SRI CHAITANYA IIT ACADEMY, INDIA 23-03-25_ Sr.

S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-28/23_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.S60_Elite, Target & LIIT-BTs JEE-MAIN Date: 23-03-2025
Time: 09.00Am to 12.00Pm GTM-28/23 Max. Marks: 300^
KEY SHEET
MATHEMATICS
1 3 2 2 3 1 4 3 5 2
6 2 7 4 8 3 9 2 10 1
11 2 12 2 13 1 14 3 15 2
16 1 17 3 18 3 19 4 20 2
21 2 22 1 23 3 24 112 25 6

PHYSICS
26 3 27 4 28 4 29 2 30 1
31 1 32 4 33 4 34 1 35 4
36 3 37 3 38 2 39 4 40 1
41 4 42 4 43 2 44 1 45 4
46 50 47 175 48 8 49 6 50 4

CHEMISTRY
51 1 52 1 53 4 54 2 55 3
56 1 57 3 58 4 59 4 60 1
61 2 62 3 63 4 64 3 65 3
66 2 67 1 68 2 69 1 70 4
71 917 72 4 73 200 74 300 75 5

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 SRI CHAITANYA IIT ACADEMY, INDIA 23-03-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-28/23_KEY &SOL’S

SOLUTIONS
MATHEMATICS
1. Let R be relation an X. Then R should contain 1,1 ,  2, 2  3,3 2,31,3 . then it is reflexive
and transitive but not symmetric so the required
R1  1,1 2, 2  3,3 2,31,3
1,1 2, 2  3,3 2,31,3 
R2   
1, 2  
1,1 2, 2  3,3 2,31,3 
R3   
1, 2  ,  2,1 
1,1 2, 2  3,3 2,31,3 
R4   
 3,1 2,1 
1,1 2, 2  3,3 2,31,3 
R5   
 2,1 3,1 
1,1 2, 2  3,3 2,31,3 
R6   
 3,1 3, 2  2,1 
6!
The general term in the expansion 1  21/2  31/3  is 1  2   3
6 P q/2 r /3
2.
p ! q !r !
When O  P, Q, r  6, P  q  r  6 q  2k ; r  3l
p, q, r can be taken
p q r Value of rational term
6 0 0 1
4 2 0 15  2  30
2 4 0 15  4  60
0 6 0 1 8  8
3 0 3 20  3  60
1 2 3 60  6  360
0 0 6 1 9  9
3. Clearly trace (B) = Trace  det  3 A  .3 A  =81
And det (B) = | 3 A |4  312 | A |4  38 = 6561
 cos 
4. Pq  ; pq  1/ 2
2
cos 2   4
 p2  q2 
4
 cos   4  8
2 2

And P  q 4 4

16
Max and min values of cos 2  are 1 and 0 respectively, so the max and min values of
17 8
p 4  q 4 are and
16 16
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 SRI CHAITANYA IIT ACADEMY, INDIA 23-03-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-28/23_KEY &SOL’S

5.     xi. P  X  xi   4  1 / 8  1 / 2
1 1
 2   xi2 .P  X  xi    2  4    1/ 4
8 4
1 1
 64  2     64     48
4 2
6. vowels = 2, consonants = 6
6!
Required number of arrangements = 7 P2  15120
2!
7. x  2 y  3z  2
2 x  py  5 z  5
14 x  3 y  qz  33
By cramers’ rule,   0 and  z  0
p  q  12
8. f '  x   0  f  x  is one  one
9. Point of intersection is  a  b  Length of the  ar
AB  AC

| AB |
10. Conceptual
5 6
1 1 1
  .     ... 1
11. 2 2 2 
3 4
1 1 1 1 4
      ...
2 2 2 2
  x  5   y 2  16
2
12. | z  5 | 4
So, points (x,y) lie inside or on the circle whose center is (-5,0) and radius is 4.
Comparing these with    2, we get   32,   16     48
13. in the figure circle S1 , S2 and S3 have b,c and a, respectively.
AC1  bBC2  c and CC3  a
From the DC1  b  a, EC2  c  a, FC2  c  b
1 1 1
b  c   b  c 
2 2
  bc  ab  ac   
a c b
 1  x 2 x  1
14. 
A   x 1  x   | A |  4 x 3  4 x 2  4 x  f  x  say 
 2 x  1  x 1 
Let f '  x   0  x  1, 1/ 3
Sum of minimum and maximum value is
20 88
f 1  f  1/ 3  4  
27 27
15. M  3, 5, 7  satisfies the line L1.
3 a 5 2 7 b
 
l 3 4
b  3 and a  1  3

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 SRI CHAITANYA IIT ACADEMY, INDIA 23-03-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-28/23_KEY &SOL’S

M is foot of perpendicular from P  4,3,8  on line L1.

   
Also, v1  2i  3 j  4k and v 2  3i  4 j  5k
  
 v1  v 2  i  2 j  k
  
AB. v1  v 2
Shortest distance    
1  
v1  v 2 6
16. Given differential equation
dy 2e 4 x
  8  4cot 2 x  y   2sin 2 x  cos 2 x 
dx sin 2 2 x
 8 4cot 2 x dx
If= e  e8 x  2loge sin 2 x  e8 x .sin 2 2 x
Solution is
y  e8 x .sin 2 2 x    2e 4 x  2sin 2 x  cos 2 x  dx  C

e4 x
 y  x 
sin 2 x

4
  e 6 2  23
 y    e
 6  sin  2.   3
 
 6
x2 y 2
17. Equation of hyperbola is  1
4 2
a 2 e2  a 2b 2  4  2  6
So, focus F  6, 0  
Equation of tangent at p  4, 6  is
4 x  2 6 y  4 or 2 x  6 y  2
Solving it with latus rectum line, x  6 we get

R   6,

2
6
 
6 1 


Also, Q  1, 0 
So, area of QFR 
1
2
 6 1 .  2
6
 
6 1 
7
6
2

18. Conceptual
1   5   10   5  n  1  
19. f  x   x  1, lim 1    1    1   ....   1 
n  n
  n   n   n  
1  1  2  3  ...n  1   5  n  1 5 7
lim  n  5     lim1   1 
n  n n 2n 2 2
    n 
20. cos x  cos y  cos z  0 and sin x  sin y  sin z  0
cos x  cos y   cos z

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and sin x  sin y   sin z
Squaring and adding we get,
1  1  2  cos x cos y  sin x sin y   1
 2  2cos  x  y   1
 2 cos  x  y   1
1
 cos  x  y   
2
 x  y  1
 cos  
 2  2

 r  cos   x  cos 2 x  sin x sin 2 x sec x
4 
 
 cos x sin 2 x sec x  cos   x  cos 2 x
4 
    
 cos   x   cos   x   cos 2 x
 4  4 
 (cos x sin 2 x sec x  sin x sin 2 x sec x)
2
 sin x cos 2 x   cos x  sin x  sin 2 x sec x
2
 2 sin x cos 2 x   cos x  sin x  2sin x
1 1  
  x  sec x  sec  2
2 cos x  sin x 4 4
21. Sketch the graph
22. y  xt  2at  at 3
f '  t   9t 2  23;  0  only one normal
23. Let f  x   k x
1
1
24.  f   x d   af  x   x  t d   x dt
0
x x
1
f  t  dt  af  x  f  t  dt  axf  x 
x 0 0

f  x   a  xf  x   f  x  
f ' x 1  a  1
1  a  f  x   a.xf  x  
f  x a x
1 a
n  f  x    nx  c
a
1
x  1, f 1  1  c  0 x  16, f 16  
8
1 1 a
4  4a
 16  a  3  a4
8 a
3
3 7
f  x  x 4 f ' x   x 4
4
25. Conceptual

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PHYSICS
26.   60 . solid angle subtended by BCD is
0

  2 1  cos    
Solid angle subtended by ABDE is
 ABCDE    BCD  2    
q  q
Hence, flux through ABDE is    
0 4 4 0
hc
27. K  0 (i)

4hc
and K '   0 (ii)
3
4hc hc
From Eq/s (i)&(ii),we get  K ' K  
3 
hc hc K 
K ' K  . But from Eq. (i)  K   K ' K   0
3  3 3
4 K 0 4K
 K ' K   Or K ' 
3 3 3
 R   X L  XC  ;
2 2
28. Z
R  10, X L   L  2000  5  10 3  10
1 1
XC    10 i.e Z  10
C 2000  50 106
V 20
Maximum current i0  0   2 A
Z 10
2
Hence irms   1.4 A And Vrms  4  1.41  5.64V
2
 N2A
29. Self inductance of coil L  0
2 R
30. Circuit can be redrawn as follows:

5  25   10  2  35 35
Now , Vx  Vy ,Ceq      F
 5  25   10  2  6 6
31. Work done by the friction block is  216J
Therefore the work done by the motor is  2  216 J  432 J
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M R
2

 2   M R 2
MR  4 2     13
32. I    I MR 2
2  2 4 2  32
 
 
33. Using Bernoulli’s’ equation
1 1
P1   v12   gh1  P2   v22   gh2
2 2
For horizontal pipe, h1  0 and h2  0 and taking
P 1 P 1
P1  P, P2  , we get  P   v 2   V 2
2 2 2 2
p 1 1 P
   v 2  V 2  V  v 2 
2 2 2 
34. Equation of the BC is given by two point straight line equation
P  P0 3P  P 2P
  0 0  P  P0  0 V  2V0 
V  2V0 V0  2V0 V0
2 p0V 2
0 
PV  4 PV
0
V0
Using PV=nRT Temperature, T 
1 R
 n  1mole given 

P0 2V 2  dT 4V 5
T  5V  ,  0 5  0  V  V0
R V0  dV V0 4
P  5V 2 25  25 PV
T  0 5  0   V02   0 0

R 4 V0 16  8 R
i F
35. B 0 B M  i A   c
2 r m

36. From, ideal gas equation PV  nRT

 25  2
 400 103  500  106  n    300   n 
 3  25
Let n1 & n2 be no.of moles of hydrogen & oxygen respectively
m m1 m2 2
Also, n1  n2  n Using n=  
M 2 32 25
m 16
And m1  m2  0.76 gm 2 
m1 3
v
37. S1  v1  a  n  1 / 2  O  v1  at t  1
a
v  v 
S1  v1  a  1  1/ 2  S 2  v2  a  2  1/ 2 
a  a 
v 
S3  v3  a  3  1/ 2  S1  S 2  S3
a 
38. Conceptual
 1 r2   2 r1
39. 
r1  r2

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1 1 1 2 L
40.     LP 
Lp L L L 2
1.8  10 4
Where L is inductance of each part,   0.9  104 H
2
L 0.9 104
 LP    0.45 10 4 H
2 2
6 1 1 1 2
Resistance of each part, r   3 Now,   
2 rp 3 3 3
LP 0.45  104
Time constant of circuit,    3 105 s
rp 1.5
41. When the spherical conductors are connected by a conducting wire, charge is
redistributed and the spheres attain a common potential V.
1 QA 1 C AV  4 0 RA  V
 intensity E A   or E A  
4 0 RA 4 0 RA2 4 0 RA2 RA
V E R 2R 2
Similarly EB   A  B  
RB EB RA R 1
PV PV
42. If final temp is T 0 0
CV  4T0  T   0 0 Cv T  T0 
4 RT0 RT0
4T0  T 8T
 T  T0 4T0  T  4T 8T0  5T T  0
4 5
8
T T0
2
Final pressure in left Pf  f Pt  5 P0  P0
T0 4T0 5
8
T0
Force =  0  0  A  0
8 8P 2P 6P A
In right Pf  5 P0  P0 ,
T0 5  5 5  5
43. Assertion is false because em waves have momentum.
44. The acceleration of ball during upward motion is g  a, where a is the acceleration due to
u
resistive force. The time of accent, t1  1
g a
v
The acceleration during descent g-a and time taken is t2  ...  2 
ga
The time taken can also be written as
u2
2h ga u2
t2    t22  ....  3
g a g a  g  a  g  a 
t2 u
Dividing equation (3) by equation (1) and (2) 
t1 v
45. Ans. (4)
Sol. Solids have higher value of bulk modulus than
gases.
P 7 106
 10  102  V  50 mm 3
3
46. B V 
V 1.4  1011

V
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47. For wire if

M  mass,   density, A  Area of cross section
V  volume, l  length, l  change in length
M Al 
Then mass per unit length m    A
1 1
T/A Y lA
And Young’s modulus of elasticity Y  T 
1/1 1
Hence lowest frequency of vibration
 l 
Y
1 T 1  1  1 Y l 1 9 1010  4.9 104
n      n 
2l m 2l  A  2l l  2 1 1 9  103
 
V2
48. Acceleration a 
r
Z n2 Z3
Where V  &r   a  4  both are in ground state i.e n=1
n Z n
3 3
a  Z  
So, a  Z 3 He   He      8
2
aH  ZH   1 
49. Surface area of bubble of radius r  4 r 2 . Surface area of bubble of radius
2r  4  2r   16 r 2 . Therefore, increases in surface =  16 r 2  4 r 2  12 r 2
2

Since a bubble has two surface, the total increase in surface area  24 r 2
Energy spent=work done  24 r
2

50. 2mv2  3mv, 2  6   3v, v  4 m / s

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CHEMISTRY
51. Named reactions
52. Aldol condensation
53. Amino acid one letter code
Tyrosine Y
Tryptophan W
Glutamine Q
Aspartic acid D
54. NCERT structures
55. Statement-I : The boiling points of alcohols and phenols increases with increase in the
number of carbon atoms (Increased in Vanderwaals forces)
Statement-II : The high boiling points of alcohols and phenols are higher in comparison
to other class of compounds such as ethers, haloalkanes, due to presence of
intermolecular hydrogen bonding in them which is lacking in ethers & Hydrocarbons
56. Orientation effect of groups
KNO2
57. COS 
Aquaregia
 COCl2 K 3 Co  NO2 6  
CH 3COOH yellow ppt

58. NCERT lines

59. NCERT lines
60. Estimation of ‘N’ is done by Duma’s and kjeldahl’s method. In duma’s method N in
organic compound is converted to free N2 when compound is heated with CuO in an
atmosphere of CO2
 y y z  y
C x H y N z   2 x   CuO  xCO2  H 2O  N 2   2 x   Cu.
 2 2 2  2
61. Energy order:
Radio<micro<infra red< visible< U.V< X-rays<Gamma<Cosmic rays.
62. eq  KMnO4   eq.  FeC2O4 
M  3  5  0.1 20  3  M  0.4M
63. Correct unit is Scm 2 mol 3/ 2 L1/2
b C  Scm 2 mole1
Units of  m  0m  b C
Units of b  scm 2 mole 3/2 L1/2
64. Conc. Of calcium lactate  0.005M
 2  0.005N
 10 2.
Calcium lactate is a salt of weak acid + strong base
1
 pH  7   pKa  log c 
2
1
 7  5  log 102  
2
1
 7  5  2
2
 7  1.5  8.5  85  10 1
65. Let V.P of pure A be PA0
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0
Let V.P of pure A be PB
When X A  0.7 & X B  0.3
Ps  350
 PA0  0.7  PB0  0.3  350...  i 
When X A  0.2 X B  0.8
Ps  410
 PA0  0.2  PB0  0.8  410...  ii 
Solving (i) and (ii)
PA0  314mm Hg
PB0  434 mm Hg
 PA0  314mm Hg
66. 1 2  Isobaric process
2 3  Isochoric process
3  1  Isothermal process
W  W12  W23  W31
   V2   
   P V2  V1   0   PV
1 1 in   
  V1   
 
   20   
  1  40  20   0   1 20in    
   40   
 20  20 ln 2
 20  20  2.3  0.3
 6.2 barL
| W | 6.2bar.L  620 J
67. Correct option (1) 0,1,2,1
 2 pz2
 ls 2 *is 2 2 s 2 * 2 s 2 2 px2   2 p 2y
HOMO
2  2 p2
1
N 2   ls  is  2s  2 s  2 px   2 p y
 2 * 2 2 2 2

HOMO
O2   is 2 *ls 2 2 s 2 * 2 s 2 2 pz2
 2 p1x   2 p1y  HOMO 
N 2  0 unpaired e  in HOMO
N 2   1 unpaired e  in HOMO
O2  2 unpaired e in HOMO
O2   1 unpaired e  in HOMO

68. Based on " n  l " rule only (B) has pair of electron in degenerate orbital’s
H sys 180  1000
S surrounding    600
69. T 300
J / mole / K
S sys  S reaction  SCO2  SCaCO3  39  213  93  159

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Stotal  ssys  S surr  159  600 J  441
J / mole / K
70. E.N of VA group : As per NCERT
N  3.0   P  2.1  As  2.0   Sb 1.9   Bi 1.9  .
71. Cr2O7 2   14 H   6e   2Cr 3  7 H 2O
2
0.059 Cr 3 
Ecell  E 0
log 14
6 Cr2O72   H  
 101 2 
0.059
 1.330  log  
6  102 103 14 
 
 1.330  0.413
 0.917
 917  103
72. MnO2  KOH  O2  K 2 MnO4  H 2O
K 2 MnO4 
Netural / acidic solution
 KMnO4  MnO2
Mn4 :   Ar  3d 3
n  3,   3  3  2   3.87 B.M
Nearest integer is (4)
73. Ea  Ea1  Ea2  Ea3
500  400  300  Ea3
 Ea3  200kJ | mol.
74. K  A.e  Ea / RT
10 3
K  3  10 3 , e  Ea / RT   10 5 , A  ?
100
K 3  103
A   3  1053  300
e  Ea / RT 105
 A  300 min 1
75. x  1, y  4

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