ANSWER KEY

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
A. 1 2 3 1 1 2 1 3 1 2 4 2 1 4 4 3 4 3 4 4 2 1 3 3 1 4 2 1 2 2
Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A. 1 4 2 3 4 3 1 2 4 1 2 2 1 2 2 3 3 2 1 1 4 3 2 2 1 2 4 2 1 2
Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90

A. 4 1 1 2 2 1 4 2 3 4 3 4 2 1 3 3 3 2 1 4 2 3 1 2 3 3 4 3 1 4
Q. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120

A. 1 2 3 4 2 1 4 2 4 3 4 1 3 3 3 3 1 4 3 4 2 4 3 4 3 4 1 3 3 4
Q. 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150

A. 3 1 4 3 3 3 1 2 2 1 3 3 2 3 3 2 4 4 1 2 3 3 2 3 1 2 1 4 2 4
Q. 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180

A. 4 4 3 1 3 4 3 1 2 2 2 3 4 2 3 3 2 4 3 4 1 1 3 1 3 3 4 1 4 1

HINT – SHEET

1. Ans ( 1 ) 3. Ans ( 3 )
When electron beam of 12.75 eV is incident over H-gaseous. h
λ=
Energy of H-atoms will be √
2mqV

= –13.6 + 12.75 = –0.85 eV,

4. Ans ( 1 )
248 nm = (1240/248) eV = 5 eV
Which corresponds to n = 4 excited state
310 nm = (1240/310) eV = 4 eV
K. E1 4 5eV − W
= =
K. E2 1 4eV − W
⇒ 16 – 4W = 5 – W ⇒ 11 = 3W
11
⇒ W= = 3.67 eV ≅ 3.7 eV
Clearly, emitted radiation lies in lyman series (A, B and C) 3

few emissions are is Balmer series (D and E). One of them 5. Ans ( 1 )
E 1 × 106 × 1.6 × 10−19
(n=4 to n=3) lies in paschen series (F). P= =
C 3 × 108
2. Ans ( 2 ) = 0.53 × 10 – 21 kg ms – 1
BE = [(3 MH + 4 Mn) – MLi] × 931 MeV 7. Ans ( 1 )
Be = [(3 × 1.007825 + 4 × 1.008665) 100 200
= ⇒ Req = 20Ω
Req 40
– 7.016005] × 931 MeV
R × 100
= 39.2 MeV Req = = 20Ω ⇒ R = 25 Ω
100 + R
8. Ans ( 3 ) 13. Ans ( 1 )
Here, P = 100 W, V = 230 V For eye piece
Let R be resistance of the filament of the bulb.
2 ue = ?
Now, electric power, P = V i = V
R ve = – 25
V2 (230)2
Therefore, R = = 100 = 529 Ω fe = 6.25
P
When the voltage drops to 115 V, heat and light 1 1 1
energy produced by the bulb in 20 min is given by using − =
v u f
V2 (115)2
W = V it = t= × 20 × 60= 30000 J then, ue = – 5 cm
R 529
9. Ans ( 1 ) v0 = L – |ue| = 10 cm
t = 0, L → open CKT For objective
E 2
I0 = = f0 = 2 cm
R + 20 10 + 20
1 u0 = ?
= A
15 1 1 1
t = ∞ , L→ conductor [short circuit] Using − =
v u f
E 2 1
I∞ = = = A
20 20 10 u0 = – 2.5 cm
10. Ans ( 2 ) 14. Ans ( 4 )
1 1 1
W= 2
CV22 − CV12 = C(900 − 225)
2 2 fw (a μg − 1)
=
C= 2 W fa (W μg − 1)
675 f (1.5 − 1)
Now in 2nd case ⇒ w = ⇒ fw = 32 cm
1 2 2 1 fa (
1.5×3
− 1 )
C [(60) − (30) ] = C [3600 − 900]
15. Ans ( 4 )
4
2 2
1 2
= . W [2700] = 4W
f
2 675
11. Ans ( 4 ) −5 =
f−u
RS −60
G= −5 = ⇒ u = −72 cm
R−S −60 − u
(4900) (98)
4900 − 98
= 100Ω 16. Ans ( 3 )
Full scale current KQx KQ√8R √ 8 KQ
E 5 E= = =
Ig = = = 1mA (R2 + x2 )3/2 (9R2 )3/2 27 R2
R+G 4900 + 100
F.O.M. 2√2KQ
=
current
=
1mA
= 50μA/div
=
Deflection (or Division) 20 27R2

12. Ans ( 2 ) 17. Ans ( 4 )

d
dapp. = ac W = – q (VF – VI)
μ
3 3
dapp. = 2 + = 4.0cm ⇒ μ =
μ 2 Where VF = 0
kq
VI = 8 × √
3
(
2
a)
16 kq
=
√ 3a
18. Ans ( 3 ) 22. Ans ( 1 )
1
Intensity, I = εvEp2
2
1 1 c
v= = =
√με √ (4μ0 )(ε0 ) 2
1 c 1 3 × 108
I= ε0 ( ) Ep2 = × 8.8 × 10−12 × ( ) (50)2
2 2 2 2
I = 1.65 W/m 2

Path of proton will be helix

mν sin 30∘
23. Ans ( 3 )
r= nenh = n2i
qB 1
1.67 × 10−27 × 2 × 106 ×
1 where ne = × 5 × 1022 × 106 m−3
2 106
r= ni = 1.5 × 1016 m – 3
1.6 × 10−19 × 0.104
r = 0.1 m 24. Ans ( 3 )
2π × 1.67 × 10−27
T = 2πm =
qB 1.6 × 10−19 × 0.104
– 7
T = 2 π × 10 sec.
19. Ans ( 4 )
(e) τ is zero. [ ∵ Angle between plane of loop and ¯¯¯¯¯¯¯¯¯¯
direction of magnetic field is 90°] stable equilibrium. Y = (A + B). (A. B)
¯ + B)
= (A + B) . (A ¯
(f) τ is zero. yet equilibrium is not stable.
Resultant force is zero in each case. Y = A. B¯ + A.
¯ B (XOR)
20. Ans ( 4 ) 25. Ans ( 1 )
Force on SR and PQ are equal but opposite so their net T = μ v2 = 1.3 × 10 – 4 × (30)2 ≃ 0.12
force will be zero. Force between two parallel conductors
carrying currents I1 and I2.
26. Ans ( 4 )
μ
F = 0 I1 I2 ℓ
2π r
where, r = distance between two parallel conductors
10−7 × 2 × 20 × 20 × 15 × 10−2 1
FPS = −2
= 6 × 10−4 N f∝
2 × 10 ℓ
10−7 × 2 × 20 × 20 × 15 × 10−2 f+4 31
FQR = = 1 × 10–4 f−4
=
30
12 × 10−2
N ⇒ 30f + 120 = 31f – 124
∴ Fnet = FPS – FQR f = 244 Hz
= 6 × 10–4 – 1 × 10–4 = 5 × 10–4 N. 27. Ans ( 2 )
21. Ans ( 2 ) [E] = [M]x [L]y [F]z = [M]x [L]y [T – 1]z
P = VrmIrm cos θ [M1L2T – 2] = [Mx] [Ly] [T – z]
1500 = 250 × 10 cos θ x = 1, y = 2, z = 2
15 3 4 ⇒x+y+z=5
∴ cos θ = = ⇒ sin θ =
25 5
∴ Iwattless = I sin θ
5
28. Ans ( 1 )
4
In addition and subtraction, see minimum decimal
= 10 × =8A point.
5
29. Ans ( 2 ) 35. Ans ( 4 )
mg = Kx0 94 − 86 94 + 86
=K ( − 20) ....(i)
m x0 0.2 2 2
= =
K g 10 71 − 69 71 + 69
=K ( − 20) ....(ii)
m 0.2 2 t 2
T = 2π√ = 2π√ = 2√
K 10 10 Dividing (i) by (ii), we get
2 7
{T = sec} t= min = 42 sec
√5 10
30. Ans ( 2 ) 36. Ans ( 3 )
u+v Q
S=( )t Q = W + ΔU [W = ]
2 4
Q
200 = ( 20 +2 80 ) t Q =
4
+ ΔU (C = Molar specific heat)

t = 4sec 3Q 3 3
ΔU = ⇒ µCv Δ T = µC Δ T ⇒ Cv = C
4 4 4
31. Ans ( 1 ) 4 4 f
C = Cv = ( R) [For diatomic gas, f = 5]
3 3 2
4 5 10
C = × R = R
3 2 3
37. Ans ( 1 )
mgℓ
W=
Vy = – gt ⇒ Vy = – 100 2n2
Vx = 500 5
n=
Vy 2
100 1 2mgℓ
tan θ = = ⇒ θ = tan−1 W=
Vx 500 5
25
32. Ans ( 4 ) 38. Ans ( 2 )
(Vrms )O2 = (Vrms )H2
ℓ ϕ = R. θ
T O2 T H2
= (1)(0.8)
MW O2 MW H2 ϕ= = 0.004rad
20 × 32 200
T O2 =
2 39. Ans ( 4 )
TO2 = 320K NCERT-XI, Pg. # 263
TO2 = 47°C

33. Ans ( 2 )
At 0°C reading of scale is 25 cm.
At 20°C, the reading is correct, means the rod
length < 25 cm on actual scale (at 20 °C).
It means resultant shape of meniscus is convex
angle of contact is obtuse liquid will not wet glass
2T cos θ 2T (−ve)
h= = = −ve
Rρg Rρg
means liquid will descend in capillary.

34. Ans ( 3 )
In conical pendulum, about vertical axis net torque
is zero and hence angular momentum remains
served.
40. Ans ( 1 ) 43. Ans ( 1 )

Before collision
by COLM, m (u) + 0 = m(v) + m(2v)
⇒ u = 3v .......(1)
→v2 − →v1
∣ ∣ 2v − v v v
e=∣ ∣ ⇒e= = =
∣ →u1 − →u2 ∣ u−0 u 3v
1
⇒e=
3
44. Ans ( 2 )
By equilibrium of mass m, T'=mg ...(i)
By equilibrium of mass 2m, T=2mg+T'...(ii)
From (i) and (ii), T=2mg+mg=3mg ...(iii)
When the string is cut :
For mass m :
By τ net = 0
Fnet = mam ⇒ mg = mam ⇒ am = g (down wards) 10g (33) = mg (5)
For mass 2m : m = 66 gm

Fnet = 2ma2m ⇒ T – 2mg = 2m a2m

45. Ans ( 2 )
m π
g ρ= = 3
⇒ 3mg – 2mg=2ma2m ⇒ a2m = (up wards) V 4
2 × 3 π(0.5)
2
41. Ans ( 2 ) 3
= ×
8 0.125
1
= 3gm/cc
M 3M
GM 2 ′ G 2 . 2 r2 (ρ − σ)
F=
GM. M
= ,F = 2
Now η = 2 g [ VT = ]
S
d2 d2 d 9 VT t
( )
2 (0.25) (3 − 1.2) (980) (5)
3GM =2 = 9.8 poise
F′ = = 3F 9 50
d2
Gravitational force does not depend on medium
46. Ans ( 3 )
Fact.
42. Ans ( 2 ) 48. Ans ( 2 )
Crossing with critical speed at top most point.

isopropyl acetate → common name

50. Ans ( 1 )

when string is horizontal,

(v')2 = v2 + 2(g) (R) ⇒ (v')2 = gR + 2gR = 3gR

(v′ )2 3gR
ac = = = 3g
R R
51. Ans ( 4 ) 84. Ans ( 2 )
Carbonyl group can be reduce to alkane by HI/P, n2
Zn – Hg|HCl or NH2 – NH2|OH ϴ |ethylene glycol. 2 π rn = n λ ⇒ 2 π × 0.53 = nλ
z
52. Ans ( 3 ) λ = 2 π × 0.53 ×
n
z
1 z2
Heat of hydrogenation ∝ Esep = 3.4 = 13.6
stability n2
56. Ans ( 2 ) ⇒
n
z
=2
Fact λ = 2 π × 0.53 × 2 = 6.66 Å
60. Ans ( 2 ) 88. Ans ( 3 )
xBrO−3 + yCr+3 + zH2 O → Br2 + HCrO−4 + H +
+ 5 3 0 6 +

3 Br O−3 + 5Cr+3 → Br2 + 5H Cr O−4

61. Ans ( 4 ) − +3
2
3
PCl5 is reactive molecule because P – Cl(axial) is [3BrO + 5Cr
3 → Br2 + 5HCrO−4 ] × 2
2
weaker than P – Cl(equatorial). 22H2 O + 6BrO−3 + 10Cr+3 → 3Br2 + 10HCrO−4 + 34H +
66. Ans ( 1 ) ↓ ↓ ↓
Basic+2Radicals Group Number z x y
B. Cu II x = 6, y = 10, z = 22
A. Al +3 III
D. Co +2 IV 90. Ans ( 4 )
C. Ba+2 V W = – 10(5.2 – 4.2) = – 10 atm L = – 1013 J
E. Mg+2
Ans. (1) B, A, D, C, E
VI 91. Ans ( 1 )
New NCERT Page #75
68. Ans ( 2 ) 92. Ans ( 2 )
MnF4 is stable but MnF7 is non-existing. NCERT Page #72
93. Ans ( 3 )
+ 7
→ 'O' form multiple bond so Mn with oxygen is
possible eq. Mn2O7, MnO4 – NCERT 73, 74 Figure 6.3(a)
71. Ans ( 3 ) Note : Sunflower root is tetrach.
Monodentate ligands do not show chelation. 94. Ans ( 4 )
73. Ans ( 2 ) NCERT 11th Page #160
Fe4[Fe(CN)6]3 95. Ans ( 2 )
Prussian blue only one type of ligand is present. NCERT 11th Page #159
77. Ans ( 3 ) 97. Ans ( 4 )
NCERT 11th Page #118
(ROD)A (ROD)B
ROR =
3
=
2
= (ROA)C 98. Ans ( 2 )
78. Ans ( 2 ) NCERT XI Page #32

Specific conductance ( κ ) =
1
×
ℓ 99. Ans ( 4 )
R A NCERT XI Page # 27, 28
= 0.02
50 × 0.0004
= 1 Sm−1 100. Ans ( 3 )
82. Ans ( 3 ) NCERT XI Page #33

YA =
XA PAo 101. Ans ( 4 )
XA PAo + XB PBo NCERT XI Page #5,7,9
=
1
XB PBo
=
1
2 2
=
1
5
= 0.2 102. Ans ( 1 )
1+ 1+ 1
× 1 NCERT XI Page #14,16,18,21
XA PAo
103. Ans ( 3 ) 121. Ans ( 3 )
NCERT XII Page #195, 196(E) NCERT 11th Page #142,145,148,150
NCERT XII Page #213, 214(H)
122. Ans ( 1 )
104. Ans ( 3 ) NCERT Page # 18
NCERT XII Page #197-202 (E)
NCERT XII Page #216-220 (H) 123. Ans ( 4 )
105. Ans ( 3 ) NCERT Page #22
NCERT XII Page #199, 200 (E) 124. Ans ( 3 )
NCERT XII Page #218, 219 (H) NCERT Pg. # 9,20
106. Ans ( 3 ) 125. Ans ( 3 )
NCERT Page #56
NCERT XII Page # 192, 195, 196 (E)
NCERT XII Page # 210, 211, 214 (H) 126. Ans ( 3 )
107. Ans ( 1 ) NCERT Page #61
127. Ans ( 1 )
NCERT 12th Page #96, 97, 98 (E)
NCERT Page #57
NCERT 12th Page #89, 90, 91 (H)
108. Ans ( 4 ) 128. Ans ( 2 )
NCERT Page #62
NCERT Page# 90
109. Ans ( 3 ) 129. Ans ( 2 )
NCERT Page #157
NCERT 12th Page #98,99 (E)
110. Ans ( 4 ) 130. Ans ( 1 )
NCERT Page #205
NCERT 12th Page #100, 101 (E)
111. Ans ( 2 ) 131. Ans ( 3 )
NCERT Page #209
NCERT 12th Page #97, 72 (E)
NCERT 12th Page #79, 80,107 (H) 132. Ans (3)
NCERT Page #205
112. Ans ( 4 ) 133. Ans ( 2 )
NCERT 12th Page #94, 95 (E)
NCERT Page #217
113. Ans ( 3 ) 134. Ans ( 3 )
NCERT 12th Page #83, 98, 106 (E)
NCERT Page #217
114. Ans ( 4 ) 135. Ans ( 3 )
NCERT XI Page #170 NCERT Page #217
115. Ans ( 3 ) 136. Ans ( 2 )
NCERT XI Page #176, 173
NCERT Pg. # 236
116. Ans ( 4 ) 137. Ans ( 4 )
NCERT XI Page #63-65
NCERT Pg. # 232,233
117. Ans ( 1 ) 138. Ans ( 4 )
Old NCERT XI Page #79
NCERT Pg. # 34
118. Ans ( 3 ) 139. Ans ( 1 )
From new families
NCERT, Pg. # 38
119. Ans ( 3 ) 140. Ans ( 2 )
NCERT 11th Page #135 NCERT, Pg. # 44
120. Ans ( 4 ) 141. Ans ( 3 )
NCERT 11th Page #146 NCERT, Pg. # 44
142. Ans ( 3 ) 162. Ans ( 3 )
NCERT, Pg. # 112 NCERT, Pg. # 95
143. Ans ( 2 ) 163. Ans ( 4 )
NCERT, Pg. # 113 Old NCERT, Pg. # 101
144. Ans ( 3 ) 164. Ans ( 2 )
NCERT, Pg. # (E)-245, (H)-245 Old NCERT, Pg. # 101
145. Ans ( 1 ) 165. Ans ( 3 )
NCERT, Pg. # (E)-246, (H)-246 Old NCERT, Pg. # 112
146. Ans ( 2 ) 166. Ans ( 3 )
NCERT, Pg. # (E)-243, (H)-243 NCERT Pg. # 187
147. Ans ( 1 ) 167. Ans ( 2 )
NCERT, Pg. # (E)-205, (H)-206 NCERT Pg. # 189
148. Ans ( 4 ) 168. Ans ( 4 )
NCERT, Pg. # (E)-209, (H)-209 NCERT Pg. # 38, 39
149. Ans ( 2 ) 169. Ans ( 3 )
NCERT, Pg. # 225 (New) NCERT Pg. # 47
150. Ans ( 4 ) 170. Ans ( 4 )
NCERT, Pg. # 144
NCERT Pg. # 50
151. Ans ( 4 )
NCERT, Pg. # 148,151,144 171. Ans ( 1 )
152. Ans ( 4 ) NCERT Pg. # 201
NCERT-XII, Pg. # 135,136,137,138 172. Ans ( 1 )
153. Ans ( 3 ) NCERT Pg. # 196
NCERT-XII, Pg. # 136
154. Ans ( 1 ) 173. Ans ( 3 )
NCERT-XII, Pg. # 130,131 NCERT 12th Page #165
155. Ans ( 3 ) 174. Ans ( 1 )
NCERT-XII, Pg. # 146 NCERT 12th Page no #171
156. Ans ( 4 ) 175. Ans ( 3 )
NCERT, Pg. # 88 NCERT 12th Page # 165,166
157. Ans ( 3 ) 176. Ans ( 3 )
NCERT, Pg. # (E)-94, (H)-95 NCERT 12th Page #168
158. Ans ( 1 ) 177. Ans ( 4 )
NCERT, Pg. # 95
NCERT 12th Page #170
159. Ans ( 2 ) 178. Ans ( 1 )
NCERT, Pg. # 101 NCERT 12th Page #180
160. Ans ( 2 ) 179. Ans ( 4 )
NCERT, Pg. # 129 NCERT 12th Page #182
161. Ans ( 2 ) 180. Ans ( 1 )
NCERT 12th Page # 179, 180, 181, 182, 168
NCERT, Pg. # 120,121,122,124