CHAPTER TEST

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A. Multiple Choice
1. Which row is correct to describe a reversible or irreversible reaction?
Description
A Reversible reaction is a reaction that cannot be reversed
B Corrosion is an example of reversible reaction
C Irreversible reaction is a reaction where the reactants cannot be reproduced
D Every reversible reaction is an equilibrium reaction

2. Haber Process is an exothermic process where ammonium gas is produced by reacting

nitrogen gas with hydrogen gas as shown below.
N2(g) + 3H2(g) ⇌ 2NH3(g)
According to the Le Chatelier’s Principle, which of this following sentence is true if the
temperature of this reaction is changed?
A. Equilibrium will shift to left when temperature is increased
B. Equilibrium will shift to right when temperature is decreased
C. Equilibrium will not be affected by temperature change
D. Equilibrium will shift to the side with fewer gas molecules when temperature is
increased
3. Calcium carbonate can be decomposed to form calcium oxide and carbon dioxide gas as
stated below.
CaCO3(s) ⇌ CaO(s) + CO2(g)
Which of this following choice is correct about the equilibrium expression of this
reaction?
A [ Ca CO 3 ][CaO] 1 D [ CO 2 ]
B. C. [ CO 2 ]
. [ CO 2 ] [ CO 2 ] . [ Ca CO 3 ][CaO]
4. When 0,20 mol of hydrogen gas and 0,15 mol of iodine gas are heated at 723K until
equilibrium is established, the equilibrium mixture contains 0,26 mol of hydrogen iodine.
The equation for the reaction is as follows.
H2 (g) + I2 (g) ⇌2HI (g)
What is the correct expression for the equilibrium constant Kc?
A 2 x 0,26 ( 2 x 0,26 )
2 2
( 0,26 )
2
( 0,26 )
B. C. D.
. 0,20 x 0,15 0,20 x 0,15 0,07 x 0,02 0,13 x 0,13

5. Lithium reacts with nitrogen at room temperature to form solid Li3N.

Three vessels of equal volume are connected by taps 1 and 2 as shown.

At the start, taps 1 and 2 are closed, the left-hand vessel is evacuated, the middle vessel
has the indicated reaction at equilibrium and the right-hand vessel contains lithium only.
Which action would allow the equilibrium mixture to contain the most ammonia?
A. Keep both taps 1 and 2 closed
B. Open both taps 1 and 2
C. Open tap 1 only
D. Open tap 2 only
6. What is the acid-base nature and structure of SO2?
Acid-base nature Structure
A Acidic Giant covalent lattice
B Acidic Simple molecular
C Basic Giant covalent lattice
D Basic Simple molecular

7. V and W are two compounds. Each one contains a different Group 2 element.
A sample of each solid is added to water, shaken, and the pH of the resulting solution is
measured.
Compound V W
pH 13,6 9,4
 Which row could identify V and W?
V W
A BaSO4 MgSO4
B MgSO4 BaSO4
C Ba(OH)4 Mg(OH)2
D Mg(OH)2 Ba(OH)4

8. Three statements about ammonia molecules and ammonium ions are given.
1. In aqueous solution, ammonia molecules from coordinate bonds with hydroxide ions
2. Ammonium ions are Brønsted-Lowry acids
3. The H-N-H bond angle is large in the ammonium ion than in the ammonia molecule
Which statements are correct?
A. 1 and 2 only
B. 1 and 3 only
C. 2 and 3 only
D. 1, 2, and 3
9. Why does the rate of a gaseous reaction increase when the pressure is increased at a
constant temperature?
A. More particles have energy that exceeds the activation energy
B. The particles have more space in which to move
C. The particles move faster
D. There are more frequent collisions between particles.
10. Gaseous hydrogen and gaseous iodine react to form gaseous hydrogen iodide.
H2 (g) + I2 (g) ⇌2HI (g)
In an experiment, 2.0 mol of hydrogen and 2.0 mol of iodine are placed in a sealed
container of volume 1.0 dm3.
The Kc value for this reaction under the condition used is 9.0.
How many moles of hydrogen iodide are present at equilibrium?
A. 0,57 mol
B. 1,2 mol
C. 1,5 mol
D. 2,4 mol
B. Structured Questions
1. This questions is about the following reactions:
CH3COOH (l) + C2H5OH (l) ⇌CH3COOC2H5 (l) + H2O (l)
Ethanoic acid ethanol ethyl ethanoate water
9,2 gram of ethanol are mixed with 12 g of ethanoic acid in an inert solvent. The total
volume of solution is 250 cm3. The mixture is left to equilibrate for several days. At
equilibrium 65% of the reactants are converted to products.
a. Calculate the concentration of each reactant at the start [4]
b. Calculate the concentration of each reactant at equilibrium [4]
c. Calculate the concentration of each product at equilibrium [4]
d. i. write the equilibrium expression for this reaction [2]
ii. calculate the value of Kc for the reaction [2]
iii. explain why there are no units for Kc for this reaction [2]
e. Deduce what will happen to the numerical value of Kc if 100 cm 3 of water
is added to the equilibrium mixture [2]
f. Deduce what will happen to the yield of ethyl ethanoate if 100 cm3 of water
is added to the equilibrium mixture. Explain your answer [4]
[Total: 24]
2. Ethanol can be manufactured by reacting ethane, C2H4, with steam.
C2H4 (g) + H2O (g) ⇌ C2H5OH (g)
a. c. Write the equilibrium expression in term of partial pressure, K p, for this
reaction [2]
d. f. State the units of Kp for this reaction [2]

g. i. The reaction is at equilibrium at 290℃ and 7.00 x 10 6 Pa pressure. Under

these conditions the partial pressure of ethene is 1,50 x 10 6 Pa and the
partial pressure of steam is 4,20 x 106 Pa.
i. iii. Calculate the partial pressure of ethanol [2]

iv. vi. Calculate the value of the equilibrium constant, K p, under these
conditions. [2]
j. l. The reaction is carried out in a closed system. Explain the meaning of the
term closed system [2]
m. o. The result in the table below show the effect of temperature on
 percentage of ethane converted to ethanol at constant pressure use this
information to deduce the sign of the enthalpy change for this reaction.
Explain your answer
Temperature/ % of ethene converted
℃
260 40
290 38 [8]
320 36
[Total: 18]
3. a. Sketch the graph of pH that would be obtained when 10 cm 3 of 0,2 mol
dm-3 HCl titrated against 0,2 mol dm-3 aqueous ammonia [6]
b. Explain why methyl orange is suitable indicator for this titration but
phenolphthalein is not [4]
c. Sketch the graph that would be obtained if 25 cm 3 of 0,2 mol dm-3 sodium
hydroxide is titrated against 0,1 mol dm-3 ethanoic acid solution [6]
d. Explain why phenolphthalein is suitable indicator for this titration but
methyl orange is not [4]
e. Bromocresol green and bromothymol blue are indicators. Bromocresol
green has a pH range of 3,8 to 5,4 and bromothymol blue has a pH range
6 to 7,6. Would either of these indicators be suitable for the titration in
part a or the titration in part c? explain your answer. [8]
[Total: 28]
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