SR.

IIT_*CO-SC(MODEL-A& APEX Date:31-03-25

Time: 3HRS GTM-13(PHASE-III)-FN Max. Marks: 300

PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. If the first minima in a Young’s double slit experiment occurs directly in front of one of the
slits. (distance between slit & screen D  12 cm and distance between slits d  5 cm ) then
the wave length of the radiation used is:
1) 1 cm 2) 4 cm 3) 2 cm 4) ½ cm
2. When a metallic surface is illuminated with monochromatic light of wavelength  , the
stopping potential is 5 V0 . When the same surface is illuminated with light of wavelength 3,
the stopping potential is V0 . Then the work function of the metallic surface is:
hc hc hc 2hc
1) 2) 3) 4)
6 5 4 4
3. A beam of fast moving electrons coming from an electron gun is diffracted through a narrow
aperture. The angular width of the central maxima would increase if
1) Accelerating voltage in the gun is decreased 2) Aperture width is increased
3)Accelerating voltage is increased 4) None of these
5
4. The cross section ABC of an optical media of refractive index   is as shown in figure.
3
The curved surface is given by y  x 2. A ray of light travelling parallel to x-axis is incident
normally on face AB. The minimum distance of the incident ray from point A to get refracted
from surface AC is:

Page 1 of 16
 1) 1 cm 2) 2/9 cm 3) 4/9 cm 4) 2/3 cm
5. There are three concentric thin spheres of radius a, b, c  a  b  c  . The total surface charge

densities on their surface are , ,  respectively. The magnitude of electric field at r
(distance from center) such that a  r  b is:

1) 0 2)
0 r 2b2  c 2 
 
3)
0 r 2a 2  b2  4)
0 r 2a 2  b2 
6. The observe ‘O’ sees the distance AB as infinitely large. If refractive index of liquid is 1 and

1
that of glass is 2, then is:
2

1) 2 2) 1/2 3) 4 4) None of these

GM
7. If the particle shown is the figure is projected with orbital speed v0  , it returns after
2R
time T. If it is projected such that time period of revolution is 8T then what is maximum
distance of the particle from the center of the earth?

1) 7R 2) 3R 3) 14 R 4) 15 R

8.  & pk
Two short dipoles pk  are located at  0,0,0  & 1m,0,2m respectively. The
2
resultant electric field due to the two dipoles at the point (1 m 0, 0) is:
9p  7 p  7p 
1) k 2) k 3) k 4) None of these
32 0 32 0 32 0
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9. The maximum current in a galvanometer can be 10 mA. It’s resistance is 10 . To convert it
into an ammeter of 1 Amp. a resistor should be connected in
1) series, 0.1 2) parallel, 0.1 3) series, 100  4) parallel, 100 
10. An electron is at rest in a region having uniform and constant magnetic field. The magnitude
of the magnetic field is suddenly doubled keeping its direction same. After the sudden change,
the magnetic field is again uniform and constant. After the magnetic field becomes double,
(Neglect the effect of gravity)
1) The electron continues remains at rest
2) The electron starts to move along a straight line.
3) The electron moves along a circular path.
4) The electron moves along a helical path.
11. In a series R-L-C circuit, the frequency of the source is half of the resonance frequency. The
nature of the circuit will be:
1) capacitive 2) inductive 3) purely resistive 4) None of these
12. An object is kept on the principal axis of a diverging mirror of focal length 90 cm at a distance
of 90 cm from the pole. The object starts moving with velocity 2 cm/s towards the mirror at
x
angle 30 with the principal axis. If speed of the image (in cm/s) is then y-x is equal to
y
1) 3 2) 6 3) 9 4) 12
13. A toroid of mean radius ‘a’, cross section radius ‘r’ and total number of turns N. It carries a
current ‘i’. The torque experienced by the toroid if a uniform magnetic field of strength B is
applied:
1) BNia 2) Bir2 3) BNir 2 4) Zero
14. A wire of fixed length is wound in such a way that it forms a solenoid of length '  ' and radius
'r'. Its self inductance is found to be L. Now if same wire is wound in such a way that if forms
 r
a solenoid of length and radius , Find the self inductance now?
2 2
L
1) L 2) 3) 2L 4) 4L
2
15. Time (T), velocity (C) and angular momentum (h) are chosen as fundamental quantities instead
of mass, length and time. In terms of these, the dimensions of mass would be

1) M   T 1C2 h 2) M   T 1C2 h

3) M   T 1C 2 h1  4) M   TC2 h 

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16. Moment of inertia of an equilateral triangular lamina ABC, about the axis passing through its
center O and perpendicular to its plane is I0 as shown in the figure. A cavity DEF is cut out
from the lamina, where D, E, F are the mid points of the sides. Moment of inertia of the
remaining part of lamina about the same axis is:

7 15 3 31
1) I0 2) I0 3) I0 4) I0
8 16 4 32
17. The machine as shown has 2 rods of length 1m connected by a pivot at the top. The end of
one rod is connected to the floor by a stationary pivot and the end of the other rod has a roller
that rolls along the floor in a slot. As the roller goes back and forth, a 2kg weight moves up
and down. If the roller is moving towards right at a constant speed, the weight moves up with
a

1) constant speed 2) increasing speed

3
3) speed which is th of that of the roller when the weight is 0.4m above the ground
4
4) decreasing speed

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18.

The above is a plot of binding energy per nucleon Eb , against the nuclear mass M;
A,B,C,D,E,F correspond to different nuclei. Consider four reactions
i) A  B  C   ii) C  A  B   iii) D  E  F   iv) F  D  E  
Where  is the energy released? In which reactions it is negative?
1)  i  and  iii  2)  ii  and  iv  3)  ii  and  iii  4)  i  and  iv 

19. An ideal gas goes through a reversible

cycle a  b  c  d  a has the V - T diagram shown below. Process
d  a and b  c are adiabatic.

The corresponding P - V diagram for the process is (all figures are schematic and not drawn
to scale):

1) 2) 3) 4)

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20. Suppose the drift velocity  d in a material varied with the applied electric field E as  d  E
; Then V - I graph for a wire made of such a material is best given by

1) 2)

3) 4)

SECTION - II
(NUMERICAL VALUE ANSWER TYPE)
 This section contains 5 questions. The answer to each question is a Numerical Value. If the Answer in the
decimals, Mark nearest integer only.
 Question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

21. In an experiment a sphere of aluminium of mass 0.20 kg is heated up to 150  C .

Immediately, it is put into water of volume 150 cc at 27  C kept in a calorimeter of water

equivalent to 0.025 kg. Final temperature of the system is 40  C . The specific heat of
aluminium is (in J/kg -C ): (take 4.2 Joule=1 calorie)
22. Two wires W1 and W2 have the same radius r and their respective densities are 1 and 2

such that 2  41 . They are joined together at the point O, as shown in the figure. The
combination is used as a sonometer wire and kept under tension T. The point O is midway
between the two bridges. When a stationary wave is set up in the composite wire, the joint is
found to be a node. The ratio of the number of antinodes formed in W2 to W1 is

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23. A 9 V battery with internal resistance of 0.5 Ω is connected across an infinite network as shown
in the figure. All ammeters A1, A 2 , A 3 and voltmeter V are
ideal. Find the reading of ammeter A2 ?( in Amp)

24. An inductor  L  0.03H and a resistor  R  0.15  are connected in series to a battery

of emf 15V in a circuit shown below. The key K1 has been kept closed for a long time. Then
at t  0 , K1 is opened and key K 2 is closed simultaneously. At t  1ms, the current (in A )


in the circuit will be e5  150 

25. In an ideal gas at temperature T, the average force that a molecule applies on
the walls of a closed container depends on T as Tq . A good estimate for q is:

CHEMISTRY MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

26. Which of the following statement is incorrect?

1) The almost identical radii of Zr and Hr is consequence of lanthanide contraction
2) Eu 2 act as a strong reducing agent
3) An alloy of lanthanoid metal called misch metal is used in making bullets
4) Sm3 is colorless in aqueous solution

Page 7 of 16
27 Which of the following arrangement represent the increasing order (smallest to largest) of
ionic radii of the given species O 2 , S 2 , N 3 , P 3 .

1) O2  N 3  S 2  P3 2) O2  P3  N 3  S 3

3) N 3  O 2  P 3  S 2 4) N 3  S 2   O2  P3

28. Diborane reacts independently with O2 and H 2O to produce respectively

1) H 3 BO3 and B2O3 2) B2O3 and H 3 B O3

3) HB O2 and H 3 B O3 4) B2O3 and  BH 4 

29.
Column-I (complex Column-II (m in B.M)

I) Cr  OX 3 
3
P) 2.82

II)  Ni  H 2O 6 
2
Q) Zero

III)  Fe  CN 6 
4
R) 3.87

IV)  Mn  CN 6 
4
S) 1.73

The correct option related to spin only magnetic moment is

1) I  P; II  Q; III  R; IV  S 2) I  Q; II  P; III  R; IV  S
3) I  R; II  P; III  Q; IV  S 4) I  S ; II  P; III  Q; IV  R
30. For the non-stoichiometric reaction 2 A  B  C  D, the following kinetic data were obtained in
three experiments, all at 298 K

Initial Initial Initial rate of

Concentration (A) Concentration (B) Formation of C
 mol . L1 . S 1 
0.1M 0.1M 1.2  103

0.1M 0.2M 1.2  103

0.2M 0.1M 2.4 103

2
1) rate  k  A B 2) rate =  k  A B 

3) rate =  k  A B  4) rate =  k  A

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31. At which of the following conditions a reaction is spontaneous at all temperatures?
1) H   ve; S   ve 2) H   ve; S   ve
3) H  ve; S   ve 4) H   ve; S  ve
32. The values of E 0 of some reactions are given
I 2  2e   2 I  E0  0.54volts

Sn 4  2e   Sn 2 E0  0.152volts

Cl2  2e   2Cl  E0  1.36volts

Fe 3  e   Fe 2  E0  0.76volts

Ce 4  e   Ce3 E0  1.6volts

Which of the following is incorrect

1) Fe3 oxidizes Ce 3 2) Ce 4  can oxidize Fe 2 
3) Sn 2  will reduce Fe3 to Fe 2  4) I 2 will be liberated from KI by passing Cl 2
KMnO SOCl H lPd
33. Cumene 
 CO2  A 
4
 B  2
BaSO
 C the product ‘C’ in above sequence is :
2
4

1) 2) 3) 4)

34.

1) 2)

3) 4) Formation of A and B is not possible

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35. Sucrose on hydrolysis produces the products X and Y. The X and Y can be distinguished by:
1) Molisch test 2) Barfoed test
3) Tollens test 4) Seliwanoff’s test
36. The rate of solvolysis of I-IV follows:

I) II) III) IV)

1) I  II  III  IV 2) III  I  II  IV
3) III  II  I  IV 4) IV  I  II  III

37.

1) 2)

3) 4) None

38. The major product of the following reaction is :

t
(1) BoOK

( 2) Conc . H 2 SO4 / 


1) 2)

3) 4)

Page 10 of 16
39.  C  D is 100. If the initial
The equilibrium constant at 298 K for a reaction A  B 
concentration of all the four species were 1 M each, then equilibrium concentration of D (in
mol L1 ) will be
1) 0.182 2) 0.818 3) 1.818 4) 1.182
40. Which one among the following pairs of ions cannot be separated by H 2 S in dilute
hydrochloric acid
1) Bi 3 , Sn4 2) Al 3 , Hg 2 3) Zn2 , Cu 2 4) Ni 2 , Cu 2
41. One mole of an ideal gas is allowed to expanded reversibly and adiabatically from a
temperature of 27 0 C. If the work done during the process is 3 kJ, then final temperature of
the gas is  Cv  20 J / K 

1) 100 K 2) 150 K 3) 195 K 4) 255 K

42. The K sp of Mg  OH 2 is 11012 , 0.01M Mg  OH 2  will precipitate at the limiting pH:

1) 3 2) 9 3) 5 4) 8
43. The IUPAC name of the following compounds is

1) 5,6 – diethyl-3-methyldec-4-ene 2) 5,6 diethyl-8-methyldec-6-ene

3) 5,6 – diethyl-8-methyldec-6-ene 4) 5,6 – diethyl-3-methyl-4-ene
44. Propene, CH 3  CH  CH 2 can be converted to 1- propanol by oxidation. Which set of reagent
among the following is ideal to effect the conversion?
1) Alkaline KMnO4 2) B2 H 6 and alkaline H 2O2
3) O3 / Zn dust 4) cis only

45. The isomer (s) of Co  NH 3 4 Cl2  that has/have a CI  Co  CI angle of 900 , is / are:

1) meridional and trans 2) cis and trans

3) trans only 4) cis only

Page 11 of 16
 SECTION - II
(NUMERICAL VALUE ANSWER TYPE)
 This section contains 5 questions. The answer to each question is a Numerical Value. If the Answer in the
decimals, Mark nearest integer only.
 Question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

46. The lattice energy of solid KCl is 181 kcal mol 1 and the enthalpy of solution of KCl in H 2O is 1.0

kcal mol 1. If the hydration enthalpies of K  and Cl  ions are in the ratio of 2:1 then the enthalpy of
hydration of K  is -20x K cal mol 1. Find the value of x
47. The work function   of some metals is listed below. The number of metals which will show

photoelectric effect when of 300nm wavelength falls on the metal is? Metal
Li Na K Mg Cu Ag Fe Pt W

  eV  2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75

48. Among the following the total number of compound soluble in aqueous NaOH is

49. The Vapour pressure of a Pure liquid ‘A’ is 70 torr. 27 0 C . If forms an ideal solution with another
liquid B. The mole fraction of B is 0.2 and pressure of the solution is 84 torr at 27 0 C . The vapour
pressure of pure liquid B at 27 0 C in torr is
50. The percentage of carbon in the major product (P) of the following reactions is :
(Round off to nearest integer)

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MATHS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

 1   1   1 
51. The vertices of a triangle are  ab,  ,  bc,  and  ca ,  where a, b, c are the roots of the
 ab   bc   ca 

equation x 3  3 x 2  6 x  1  0 . The coordinates of its centroid are

1) 1, 2  2)  2, 1 3) 1, 1 4)  2,3

52. If z  2 and locus of 5z  1 is the circle having radius a and z12  z22  2 z1 z2 cos   0, then

z1 : z2 is equal to

1) a :1 2) 2a :1 3) a :10 4) a : 5
2 2 2
53. Let the minimum value v0 of v  z  z  3  z  6i , z  C is attained at z  z0 . Then
3 2

 
2 z02  z0  3  v02 is equal to

1) 1000 2) 1024 3) 1105 4) 1196

n

  x  dx n
54. If f  x   0
n
, then f  x  is equal to (where  and  denotes GIF and fraction parts of
n 1
  x dx
0

x) n  N
n2  n n  n  1
1) n 2  1 2) 3) 4) n 2  1
2 2
55. If S  {a  R : 2a  1  3 a   2{a}}, (where [.] denotes the G.I.F and {t} represents the

fractional part of t) then 4 a is equal to ….

aS

1) 2 2) 1 3) 3 4) 5
x2 y 2
56. The foci of a hyperbola coincide with the foci of the ellipse   1, then the equation of
49 24
5
hyperbola with eccentricity is:
2

x2 y 2 x2 y2
1)  1 2)  1 3) 2 x 2  23 y 2  1 4) x 2  y 2  1
2 23 23 2
Page 13 of 16
57. In a random experiment, a fair coin is tossed. If Head is obtained, then an unbiased die is
thrown 2 times and sum of number is recorded. If Tail is obtained, then 2 Tokens are drawn,
from a box that contains tokens numbered as 1,2,3,………, 10, with replacement, and sum of
the number is recorded. If it is known that sum recorded is prime than the probability that the
head was obtained, is :
125 126 121 121
1) 2) 3) 4)
236 235 236 235
58. log 3x .log 33 x .log 93 x  1, then smallest natural value of x will be:

1) 2 2) 3 3) 4 4) 1
59. Variance of first 11 terms of an Arithmetic Progression, with common difference -5 is:
1) 150 2) 350 3) 250 4) 450
2 100
60. Coefficient of x 99 in x100  2 x99 1  x   3 x98 1  x   ..........  1011  x  will be
101
1) C99 101 C98 2) 100 101C99 101 C98

3) 101101 C99 101 C98 4) 101101 C98 101 C99

61. Consider a tetrahedron ABCD with AB  12, CD  6. The shortest distance between the skew

lines AB and CD is 8 and the angle between them is . If the volume of tetrahedron is v, then
6
v
is
12
1) 5 2) 8 3) 4 4) 2
62. Let A,B,C,D be non-singular real matrices such that
AT  BCD, BT  CDA, C T  DAB & DT  ABC for the matrix M  ABCD , then find M 2018

1) M 2) M 2 3) M 3 4) M 1

63. If lim
x 
 
x 2  x  2  ax  b  2 , then equation of circle whose center is  a,2b  and radius 1 units

is
1) x2  y 2  2 x  6 y  9  0 2) x2  y 2  2 x  6 y  1  0

3) x2  y 2  2 x  6 y  9  0 4) x 2  y 2  4
64. Consider the parabola x2  4 x  2 y  6  0 . If its chord AB 2 mx  2 y   4 m  3  0 intersect its axis at
K and directrix at M. Then AM, KM and BM are in
1) A. P 2) G. P 3) HP 4) AGP

Page 14 of 16
 z1  z2
65. The relation R on the set of complex numbers, defined by z1 Rz2 if and only if is real, is
z1  z2

1) reflexive but not symmetric 2) reflexive but not transitive

3) symmetric but not transitive 4) an equivalence relation
min  x  6  , x 2   4  x  0

66. Let f : [-4,2]  R be given as f  x    If the area bounded by
2

max x , x 0  x  2 
y  f  x  and x- axis is A then the value of 3A is equal to?
1) 19 2) 35 3) 37 4) 32
67. Three distinct numbers are chosen one by one without replacement from set {1,2,3, ……..9).
If it is known that sum of first two chosen numbers is even, then the probability that sum of
all three numbers is even is
15 11 13 17
1) 2) 3) 4)
28 28 28 28
89
1 cot 90k 2
68. If    , then k is given by
n1 sin   n  1 k  sin nk sin k 3

1) n   ; n  I 2) 2n 

;n  I 3) n   ; n  I 4) 2n 

;n I
3 3 6 6

   3  5  7 
69. 1  cos 1  cos 1  cos 1  cos  is equal to
 8  8  8  8 

1  1 1 2
1) 2) cos 3) 4)
2 8 8 2 2

70. A rectangular sheet of fixed perimeter with sides having their length in the ratio 8:15 is
converted into an open rectangular box by folding after removing squares of equal area from
all four corners. If the total area of removed squares is 100, the resulting box has maximum
volume. The lengths of the sides of the rectangular sheet are
1) 24 2) 32 3) 45 4) 60
SECTION - II
(NUMERICAL VALUE ANSWER TYPE)
 This section contains 5 questions. The answer to each question is a Numerical Value. If the Answer in the
decimals, Mark nearest integer only.
 Question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

71. Numbers of 6 digit numbers (Formed without using zero & without repetition) such that first
3 places of the numbers are in increasing order and last 3 places are in decreasing order will
be

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 dy y3
72. The curve f  x, y   0 passing through  0, 2 satisfy the differential equation  x . If the line
dx e  y 2

x  ln 5 intersects it at points y  and y   , then the value of  2   2   is

73. Consider f  x 
x 2
 1 x 2  9 
, x  R  {a, b}, where g  x  is a polynomial of degree  4. f  x  has a
g  x

removable type of discontinuity at xa and x  b .The following three information are also
known (i) lim f  x   
x 
(ii) lim f  x   4
x 1
(iii) lim f  x   a
x 3
non-zero finite

number let L and M denotes the number of points of discontinuity and the number of points
of non- differentiability of y  f(x) respectively in R (the set of all real numbers). Then the

value of (L+M) is
   
74. Let x , y and z be unit vectors such that x  y  z  p, x  ( y  z )  q and ( x  y )  z  r . If p  7, q. y  5

and p is perpendicular to x , then the number of positive integral solutions of the equation
4
x1 x2 x3   x.y   y.z   z.x  is

 2k  1 2 k 2 k  0 2k  1 k 
   
75. Let k be a positive real number and let A 2 k 1 2k  and B  1  2k 0 2 k
   
 2 k 2k 1    k 2 k 0 

If det (adj A)+ det (adj B)= 106 , then k  is equal to ……..

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