

(A)

(B)

(C)

(D)

24. Which of the following statements are not correct?

(A) A meso compound has chiral centres but exhibits no optical activity
(B) A racemic mixture is optically inactive because of two equal and opposite
rotation of same molecules in mixture.
(C) Meso compounds are molecules which are superimposable on their mirror images even
though they contain chiral centres
(D) A meso compound is optically inactive because the rotation caused by any molecule is
cancelled by and equal and opposite rotation caused by another molecules that is the mirror
image of the first.

25. Acetone (CH3COCH3) is the major product in :

I H3 O
CH2  C  CH2  
II CH3 C  CH 
H2 SO 4 /HgSO 4 /H2 O

III CH3 C  CH 3
BH  THF


H O /OH
2 2

(A) I (B) II (C) III (D) None

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 10

26. Which of the following statements would be incorrect about this compound?
NO2
3

1 5

NO2 NO2
Br
(A) All three C – N bond are of same length
(B) C1 – N and C3 – N bonds are of same length but longer than C3 – N bond
(C) C1 – N and C5 – N bonds are of same length but longer than C3 – N bond
(D) C1 – N and C3 – N bonds are of different length but both are longer than C5 – N bond

27. Which resonating structure is/ are correct :-

(A) (B) +

(C) (D)

..


28. Which of the following statements is/are true :-

(A)
The product of reaction of with conc. H2SO4 is
CH2 – OH
(B) 4
3
The best position for EAS in pyridine 2 is 4.
N
1
(C) The addition of HBr to butadiene at –80°C to give 1, 2-adduct is kinetically controlled
while that at 40°C to give 1, 4-adduct is thermodynamically controlled.
(D) Propyl chloride shows maximum dipole moment in anti conformer.

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 11

29. Which of the following combinations is/are correct :

(A)

Potential energy
A

B - Fluorination of Alkane

C
Reaction CO-ordination

(B)

A B
- Iodination of Alkane

(C)
Potential energy

B
- Bromination of Alkane
C
Reaction CO-ordination

(D)

A B
- Chlorination of Alkane
C

30. Which of the following statements is\are true about the following compounds.
O

O O
(I) (II) (III)

(A) (I)and (III)are structural isomers. (B) (I)and (II)are geometrical diastereomers
(C) (II)and (III)are structural isomers (D) (I)and (II)are identical

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 12

SECTION – B
Integer Type

31. Total number of stereoisomers possible for molecule A will be :-

H3C CH = CH CH = CH

32. An isomer of C5H12 gives total six isomeric products on monochlorination. Calculate the
percentage yield (x%) of the primary monochloride which is chiral. Consider the following relative
reactivity of C–H bonds for chlorination.

Degree of C – H 1 C – H 2 C – H 3 C – H
Relative reactivity for 1 3 5
chlorination (RR)
Report the answer as x/10.

33. IUPAC name of :-

Cl
CH3

Br C2H5

X-Bromo-Y-chloro-Z-ethyl-A-methylcyclohex-B-ene
Report you answer as :-
X + Y + Z – (A + B)

34. The number of chiral centres present in the following compound is:-
CH2OH

H O H
H
OH H

OH
H HO
O
HOH2C O D (+) - Sucrose

H OH
H
CH2OH
OH H

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 13

35.
CH3CI/AICI3 Br2/h (1 eq.) Na/ether
(1) (2) (3)
(4) Br2/h (1 eq.)
(monobromination)

(5) alc.KOH
(i) O3
(P)
(2 moles) (ii) Zn/CH3COOH
Find the sum of digits of molecular weight of product ‘P’.

36. How many of the following statements regarding the product are correct

HCI + OH –
O CI

A
(A) In 'A' the ring is aromatic
(B) 6 pi electrons are present
(C) Ring in A is de-stabilised by closed loop conjugation
(D) Both Aromatic and anti aromatic rings are stable at room temperature.

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 14

SUBJECT – III (Mathematics)

SECTION – A
Single Correct Type

37. If │z – 1│ + │z + 3│ ≤ 4, then the range of values of │z – 4│, (where i  1 ) is

(A) [0, 7] (B) [1, 8] (C) [3, 7] (D) [2, 5]

2n 2n

 a  x  1   b  x  2 
r r
38. If r r
and br = (-1)r-n for all r  n, then an =
r 0 r 0

(A) 2n+1Cn-1 (B) 3nCn (C) 2n+1Cn (D) 0

x2 y2
39. The line lx  my  n  0 will be a tangent to the hyperbola   1 , if
a2 b 2
(A) a2l2  b2m2  n2 (B) a2l2  b2m2  n2 (C) am2  b2n2  a2l2 (D) None of these

40. Number of ways in which 8 people can be arranged in a line if A and B must be next to each
other and C must be somewhere behind D, is equal to
(A) 10080 (B) 5040 (C) 5050 (D) 10100

One or More Than One Correct

The coefficient of three consecutive terms in the expansion of 1  x  are in the ratio 1 : 7 : 42,
n
41.
then
(A) n is divisible by 5 (B) n is divisible by 7
(C) n is divisible by 11 (D) n = 45

42. If the vertices of an equilateral triangle are situated at z  0, z  z1 and z  z 2 , then which of
the following are true?
(A) z1  z2 (B) z1  z2  z1  z 2

(C) z1  z2  z1 (D) argz1  arg z 2 
3
43. For r = 0, 1, ...., 10, let Ar, Br and Cr denote, respectively, the coefficient xr in the expansions of
10
(1 + x)10, (1 + x)20 and (1 + x)30. Then  A (B
r 1
r 10 Br  C10 Ar ) is equal to

(A) B10 – C10 2

(B) A10 (B10  C10 A10 ) (C) C10 – B10 (D) None of these

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 15

5
 3 3 1
44. The coefficient of x in the expansion of  x  3x   3  must be
7

 x x 
15 10
(A) odd (B) even (C) C4 (D) C5

45. If the tangent drawn at point (t2, 2t) to the parabola y2 = 4x is the same as the normal at the point
 
5 cos ,2 sin  on the ellipse 4x 2  5y 2  20 , then
 1   1  2 1
(A)   cos1   (B) cos 1   (C) t = (D) t =
 5  5 5 5

x2 y2 x2 y2
46. If the foci of the hyperbola   1 be the major axis vertices of the ellipse
 1 and 
A 2 B2 a 2 b2
foci of the ellipse be the transverse axis vertices of the hyperbola. Let the eccentricity of the
ellipse and hyperbola be eE and eH respectively then.
b b
(A)  2 (B) eH  eE  2 (C) eH  eE  2 (D)  1
B B

47. If  and 2 are non-real cube roots of unity, then

2015 1007
 1 3 1 3
(A) 4  5    i   5  i   1
 2 2  2 2 
 
2  3  52 2  3  52
(B)   1
5  2  32 3  5  22
1 1 1
(C)    0 where , ,  are the roots of the x3 – 3x2 + 3x + 7 = 0
1   1  1  
1 1 1
(D)   1
1  2 2   1  

48. If │z – iRe(z)│= │z – lm(z)│, (where i  1 , then


(A) Re(z) = Im(z) (B) lm(z) = 2 (C) Re(z) + lm(z) = 0 (D) Arg(z) =
4

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida
CLASS-XI 2426 A LOT –PHASE-3-(Paper-1)-PCM-IITJEE/26 16

SECTION – B
Integer Type

49. If n C3  n C2  n 1 C2 n  2 C2 , then least value of n  N is

50. The number of ways of arranging 4 A’s and 5 B’s in a row so that every arrangement reads the
same backwards and forward is

51. If  is non real fifth root of unity then 101  102  103  104  105 is ___________

1 x 
10
52. The number of odd coefficients (coefficients having odd value) in the expansion of is
k
2 , then the value of k must be

x2 y2
53. The ordinate MP of a hyperbola   1 is produced to the point Q so that MQ = SP
30 21
Locus of Q is a line L1. Similarly we have another locus L2 of a point Q’ where Q’ is obtained on
3
producing MP so that MQ’ = S’P. If d is the distance between L1 and L2. Find the value d.
5

54. If the locus of midpoints of portions of tangents intercepted between coordinate axes of hyperbola
x2 y2  9  
  1is 2  2   , then is…..
16 9 x y 5

space for rough work

Corporate Branch Office : Noida Sec-62 Branch : C-56/33, 1st Floor, Sector-62, Noida