Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.S60_Elite, Target & LIIT-BTs JEE-MAIN Date: 23-03-2025
Time: 09.00Am to 12.00Pm GTM-28/23 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 75 Questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Mathematics, Physics and Chemistry
having 25 Questions in each subject and subject having two sections.
(I) Section –I contains 20 Multiple Choice Questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 05 Numerical Value Type Questions.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the Nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted Question 21. Bubble on 21 as shown belo w
 SRI CHAITANYA IIT ACADEMY, INDIA 23-03-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-28/23_Q.P

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
23-03-2025_Sr.S60_Elite, Target & LIIT-BTs_Jee-Main-GTM-28/23_Test Syllabus
MATHEMATICS : TOTAL SYLLABUS
PHYSICS : TOTAL SYLLABUS
CHEMISTRY : TOTAL SYLLABUS

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 SRI CHAITANYA IIT ACADEMY, INDIA 23-03-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-28/23_Q.P
MATHEMATICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. If X  {1, 2, 3}, then the number of relations on X that are reflexive, transitive but not
symmetric and containing (2,3) and (1,3) is
1) 4 2) 5 3) 6 4) 7
The sum of rational terms of the expansion 1  21/ 2  31/3  is
6
2.

1) 638 2) 528 3) 728 4) 729

3. If det (A) = 1/3 and B =Adj (Adj (3A)),A is 3x3 square matrix such that trace (A)= 3 then

the value of trace (B) +det (B) =

1) 6642 2) 6561 3) 6588 4) 6534

4. If 2x2   cos   x 1  0 where   0, 2  has roots p and q. Then the sum of maximum and

minimum values, of P 4  q 4 is
21 23 25 27
1) 2) 3) 4)
6 16 16 16
5. A coin is tossed three times. Let the random variable X be defined as head follows tail in the
event. If the mean and variance of X are  and  respectively, the value of 64  2   

1) 32 2) 48 3) 64 4) 128
6. The number of words that can be formed from the word ‘GRANDSON’ such that all vowels
do not come together is
1) 11520 2) 15120 3) 19800 4) 18900

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 SRI CHAITANYA IIT ACADEMY, INDIA 23-03-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-28/23_Q.P
7. If the system of equations
x  2 y  3z  2
2 x  py  5 z  5
14 x  3 y  qz  33
has infinite number of solutions then p  q 
1) 13 2) 10 3) 11 4) 12
 1  x  x2 
If f  x    e tan x  dx, f  0   0, then f : R  R is
1
8.
 1 x 
2

1) One one 2) Onto

3) One one and onto 4) Neither one one nor onto
9. Let a  i  j , b  2 j  k be the position vectors of two points A,B respectively. Then length of
the perpendicular from the point of intersection of the line r  a  b  a and r  b  a  b to the
line joining the points A and B is
1) 3 2) 2 3) 1 4) 2
The area of the region bounded by the parabola  y  2    x  1 , the tangent to it at the point
2
10.
whose ordinate is 3 and the x-axis is:
1) 9 2) 10 3) 4 4) 6
11. A fair coin is tossed repeatedly until a head obtained. If X denotes the number of tosses
required, then the conditional probability of X  6, given that X  3 is
1 1 2
1) 2) 3) 4) 1
2 4 3

12. Let z be those complex number, which satisfy | z  5 | 4 and z 1  i   z 1  i   10, i  1. If the
maximum value of | z  1|2 is    2, then the value of     is _____where  &  are
natural numbers.
1) 84 2) 48 3) 88 4) 454

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13. Three circles of radii a,b, and c (a<b<c) touch each other externally. If they have x-axis as a
common tangent, then
1 1 1 1 1 1 1 1 1
1)   2)   3) a , b , c are in A.P 4)  
a b c c a b b a c

 1, if i  j

14. Let A   aij  be a 3 3 matrix, where aij    x if | i  j | 1 Let a function be defined as
 2 x  1, otherwise


f  x   det  A  then the sum of maximum and minimum values of f(x) on R is equal to

88 20 88 20
1) 2) 3) 4) 
27 27 27 27
x a y 2 z b
15. If the foot of the perpendicular from point (4,3,8) on the line L1 :   , l  0 is
l 3 4
x2 y 4 z 5
(3,5,7) then the shortest distance between the line L1 and line L2 :   is equal to:
3 4 5

1 1 2 1
1) 2) 3) 4)
2 6 3 3

16. If y  y  x  , x   0,  be the solution curve of the differential equation
 2
dy    
 sin 2

dx
2x 
  8sin 2 2 x  2 sin 4 x  y  2.e 4 x  2sin 2 x  cos 2 x  , with y    e  , then y   is equal to
4 6
2 2 /3 2 2 /3 1 2 /3 1 2 /3
1) e 2) e 3) e 4) e
3 3 3 3
17. Consider a hyperbola H : x2  2 y 2  4. Let the tangent at a point P  4, 6  meet the x-axis at Q

and latus rectum at R  x1, y1  , x1  0. if F is a focus of H which is nearer to the point P, ,then the
area of QFR is equal to
7
1) 4 6 2) 6  1 3) 2 4) 4 6  1
6

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 SRI CHAITANYA IIT ACADEMY, INDIA 23-03-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-28/23_Q.P
18. Statement 1: Total number of different functions from a set “A” having 4 elements to the Set
B having 2 elements is 16
Statement2: The number of ways in which ‘m’ different things can be distributed into ‘n’
different parcels, is ‘m’ (blank lots is admissible)
1) Both the statements are true
2) Both the statements are False
3) Statement 1 is True, Statement 2 is False
4) Statement 1 is False, Statement 2 is True
19. If f : R  R is given by f  x   x  1 then the value of
1 5  10   5  n  1  
lim  f  0   f    f    .....  f   is 
n  n
 n  n   n  
1 5 3 7
1) 2) 3) 4)
2 2 2 2
20. Match List-1 with List-II and select the correct answer using the codes given below the lists:
List-I List-II
P)   cos tan 1 y  y sin tan 1 y  I)
   
1/2
1  1 5
 2  y 4
 takes value 2 3
 y  cot  sin y   tan  sin y  
1 1

   
Q) If cos x  cos y  cos z  0  sin x  sin y  sin z then II) 2
x y
possible value of cos is
2
R) If cos III) 1/ 2
   
  x  cos 2 x  sin x sin 2 x sec x  cos x sin 2 x sec x  cos   x  cos 2 x
4  4 
Then possible value of sec x is
S)
 1

1
If cot sin 1  x  sin tan x 6 ,
2
   x  0, then possible IV) 1

value of x is
Codes:
1) P- IV;Q- III;R- I;S- II 2) P- IV;Q- III;R- II;S-I
3) P- III;Q- IV;R- II;S- I 4) P- III;Q- IV;R- I;S- II
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off
to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than
11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
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21.
max
Let f  x   
 | x |, cos x, if x  0 Then number of points where f(x) is continuous, but not
min
  | x |, cos x , if x  0
differentiable is

22. The number of distinct normals that can be drawn from the point (2,8) to the parabola

y 2  6 x is

n
23. The natural “a” for which  f  a  k   16  2
k 1
n
 1 ; when the function ‘f’ satisfies

f  x  y   f  x  . f  y  ; for all natural number x,y and f 1  2 is ____

1
24. Let f :  0,    R be a twice differentiable function, If for some a  0,  f   x  d   af  x  ,
0

1 1
f 1  1 and f 16   , then 16  f '   is equal to
8  16 

25. Consider the data on X taking value 0, 2, 4,8,..., 2n with frequencies n C0 ,n C1,n C2 ,....n Cn

728
respectively. If the mean of this data is then n =
2n

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 SRI CHAITANYA IIT ACADEMY, INDIA 23-03-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-28/23_Q.P
PHYSICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
26. Flux Passing through the shaded surface of a sphere when a point charge q is placed at the
center is (radius of the sphere is R)

1) q /  0 2) q / 2 0 3) q / 4 0 4) zero
27. In a photo–emissive cell, with exciting wavelength  ,the maximum kinetic energy of the
electron is K. If the exciting wavelength is changed to 3  / 4, the kinetic energy of the
fastest emitted electron will be
3K 4K 4K 4K
1) 2) 3) Less than 4) More than
4 3 3 3
28. In the circuit shown in the figure, the ac source gives a voltage V  20cos  2000t  Neglecting
source resistance, the voltmeter and ammeter reading will be

1) 0V , 2 A 2) 2V ,1A 3) 4V , 2 A 4) 4 2V , 2 A
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29. Regarding self-inductance:
A: The self-inductance of the coil depends on its geometry.
B: Self-inductance does not depend on the permeability of the medium.
C: Self-induced e.m.f. opposes any change in the current in a circuit.
D: Self-inductance is electromagnetic analogue of mass in mechanics.
E: Work needs to be done against self-induced e.m.f. in establishing the current.
Choose the correct answer from the options given below:
1) A, B, C, D only 2) A, C, D, E only 3) A, B, C, E only 4) B, C, D, E Only
30. Find the equivalent capacitance across A and B

35 25
1) F 2) F 3) 15 F 4) None of these
6 6
31. A 300 kg crate is dropped vertically onto a conveyor belt that is moving at 1.20 m/s. A
motor maintains the belts’s constant speed. The belt initially slides under the crate with a
coefficient of friction of 0.4. After a short time, the crate is moving at the speed of the belt.
During the period in which the crate is being accelerated, find the work done by the motor


which drives the belt. take g  10m / s 2 

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1) 432 J 2) 216 J 3) 108 J 4) 54 J
32. A uniform circular disc of radius ‘R’ and mass ‘M’ is rotating about an axis perpendicular to
its plane and passing through its centre. A small circular part of radius R/2 is removed from
the original disc as shown in the figure. Find the moment of inertia of the remaining part of
the original disc about the axis as given above.

7 9 17 13
1) MR 2 2) MR 2 3) MR 2 4) MR 2
32 32 32 32
33. A fluid is flowing through a horizontal pipe of varying cross-section, with speed v ms-1 at a
P
point where the pressure is P Pascal. At another point where pressure is Pascal its speed
2

is V ms 1 . If the density of the fluid is ρ kg m-3 and the flow is streamline, then V is equal to:
P 2P P P
1) v 2)  v2 3)  v2 4)  v2
  2 

34. One mole of an ideal monoatomic gas is taken along the path ABCA as shown in the PV
diagram. The maximum temperature attained by the gas along the path BC is given by

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25 P0V0 25 P0V0 25 PV 5 PV
1) 2) 3) 0 0
4) 0 0

8 R 4 R 16 R 8 R
35. Match List-I with List-II
List-I List-II
A) Permeability of free space I)  ML2T 2 
B) Magnetic field II)  M T 2 A 1 
C) Magnetic moment III)  M L T 2 A2 
D) Torsional constant IV)  L2 A 
Choose the correct answer from the options given below:
1) (A)-(I), (B)-(IV), (C)-(II), (D)-(III) 2)(A)-(II), (B)-(I), (C)-(III), (D)-(IV)
3) (A)-(IV), (B)-(III), (C)-(I), (D)-(II) 4)(A)-(III), (B)-(II), (C)-(IV), (D)-(I)
36. A mixture of hydrogen and oxygen has volume 500cm3 , temperature 300K, pressure
400kPa and mass 0.76g. The ratio of masses of oxygen to hydrogen will be
 25 
R  J / mol  k 
 3 
1) 3:8 2) 3:16 3) 16:3 4) 8:3
37. Three particles move in a straight line with initial velocities v1 , v2 and v3  v1  v2  v3  each
with constant retardation ‘a’ such that the motion continues for more than one second
before velocity of each particle becomes zero. If s1, s2 and s3 respectively be the distances
travelled in the last one second before velocity becomes zero, then
1) s1  2s2  3s3 2) s1  s2  s3 3) s1  s2  s3 4) s1  s2  s3
38. A rod of mass m and length l is hinged at one of its ends A as shown in figure. A horizontal
force F is applied at a distance x from A as shown. The linear acceleration of center of mass
‘a’ of rod just after the application of force varies with x as

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1) 2)

3) 4)
39. Given below are two statements:
Statement-I The equivalent emf of two nonideal batteries connected in parallel is smaller
than either of the two emfs.
Statement-II: The equivalent internal resistance of two nonideal batteries connected in
parallel is Smaller than the internal resistance of either of the two batteries.
In the light of the above statements, choose the correct answer from the options given below.
1) Statement-I is true but Statement-II is false
2) Both Statement-I and Statement-II are false
3) Both Statement-I and Statement-II are true
4) Statement-I is false but Statement-II is true
40. A uniform wound solenoidal coil of self-inductance 1.8  104 H and resistance 6  is broken
up into two identical coils. These identical coils are then connected in parallel across a 12 V
battery of negligible resistance. The time constant of the circuit is
5 5 5 5
1) 3  10 s 2) 1.5  10 s 3) 0.75 10 s 4) 6 10 s
41. Two spherical conductors A and B of radii R and 2R respectively, are separated by a large
distance. If some charge is given to both the spheres and later they are connected by a
conducting wire, then in equilibrium condition, the ratio of the magnitudes of the electric
fields at the surfaces of spheres A and B is
1) 1: 4 2) 4 :1 3) 1: 2 4) 2 :1
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42. A cylindrical adiabatic container of total volume 2V0 is divided into two equal parts by a
conducting piston which is free to move as shown in the figure. Each part contains identical
gas at pressure P0. Initially the temperatures of the left and right parts are 4T0 and T0
respectively. An external force is applied on the piston of area A to keep the piston at rest at
initial position. The value of external force required when thermal equilibrium is reached is

8 2 5 6
1) P0 A 2) P0 A 3) P0 A 4) P0 A
5 5 6 5
43. Given below are two statements : one is labelled as Assertion (A) and other is labelled as
Reason (R).
Assertion (A) : Electromagnetic waves carry energy but not momentum.
Reason (R) : Mass of a photon is zero.
In the light of the above statements, choose the most appropriate answer from the options
given below :
1) (A) is true but (R) is false.
2) (A) is false but (R) is true.
3) Both (A) and (R) are true but (R) is not the correct explanation of (A).
4) Both (A) and (R) are true and (R) is the correct explanation of (A)

44. A ball is thrown vertically up in air where the resistive force can be considered to be
constant. If time of ascent is t1and time of descent is t2, then the ratio of speed of projection
to the speed just before it hits the ground is
t2 t 
2
 2t  t2
1) 2)  2  3)  2  4)
t1  t1   t1  2t1

45. Given below are two statements: one is labelled as Assertion A and the other is labelled as
Reason R
Assertion A: A sound wave has higher speed in solids than gases.
Reason R: Gases have higher value of Bulk modulus than solids.
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In the light of the above statements, choose the correct answer from the options given below
1) Both A and R are true and R is the correct explanation of A
2) A is false but R is true
3) Both A and R are true but R is NOT the correct explanation of A
4) A is true but R is false.
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
46. The volume contraction of a solid copper cube of edge length 10 cm, when subjected to a
hydraulic pressure of 7 106 Pa, would be___mm3.
(Given bulk modules of copper= 1.4 1011 Nm2 )
47. A wire density 9 103 kg / m3 is stretched between two clamps 1 m apart and is subjected to an
x
extension of 4.9 104 m . The lowest frequency of transverse vibration in the wire is Hz , the
5

value of x is___ Y  9  1010 N / m 2 

48. Find the ratio between total acceleration of the electron in singly ionized helium atom and
hydrogen atom (both in ground state).
49. A soap bubble of radius r is blown up to form a bubble of radius 2r under isothermal
conditions. If  is the surface tension of soap solution, the energy spent in doing so is
x  4 r 2  . Find the x
50. Three objects A, B and C are kept in a straight line on a friction less horizontal surface.
These have masses m, 2m and m respectively. The object A moves towards B with a speed
9m/s and makes an elastic collision with it. Thereafter B makes completely inelastic
collision with C. All motions occur on the same straight line. Find the final speed
(in m/s) of object C

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CHEMISTRY Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. Column-I Column-II
a) R  X  NaI  R  I  NaX p)Gatterman reaction
 X  Cl , Br 
b) CH3  Br  AgF  CH3  F  AgBr q) swarts reaction

N 2 X  Cl

Cu2Cl2
 N2

c) r) sandmeyer reaction
N 2 X  Cl

Cu CuX
HCl
d) s) finkelstein reaction
1) a  s, b  q, c  r , d  p 2) a  p, b  q, c  r , d  s
3) a  q , b  s, c  r , d  p 4) a  r , b  q, c  s, d  p

O
Ba  OH  2
2CH 3  C  CH 3  A 

H O
 B,2
52. then A&B are respectively.
CH 3 O

A : CH 3 C CH 2  C  CH 3 CH 3 O

OH
B : CH 3 C  CH  C  CH 3
1)

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CH 3 O CH 3 O
A : CH 3 C CH  C  CH 3 B : CH 3 C  CH  C  CH3
OH
2) H

CH 3 CH 3 O
O

A : CH 3 C CH  C  CH 3 B : CH 3 C CH 2  C CH 3

3) OH

CH 3 CH 3 O
O

C CH  C  CH 3 B : CH 3 C CH  C CH 3
A : CH 3

H OH
4)
53. Which of the following is the correct one letter code for Amino acid Tryptophan?
1) D 2) Q 3) Y 4) W
54. Which of the following is the correct structure for Uracil?

1) 2)

3) 4)
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55. Given below are two statements:
Statement (I): The boiling points of alcohols and phenols increase with increases in the
number of C-atoms.
Statement (II): The boiling points of alcohols and phenols are higher in comparison to other
class of compounds such as ethers, haloalkanes.
In the light of the above statements, choose the correct answer from the options given below:
1) Statement-I is correct, Statement-II is incorrect.
2) Statement-I is incorrect, Statement-II is also incorrect.
3) Statement-I is correct, Statement-II is also correct.
4) Statement-I is incorrect, Statement-II is correct
56. Assertion (A):
NH 2 NH 2 NH 2 NH 2

NO2
HNO3 , H 2 SO4
288K  

NO2

NO2
 47%   2% 
 51% 
Reason (R):In presence of strongly acidic medium aniline is protonated to form the
anilinium ion which is meta directing. That is why besides the ortho and para derivatives,
significant amount of meta derivative is also formed.
In the light of the above statements, choose the correct answer from the options given below
1) Both A and R are true and R is the correct explanation of A
2) A is false but R is true
3) Both A and R are true but R is NOT the correct explanation of A
4) A is true but R is false.
Aquaregia KNO2
Compound (B) yellow ppt
(A) CH 3COOH
57.
Then Compound A is?
1) NiS 2) ZnS 3) CoS 4) MnS
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58. If the bidentate ligand, ethane-1,2-diamine (en) is progressively added to aqueous solution of
nickel(II) chloride in the molar ratio en: Ni, 1:1, 2:l,3:l the following reactions occur.
2 2
 Ni  H 2O 6   en aq    Ni  H 2O  4  en    2 H 2O
 aq   aq 
(A) (B)
2 2
 Ni  H 2O 4  en    en aq    Ni  H 2O  2  en 2   2 H 2O
 aq   aq 
(C)
2 2
 Ni  H 2O  2  en  2 
  Ni  en 3 
  aq   en( aq )   
 aq 
 2 H 2O
(D)
The colour of complexes A,B,C & D respectively are ?
1) Pale blue, green, , blue, violet 2) blue, violet, green, pale blue
3) Violet, green, pale blue, blue 4) green, pale blue, blue, violet
59. Which of the following represents incorrect electronic configuration?
1) Th3   Rn 5 f 1 2) Ce3   Xe 4 f 1 3) Gd 3   Xe 4 f 7 4) Eu 3   Xe 4 f 7
60. Statement-I: Duma’s method is used for estimation of nitrogen
Statement-II: In Duma’s method ‘N’ present in organic compound is converted to  NH 4 2 SO4
1) Statement-I is correct, Statement-II is incorrect.
2) Statement-I is incorrect, Statement-II is also incorrect.
3) Statement-I is correct, Statement-II is also correct.
4) Statement-I is incorrect, Statement-II is correct.
61. Arrange the following in ascending order of energy
E1  Infra red rays
E2  Micro waves
E3  U.V rays
E4  Cosmic rays
1) E1  E2  E3  E4 2) E2  E1  E3  E4
3) E3  E1  E2  E4 4) E1  E2  E3  E4
62. Only 3ml of KMnO4 solution of unknown molarity is required to reach the end point of a
titration of 20 ml of ferrous oxalate (0.1M) in acidic medium. The Molarity of KMnO4
solution should be__M.
1) 0.2 M 2) 0.3 M 3) 0.4 M 4) 0.5 M
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½
63. Assertion (A): For a strong electrolyte, a plot of molar conductivity against (concentration)
is a straight line, with a negative slope, the correct unit for the slope is S cm2 mol 3/2 L1/2
Reason (R): Debye-Huckel Onsagar equation is m  m  b C
0

In the light of the above statements, choose the correct answer from the options given below
1) Both A and R are true and R is the correct explanation of A
2) A is false but R is true
3) Both A and R are true but R is NOT the correct explanation of A
4) A is true but R is false.
64. If the Pka of Lactic acid is 5, then the pH of 0.005 M calcium lactate solution at 25 0C is
___  10 1 (nearest integer).
H

CH 3  C  COOH

Lactic acid :
OH
1) 75 2) 65 3) 85 4) 95
65. The total pressure observed by mixing two liquids A and B is 350 mm Hg when their mole
fractions are 0.7 and 0.3 respectively. The total pressure becomes 410 mm Hg if the mole
fractions are changed to 0.2 and 0.8 respectively for A and B. The vapour pressure of pure A
is ___mm Hg. (nearest integer)
Consider the liquids and solutions behave ideally.
1) 300 2) 320 3) 314 4) 434
66. One mole of an ideal monatomic gas is subject to changes as shown in the graph. The
magnitude of the work done (by the system or on the system ) is___J
(neatest integer) (Given:log2=0.3, ln 10 = 2.3,1bar.lit=100J)

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1) 600 2) 620 3) 640 4) 660

67. What is(are) the number of unpaired electron(s) in the highest occupied molecular orbital of
the following species: N 2 ; N 2 ; O2 ; O2  ?
1) 0,1, 2,1 2) 2,1, 2,1 3) 0,1, 0,1 4) 2,1,0,1
68. Consider the following pairs of electrons
1
 a  n  3, l  1, ml  1, ms  
A) 2
1
 b  n  3, l  2, ml  1, ms  
2
1
 a  n  3, l  2, ml  2, ms  
B) 2
1
 b  n  3, l  2, ml  1, ms  
2
1
 a  n  4, l  2, ml  2, ms  
C) 2
1
 b  n  3, l  2, ml  2, ms  
2
the pairs of electron present in degenerate orbitals is/are:
1) Only A 2) Only B 3) Only C 4) (B) and (C)
69. CaCO3 s   CaO s   CO2 g  , H  180 KJ . If entropies of CaCO3 , CaO & CO2 respectively
are 93,39 and 213 J/mol/K, then Stotal  inJ / K  at 300 K is :
1) -441 2) +441 3) +882 4) +220.5

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70. Which of the following graph is incorrect?
B B
Al Al
m.pt B.pt
Ga

Tl In
In
Ga
Tl

1) At.no(z) 2) At.no(z)
B N

E.N Tl E.N As
In Sb
Ga
Bi
Al

3) At.no(z) 4) At.no(z)
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
71. At 298k,a 1 liter solution containing 10 milli moles of Cr2O72 and 100milli moles Cr 3
2.303 RT
shows a pH of 3.0 given Cr2O7  Cr ; E  1.330V and  0.059V . The potential for
2 3 0

F
the half cell reaction is a 103V . The value of a is?

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72. Consider the following reaction
MnO2  KOH  O2  A  H 2O.
Product ‘A’ in neutral or acidic medium disproportionate to give products ‘B’ and ‘C’ along
with water. The sum of spin-only magnetic moment values of B and C is __BM. (nearest
integer )
(Given atomic number of Mn is 25)
73. Consider the following transformation involving first order elementary reaction in each step
step 1
Step 2

at constant temperature as shown below. A  B  C  P
step 3
Some details of the above reaction are listed below
Step Rate constant Activation energy
(sec-1) (kJ mol-1)
1 k1 400
2 k2 300
3 k3 Ea3
k1k2
If the overall rate constant of the above transformation (k) is given as k  and the overall
k3
activation energy  Ea  is 500 kJ mol 1 , then the value of Ea3 is ___kJ Mol—1 (nearest integer)
74. The rate constant of a reaction at 270 C is 3 103 min 1 . The fraction of molecules crossing the
energy barrier of the reaction at that temp is 103%. If temp is increased, the maximum.
Value of rate const ‘k’(in min-1) can be attained is?
75.
O

R  C  NH 2  xBr2  y NaOH  R  NH 2  zNa2CO3  wNaBr  nH 2O

then x  y  ?

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