PEARSON CORRELATION - SUNFLOWER Santalla2003
PEARSON CORRELATION - SUNFLOWER Santalla2003
High oleic sunflower seeds evaluated at 5.6% moisture content (dry basis) showed a surface area of
approximately 102.41 mm2 with an average length, width, thickness and unit mass of 11.526, 5.008 and
2.809 mm and 0.055 g, respectively. Corresponding values for the kernel were 8.802, 3.897 and 1.907 mm
and 0.036 g. The mean equivalent diameter and sphericity of the seeds were 5.49 mm and 0.46, respectively,
while corresponding values for the kernels were 4.01 mm and 0.44. True density increased, within a
moisture range of 4–26% d.b., between 652 and 708 kg/m3 for the seed, between 1015 and 1057 kg/m3 for
the kernel and between 636 and 760 kg/m3 for the hull. The bulk density decreased from 386 to 373 kg/m3
for seeds and from 260 to 220 kg/m3 for hulls and increased from 535 to 553 kg/m3 for the kernels. Porosity
increased from 41.2 to 47.1% in seeds, from 47.2 to 47.7% in kernels and from 59.2 to 70.1% in hull.
Terminal velocity of seeds increased with moisture content between 2.8 and 5.5 m/s for seed, between 1.8
and 3.8 m/s for kernel and between 1.1 and 1.9 m/s for hull. Drag coefficient decreased when moisture
content increased and varied between 4.7 and 1.4 in seed and between 12.5 and 3.1 in kernel. Angle of
repose increased with moisture content between 25 and 46 in seeds, between 35 and 55 in kernels
and between 49 and 66 in hull on different surfaces and resulted higher for hull and kernel than for seed.
The coefficient of static friction was higher for kernel than that for seed and hull and also was higher
on wood (with grain perpendicular to the direction of the motion) and lower on acrylic and galvanised
iron. This coefficient increased with moisture content from 0.23 to 0.50 for seed, from 0.37 to 0.69
for kernel and from 0.31 to 0.60 for hull. All engineering properties evaluated showed a linear dependence
with moisture content, leading to simple and accurate formulae, adequate to predict their variation in the
range of moisture considered.
435
436 E.M. SANTALLA AND R.H. MASCHERONI
Samples
Trisum 568 (Mycoyen-Morgan), a striated high oleic 0.5 kg were randomly taken from the bulk sample. From
genotype of sunflower (Helianthus annuus L.) was each of three 0.5 kg sub-samples, 200 seeds were picked
selected to carry out this study. Ten bulk samples, out and the 600 seeds thus obtained were mixed
each consisting of 5 kg of seed, were procured from thoroughly. Finally, 100 seeds were randomly selected
1998/99 harvest season from Oriente, Coronel Dorrego, and labelled for easy identification (Dutta et al., 1988,
Argentina, after 80 days of physiological maturity stage. Joshi et al., 1993). For each individual seed and its
The seeds were manually cleaned for foreign matter, kernel, three principal dimensions (Gupta and Das,
broken and immature seeds. The initial moisture content 1997), namely length, width and thickness were
of the seeds was about 13% d.b. Whole kernels and hull measured using a micrometer (least count 0.01 mm).
were both obtained from manual dehulling of the seeds. Because of the irregular shape of the sunflower seed
Seeds, kernels and hulls were packed separately and kernel, only the greatest values of both, width
in double-layered low-density polyethylene bags sealed and thickness were taken (Figure 1). Each seed and
and stored at low temperature (5 C). For each test, kernel were weighed on a precision electronic balance
the required amount of seed and kernel was taken out reading to 0.001 g. The equivalent diameter (De) and
and allowed to warm up for approximately 2 h (Joshi sphericity () for both seed and kernel were determined
et al., 1993). To evaluate the effect of moisture content using the following expressions according to Mohsenin
of the sample on some of its physical properties, samples (1978):
of seeds, kernels and hulls at the desired moisture
levels were prepared by adding calculated amounts
of distilled water and sealing in separate polyethylene De ¼ ðLWTÞ1=3 ð1Þ
bags. The samples were kept at low temperature in ¼ ðLWTÞ1=3 =L ð2Þ
a refrigerator to avoid the growth of microorganisms.
Before starting a test, the required quantity of the
sample was taken out of the refrigerator and was where L, W and T are length, width and thickness
allowed to warm up to room temperature (Shepherd and respectively.
Bhardwaj, 1986). Seeds were classified into three categories, namely,
large, medium and small, using ASTM sorting sieves.
Methods This classification simplifies the operation conditions
(storage, drying, dehulling). The distribution of seeds
The physical properties of the seeds were determined
by number as well as by mass for each category of size
at the following moisture contents: 4.2, 8.6, 14.3, 21.1
was determined. Relationships between seed and kernel
and 26.4% d.b. in seeds; 5.0, 8.1, 13.2, 19.3 and 23.8%
dimensions were also established using regression
d.b. in kernels and 7.5, 14.4, 18.2 and 23.2% d.b. in
analysis.
hulls. Moisture content was determined by oven drying
High oleic sunflower seeds tend to have the shape
method (ASAE Standard, 1999).
of a cone-elliptical cylinder with a major axis signifi-
Spatial Dimensions, Size, Sphericity, Surface Area cantly greater than the intermediate axis. The seeds
may therefore be described as being oval in shape.
In order to determine the size and shape of the seed The surface area (S ) was determined according to two
and its components, three sub-samples, each weighing different empirical relationships developed in terms of
Physical Properties of Sunflower Seeds 437
Table 1. Some physical and chemical characteristics of sunflower seed according to previous works.
1000 Seed Oil Content Hull/Kernel Oleic/Linoleic
Sunflower Seeds Weight (g) (% d.b.) Ratio Ratio
Trisum 568 (HO) (Gely and Santalla, 2000) 50–52 43–45 0.53–0.55 8.2
Trisum 80 (Fernández San Juan, 1993) – – – 7.5
Others HO (Fernández San Juan, 1993) – – – 7.0–8.8
CF9 Argentinian genotype (Gely and Santalla, 2000) 42–48 49–51 0.32–0.34 0.25–0.29
Worldwide collection 27–71 41–56 0.20–0.43 0.60
(Fernández Martı́nez and Domı́nguez Giménez, 1985)
Traditional (Salunkhe et al., 1992) – 38–54 0.10–0.60 0.20–0.70
Table 2. Size distribution of seeds and kernels at 5.6 % moisture content (d.b.).
Size Category
Table 3. Correlation of seed and kernel dimensions to their length than to their thickness, but also the mass
at 5.6 moisture content (d.b.). of seed and kernel are correlated to their length. The
higher correlation coefficients for the relations L/l, W/w,
Degrees of Correlation
T/t and W/w also indicated that, in general, greater
Ratios Value Freedom Coefficient
seeds give greater kernels when dehulled and that kernel
L/W 2.26 98 0.453* size is directly proportional to seed size.
L/T 4.18 98 0.226**
L/M 209.44 98 0.427*
The highest correlation between linear dimensions
l/w 2.25 98 0.298* and moisture content was found for the mass (R2 ¼ 0.85)
l/t 4.66 98 0.194 followed by the thickness (R2 ¼ 0.42) and the width
l/m 247.10 98 0.392* (R2 ¼ 0.32) of the seed (Table 4). It can also be seen
L/l 1.32 98 0.482* that grains expand relatively more along their thickness
W/w 1.31 98 0.592*
T/t 1.48 98 0.672*
than along the main axes. Other correlations were not
M/m 1.55 98 0.857* significant.
W/M 92.68 98 0.798* The mean equivalent diameter for high oleic sun-
T/M 50.59 98 0.765* flower seed in the range of 4.22–26.44% moisture
w/m 110.05 98 0.565* content (d.b.) was 5.34 mm ( 0.07) and for kernel it
t/m 53.06 98 0.764*
was 3.88 mm ( 0.12) (Table 4). Sphericity of high oleic
*Significant at 1% level. **Significant at 5% level. sunflower varied between 0.449 and 0.479 for seed and
between 0.434 and 0.464 for kernel with the maximum
standard deviation for seed and kernel of 0.030 and
The coefficients of correlation obtained for the ratio 0.035, respectively.
between the main dimensions and mass (Table 3) Surface area increased with moisture content between
showed that length of seed is mostly related to width 101.85 and 105.14 mm2 (according to Equation (3)) and
(less in kernel) than to thickness but the mass is more 104.24 and 107.28 mm2 (according to Equation (4))
related with thickness and width than with length. for seed and between 55.22 and 58.26 mm2 (according to
Higher values for correlation coefficients showed that Equation (3)) and 56.92 and 59.77 mm2 (according to
width of seed and kernel were more strongly correlated Equation (4)) for kernel.
Physical Properties of Sunflower Seeds 439
Table 4. Size, mass and morphology of high oleic sunflower seeds and kernels (Trisum 568) at different moisture
contents (n ¼ 100).
Moisture Mass Length Width Thickness Equivalent
(% d.b.) (kg) (mm) (mm) (mm) Diameter (mm) Sphericity
Seed 4.22 0.049 11.623 4.926 2.489 5.224 0.449
8.60 0.056 11.207 5.095 2.716 5.373 0.479
14.33 0.057 11.386 4.998 2.676 5.340 0.469
21.13 0.058 11.465 5.049 2.677 5.371 0.468
26.44 0.063 11.412 5.079 2.717 5.400 0.473
R2 0.85 0.01 0.32 0.42 0.59 0.444
Kernel 5.04 0.031 8.567 3.737 1.717 3.802 0.456
8.14 0.034 8.717 4.001 1.895 4.044 0.464
13.19 0.035 8.511 3.818 1.801 3.883 0.464
19.30 0.032 8.578 3.596 1.669 3.720 0.434
23.75 0.035 8.768 3.777 1.845 3.938 0.449
R2 0.12 0.14 0.16 0.00 0.01 0.11
One Thousand Seed Weight The variations with moisture content were repre-
sented by the following correlations:
In the range of 4.22–26.44% moisture (d.b.) the
thousand grains mass increased from 49 to 63 g in seed s ¼ 651.1 þ 2.14 Mc (R2 ¼ 0.871)
and from 31 to 37 g in kernel. A close linear relationship k ¼ 1012.4 þ 2.04 Mc (R2 ¼ 0.849)
was found between this property and the moisture
content in seed (1000 grain mass ¼ 47.3 þ 0.59 Mc R2 ¼ h ¼ 572.2 þ 7.90 Mc (R2 ¼ 0.989)
0.979) but no relationship was found for the kernel. These fittings showed that for the three components
of high oleic sunflower genotype, their densities are
Gravimetric Properties linearly related with the moisture content. Similar trends
were obtained for seeds of traditional oilseed type
Bulk Density sunflower (Gupta and Das, 1997), pumpkin (Joshi et al.,
1993) and safflower (Gupta and Prakash, 1992).
The bulk densities of seed, kernel and hull were deter-
It was also observed that the bulk density of hull
mined in the range of moisture content of 4–26% d.b.,
was much lower than that of seed and kernel but the
5–24% d.b. and 7–24% d.b., respectively. The bulk
true density of hull of high oleic hybrid was close to the
density of seeds (374–386 kg/m3) resulted lower than
seed value (636–760 kg/m3) for the moisture range
that of kernels (535–552 kg/m3) and higher than that
evaluated.
of hulls (220–260 kg/m3) at the same moisture level
and varied with moisture content as indicated by the
following expressions: Porosity
bs ¼ 387.4 0.53Mc (R2 ¼ 0.799) The porosities of seed, kernel and hull were found
2 to vary between 41.0 and 47.0%, 47.2 and 47.7% and
bk ¼ 533.7 þ 0.85Mc (R ¼ 0.899)
59.0 and 70.0%, respectively. This physical property
bh ¼ 275.34 2.36Mc (R2 ¼ 0.786) increased linearly with the increase of moisture content
according to the following expressions:
These results were in agreement with those obtained
for traditional sunflower. Besides, for the same level of "s ¼ 40.62 þ 0.25Mc (R2 ¼ 0.975)
moisture content, bulk density of high oleic sunflower
was lower than those for corn (Nelson, 1980) and "k ¼ 47.30 þ 0.022Mc (R2 ¼ 0.585)
safflower (Gupta and Prakash, 1992) and higher than "h ¼ 53.88 þ 0.74Mc (R2 ¼ 0.939)
for pumpkinseed (Joshi et al., 1993).
The highest variation with moisture content was
observed for hull. These results showed lower variation
True Density with moisture content than those of traditional sun-
flower (Gupta and Das, 1997). Similar trends were
The true densities of the seed, kernel and hull were reported for traditional sunflower (Gupta and Das,
determined in the same range of moisture content than 1997) and gram (Dutta et al., 1988) however this
bulk density and were found to vary between 652 tendency was opposed to the results reported for
and 708 kg/m3, 1015 and 1057 kg/m3 and 636 and safflower (Gupta and Prakash, 1992) and pumpkin
760 kg/m3 respectively. seed (Joshi et al., 1993).
440 E.M. SANTALLA AND R.H. MASCHERONI
Joshi D.C., Das S.K. and Mukherjee R.K. (1993). Physical Oje K. and Ugbor E.C. (1991). Some physical properties of
properties of pumpkinseeds. Journal of Agricultural oilbean seed. Journal of Agricultural Engineering
Engineering Research 54(3): 219–229. Research 50: 305–313.
Kachru R.P., Gupta R.K. and Alam A. (1994). Physico- Salunkhe D.K., Chavan J.K., Adsule R.N. and
chemical Constituents & Engineering Properties. Jodhpur, Kadam S.S. (1992). World Oilseeds, Chemistry,
India: Scientific Publishers. Technology and Utilization. New York, NY: Van
Mc Cabe W.L., Smith J.C. and Harriott P. (1991). Nostrand Reinhold.
Unit Operations of Chemical Engineering. Madrid: Sheperd H. and Bhardwaj R.K. (1986). Moisture
Mc Graw-Hill, Inc. dependent physical properties of pigeon pea. Journal of
Mohsenin N.N. (1978). Physical Properties of Plant and Agricultural Engineering Research 35(4): 259–268.
Animal Materials. New York: Gordon and Breach Thompson R.A. and Isaac G.W. (1967). Porosity determi-
Science Publishers. nation of grains and seeds with air comparison pycn-
Nelson S.O. (1980). Moisture dependent kernel and bulk ometer. Transactions of the American Society of
density relationships for wheat and corn. Transactions of Agricultural Engineers 10: 693–696.
the American Society of Agricultural Engineers 23(1):
139–143.