Sec: SR.

IIT_*SUPER CHAINA MODEL-A Date: 23-03-2025

Time: 3hrs (2022_P2) Max. Marks: 180

Name of the Student: ___________________ H.T. NO:

23.03.25_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP YLLABUS

MATHS: TOTAL SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

IMPORTANT INSTRUCTIONS Max Marks: 180

MATHS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Sec – I(Q.N : 1 – 8) Questions with Single digit integer(0-9) +3 -1 8 24
Questions with Multiple Correct Choice
Sec – II(Q.N : 9 – 14) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – III(Q.N :15-18) Single Correct option type +3 -1 4 12
Total 18 60

PHYSICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Sec – I(Q.N :19– 26) Questions with Single digit integer(0-9) +3 -1 8 24
Questions with Multiple Correct Choice
Sec – II(Q.N:27 –32) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – III(Q.N :33-36) Single Correct option type +3 -1 4 12
Total 18 60

CHEMISTRY:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Sec – I(Q.N :37- 44) Questions with Single digit integer(0-9) +3 -1 8 24
Questions with Multiple Correct Choice
Sec – II(Q.N:45-50) +4 -2 6 24
(partial marking scheme) (+1,0)
Sec – III(Q.N :51-54) Single Correct option type +3 -1 4 12

Total 18 60

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL
MATHS MAX.MARKS: 60
SECTION - I
(Maximum Marks: 24)
This section contains EIGHT (08) questions.
The answer to each question is A SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
Numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen. (i.e. the question is un answered)
Negative Marks: –1 In all other cases.
1. The shortest distance between any two opposite edges of tetrahedron formed by the
planes y  z  0, x  y  0 , x  z  0 and x  y  z  4 6 is
2. The number of ways that a necklace can be made with 3 beads of one colour and 6 beads
of another colour, beads of same colour being identical is
 5  5x  6
3. The number of solutions of the equation tan   cot 1  2r 2    is
 r 1  6x  5
4. If a , b are two vectors such that a  1, b  4, a .b  2 and 2a  b  3b  c , then the

angle between b , c is x radians. The integer part of 2x is __

5. A non zero complex number Z given by Z  x  y i where x, y  R and

2 3 4
iZ 2  1   2  3  ... , where i  1 then x  y  ___
Z Z Z
6. Three distinct natural numbers are selected from 1 to 20. The probability that they are in
p
G.P is ,where p,q are relatively prime. Then the number of prime divisors of pq is ___
q
1
7. Let g  x  be a function, continuous everywhere such that g 1  5 and  g  t dt  2 .
0

x
1 2
If f  x     x  t  g  t  dt , then f  1  f  1  ___
20
2
8. The number of real solutions of  log 2 x    x  1 log 2 x  6  2 x is

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL
SECTION- II
(Maximum Marks: 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
9. Let S  O.S 1  O be two externally touching circles whose centres are at C1 , C2
respectively, where S  O is the smaller one. Let the common tangent drawn from a
point P, touches S=O at A, S 1  O at B where PA=4, PB=8 and P, C1 , C2 are collinear.

Let the common tangent to S  O, S 1  O at their point of contact Q meets AB at C.

Which of the following is/are correct?
A) Area of smaller circle is 2
B) Area of S 1  O is 4
C) Area of triangle C1CC2 is 3 2 Sq.units
D) AC1 , CQ , BC2 are in A.P
10. When the natural number 1 to n listed, the number of times 1 appears is denoted by
f  n  , where f 10n   n.10n 1  1 . Then

A) f 120   53
10
B)  100
Cr .9r  f 10100   1
r 0

100 100 r

C)  r.
r 0
100
Cr  9   10
 f 1010   1
D) f 120   52

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

11. Let R be a point on a variable line passing through origin and which cuts the lines
2 x  5 y  3  0 and 4 x  7 y  3  0 at P,Q such that OP, OR,OQ are in harmonic
progression. Then the locus of R
A) Passes through  3, 1

3
B) Form a triangle of area sq.units with given lines.
2
C) is a bounded curve
7
D) Encloses an area of sq.units
2

12. A triangle PQR is inscribed in the parabola x2  8 y such that Q  Let L1 , L2 be the
2
tangents drawn at P, R respectively. If the equation of the parabola whose axis is along
y-axis, whose latus rectum is along x-axis and its length is the minimum length of
intercept on x-axis cut off by L1 , L2 is y  ax 2  bx  c , then, which of the following
is/are true?
A) 2016a  2018b  2020c  3784 B) 2016a  2018b  2020c  3784
C) ab  c  0 D) ab  c
cos  x    cos  x    cos  x  r 
 
13. f  x   sin  x    sin  x    sin  x  r  , where x  0,  ,     r , then
 2
sin    r  sin  r    sin     

A) f  x  is negative if , ,  are angles of acute angled triangle

B) f  x  is negative if , ,  are angles of obtuse angled triangle

C) f  x  is negative if , ,  are angles of right angled triangle

D) f  x  is strictly increasing function for every choice of , ,   R

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL
2
14. Let f  x   2 x3  3 x 2  6 x  12 and g 1  x    x  1 x  2  x  3   x 2  1 x 2  9  . If

n1 , n2 , n3 denote the number of local minimum, local maximum points of inflection

respectively of the function f  g  x   then

A) n1  n2  4 B) n1  n3  3 C) n2  n3  3 D) n1  n3  4
SECTION - III
(Maximum Marks: 12)
This section contains 4 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) out of which
ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
15. If n be an odd positive integer and 1, a1 , a2 ,......., an1 are nth roots of unity and if

 4  a1  4  a2 .... 4  an1  is equal to

4
K then K 
 3  a1  3  a2 .... 3  an1  5
2
3n  1
A) n
4n  1
B) n
4n  1
C) n D)
2 n
 1
4 1 3 1 3 1 3n  1
16. The set of all value of  for which the points of extremum of the function
f  x   x 3  3x 2  3   2  1 x  1 lie in the interval  2,4  will be equal to

A)  1,3 B)  3,4  C)  4, 2  D)  2, 1

n 1
1
n  2 x  7 x  14 x
7n 2n n
 n

x  x 2 n  x n  2 x 6 n  7 x n  14  dx 
7n n
17. If  C where n  N ,
K  n  1
then K 
A) 4 B) 7 C) 10 D) 14
18. Two integers x and y are chosen from the set 0,1,2,3,....,2n , with replacement, the

probability that x  y  n  n  N  is

3n 2  3n  1 3n 2  3n 3n 2  1 n2  n  1
A) 2
B) 2
C) 2
D) 2
 2n  1  2n  1  2n  1  2n  1

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL
PHYSICS MAX.MARKS: 60
SECTION - I
(Maximum Marks: 24)
This section contains SIX (08) questions.
The answer to each question is A SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
Numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen. (i.e. the question is un answered)
Negative Marks: –1 In all other cases.
19. A particle having mass m, charge q is projected with velocity v 0 along y- axis in a
region of uniform magnetic field B0 which is outward and perpendicular to the plane of
the paper as shown in the figure. The particle is continuously subjected to a frictional
 
force which varies with velocity as Fr   v , where  is a constant. Consequently the
particle moves on a spiral path till it comes to rest at point P. The x- co-ordinate of point
P is 5k meters. Find k

 Take   10 3
kg / s , q  103 C , B0 = 1T, v0  1m / s, m  20 gm 

R
v0
x

20. The circuit shows a resistance R  0.01 and inductance L = 3 mH connected to a

conducting rod PQ of length   2m which can slide on a perfectly conducting circular
path of radius equal to  with its centre at P. Assume that friction & gravity are absent
and a constant uniform magnetic field B = 0.1 T exists as shown in the figure. At t = 0,
the circuit is switched on and simultaneously an external torque is applied on the rod so
that it rotates about P with a constant angular velocity ω  2 rad/sec. Find the magnitude
of this torque (in N-m) at t   0.3 n 2  second

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL
X X X X X
X X X X X
X X
P X X X
B  0.1 T
ω
S

L  3mH R  0.01 Ω

21. One face of a prism ABC of μ  2 is silvered and the ray incident at angle 45 retraces
its initial path. Then the angle CAB is n  10 . Then the value of n is

i μ 2

B
C

22. The outer surface of a transparent glass slab of refractive index μ1  1.5 is coated by a
thin layer of transparent medium of refractive index μ 2  1.6 . Orange light of wave
o
length 6400 A fall normally on the coat (from the air) . The reflected light at the upper
surface and at the lower surface of the coat interfere destructively. If thickness of the
coat is 5K  10 8 m , calculate the minimum value of K.
23. A sample of hydrogen like gas has its electrons in ground state. When this sample is
radiated by photons of energy E = 204 eV. The electrons get transfer to 3rd excited state.
If photons released during dexcitation to 1st excited state are being incident on a metal
surface, the stopping potential is 32.22 volt. If the photons released during dexcitation to
2nd excited state are being incident on the same metal surface. The stopping potential in
volt is
π
24. Determine magnitude of potential difference (in volts) across capacitor at t  sec .
16
[Emf of AC source is in volts and ‘ t ’ is in seconds]

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

100 
v  10cos  4t  45 5H 10mF

25. In the shown circuit all the sources of emf are ideal. Current through 5 resistance is I1

I 
and through 10 resistance is I 2 . Find the ratio  1 
 I2 
I1 5 2V 5V

20
3V
5V 15
20
10
I2
5V 5V

10V
26. A dipole is placed in uniform electric field of magnitude E such that its potential energy
is minimum. The distance between the charges is 'd '. The charge's '  q ' and ' q ' have
masses 'm' and '3m 'respectively. IF magnitude of qE is equal to magnitude of 3md. All
physical quantities mentioned to be taken in their respective S.I. units. Now, this dipole
is placed in the same electric field E, such that its dipole moment makes angle 3 degrees
with the electric field and then released at time t = zero. The time after which it makes

angle 1.5 degrees with the electric field for the first time is given as seconds, find the
k
value of k.

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL
SECTION- II
(Maximum Marks: 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
R
27. An uncharged conducting sphere of radius R, has a hollow cavity sphere of radius , as
2
shown. Which of the following is/are correct about electrostatic energy?

R
R
2
Q

A) Interaction energy of induced charges with charge placed at centre of cavity is

 1  Q2 
  
 4πε 0   R 
B) Interaction energy of induced charges with charge placed at centre of cavity is
 1  Q2 
  
 4πε 0   R 
1  Q2 
C) Electrostatic energy outside sphere is  
4πε 0  9R 

 1  Q2 
D) Electrostatic energy outside sphere is   
 4πε 0   R 
28. Two capacitors are connected to a resistance and battery as given. Capacitor with
capacitance C is charge upto 2V0 where V0 is potential of battery and capacitor of 2C

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

capacitance is initially uncharged. If switch is closed at t = 0 then choose CORRECT

statement(s)
C, 2V0

R  

V0

2C

A) Ratio of final charge on C to 2C is 2

2CV02
B) Total work done by battery after switch is closed is
3
2CV02
C) Total work done by battery after switch is closed is
3
1
D) Total heat loss across resistance after closing switch is CV02
3
29. A long current carrying cylindrical conductor of radius 'R' has a uniform current density
'j' over its cross section inside it. If we consider the two halves that are obtained by
dividing the conductor by a plane containing the axis of the conductor. Then choose the
correct option(s).

 μ j2R 3 
A) The force of interaction per unit length between the two halves is F   0 
 6 
 μ j2R 3 
B) The force of interaction per unit length between the two halves is F   0 
 3 
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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

'R '
C) The magnetic field inside the conductor at a radial distance from its axis is
2
μ 0 jR
B
4
'R '
D) The magnetic field inside the conductor at a radial distance from its axis is
2
μ 0 jR
B
2
30. A L-shaped conducting rod OAB is rotating in a constant magnetic field of B0  100
Tesla acting along x-axis. The length of rod OA = 20 cm and AB = 20 cm. If rod is
rotating about y-axis with constant angular velocity of 5 rad/second then at a given
instant. Choose correct options
Y

ω B

O X
A
B0

A) Potential difference across OA is 10 Volt

B) Potential difference across OA is zero Volt
C) Potential difference across AB is 20 Volt
D) Potential difference across OB is 10 Volt
31. Choose the correct statement(s).
A) A particle of mass m at rest disintegrates into two particles of masses m1 and m 2 . Let
λ1 and λ 2 are their de-Broglie wavelengths respectively. It is given that m1  m 2 then
λ1  λ 2
B) The process of photoelectric emission is different to that of thermionic emission.

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

C) Two radioactive samples A and B initially contain same number of nuclei. Sample A
has half life of 1 year and B has half life of 2 years. At the end of 2 years, both samples
have the same activity.
D) When ultraviolet light is incident on a photocell, stopping potential is V0 and the
maximum kinetic energy of the photoelectrons is K max When the ultraviolet light is
replaced by x- ray. K max increases but V0 decreases.
32. In the figure shown a point object O is placed in air on the principal axis. The radius of
curvature of the spherical surface is 60 cm. If is the final image formed after all the
refractions and reflections. Choose the correct option(s).

ng = 3/2
O

d1
d2
A) If d1  120cm , then the ‘ I f ’ is formed on 'O' for any value of d 2 .
B) If d1  240cm , then the ‘ I f ’ is formed on 'O' only if d 2  360cm .
C) If d1  240cm , then the ‘ I f ’ is formed on 'O' for all values of d 2 .
D) If d1  240cm , then the ‘ If ’ cannot be formed on 'O'.
SECTION - III
(Maximum Marks: 12)
This section contains 4 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) out of which
ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
33. A triangle is made from thin insulating rods of different lengths; the linear charge
density on each rod is uniform and the same for all three. At which point in the plane of
the triangle at which the electric field strength is zero.
A) Incentre of the triangle B) Centroid of the triangle

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

C) Circumcenter of the triangle D) None of these

34. Two conductor are embedded in a material of conductivity σ and dielectric constant ε T .
The resistance between the two conductors is measured to be R. The capacitance
between two conductors is :
ε 0ε r ε 0ε r 2ε 0ε r 5ε 0ε r
A) B) C) D)
2σR σR σR σR
35. Consider the YDSE (young's double slits experiment) arrangement shown in figure. The
slits S1 and S2 are fixed while the screen in the arrangement starts accelerating from rest

in positive x-direction from origin, with acceleration a  2t m/s 2 , at t = 0. Magnitude of

velocity of 3rd maximum above the point 'O' at time t = 4 sec in the ground frame is
93
( D  d and d  5λ where λ is the wavelength of the light, take 34  )
16

S1
d
O x

S2
D a  2t
t 0

A) 20 m/s B) 18.6 m/s C) 15 m/s D) 10 m/s

36. The conducting plates of a parallel plate capacitor have area A and distance between
them is d. A potential difference V is maintained across the capacitor by a battery. Two
d
identical dielectric slabs D and a metal slab M each of thickness are inserted in the
3
capacitor as shown in the figure. The dielectric constant of each of the dielectric slab is
K. The modulus of the force of electrostatic interaction on each plate of the capacitor is

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

V
D M D

K K

d/3 d/3 d/3

3 0 AK 2 V 2 3 0 AK 2 V 2
A) B)
8d 2 4d 2
9 0 AK 2 V 2 9 0 AK 2 V 2
C) D)
8d 2 4d 2
CHEMISTRY MAX.MARKS: 60
SECTION - I
(Maximum Marks: 24)
This section contains EIGHT (08) questions.
The answer to each question is A SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
Numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen. (i.e. the question is un answered)
Negative Marks: –1 In all other cases.
  
37. A beam of light has three ,4144 A 4972 A and 6216 A with a total intensity of
3.6  103 Wm 2 equally distributed amongst the three  . The beam falls normally on an
area 1.0cm 2 of a clean metallic surface of work function 2.3 eV. Assume that there is no
loss of light by reflection etc. Calculate the no. of photoelectrons emitted in 2 sec, in
scientific notation, x  10 y find the value of y.
leached with
38. Native 'Ag' ore 
aq . NaCN ,O2
 Complex of Ag   A   other products

leached with
Native 'Au' ore 
aq . NaCN ,O2
 Complex of Au   B   other products

B  aq   Zn  Complex of Zn2  C   other products

Coordination numbers of metal ions in complexes A, B, C are p, q, r respectively.

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

The spin only magnetic moment of metal ion complex 'C' in B.M. is 's'. The value of
 p  q  r  s  is
39. A certain mass of a substance when dissolved in 100 g C6 H 6 , lowers the freezing point
by 1.28C . The same mass of solute dissolved in 100 g of water lowers the freezing
point by 1.40C . If the substance has normal molecular mass in benzene and is
completely dissociated in water, into how many ions does it dissociate in water? ( K f for

H 2O and C6 H 6 are 1.86 and 5.12 K mol 1kg respectively).

40. Find the number of moles of sodium hydroxide which would exactly neutralize all the
acids produced by complete hydrolysis of one mole of SO2Cl2 . Assume 100%
efficiency of all the reactions involved.
41. 10% sites of catalyst bed have been occupied by H 2 . On heating H 2 gas is evolved from

sites and collected at 0.03 atm and 300 K in a small vessel of 2.46 cm 3 . No. of sites
available is 6  1015 per cm 2 and surface area is 1000 cm 2 . The number of molecules of
H 2 adsorbed per site of catalyst is (Given: N A  6  1023 )

42. How many of the following are optically active compounds ?

COOH COOH Cl

i)
ii) Br

iii)

iv)

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

N N

v) vi)

vii) Cl

F Cl Br
Br

viii) Cl Br
Br Cl F

Br
Cl

x) Cl

Br
ix)

N N

N
N

xii)
xi)

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

i) Me  I Excess
P 3a min e
ii) Ag 2O / 
iii) 
43.

+ analy Zn . Hg / HCl SOCl2 anly AlCl3

P O 
AlCl3
      Q

Number of moles of CH 3 -I used  x

Double bond equivalent of Q  y

Then x  y is

(i) NaNH2
Product.
(ii) CO2
(iii) H
44.
(iv) SOCl2
(v) H2/Pd-BaSO4

The number of sp2 carbons in the product is

SECTION- II
(Maximum Marks: 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.

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45. Valance shell electron pair repulsion theory, proposed by Nyholm and Gillespie, cannot
explain

A) Decrease in bond angle in H 2O from 10928 ’

2
B) Structure of  Ni  CN  4 
C) Decrease in C  Cl bond length from CH 3Cl to CCl

D) Planar geometry of C  CN 3 
46. Which of the following statement(s) is (are) correct regarding the root mean square
speed U rms  and average translational kinetic energy   av  of a molecule in a gas at
equilibrium?
A)  av at a given temperature does not depend on its molecular mass
B) U rms is doubled when its temperature is increased four times
C)  av is doubled when its temperature is increased four times
D) U rms is inversely proportional to the square root of its molecular mass
47. Which of the following statement(s) is / are correct?

A) KBr on heating with MnO2 inpresence of H 2 SO4 liberates Br2 and SO2 gases

B) NaBr on heating with concentrated H 2 SO4 liberates Br2 and SO2 gases

C) KBr forms HBr with concentrated H 3 PO4 in open beaker

D) KCl on heating with concentrated H 2 SO4 forms Cl2 and SO2 .

48. Each of the following options contains a set of four molecules, Identify the option(s)
where all four molecules possess permanent dipole moment at room temperature.
A) SO2 , C6 H 5Cl , H 2 Se, BrF5
B) BeCl2 , CO2 , BCl3 , CHCl3
C) BF3 , O3 , SF6 , XeF6
D) NO2 , NH 3 , POCl3 , CH 3Cl

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49. The correct product(s) is (are) mentioned in

O O

H3 C CH3 H 
i) LiAlCH 4 H3 C CH3
H 2C  CH 2  
ii) H O

3

OH OH
(1 equivalent)

A) O O


H
H2 N   CH 2 3  C  CH2  CH3 
dil HCl
 C2H5

B) N

O
CH3MgBr
CH3  C  CH 2  CH 2  CH 2  Br 


C)
O

 
tO Na
  COOt

D) Cl

50. The correct products are mentioned in

OH

SOCl 2
H 3C   CH 3

A) Cl

H CH 3
SOCl 2
OH   Cl

CH 3 H
B)

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23.03.2025_SR.IIT_STAR SUPER CHAINA_JEE ADV_GTA-9_(spl GTA-4)_(2022_P2)_QP FINAL

NaCN
CH 2  Cl 
H 2O

O NC O CH 3
C)
CH 3 CH 3

O2 N
HNO3

H 2SO 4

OCH3 OCH3
CH
H 3C NO 2
CH 3
D)
SECTION - III
(Maximum Marks: 12)
This section contains 4 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) out of which
ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
NaBO3
51. Alkaline solution of (X)   Canary yellow colored solution
NaBiO3
Acidic solution of (Y)   Lilac colored solution
(X) & (Y) are respectively :
A) Fe  OH 3 , Mn  OH 2 B) Cr  OH 3 , Pb  OH  2
C) Fe  OH 3 , Zn  OH 2 D) Cr  OH 3 , Mn  OH 2
52. Molar conductivity (  m) of aqueous solution of sodium stearate, which behaves as a
strong electrolyte, is recorded at varying concentrations (c) of sodium stearate. Which
one of the following plots provides the correct representation of micelle formation in the
solution?

(critical micelle concentration (CMC) is marked with an arrow in the figures

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CMC CMC

m m

A) c B) c

CMC

m m

CMC

C) c c
D)

53. For a gaseous reaction A+B 

 2C, the rate law is r  k [ A]1 [ B ]2 . Which of the
following statement is CORRECT?

A) If the initial concentration of ‘A’ is double of ‘B’, then the half – life of reaction will
remain same throughout the reaction.
B) If initially ‘A’ is taken in very large amount, then the half-life of reaction will keep on
decreases as reaction proceeds.
C) If initially ‘B’ is taken in very large amount, then the half-life of reaction will remain
same throughout the reaction.
D) If ‘A’ and ‘B’ are taken in equal concentration, then both will be reduced to half of
the original amount in the same time.
54. X and Y are two volatile liquids with molar weights 10gmol−1 and 40gmol−1 respectively.
Two cotton plugs, one soaked in X and the other soaked in Y, are simultaneously placed
at the ends of a tube of length L=24 cm, as shown in the figure. The tube is filled with an
inert gas at 1 atm pressure and a temperature of 300K. Vapours of X and Y react to form
a product which is first observed at a distance d cm from the plug soaked in X.

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Take X and Y to have equal molecular diameters and assume ideal behaviour for the
inert gas and two vapours

The experimental value of d is found to be smaller than the estimate obtained using
Graham's law. This is due to

A) larger mean free path for X as compared to that to Y

B) larger mean free path for Y as compared to that of X

C) increased collision frequency of Y with the inert gas as compared to that of X with
the inert gas

D) increased collision frequency of X with the inert gas as compared to that of Y with
the inert gas

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